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    • 3. 发明授权
    • Combinatorial material analysis using X-ray capillary optics
    • 使用X射线毛细管光学的组合材料分析
    • US06577705B1
    • 2003-06-10
    • US09824268
    • 2001-04-02
    • William ChangXiao-Dong XiangEdward D. Franco
    • William ChangXiao-Dong XiangEdward D. Franco
    • G01N23223
    • G21K1/06G01N23/223G01N2223/076
    • Method and system for analyzing local composition and structure of a compound having one or more non-zero gradients in concentration for one or more selected constituents in a selected direction. A beam of X rays having representative energy E is received by a mono-capillary or poly-capillary device and is directed at a selected small region of the compound. A portion of the X rays is diffracted at the selected region by one or more constituents of the compound, at each of two or more diffraction angles relative to a selected surface or lattice plane(s) of the compound; and the diffracted portion of X rays for each of these diffraction angles is received and analyzed at an X-ray detector. A portion of the X rays excites fluorescence radiation that is received by a fluorescence detector to estimate the relative concentrations in a compound having two or more constituents. Fluorescence X rays and diffraction X rays can be detected at each desired translational position and rotation for a target site. As a result, a concentration map for various constituents in the compound can be prepared, together with a phase map illustrating the structure of a combinatorial compound. An X-ray detector monochromator can be removed and a capillary diameter can be reduced in some situations.
    • 用于分析具有一个或多个非零梯度的化合物的局部组成和结构的方法和系统,所述非零梯度在选定方向上的一个或多个选定成分的浓度。 具有代表性能量E的X射线束由单毛细管或多毛细管装置接收并且被引导到化合物的选定的小区域。 X射线的一部分在化合物的一个或多个成分的选定区域衍射,相对于化合物的选定表面或晶格面,在两个或更多个衍射角度的每一个处; 并且在X射线检测器中接收和分析这些衍射角中的每一个的X射线的衍射部分。 X射线的一部分激发由荧光检测器接收的荧光辐射以估计具有两个或更多个成分的化合物中的相对浓度。 可以在目标位置的每个所需的平移位置和旋转处检测荧光X射线和衍射X射线。 结果,可以制备化合物中各种成分的浓度图,以及说明组合化合物的结构的相图。 可以去除X射线检测器单色仪,并且在某些情况下可以减少毛细血管直径。