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1. 发明授权

EP1788014B1 Thermosensitive adhesive composition, method of manufacturing the same and thermosensitive adhesive article 有权
标题翻译：热敏粘合剂组合物，其制备方法，和热敏感粘合剂制品
公开(公告)号：EP1788014B1
公开(公告)日：2016-03-09
申请号：EP06023901.9
申请日：2006-11-17
申请人： Ricoh Company, Ltd.
发明人： Yamaguchi, Takehito , Matsui, Hiroaki , Morita, Mitsunobu , Sasaki, Takayuki , Hayakawa, Kunio
IPC分类号： B41M5/40 , B41M5/50 , C09J7/02 , C09J11/02 , C08K5/11
CPC分类号： C09J11/02 , B41M5/42 , B41M5/504 , B41M2205/32 , C08K5/0016 , C08K5/11 , C08K5/3475 , C08K5/50 , C08L43/00 , C09J7/29 , C09J7/35 , C09J2201/162 , C09J2205/102 , C09J2205/11 , Y10T428/24355 , Y10T428/24802 , Y10T428/249971 , Y10T428/31504
摘要： A thermosensitive adhesive composition including a thermosensitive plastic resin,a dispersing agent,a solid plasticizing agent and a eutectic agent represented by the following chemical structure (1): wherein, X 1 and X 2 independently represent any one of a hydrogen atom, a halogen atom and an alkyl group, p and q independently represent an integer of from 1 to 5.

2. 发明授权

EP1491354B1 Reversible thermosensitive recording medium, label, and image recording method 有权
标题翻译： Reversibeles热敏记录材料，礼仪，和图像记录方法
公开(公告)号：EP1491354B1
公开(公告)日：2008-01-16
申请号：EP04014890.0
申请日：2004-06-24
申请人： Ricoh Company, Ltd.
发明人： Shimbo, Hitoshi , Tatewaki, Tadafumi , Yamamoto, Shin , Hayakawa, Kunio , Kawahara, Shinya
IPC分类号： B41M5/30 , B41M5/42 , G09F3/10
CPC分类号： B41M5/42 , B41J2/4753 , B41M5/305 , B41M5/423 , B41M5/426 , B41M2205/04 , B41M2205/18 , B41M2205/40

3. 发明授权

EP1398171B1 Thermal recording material 有权
公开(公告)号：EP1398171B1
公开(公告)日：2005-02-16
申请号：EP03020815.1
申请日：2003-09-12
申请人： Ricoh Company Ltd.
发明人： Naruse, Mitsuru , Morita, Mitsunobu , Hayakawa, Kunio
IPC分类号： B41M5/40
CPC分类号： B41M5/42 , B41M5/426 , B41M5/443

4. 发明公开

EP1882726A1 Heat-sensitive pressure-sensitive adhesive and heat-sensitive adhesive material 审中-公开
标题翻译： Klebemasse和wärmeempfindlichesKlebematerial
公开(公告)号：EP1882726A1
公开(公告)日：2008-01-30
申请号：EP07113344.1
申请日：2007-07-27
申请人： Ricoh Company, Ltd.
发明人： Sasaki, Takayuki , Morita, Mitsunobu , Yamaguchi, Tekehito , Hayakawa, Kunio , Shimbo, Hitoshi , Kuga, Yutaka
IPC分类号： C09J7/02 , C08K5/00
CPC分类号： B41M5/42 , B41M5/423 , B41M5/44 , B41M2205/04 , B41M2205/36 , C08K5/005 , C08K5/1345 , C08K5/50 , C08K5/526 , C08L13/00 , C09J7/29 , C09J7/385 , C09J2201/162 , C09J2205/102 , C09J2205/106 , C09J2205/11 , C09J2433/00 , C09J2453/00 , Y10T428/24942 , Y10T428/25 , Y10T428/273 , Y10T428/2826
摘要： A heat-sensitive pressure-sensitive adhesive which contains at least a thermoplastic resin and a thermofusible material, wherein the thermoplastic resin has a glass transition temperature of-70°C to -30°C, and the thermofusible material comprises triphenylphosphine, and at least any one of tris (2,4-di-t-butylphenyl) phosphite and tetrakis [3-(3,5-di-t-butyl-4-hydroxyphenyl) propionate] methane, or a heat-sensitive pressure-sensitive adhesive which contains at least a thermoplastic resin, a thermofusible material and a non-thermofusible material, wherein the thermofusible material contains triphenylphosphine
摘要翻译：一种热敏粘合剂，其至少包含热塑性树脂和热熔性材料，其中所述热塑性树脂的玻璃化转变温度为-70℃至-30℃，并且所述热熔性材料包含三苯基膦，并且至少亚磷酸三（2,4-二叔丁基苯基）酯和四[3-（3,5-二叔丁基-4-羟基苯基）丙酸酯]甲烷中的任一种或热敏压敏粘合剂含有至少热塑性树脂，热熔性材料和非热熔性材料，其中所述热熔性材料含有三苯基膦

