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1. 发明授权

US08404757B2 Radiation curable sealing agent composition and member with sealing layer 有权
标题翻译：辐射固化型密封剂组合物和密封层组件
公开(公告)号：US08404757B2
公开(公告)日：2013-03-26
申请号：US12999383
申请日：2009-06-17
申请人： Riichiro Maruta , Haruhiko Nishida
发明人： Riichiro Maruta , Haruhiko Nishida
IPC分类号： C08F299/06
CPC分类号： C08G18/44 , C08G18/664 , C08G18/673 , C08G2190/00 , C09K3/1021 , C09K2003/1062
摘要： An photo-curable sealing agent composition comprising (A) an unsaturated group-containing urethane resin having a number average molecular weight of 1,000-100,000 and an unsaturation degree of 0.1-1 mol/kg, which is obtained by reaction of (a) a polycarbonate diol having a number average molecular weight of 500-3,000, (b) a bifunctional epoxy (meth)acrylate having two hydroxyl groups and two ethylenically unsaturated groups, and (c) a polyisocyanate; (B) a (meth)acrylic acid ester monomer, wherein an alcohol residue, ester-bonded with an (meth)acyloyl group, is a hydrocarbon group which may contain an oxygen atom, and has 1-20 carbon atoms and a molecular weight of not larger than 1,000; and (C) a photo-polymerization initiator. The sealing agent composition exhibits a high curability performance and gives a cured product having a low hardness and enhanced flexibility and elongation, and improved physical and mechanical strength and enhanced durability.
摘要翻译：一种光固化型密封剂组合物，其包含（A）数均分子量为1,000〜10000000，不饱和度为0.1〜1mol / kg的不饱和基团的聚氨酯树脂，其通过（a）数均分子量为500〜3000的聚碳酸酯二醇，（b）具有两个羟基和两个烯键式不饱和基团的双官能环氧（甲基）丙烯酸酯，和（c）多异氰酸酯; （B）（甲基）丙烯酸酯单体，其中与（甲基）丙酰基酯键合的醇残基是可以含有氧原子的烃基，并且具有1-20个碳原子和分子量不大于1000; 和（C）光聚合引发剂。密封剂组合物表现出高的固化性能，并且得到硬度低，柔韧性和伸长率提高的固化产物，提高了物理和机械强度并提高了耐久性。

2. 发明申请

US20110092611A1 RADIATION CURABLE SEALING AGENT COMPOSITION AND MEMBER WITH SEALING LAYER 有权
标题翻译：辐射可固化密封剂组合物和密封层的成员
公开(公告)号：US20110092611A1
公开(公告)日：2011-04-21
申请号：US12999383
申请日：2009-06-17
申请人： Riichiro Maruta , Haruhiko Nishida
发明人： Riichiro Maruta , Haruhiko Nishida
IPC分类号： C08J3/28
CPC分类号： C08G18/44 , C08G18/664 , C08G18/673 , C08G2190/00 , C09K3/1021 , C09K2003/1062
摘要： An photo-curable sealing agent composition comprising (A) an unsaturated group-containing urethane resin having a number average molecular weight of 1,000-100,000 and an unsaturation degree of 0.1-1 mol/kg, which is obtained by reaction of (a) a polycarbonate diol having a number average molecular weight of 500-3,000, (b) a bifunctional epoxy (meth)acrylate having two hydroxyl groups and two ethylenically unsaturated groups, and (c) a polyisocyanate; (B) a (meth)acrylic acid ester monomer, wherein an alcohol residue, ester-bonded with an (meth)acyloyl group, is a hydrocarbon group which may contain an oxygen atom, and has 1-20 carbon atoms and a molecular weight of not larger than 1,000; and (C) a photo-polymerization initiator. The sealing agent composition exhibits a high curability performance and gives a cured product having a low hardness and enhanced flexibility and elongation, and improved physical and mechanical strength and enhanced durability.
摘要翻译：一种光固化型密封剂组合物，其包含（A）数均分子量为1,000〜10000000，不饱和度为0.1〜1mol / kg的不饱和基团的聚氨酯树脂，其通过（a）数均分子量为500〜3000的聚碳酸酯二醇，（b）具有两个羟基和两个烯键式不饱和基团的双官能环氧（甲基）丙烯酸酯，和（c）多异氰酸酯; （B）（甲基）丙烯酸酯单体，其中与（甲基）丙酰基酯键合的醇残基是可以含有氧原子的烃基，并且具有1-20个碳原子和分子量不大于1000; 和（C）光聚合引发剂。密封剂组合物表现出高的固化性能，并且得到硬度低，柔韧性和伸长率提高的固化产物，提高了物理和机械强度并提高了耐久性。

