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1. 发明授权

US5728760A Use of ring-brominated benzoate compounds as flame retardants and/or plasticizers 失效
标题翻译：使用环溴苯甲酸酯化合物作为阻燃剂和/或增塑剂
公开(公告)号：US5728760A
公开(公告)日：1998-03-17
申请号：US419814
申请日：1995-04-11
申请人： Richard S. Rose , Bhabatosh Bhattacharya , Nicolai A. Favstritsky
发明人： Richard S. Rose , Bhabatosh Bhattacharya , Nicolai A. Favstritsky
IPC分类号： C08K5/101 , C08K5/12 , C08J5/10 , C08K5/09 , C08K5/10 , C08L75/04
CPC分类号： C08K5/101 , C08K5/12
摘要： A method of making flame retarded polyurethanes by including a bromobenzoate compound in the polyurethane mixture. Also disclosed is a method of making flame retarded polyvinyl chlorides, unsaturated polyesters and epoxy resins by incorporating a bromobenzoate compound into the polymer system. The bromobenzoate compounds of the invention may also be used as plasticizers for PVC and rubber.
摘要翻译：通过在聚氨酯混合物中包含溴苯甲酸酯化合物制备阻燃聚氨酯的方法。还公开了通过将溴代苯甲酸酯化合物引入聚合物体系制备阻燃聚氯乙烯，不饱和聚酯和环氧树脂的方法。本发明的溴代苯甲酸酯化合物也可用作PVC和橡胶的增塑剂。

2. 发明授权

US4892892A Flame retardant polyurethane foam compositions containing polynuclearbrominated alkylbenzene 失效
标题翻译：含有多溴化烷基苯的阻燃聚氨酯泡沫组合物
公开(公告)号：US4892892A
公开(公告)日：1990-01-09
申请号：US107627
申请日：1987-10-09
申请人： Nicolai A. Favstritsky , Richard S. Rose , Dennis M. Borden , David J. Honkomp
发明人： Nicolai A. Favstritsky , Richard S. Rose , Dennis M. Borden , David J. Honkomp
IPC分类号： C08J9/14 , C08G18/00 , C08J9/00 , C08K3/32 , C08K5/03 , C08K5/521 , C08K5/523 , C08L75/00 , C08L75/04 , C08L75/08
CPC分类号： C08K5/03 , C08K5/523
摘要： Flame retardant polyurethane foam compositions incorporate an effective amount of a polybrominated higher alkylbenzene as a flame retardant and, optionally, a polyaryl phosphate agent.
摘要翻译：阻燃聚氨酯泡沫组合物包含有效量的作为阻燃剂的多溴代高级烷基苯和任选的聚芳基磷酸酯试剂。

3. 发明授权

US5296306A Flame retardant brominated styrene graft latex coatings 失效
标题翻译：阻燃溴化苯乙烯接枝胶乳涂料
公开(公告)号：US5296306A
公开(公告)日：1994-03-22
申请号：US977911
申请日：1992-11-18
申请人： Jin-liang Wang , Nicolai A. Favstritsky , Richard S. Rose
发明人： Jin-liang Wang , Nicolai A. Favstritsky , Richard S. Rose
IPC分类号： C08J5/04 , B32B7/10 , B32B25/08 , B32B25/10 , C08F279/02 , C09D5/18 , C09D151/00 , C09D151/04 , B32B27/30
CPC分类号： C09D151/04 , C08F279/02 , C09D5/18 , Y10T428/31935 , Y10T428/31938
摘要： Flame retardant latex coatings are disclosed which include natural or synthetic latex grafted with ring-halogenated, ethylenically unsaturated aromatic monomers. The grafted latex is used alone or in combination with non-grafted natural or synthetic latex. The coatings are useful for a wide variety of applications, including fabric backcoatings, carpetings, paints, adhesives, sealants, caulks, non-woven binders and so on.
摘要翻译：公开了阻燃乳胶涂料，其包括接枝有环 - 卤化烯属不饱和芳族单体的天然或合成胶乳。接枝的胶乳单独使用或与非接枝的天然或合成胶乳组合使用。涂料可用于各种应用，包括织物背涂，地毯，油漆，粘合剂，密封剂，填缝料，无纺粘合剂等。