5. 发明公开

EP1788014A1 Thermosensitive adhesive composition, method of manufacturing the same and thermosensitive adhesive article 有权
标题翻译： WärmeempfindlicheKlebstoffzusammensetzung，HerstellungsverfahrendafürundwärmeempfindlicherKlebeartikel
公开(公告)号：EP1788014A1
公开(公告)日：2007-05-23
申请号：EP06023901.9
申请日：2006-11-17
申请人： Ricoh Company, Ltd.
发明人： Yamaguchi, Takehito , Matsui, Hiroaki , Morita, Mitsunobu , Sasaki, Takayuki , Hayakawa, Kunio
IPC分类号： C08K5/00 , C09J11/02 , C09J7/02
CPC分类号： C09J11/02 , B41M5/42 , B41M5/504 , B41M2205/32 , C08K5/0016 , C08K5/11 , C08K5/3475 , C08K5/50 , C08L43/00 , C09J7/29 , C09J7/35 , C09J2201/162 , C09J2205/102 , C09J2205/11 , Y10T428/24355 , Y10T428/24802 , Y10T428/249971 , Y10T428/31504
摘要： A thermosensitive adhesive composition including a thermosensitive plastic resin,a dispersing agent,a solid plasticizing agent and a eutectic agent represented by the following chemical structure (1):

wherein, X 1 and X 2 independently represent any one of a hydrogen atom, a halogen atom and an alkyl group, p and q independently represent an integer of from 1 to 5.
摘要翻译：一种热敏粘合剂组合物，其包含热敏塑料树脂，分散剂，固体增塑剂和由以下化学结构（1）表示的共晶剂：其中，X 1和X 2独立地表示氢原子，卤素原子和烷基，p和q独立地表示1〜5的整数。

6. 发明公开

EP1491354A1 Reversible thermosensitive recording medium, label, image recording apparatus and method. 有权
标题翻译：复活节äem ind lic lic ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren
公开(公告)号：EP1491354A1
公开(公告)日：2004-12-29
申请号：EP04014890.0
申请日：2004-06-24
申请人： Ricoh Company Ltd.
发明人： Shimbo, Hitoshi , Tatewaki, Tadafumi , Yamamoto, Shin , Hayakawa, Kunio , Kawahara, Shinya
IPC分类号： B41M5/30 , B41M5/40 , G09F3/10
CPC分类号： B41M5/42 , B41J2/4753 , B41M5/305 , B41M5/423 , B41M5/426 , B41M2205/04 , B41M2205/18 , B41M2205/40
摘要： The reversible thermosensitive recording medium according to the present invention comprises a support, a thermosensitive layer and a protective layer in order, the thermosensitive layer comprises an electron-donating coloring compound and an electron-accepting compound and reversibly changes the color depending on temperatures, and the protective layer comprises a reactive heterocyclic compound, and inorganic fine particles of which surface is at least partially treated into hydrophobic, alternatively the protective layer comprises inorganic fine particles of which number-average particle size is 100 nm or less and of which surface is at least partially coated with organic silane compounds.
摘要翻译：可逆热敏记录介质包括涂有顺序热敏层和保护层的载体。热敏层根据温度改变颜色; 并且包含给电子着色化合物和电子接受性化合物。保护层包括至少部分处理成表面疏水性的无机细颗粒，以及任选的反应性杂环化合物。独立权利要求包括以下内容：（1）可逆热敏记录标签，其包括设置在与图像形成侧相反的可逆热敏记录介质的表面上的粘合剂层和粘性层之一; （2）可逆热敏记录部件，包括信息存储部分和可逆显示部分，其中可逆显示部分包含可逆热敏记录介质; （3）图像处理装置，包括图像形成单元和图像擦除单元中的至少一个，其中通过加热图像形成单元中的介质在可逆热敏记录介质上形成图像，并且从记录中擦除图像介质，通过加热图像擦除单元中的记录介质; 和（4）涉及在可逆热敏记录介质上形成图像并从记录介质上擦除图像的图像处理方法。