3. 发明授权

US4874818A Primer compositions 失效
标题翻译：底漆组合物
公开(公告)号：US4874818A
公开(公告)日：1989-10-17
申请号：US78854
申请日：1987-07-28
申请人： Shosaku Yamamoto , Kazuo Kakinuma , Hiroshi Ishioka , Fumio Sodeyama , Junji Mayumi , Riichiro Maruta
发明人： Shosaku Yamamoto , Kazuo Kakinuma , Hiroshi Ishioka , Fumio Sodeyama , Junji Mayumi , Riichiro Maruta
IPC分类号： C08F283/01 , C08F285/00 , C08F287/00 , C08F290/00 , C08F299/00 , C08F299/04 , C08G18/42 , C08G18/63 , C08G63/08 , C08G81/02 , C09D5/00 , C09D151/00 , C09D151/04 , C09D151/06 , C09D167/00 , C09D167/02 , C09D167/04 , C09D187/00
CPC分类号： C08G81/027 , C08F287/00 , C08G18/4277 , C08G18/633 , C08G63/08 , C09D151/04 , C09D167/04
摘要： A primer composition usable for steel sheet and plastic sheet in vehicle bodies consists mainly of a polycaprolactone graft polymer obtained by graft-polymerizing a styrene-butadiene-styrene block copolymer or its hydrogenated polymer with a ring-opened polymer of .epsilon.-caprolactone and having a grafting ratio of the ring-opened polymer within a range of 0.5.about.50% by weight.
摘要翻译：可用于车体中的钢板和塑料片的底漆组合物主要由通过将苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物或其氢化聚合物与ε-己内酯的开环聚合物接枝聚合而获得的聚己内酯接枝聚合物，开环聚合物的接枝率在0.5％（重量）的范围内。

4. 发明授权

US4698395A Process of purifying maleic anhydride-modified polyolefin 失效
标题翻译：纯化马来酸酐改性聚烯烃的方法
公开(公告)号：US4698395A
公开(公告)日：1987-10-06
申请号：US863191
申请日：1986-05-14
申请人： Takayuki Inoue , Masafumi Hattori , Kazuhide Hayama , Riichiro Maruta
发明人： Takayuki Inoue , Masafumi Hattori , Kazuhide Hayama , Riichiro Maruta
IPC分类号： C08F6/06 , C08F8/44 , C08F8/46 , C08F255/00 , C08F8/42
CPC分类号： C08F8/46 , C08F255/00 , C08F6/06 , C08F8/44
摘要： A process of purifying maleic anhydride graft polyolefin comprising the steps of adding an aqueous solution of alkali initial hydroxide to a solution of maleic anhydride graft polyolefin containing unreacted maleic anhydride which is dissolved in an organic solvent at a temperature from 80.degree. C. to 160.degree. C., thereby precipitating maleic anhydride graft polyolefin particles to make a W/O emulsion; stirring the W/O emulsion while maintaining the temperature at a same temperature as above for less than 2 hours, thereby selectively forming the alkali metal salt of unreacted maleic anhydride; adding the aqueous solution of alkali metal hydroxide to the W/O emulsion to convert the W/O emulsion into an O/W emulsion; separating the maleic anhydride draft polyolefin particles, and washing the maleic anhydride graft polyolefin particles with water.
摘要翻译：一种纯化马来酸酐接枝聚烯烃的方法，包括以下步骤：将碱初始氢氧化物水溶液加入到含有未反应的马来酸酐的马来酸酐接枝聚烯烃溶液中，所述马来酸酐接枝聚烯烃在80℃至160℃的温度下溶解在有机溶剂中从而沉淀马来酸酐接枝聚烯烃颗粒以制备W / O乳液; 搅拌W / O乳液同时将温度保持在与上述相同的温度下少于2小时，从而选择性地形成未反应的马来酸酐的碱金属盐; 将碱金属氢氧化物水溶液加入到W / O乳液中以将W / O乳液转化为O / W乳液; 分离马来酸酐卷曲聚烯烃颗粒，并用水洗涤马来酸酐接枝聚烯烃颗粒。

5. 发明授权

US4692357A Primer composition for olefin resin 失效
标题翻译：烯烃树脂的底漆组合物
公开(公告)号：US4692357A
公开(公告)日：1987-09-08
申请号：US908956
申请日：1986-09-18
申请人： Junji Mayumi , Riichiro Maruta
发明人： Junji Mayumi , Riichiro Maruta
IPC分类号： C08J5/12 , C08J7/04 , C09D5/00 , C09D151/00 , C09D151/06 , C09D153/00 , C09D153/02 , B05D3/02 , B05D1/36
CPC分类号： C08J7/042 , C09D151/00 , C08J2323/02 , C08J2423/02 , C08J2455/02
摘要： A primer composition for olefin resins is disclosed, comprising Components (A) and (B):(A): a resin having an acid group prepared by graft polymerizing .alpha.,.beta.-unsaturated carboxylic acid or its anhydride onto a styrene-butadiene-styrene block copolymer or its hydrogenated product.(B): an organic solvent capable of dissolving the resin of Component (A).
摘要翻译：公开了用于烯烃树脂的底漆组合物，其包含组分（A）和（B）：（A）：具有通过将α，β-不饱和羧酸或其酸酐接枝聚合到苯乙烯 - 丁二烯 - 苯乙烯上制备的酸基的树脂嵌段共聚物或其氢化产物。（B）：能够溶解成分（A）的树脂的有机溶剂。