4. 发明授权

US5290636A Flame retardant brominated styrene-based coatings 失效
标题翻译：阻燃溴化苯乙烯基涂料
公开(公告)号：US5290636A
公开(公告)日：1994-03-01
申请号：US875359
申请日：1992-04-29
申请人： Richard S. Rose , Jin-liang Wang , Nicolai A. Favstritsky , David E. May , David J. Honkomp
发明人： Richard S. Rose , Jin-liang Wang , Nicolai A. Favstritsky , David E. May , David J. Honkomp
IPC分类号： C08F12/16 , C08F12/00 , C08F20/18 , C08F220/10 , C08L33/00 , C08L33/04 , C09D125/00 , C09D125/02 , C09D125/18 , C09D133/00 , C09D133/04 , C09D133/06 , B32B27/32
CPC分类号： C09D133/062 , C09D125/02 , C09D125/18 , Y10S428/92 , Y10S428/921 , Y10T428/31797 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , Y10T442/2713
摘要： Improved flame retardant latex coatings are disclosed which comprise copolymers of ring-halogenated aromatic monomer units and alkyl acrylate/methacrylate monomer units, and which may additionally include at least one other monomer. In a first embodiment, the coatings include ring-brominated aromatic monomer units and alkyl acrylate and/or alkyl methacrylate monomer units. In a second embodiment, the coatings include these first two types of monomer units and further include third monomer units from unsaturated esters of saturated carboxylic acids, halogen-free aromatic monomers or unsaturated carboxylic or dicarboxylic acid monomers. In a third embodiment, the coatings include four monomer units, namely ring-brominated aromatic monomer units, alkyl acrylate/methacrylate monomer units, halogen-free aromatic monomer units and unsaturated carboxylic or dicarboxylic acid monomer units. In one aspect, the halogenated aromatic monomers are present in an amount to provide from 7 to 20 weight percent bromine in the final latex coating. In another aspect, the halogenated aromatic monomers include polybrominated monomers, particularly to provide monomers having an average of at least about 1.5 bromines per monomer unit. The coating polymers have glass transition temperatures in the -30.degree. C. to 30.degree. C. range and are useful, for example, for coating, paint, adhesive, sealant and non-woven binder applications.
摘要翻译：公开了改进的阻燃胶乳涂层，其包含环 - 卤代芳族单体单元和丙烯酸烷基酯/甲基丙烯酸烷基酯单体单元的共聚物，并且其可另外包含至少一种其它单体。在第一个实施方案中，涂层包括环溴化芳族单体单元和丙烯酸烷基酯和/或甲基丙烯酸烷基酯单体单元。在第二实施方案中，涂层包括这些前两种类型的单体单元，并且还包括来自饱和羧酸的不饱和酯，无卤素芳族单体或不饱和羧酸或二羧酸单体的第三单体单元。在第三实施方案中，涂层包括四个单体单元，即环溴化芳族单体单元，丙烯酸烷基酯/甲基丙烯酸酯单体单元，无卤素芳族单体单元和不饱和羧酸或二羧酸单体单元。在一个方面，卤代芳族单体的存在量为最终胶乳涂料中的7至20重量％的溴。另一方面，卤代芳族单体包括多溴单体，特别是提供每单体单元平均具有至少约1.5个溴的单体。涂层聚合物的玻璃化转变温度在-30摄氏度到30摄氏度的范围内，并且可用于例如涂料，油漆，粘合剂，密封剂和无纺粘合剂应用。

5. 发明授权

US5100986A Flame retardant brominated styrene-based coatings 失效
标题翻译：阻燃稳定剂基于苯乙烯的涂料
公开(公告)号：US5100986A
公开(公告)日：1992-03-31
申请号：US606590
申请日：1990-10-31
申请人： Nicolai A. Favstritsky , Jin-liang Wang , Richard S. Rose
发明人： Nicolai A. Favstritsky , Jin-liang Wang , Richard S. Rose
IPC分类号： C08F8/20 , C08F212/00 , C08F212/14 , C08F236/04
CPC分类号： C08F212/14 , C08F8/20
摘要： Halogenated styrene-based coatings having surprisingly good physical properties in combination with flame retardancy are prepared from copolymers of ring-halogenated, ethylenically unsaturated aromatic monomers and aliphatic conjugated dienes having from 4 to 10 carbon atoms, and from terpolymers of ring-halogenated, ethylenically unsaturated aromatic monomers, halogen-free aromatic monomers, and aliphatic conjugated dienes having from 4 to 10 carbon atoms.