7. 发明公开

EP2025527A1 Reversible thermosensitive recording medium, reversible thermosensitive recording label, member, and image processing method 审中-公开
标题翻译： U ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren ren
公开(公告)号：EP2025527A1
公开(公告)日：2009-02-18
申请号：EP08162247.4
申请日：2008-08-12
申请人： Ricoh Company, Ltd.
发明人： Shimbo, Hitoshi , Hayakawa, Kunio , Maruyama, Jun
IPC分类号： B41M5/30 , B41M5/333 , B41M5/337 , G09F3/10
CPC分类号： B41M5/305 , B41M5/3335 , B41M5/3372 , G09F3/10
摘要： The present invention provides a reversible thermosensitive recording medium including:
a support, and
a reversible thermosensitive recording layer laid on the support, the recording layer containing a reversible thermosensitive composition,

wherein the reversible thermosensitive composition forms a relatively color-developed state and a colorless state depending on a difference in a heating temperature and/or a cooling rate after heating by the use of an electron-donating color-forming compound and an electron-accepting compound; a resin component contained in the reversible thermosensitive recording layer is a resin in which a polyol resin having a hydroxyl value within the range of 100 KOHmg/g to 250 KOHmg/g is crosslinked; and as the electron-accepting compound, a urea compound represented by the following General Formula (1) is used,

where "n" is an integer of 23 or greater.
摘要翻译：本发明提供一种可逆热敏记录介质，包括：载体和铺设在载体上的可逆热敏记录层，所述记录层含有可逆热敏组合物，其中可逆热敏组合物形成相对显色状态和无色状态取决于通过使用给电子成色化合物和受电子化合物的加热温度和/或加热后的冷却速度的差异; 包含在可逆热敏记录层中的树脂成分是其中羟基值在100KOHmg / g至250KOHmg / g范围内的多元醇树脂交联的树脂; 作为电子接受性化合物，使用由以下通式（1）表示的脲化合物，其中“n”为23以上的整数。

8. 发明授权

EP1571005B1 Reversible thermosensitive recording medium, imaging device and imaging method 有权
标题翻译：可逆热敏记录材料，图像形成装置和图像形成方法
公开(公告)号：EP1571005B1
公开(公告)日：2008-10-08
申请号：EP05004589.7
申请日：2005-03-02
申请人： Ricoh Company, Ltd.
发明人： Kawahara, Shinya , Hayakawa, Kunio , Shimbo, Hitoshi
IPC分类号： B41M5/30 , B41M5/337 , B41M5/36
CPC分类号： B41M5/363 , B41M5/305 , B41M5/3335 , B41M5/3372 , B41M5/3375 , B41M5/42

