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1. 发明授权

US4745176A Catalytic process for preparing polycumylene from .alpha.-cumyl halide 失效
标题翻译：从α-枯基卤化物制备聚亚甲基的催化方法
公开(公告)号：US4745176A
公开(公告)日：1988-05-17
申请号：US678167
申请日：1984-12-04
申请人： Robert Becker , Ludwig Bottenbruch , Johann Grolig , Helmut Waldmann
发明人： Robert Becker , Ludwig Bottenbruch , Johann Grolig , Helmut Waldmann
IPC分类号： C08G61/00 , C08G61/02
CPC分类号： C08G61/02
摘要： Polycumylene of a relatively high degree of polymerization is obtained in a reasonable space-time yield by Friedel-Crafts alkylation of .alpha.-cumyl halide when catalyst composition, catalyst concentration and dilution ratio are selected within certain limits.
摘要翻译：当催化剂组成，催化剂浓度和稀释比选择在一定限度内时，通过Friedel-Crafts烷基化反应，以合适的时空产率获得较高聚合度的聚亚甲基。

2. 发明授权

US4593116A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4593116A
公开(公告)日：1986-06-03
申请号：US620207
申请日：1984-06-13
申请人： Gunter Stammann , Johann Grolig , Robert Becker , Helmut Waldmann
发明人： Gunter Stammann , Johann Grolig , Robert Becker , Helmut Waldmann
IPC分类号： C07B61/00 , B01J31/00 , B01J31/28 , C07C67/00 , C07C239/00 , C07C269/00 , C07C125/065 , C07C125/067 , C07C125/073 , C07C125/075
CPC分类号： C07C269/00
摘要： Urethanes are made by reacting an organic nitro compound with an organic compound containing at least one hydroxyl group in the presence of carbon monoxide, hydrogen and a catalyst system. The carbon monoxide and hydrogen are used in quantities such that the molar ratio of CO to H.sub.2 is from 0.3:1 to 3:1. The catalyst system is made up of at least one noble metal or compound of a noble metal from Group VIIIB of the Periodic System of Elements, at least one organic nitrogen base and a co-catalyst combination of iron or copper oxidic or hydroxidic compound and a chloride compound. The product urethanes are useful in the production of isocyanates and pesticides.
摘要翻译：聚氨酯是通过在一氧化碳，氢气和催化剂体系的存在下使有机硝基化合物与含有至少一个羟基的有机化合物反应来制备的。一氧化碳和氢气的使用量使得CO与H 2的摩尔比为0.3:1至3:1。该催化剂体系由至少一种元素周期表第VIIIB族的贵金属或贵金属的化合物，至少一种有机氮碱和铁或铜氧化物或氢氧化物的助催化剂组合和氯化物。产品氨基甲酸酯可用于生产异氰酸酯和农药。

3. 发明授权

US4582923A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4582923A
公开(公告)日：1986-04-15
申请号：US735249
申请日：1985-05-17
申请人： Gunter Stammann , Robert Becker , Johann Grolig , Helmut Waldmann
发明人： Gunter Stammann , Robert Becker , Johann Grolig , Helmut Waldmann
IPC分类号： C07B61/00 , B01J31/00 , B01J31/26 , B01J31/28 , B01J31/32 , C07C269/04 , C07C271/06 , C07C271/20 , C07C271/26 , C07C271/38 , C07C125/067 , C07C125/065 , C07C125/073 , C07C125/075
CPC分类号： C07C271/06
摘要： Urethanes are made by reacting a primary amine with carbon monoxide and a compound containing at least one hydroxyl group in the presence of an oxidizing agent and a catalyst system. The catalyst system is made up of (i) a noble metal and/or a noble metal compound of a metal of the Eighth Secondary Group of the Periodic System of Elements and (ii) an oxidizing quinoid and/or a compound capable of being converted to an oxidizing quinoid compound under the reaction conditions. The catalyst system may optionally include (iii) metal compounds of elements of the Third to Fifth Main Groups and/or First to Eighth Secondary Groups of the Periodic System of Elements and/or (iv) a tertiary amine. This reaction is generally carried out at a temperature of from 100.degree. to 300.degree. C. and at a pressure of from 5 to 500 bars. The product urethanes are useful in the production of isocyanates and pesticides.
摘要翻译：聚氨酯通过在氧化剂和催化剂体系的存在下使伯胺与一氧化碳和含有至少一个羟基的化合物反应来制备。催化剂体系由（i）贵金属和/或贵金属化合物的元素周期表第八族中的金属和/或氧化醌类和/或能够转化的化合物组成在反应条件下与氧化喹啉化合物反应。催化剂体系可以任选地包括（iii）元素周期表系统的第三至第五主族和/或第一至第八中间的元素的金属化合物和/或（ⅳ）叔胺。该反应通常在100〜300℃的温度和5〜500巴的压力下进行。产品氨基甲酸酯可用于生产异氰酸酯和农药。

