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    • 1. 发明授权
    • Organoleptic uses of bicyclononenyl alcohols
    • 感官用途的双环壬烯醇
    • US4634547A
    • 1987-01-06
    • US796430
    • 1985-11-08
    • Richard M. BodenJohn R. Helm
    • Richard M. BodenJohn R. Helm
    • C11B9/00C11D3/50A61K7/46
    • C11D3/50C11B9/0049
    • Described are oxobicyclononane derivatives and mixtures of same having the generic structure: ##STR1## wherein X, Y, X' and Y' each represents the moiety having one of the structures: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond with the proviso that when X' and Y' are each the moiety: ##STR3## then the dashed line at the "2-3" position is a carbon-carbon double bond and the dashed line at the "6-7" position is a carbon-carbon single bond and one of X or Y has the structure: ##STR4## and the other of X or Y has the structure: ##STR5## and with the further proviso that when X and Y are the moieties: ##STR6## then the dashed line at the "6-7" position is a carbon-carbon double bond and the dashed line at the "2-3" position is a carbon-carbon single bond and one of X' or Y' has the structure: ##STR7## and the other of X' or Y' has the structure: ##STR8## and wherein R represents hydrogen, C.sub.1 -C.sub.3 acyl or C.sub.1 -C.sub.2 alkoxy carbonyl with the major portion of the mixtures defined according to the generic structure: ##STR9## wherein one of X or Y is the moiety: ##STR10## and the other of X or Y is the moiety: ##STR11## with R being one of hydrogen, C.sub.1 -C.sub.3 acyl or C.sub.1 -C.sub.2 alkoxy carbonyl and uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, perfumed polymers and colognes.
    • 描述了具有以下通用结构的氧代二环壬烷衍生物及其混合物:其中X,Y,X'和Y'各自表示具有以下结构之一的部分:其中虚线之一代表碳 - 碳 单键,另一个虚线表示碳 - 碳双键,条件是当X'和Y'各自为部分时:“IMAGE”,则“2-3”位的虚线是碳 - 碳双键,“6-7”位置的虚线是碳 - 碳单键,X或Y之一具有以下结构:X或Y具有以下结构:和 进一步的条件是当X和Y是部分时:“IMAGE”,则“6-7”位置处的虚线是碳 - 碳双键,“2-3”位的虚线是碳 碳单键和X'或Y'之一具有以下结构:X'或Y'具有以下结构:其中R表示氢,C 1-C3酰基或C1-C2烷氧基羰基,其主要部分是根据通用结构定义的混合物:其中X或Y之一为部分:X,Y中的另一个为部分 :其中R为氢,C 1 -C 3酰基或C 1 -C 2烷氧基羰基之一,其用于增强或增强香料组合物,香料制品,加香聚合物和古龙水的香气。
    • 2. 发明授权
    • Oxobicyclononane derivatives, process for producing same and
organoleptic uses thereof
    • 氧代双环壬烷衍生物,其制备方法和感官用途
    • US4673533A
    • 1987-06-16
    • US879417
    • 1986-06-27
    • Richard M. BodenJohn R. Helm
    • Richard M. BodenJohn R. Helm
    • C11B9/00C11D3/50A61K7/46
    • C11D3/50C11B9/0049
    • Described are oxobicyclononane derivatives and mixtures of same having the generic structure: ##STR1## wherein X, Y, X' and Y' each represents the moiety having one of the structures: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond with the proviso that when X' and Y' are each the moiety: ##STR3## then the dashed line at the "2-3" position is a carbon-carbon double bond and the dashed line at the "6-7" position is a carbon-carbon single bond and one of X or Y has the structure: ##STR4## and the other of X or Y has the structure: ##STR5## and with the further proviso that when X and Y are the moieties: ##STR6## then the dashed line at the "6-7" position is a carbon-carbon double bond and the dashed line at the "2-3" position is a carbon-carbon single bond and one of X' or Y' has the structure: ##STR7## and the other of X' or Y' has the structure: ##STR8## and wherein R represents hydrogen, C.sub.1 -C.sub.3 acyl or C.sub.1 -C.sub.2 alkoxy carbonyl with the major portion of the mixtures defined according to the generic structure: ##STR9## wherein one of X or Y is the moiety: ##STR10## and the other of X or Y is the moiety: ##STR11## with R being one of hydrogen, C.sub.1 -C.sub.3 acyl or C.sub.1 -C.sub.2 alkoxy carbonyl and uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, perfumed polymers and colognes.