9. 发明公开

EP1571005A1 Reversible thermosensitive recording medium, imaging device and imaging method 有权
标题翻译： ReversibleswärmeempfindlichesAufzeichnungsmaterial，Bilderzeugungsvorrichtung und Bilderzeugungsverfahren
公开(公告)号：EP1571005A1
公开(公告)日：2005-09-07
申请号：EP05004589.7
申请日：2005-03-02
申请人： Ricoh Company, Ltd.
发明人： Kawahara, Shinya , Hayakawa, Kunio , Shimbo, Hitoshi
IPC分类号： B41M5/30 , B41M5/36 , B41M5/40
CPC分类号： B41M5/363 , B41M5/305 , B41M5/3335 , B41M5/3372 , B41M5/3375 , B41M5/42
摘要： A reversible thermosensitive recording medium (1; 10) including a substrate (11; 103); and a reversible thermosensitive recording layer (13; 102) located on the substrate and reversibly achieving a relatively colored state and a relatively discolored state depending on the temperature to which the recording layer is heated or the cooling speed at which the recording layer is cooled after heating, wherein the reversible thermosensitive recording layer comprises a polyalkylene glycol compound having a number average molecular weight not less than 2,000, exclusive of polypropylene glycol having a number average molecular weight not greater than 5,000. A reversible thermosensitive recording device (90; 98), and an image processing method and apparatus (100) using the reversible thermosensitive recording medium are also be provided.
摘要翻译：一种包括衬底（11; 103）的可逆热敏记录介质（1; 10）; 和位于基板上的可逆热敏记录层（13; 102），根据加热记录层的温度或记录层被冷却后的冷却速度可逆地实现相对着色的状态和相对变色的状态加热，其中可逆热敏记录层包括数均分子量不小于2,000的聚亚烷基二醇化合物，不包括数均分子量不大于5,000的聚丙二醇。还提供了可逆热敏记录装置（90; 98）以及使用可逆热敏记录介质的图像处理方法和装置（100）。

10. 发明公开

EP1543985A3 Reversible thermosensitive recording medium, information storage material, reversible thermosensitive recording label, imaging method and imaging device 有权
标题翻译：可逆热敏记录材料，信息存储介质，可逆热敏记录标签，图像形成方法和图像形成装置
公开(公告)号：EP1543985A3
公开(公告)日：2005-07-13
申请号：EP04030157.4
申请日：2004-12-20
申请人： Ricoh Company, Ltd.
发明人： Hayakawa, Kunio , Kawahara, Shinya , Shimbo, Hitoshi
IPC分类号： B41M5/30 , B41M5/40
CPC分类号： B41M5/42 , B41M5/305 , B41M5/3333 , B41M5/3335 , B41M5/44
摘要： A reversible thermosensitive recording medium including a substrate, a reversible thermosensitive recording layer and an intermediate layer. The reversible thermosensitive recording layer is configured to reversibly record and erase an image therein and disposed overlying the substrate and includes a first binder resin and a reversible thermosensitive coloring composition. The reversible thermosensitive coloring composition includes an electron donating coloring compound and an electron accepting compound containing a phenol compound including a long chain aliphatic group having at least 10 carbon atoms and an active hydrogen containing group capable of forming a hydrogen bonding. The intermediate layer is disposed between the substrate and the reversible thermosensitive recording layer and includes a second binder resin and a content of hollow particles having a hollow ratio not less than 70 % and having a ratio (D100/D50) of a maximum particle diameter thereof (D100) to a 50 % cumulative particle diameter (D50) of from 2.0 to 3.0. The reversible thermosensitive recording layer achieves and maintains a colored state when heated to a temperature not lower than a melting point thereof and then cooled down, and the reversible thermosensitive recording layer achieves and maintains a discolorization state when heated to a temperature lower than the melting point and then cooled down, and wherein the reversible thermosensitive recording layer has an erasable energy range width of at least 0.1 mJ/dot when achieving the discolorization state with a thermal head.
摘要翻译：可逆热敏记录介质包括一个基底，一个可逆热敏记录层和在中间层。可逆热敏记录层被配置成可逆地记录和擦除图像。其中和设置覆盖所述衬底和包含第一粘合剂树脂和一种可逆热敏着色组合物。可逆热敏着色组合物包括给电子着色化合物和电子接受性化合物，含有包含具有至少10个碳原子，并含有活性氢能够形成氢键的基团的长链脂族基团的苯酚化合物。该中间层的基底和可逆热敏记录层之间设置并且包括第二粘合剂树脂和具有中空率不小于70％，并且具有最大粒径之比（D100 / D50）它们的中空颗粒的含量从2.0到3.0的（D100）与50％累积粒径（D50）。可逆热敏记录层达到并保持着色状态。当加热到温度不低于其熔点，然后冷却下，将可逆热敏记录层达到并保持一discolorization状态当加热到比熔点低的温度下然后冷却，并worin可逆热敏记录层具有至少0.1毫焦/点的能量擦除范围宽度当用热头实现discolorization状态。

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