4. 发明授权

US4370275A Process for the preparation of carbonic acid esters 失效
标题翻译：制备碳酸酯的方法
公开(公告)号：US4370275A
公开(公告)日：1983-01-25
申请号：US250363
申请日：1981-04-02
申请人： Gunter Stammann , Robert Becker , Johann Grolig , Helmut Waldmann
发明人： Gunter Stammann , Robert Becker , Johann Grolig , Helmut Waldmann
IPC分类号： C07C69/96 , B01J27/00 , B01J31/00 , B01J31/18 , C07C68/00
CPC分类号： B01J31/181 , B01J31/1805 , C07C68/005 , B01J2531/16
摘要： The invention relates to a process for the preparation of carbonic acid esters with high selectivity and under reaction conditions which permit high space/time yields, said process being one in which an alcohol is allowed to react with a mixture of molecular oxygen and carbon monoxide in the liquid phase in the presence of a catalyst system containing copper, chemically bonded oxygen, chemically bonded halogen and at least one nitrogen base.
摘要翻译：本发明涉及一种高选择性和在允许高空间/时间产率的反应条件下制备碳酸酯的方法，所述方法是使醇与分子氧和一氧化碳的混合物反应的方法在含有铜，化学键合的氧，化学键合的卤素和至少一个氮碱的催化剂体系存在下的液相。

5. 发明授权

US4219661A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4219661A
公开(公告)日：1980-08-26
申请号：US32581
申请日：1979-04-23
申请人： Robert Becker , Johann Grolig , Christian Rasp , Gerhard Scharfe
发明人： Robert Becker , Johann Grolig , Christian Rasp , Gerhard Scharfe
IPC分类号： C07C269/00 , B01J23/44 , B01J27/00 , B01J27/06 , B01J31/00 , C07C67/00 , C07C239/00 , C07C125/04
CPC分类号： B01J27/06 , B01J23/44
摘要： This invention relates to an improved process for the production of urethanes (i.e. carbamic acid esters) by reacting organic nitro compounds with carbon monoxide and organic compounds containing at least one hydroxy group in the presence of a unique catalyst system. The catalyst system consists of palladium or a palladium compound and iron oxychloride or a mixture of iron compounds containing iron oxychloride.
摘要翻译：本发明涉及通过有机硝基化合物与一氧化碳和含有至少一个羟基的有机化合物在独特的催化剂体系的存在下反应制备氨基甲酸酯（即氨基甲酸酯）的改进方法。催化剂体系由钯或钯化合物和三氯氧化铁或含有氯氧化铁的铁化合物的混合物组成。