6. 发明授权

US5438096A Flame retardant brominated styrene-based latices 失效
标题翻译：阻燃溴化苯乙烯基胶乳
公开(公告)号：US5438096A
公开(公告)日：1995-08-01
申请号：US243050
申请日：1994-05-16
申请人： Jin-liang Wang , Nicolai A. Favstritsky , Richard S. Rose
发明人： Jin-liang Wang , Nicolai A. Favstritsky , Richard S. Rose
IPC分类号： C08F212/14 , C08L25/14 , C08L33/14 , C08L27/10
CPC分类号： C08L33/14 , C08F212/14 , C08L25/14
摘要： Improved flame retardant polymer latices are disclosed which comprise copolymers of ring-halogenated aromatic monomer units and alkyl acrylate/methacrylate monomer units, and which may additionally include at least one other monomer. In a first embodiment, the latices include ring-brominated aromatic monomer units and alkyl acrylate and/or alkyl methacrylate monomer units. In a second embodiment, the latices include these first two types of monomer units and further include third monomer units from unsaturated esters of saturated carboxylic acids, halogen-free aromatic monomers or unsaturated carboxylic or dicarboxylic acid monomers. In a third embodiment, the latices include four monomer units, namely ring-brominated aromatic monomer units, alkyl acrylate/methacrylate monomer units, halogen-free aromatic monomer units and unsaturated carboxylic or dicarboxylic acid monomer units. In one aspect, the halogenated aromatic monomers are present in an amount to provide from 7 to 20 weight percent bromine in the final latex composition. In another aspect, the halogenated aromatic monomers include polybrominated monomers, particularly to provide monomers having an average of at least about 1.5 bromines per monomer unit. The latex polymers have glass transition temperature in the -30.degree. to 30.degree. C. range for coating, paint adhesive, sealant and non-woven binder applications.
摘要翻译：公开了改进的阻燃聚合物胶乳，其包含环 - 卤代芳族单体单元和丙烯酸烷基酯/甲基丙烯酸烷基酯单体单元的共聚物，并且其可另外包含至少一种其它单体。在第一实施方案中，胶乳包括环溴芳族单体单元和丙烯酸烷基酯和/或甲基丙烯酸烷基酯单体单元。在第二实施方案中，胶乳包括这些前两种类型的单体单元，并且还包括来自饱和羧酸的不饱和酯，无卤素芳族单体或不饱和羧酸或二羧酸单体的第三单体单元。在第三实施方案中，胶乳包括四个单体单元，即环溴化芳族单体单元，丙烯酸烷基酯/甲基丙烯酸酯单体单元，无卤素芳族单体单元和不饱和羧酸或二羧酸单体单元。一方面，卤代芳族单体的存在量为最终胶乳组合物中7至20重量％的溴。另一方面，卤代芳族单体包括多溴单体，特别是提供每单体单元平均具有至少约1.5个溴的单体。胶乳聚合物的玻璃化转变温度在-30℃至30℃范围内用于涂料，油漆粘合剂，密封剂和无纺粘合剂应用。

7. 发明授权

US07008973B2 Vacuum cooled foams 有权
标题翻译：真空冷却泡沫
公开(公告)号：US07008973B2
公开(公告)日：2006-03-07
申请号：US10757685
申请日：2004-01-14
申请人： Stephen B. Falloon , Richard S. Rose , Mathew D. Phillips
发明人： Stephen B. Falloon , Richard S. Rose , Mathew D. Phillips
IPC分类号： C08G18/00
CPC分类号： C08K5/12 , C08G18/4833 , C08G2101/0008 , C08G2101/0083 , C08K5/523 , C08L75/04
摘要： A flexible, flame-retarded, polyurethane foam comprising brominated and/or phosphorous flame retardants and an acid scavenger.
摘要翻译：包含溴化和/或磷阻燃剂和酸清除剂的柔性阻燃聚氨酯泡沫。