6. 发明授权

US5969043A Powder coating of epoxy resin and epoxidized polydiene block polymer 失效
标题翻译：环氧树脂和环氧化聚二烯嵌段聚合物的粉末涂料
公开(公告)号：US5969043A
公开(公告)日：1999-10-19
申请号：US54578
申请日：1998-04-03
申请人： Riichiro Maruta , Takako Watanabe , Yojiro Yamamoto
发明人： Riichiro Maruta , Takako Watanabe , Yojiro Yamamoto
IPC分类号： C08G59/06 , C08G59/34 , C08L53/00 , C08L53/02 , C09D153/00 , C09D153/02 , C09D163/00 , C09D163/08 , C08L63/02 , C08L63/04
CPC分类号： C08G59/027 , C08L53/00 , C08L53/02 , C09D153/00 , C09D153/02 , C09D163/00
摘要： An epoxy resin composition for powder coatings which comprises (a) 40 to 95 parts by weight of a solid epoxy resin having at least two epoxy groups in a molecule, an epoxy equivalent of 400 to 2500, and a softening point of 50.degree. C. to 150.degree. C., and (b) 5 to 60 parts by weight of an epoxidized polydiene polymer having a main structure of general Formula (I) in which aliphatic double bonds are partially epoxidized. Formula (I) is(A--B--Ap)n--Yr--(Aq--B)m (I)in which Y is a coupling agent, a monomer for coupling, or an initiator, A is a polymer block selected from a homopolymer block of a conjugated diolefine monomer, a copolymer block of a conjugated diolefine monomer, a copolymer block composed of a conjugated diolefine monomer and an aromatic hydrocarbon monomer having one alkenyl group, B is a polymer block selected from a homopolymer block of an aromatic hydrocarbon monomer having one alkenyl group or a copolymer block thereof, or a copolymer block composed of an aromatic hydrocarbon having one alkenyl group and a conjugated diolefine monomer, n is not less than 0, r is 0 or 1, and m is 0 or more, the total of n and m is 1 to 100, and p and q are 0 or 1).
摘要翻译：一种用于粉末涂料的环氧树脂组合物，其包含（a）40至95重量份的分子中具有至少两个环氧基的固体环氧树脂，环氧当量为400至2500，软化点为50℃。至150℃，和（b）5至60重量份具有通式（I）的主要结构的环氧化聚二烯烃聚合物，其中脂族双键部分环氧化。式（I）是其中Y是偶联剂，偶联单体或引发剂的（AB-Ap）n-Yr-（Aq-B）m（I），A是选自均聚物嵌段的共轭二烯单体，共轭二烯单体的共聚物嵌段，由共轭二烯单体和具有一个烯基的芳族烃单体组成的共聚物嵌段，B是选自具有芳族烃单体的均聚物嵌段的聚合物嵌段，一个烯基或其共聚物嵌段，或由具有一个烯基的芳族烃和共轭二烯单体构成的共聚物嵌段，n不小于0，r为0或1，m为0以上， n和m为1〜100，p和q为0或1）。

7. 发明授权

US4883834A Primer compositions 失效
标题翻译：底漆组合物
公开(公告)号：US4883834A
公开(公告)日：1989-11-28
申请号：US72423
申请日：1987-07-13
申请人： Shosaku Yamamoto , Kazuo Kakinuma , Fumio Sodeyama , Junji Mayumi , Riichiro Maruta
发明人： Shosaku Yamamoto , Kazuo Kakinuma , Fumio Sodeyama , Junji Mayumi , Riichiro Maruta
IPC分类号： C08J7/04 , C08G59/00 , C08G59/18 , C08G59/40 , C08L63/00 , C09D5/00 , C09D151/00 , C09D153/00 , C09D153/02 , C09D163/00 , C09D175/14
CPC分类号： C09D163/00 , C09D151/006
摘要： A primer composition usable for steel sheet and plastic sheet in vehicle bodies consists essentially of a component A composed of a resin obtained by graft-polymerizing a styrene-butadiene-styrene block copolymer or its hydrogenated polymer with .alpha.,.beta.-unsaturated carboxylic acid or its anhydride, a component B of a crosslinking agent and a component C of an epoxy compound, and has particular weight ratios as solid content of component A to component B and components A+B to component C.
摘要翻译：可用于车体中的钢板和塑料片的底漆组合物基本上由由通过将苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物或其氢化聚合物与α，β-不饱和羧酸或其氢化聚合物接枝聚合而获得的树脂组成的组分A 酸酐，交联剂的组分B和环氧化合物的组分C，并且具有作为组分A至组分B的固体含量和组分A + B至组分C的特定重量比。

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