6. 发明授权

US4339592A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4339592A
公开(公告)日：1982-07-13
申请号：US238518
申请日：1981-02-26
申请人： Robert Becker , Christian Rasp , Gunter Stammann , Johann Grolig
发明人： Robert Becker , Christian Rasp , Gunter Stammann , Johann Grolig
IPC分类号： C07C269/00 , B01J23/89 , B01J27/00 , B01J27/06 , B01J27/10 , B01J31/00 , B01J31/28 , B01J31/34 , C07B61/00 , C07C67/00 , C07C239/00 , C07C271/26 , C07C271/28 , C07C125/073
CPC分类号： B01J27/06 , B01J23/8906
摘要： A urethane is produced by reacting an organic nitro compound with carbon monoxide and an organic compound containing at least one hydroxyl group in the presence of a catalyst and a co-catalyst. This reaction is conducted in the liquid phase at elevated temperature and pressure. The catalyst employed is an element and/or compound of an element from the group of noble metals of the 8th Secondary Group of the Periodic Table. The co-catalyst used is formed from (1) a component taken from the group consisting of iron oxychloride, a mixture of iron compounds containing iron oxychloride and oxide-chloride combinations and (2) metallic iron or an iron alloy in finely divided or high surface form. The oxides which may be used in the oxide-chloride combinations of co-catalyst component (1) are the oxides and/or oxide hydrates of tetravalent tin, trivalent chromium, hexavalent molybdenum, hexavalent tungsten, pentavalent vanadium, divalent iron and trivalent iron. The chlorides which may be used in this oxide-chloride combination are chlorides of the elements of Groups IIIA, IVA, VA and IB to VIIIB of the Periodic Table and/or hydrochlorides of tertiary amines.
摘要翻译：氨基甲酸酯是通过有机硝基化合物与一氧化碳和含有至少一个羟基的有机化合物在催化剂和助催化剂的存在下反应生成的。该反应在升高的温度和压力下在液相中进行。所使用的催化剂是来自元素周期表第八族中的贵金属的元素和/或化合物。所使用的助催化剂由（1）由三氯氧化铁组成的组分，含有氯氧化铁的铁化合物和氧化物 - 氯化物组合的混合物组成的组分和（2）细碎或高分的金属铁或铁合金表面形式。可用于助催化剂组分（1）的氧化物 - 氯化物组合的氧化物是四价锡，三价铬，六价钼，六价钨，五价钒，二价铁和三价铁的氧化物和/或氧化物水合物。可用于该氧化物 - 氯化物组合中的氯化物是元素周期表IIIA，IVA，VA和IB至VIIIB族元素的氯化物和/或叔胺的盐酸盐。

7. 发明授权

US4304922A Process for the preparation of urethane 失效
标题翻译：氨基甲酸酯的制备方法
公开(公告)号：US4304922A
公开(公告)日：1981-12-08
申请号：US125395
申请日：1980-02-27
申请人： Robert Becker , Johann Grolig , Christian Rasp , Gunter Stammann
发明人： Robert Becker , Johann Grolig , Christian Rasp , Gunter Stammann
IPC分类号： C07C239/00 , C07C67/00 , C07C271/06 , C07C125/065 , C07C125/073
CPC分类号： C07C271/06
摘要： Production of urethanes by the oxycarbonylation reaction of N,N'-disubstituted ureas and organic compounds containing at least one hydroxyl group with carbon monoxide in the presence of molecular oxygen and/or organic nitro compounds and a catalyst system comprising (a) a noble metal and/or noble metal compound of the eighth subgroup of the periodic system of elements and (b) a compound of an element and/or elements of the third to fifth main group and/or first to eighth subgroup of the periodic system of elements characterized in that said compounds are capable of undergoing Redox reactions under the reaction conditions.
摘要翻译：在分子氧和/或有机硝基化合物的存在下通过N，N'-二取代的脲和含有至少一个羟基的有机化合物与一氧化碳的羰基化反应制备氨基甲酸酯和包含（a）贵金属和/或元素周期性系统的第八子群的贵金属化合物和（b）元素周期系统的元素和/或元素的第三至第五主族和/或第一至第八亚组的化合物，其特征在于因为所述化合物能够在反应条件下进行氧化还原反应。