8. 发明授权

US06667355B2 Higher alkylated triaryl phosphate ester flame retardants 有权
标题翻译：高级烷基化三芳基磷酸酯阻燃剂
公开(公告)号：US06667355B2
公开(公告)日：2003-12-23
申请号：US09943635
申请日：2001-08-30
申请人： Richard S. Rose , David L. Buszard , Matthew D. Phillips , Frank J. Liu
发明人： Richard S. Rose , David L. Buszard , Matthew D. Phillips , Frank J. Liu
IPC分类号： C08K553
CPC分类号： C08K5/523
摘要： Flame retardants for polymer compositions which are mixtures including triaryl phosphate esters represented by the following formula: where R1-R15 can independently be located in the ortho, meta or para positions on their respective phenol rings and are, independently, H or branched or linear alkyl groups having 3 to 11 carbon atoms and the mole ratio of the alkylate to phenol in the mixtures is at least about 0.77, preferably greater than about 0.81, and most preferably greater than about 0.85. The higher alkylated mixtures of triaryl phosphate esters can be incorporated into polymer compositions alone or in combination with other flame retardants.
摘要翻译：用于聚合物组合物的阻燃剂，其是包含由下式表示的磷酸三芳酯的混合物：其中R 1 -R 15可以独立地位于其各自苯酚环的邻位，间位或对位，并且独立地为H或支链或直链烷基具有3至11个碳原子的基团和该混合物中烷基化物与苯酚的摩尔比为至少约0.77，优选大于约0.81，最优选大于约0.85。磷酸三芳基酯的高级烷基化混合物可单独或与其它阻燃剂组合引入聚合物组合物中。

9. 发明申请

US20100041781A1 FLAME RETARDANTS AND FLAME RETARDED POLYMERS 有权
标题翻译：阻燃剂和阻燃聚合物
公开(公告)号：US20100041781A1
公开(公告)日：2010-02-18
申请号：US12580574
申请日：2009-10-16
申请人： Stephen B. FALLOON , Richard S. Rose , Matthew D. Phillips
发明人： Stephen B. FALLOON , Richard S. Rose , Matthew D. Phillips
IPC分类号： C08K5/52
CPC分类号： C09K21/12 , C08K5/0066 , C08K5/03 , C08K5/523
摘要： There is presented a new flame retardant composition comprising a brominated aromatic composition and a butyl substituted phenyl phosphate.
摘要翻译：提出了包含溴化芳族组合物和丁基取代的苯基磷酸酯的新的阻燃组合物。

10. 发明授权

US06239197B1 Vacuum de-aerated powdered polymer additives 失效
标题翻译：真空脱气粉末状聚合物添加剂
公开(公告)号：US06239197B1
公开(公告)日：2001-05-29
申请号：US09420438
申请日：1999-10-18
申请人： Russell Haywood , Paul Edward Inchley , Richard S. Rose
发明人： Russell Haywood , Paul Edward Inchley , Richard S. Rose
IPC分类号： C08J300
CPC分类号： C08K11/00 , C08J3/203
摘要： Increased bulk density of powdered flame retardants, flame retardant synergists and other powdered polymer additives substantially improves the processing, dispersibility, and properties of the processed polymer. Processing improvements include faster processing, more homogeneous additive dispersion throughout the polymer, less swell, and reduction or elimination of drool. Formed parts containing the increased bulk density flame retardant and flame retardant synergists are more consistent with respect to density, wall thickness, and more homogeneous and consistent flame retardancy. Physical properties such as flammability test performance and/or impact strength are also enhanced.
摘要翻译：粉状阻燃剂，阻燃增效剂和其它粉末状聚合物添加剂的堆积密度的增加基本上改善了加工聚合物的加工，分散性和性能。加工改进包括更快的加工，更均匀的添加剂分散在整个聚合物中，较少的膨胀，以及降低或消除流出。含有增加体积密度阻燃剂和阻燃增效剂的成型部件在密度，壁厚以及更均匀和一致的阻燃性方面更一致。物理性质如可燃性试验性能和/或冲击强度也得到提高。

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