    • 描述了具有以下通用结构的氧代二环壬烷衍生物及其混合物:其中X,Y,X'和Y'各自表示具有以下结构之一的部分:其中虚线之一表示 碳 - 碳单键,另一个虚线表示碳 - 碳双键,条件是当X'和Y'各自为:IMAGE时,“2-3”位的虚线为 碳 - 碳双键和“6-7”位置的虚线是碳 - 碳单键,X或Y之一具有以下结构:X或Y具有以下结构: 并且进一步的条件是当X和Y是部分:“IMAGE”时,“6-7”位置处的虚线是碳 - 碳双键,在“2-3”位置的虚线 是碳 - 碳单键,X'或Y'之一具有以下结构:X'或Y'具有以下结构:其中R表示氢 根据通用结构定义的混合物的主要部分:其中X或Y之一为部分:其中X或Y的另一个为 该部分:其中R是氢,C 1 -C 3酰基或C 1 -C 2烷氧羰基之一,其用于增强或增强香料组合物,香料制品,加香聚合物和古龙水的香气。
    • 9. 发明授权
    • Insect repellent compositions and methods for using same
    • 驱虫剂组合物及其使用方法
    • US5521165A
    • 1996-05-28
    • US522138
    • 1995-08-31
    • Craig B. WarrenJerry F. ButlerRichard A. WilsonBraja D. MookherjeeLeslie C. SmithAnna B. MarinAnubhav P. S. NarulaRichard M. Boden
    • Craig B. WarrenJerry F. ButlerRichard A. WilsonBraja D. MookherjeeLeslie C. SmithAnna B. MarinAnubhav P. S. NarulaRichard M. Boden
    • A01N49/00A01N55/00A01N55/08A01N55/10A01N25/08
    • A01N55/08A01N49/00A01N55/00Y10S424/10Y10S514/919Y10S514/964
    • Described is a method of repelling Musca domestica L. (Diptera:Muscidae), Aedes aegypti, Culex nigripalpus, Aedes atlanticus, Culex salinarius, Aedes vexans, Culex spp., Simulium spp., Psoroferia ferox, Aedes infirmatus, Drosophila melanogaster, Coccinellidae, Anopheles crucians, Psoroferia columbiae, Culicoides spp., and Aedes spp. for a finite period of time from a three-dimensional space inhabitable by these insects consisting essentially of exposing a three-dimensional space to an effective concentration and quantity of geraniol or a geraniol precursor-containing composition consisting essentially of 50-100% geraniol or a geraniol precursor (e.g., geranyloxy-1,3,2-dioxaborinane, digeranyloxydimethylsilane and geranyl glycosides, for example, geranyl 6-O-(alpha-L-rhamnopyranosyl)-beta-D-glucopyranoside) with the remainder of the composition (if indeed the composition is not 100% geraniol) being a compound selected from the group consisting of citronellol and nerol. The above-stated repellents are described to be useful as such or contained in a polymer which can be a biodegradable polymer such as compositions containing a major proportion of poly(epsilon caprolactone) homopolymers.
    • 描述了排斥Musca domestica L.(双翅目:Muscidae),埃及伊蚊,Culex nigripalpus,Aedes atlanticus,Culex salinarius,Aedes vexans,Culex spp。,Simulium spp。,Psoroferia ferox,Aedes infirmatus,Drosophila melanogaster,Coccinellidae, les,,,e e。。。。。。。。。。。。。。。 在由这些昆虫居住的三维空间的有限时间段内,基本上将三维空间暴露于有效浓度和数量的香叶醇或含有香叶醇前体的组合物,该组合物基本上由50-100%香叶醇或 香叶醇前体(例如,格列酰氧基-1,3,2-二氧杂硼杂环己烷,二基二氧基二甲基硅烷和香叶基苷,例如香叶基6-O-(α-L-鼠李糖吡喃糖基)-β-D-吡喃葡萄糖苷),其余组分(如 实际上组合物不是100%香叶醇)是选自香茅醇和橙花醇的化合物。 上述驱避剂被描述为可以这样使用或包含在聚合物中,聚合物可以是可生物降解的聚合物,例如含有主要比例的聚(ε-己内酯)均聚物的组合物。
    • 10. 发明授权
    • 3,5-dimethyl-pentenyl-dihydro-2(3H)-furanone isomer mixtures,
organoleptic uses thereof, process for preparing same and process
intermediates therefor
    • 3,5-二甲基 - 戊烯基 - 二氢-2(3H) - 呋喃酮异构体混合物,其感官用途,制备方法及其中间体
    • US5478803A
    • 1995-12-26
    • US330847
    • 1994-10-27
    • Richard M. BodenWilliam J. FylakMarie R. HannaFutoshi Fujioka
    • Richard M. BodenWilliam J. FylakMarie R. HannaFutoshi Fujioka
    • C07C69/587C11B9/00C11D3/50A61K7/46
    • C11D3/50C11B9/0076
    • Described are 3,5-dimethyl-pentenyl-dihydro-2(3H)-furanone isomer mixtures defined according to the structure: ##STR1## wherein structure represents mixtures wherein in the mixture in each of the compounds, one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond, processes for preparing same and uses thereof in augmenting or enhancing the aroma of consumable materials including perfume compositions, colognes and perfumed articles (e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, hair preparations, fabric softeners, fabric softener articles, cosmetic powders and perfumed polymers). Also described is a process for preparing such 3,5-dimethyl-pentenyl-dihydro-2(3H)-furanone isomer mixtures using as a starting material 2,7-octadienol having the structure: ##STR2## as well as the process intermediates having the structures: ##STR3## wherein R represents C.sub.1 -C.sub.4 alkyl; R.sub.1 and R.sub.2 are the same or different and each represents 2,7-octadienyl or R.
    • 描述的是根据以下结构定义的3,5-二甲基 - 戊烯基 - 二氢-2(3H) - 呋喃酮异构体混合物:其中结构表示混合物,其中在每个化合物的混合物中,虚线之一表示 碳 - 碳双键,虚线中的另一个代表碳 - 碳单键,其制备方法及其用于增强或增强消耗材料的香气,包括香料组合物,古龙水和香料制品(例如固体或液体 阴离子,阳离子,非离子或两性离子洗涤剂,毛发制剂,织物柔软剂,织物柔软剂制品,化妆粉和加香聚合物)。 还描述了使用具有以下结构的起始原料2,7-辛二烯醇制备这种3,5-二甲基 - 戊烯基 - 二氢-2(3H) - 呋喃酮异构体混合物的方法,以及具有 结构: 其中R表示C1-C4烷基; R1和R2相同或不同,各自表示2,7-辛二烯基或R.