8. 发明授权

US4297501A Process for the preparation of urethanes 失效
标题翻译：制备聚氨酯的方法
公开(公告)号：US4297501A
公开(公告)日：1981-10-27
申请号：US125394
申请日：1980-02-27
申请人： Robert Becker , Johann Grolig , Christian Rasp
发明人： Robert Becker , Johann Grolig , Christian Rasp
IPC分类号： B01J27/10 , B01J21/00 , B01J23/00 , B01J23/56 , B01J23/89 , B01J27/00 , B01J31/00 , B01J31/28 , C07C67/00 , C07C239/00 , C07C269/04 , C07C125/065
CPC分类号： C07C269/04
摘要： A process for producing urethanes by reacting primary amines, carbon monoxide and organic hydroxyl compounds in the presence of molecular oxygen and/or organic nitro compounds as oxidizing agents and a catalyst system comprising a noble metal and/or a compound of a noble metal of the 8th subgroup of the Periodic System of Elements and a compound capable of undergoing Redox reactions under reaction conditions of the 3rd to 5th main group and/or 1st to 8th subgroup of the Periodic System of Elements.
摘要翻译：在分子氧和/或有机硝基化合物作为氧化剂存在下使伯胺，一氧化碳和有机羟基化合物反应制备氨基甲酸酯的方法和包含贵金属和/或贵金属的化合物的催化剂体系元素周期元素第8族和能够在元素周期表第3至第5主族和/或第1至第8族的反应条件下进行氧化还原反应的化合物。

9. 发明授权

US4262130A Process for the production of urethanes 失效
标题翻译：生产聚氨酯的工艺
公开(公告)号：US4262130A
公开(公告)日：1981-04-14
申请号：US112780
申请日：1980-01-17
申请人： Robert Becker , Johann Grolig , Christian Rasp
发明人： Robert Becker , Johann Grolig , Christian Rasp
IPC分类号： C07B61/00 , B01J23/00 , B01J23/44 , B01J23/74 , B01J23/89 , B01J27/10 , B01J27/128 , B01J31/02 , C07C67/00 , C07C239/00 , C07C269/00 , C07C125/065 , C07C125/073
CPC分类号： B01J23/8906 , B01J27/10
摘要： The present invention relates to an improved process for the production of urethanes (carbamic acid esters) by the reaction of organic nitro compounds with carbon monoxide and organic compounds containing at least one hydroxy group in the presence of palladium and/or palladium compounds and a cocatalyst which consists of a mixture of one or more iron oxides and/or iron hydroxides and activating chloride-containing additives.
摘要翻译：本发明涉及通过有机硝基化合物与一氧化碳和含有至少一个羟基的有机化合物在钯和/或钯化合物和助催化剂的存在下反应制备氨基甲酸酯（氨基甲酸酯）的改进方法其由一种或多种氧化铁和/或氢氧化铁和活化的含氯化物的添加剂的混合物组成。

10. 发明申请

US20060164251A1 Hand held RFID reader with dipole anthenna 失效
标题翻译：手持RFID阅读器与偶极天线
公开(公告)号：US20060164251A1
公开(公告)日：2006-07-27
申请号：US11031693
申请日：2005-01-07
申请人： David Meyers , Douglas Carlson , Robert Becker
发明人： David Meyers , Douglas Carlson , Robert Becker
IPC分类号： G08B13/14 , G06K7/08 , G06K7/10
CPC分类号： G06K7/10346 , G06K7/10316 , G06K7/10881
摘要： A hand held Radio Frequency Identification (RFID) reader is provided. The reader includes a housing having a perimeter around an inner edge. The reader also includes a full-sized dipole antenna including two antenna elements coupled by a balun transformer. The antenna has nearly a unity gain over a range of angles. The reader also includes a transceiver, coupled to the dipole antenna by a suitable cable, the transceiver adapted to send and receive signals. The reader further includes a processor for processing signals received at the antenna. The first and the second antenna segments of the dipole antenna are wrapped along the perimeter around the inner edge of the housing.
摘要翻译：提供了手持射频识别（RFID）阅读器。读取器包括具有围绕内边缘的周边的壳体。阅读器还包括一个全尺寸的偶极天线，包括通过平衡 - 不平衡转换器耦合的两个天线元件。天线在角度范围内几乎具有单位增益。阅读器还包括一个收发器，通过合适的电缆耦合到偶极天线，该收发器适于发送和接收信号。读取器还包括处理器，用于处理在天线处接收的信号。偶极天线的第一和第二天线段围绕壳体的内边缘沿周边包裹。

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