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1. 发明授权

US5049302A Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties 失效
标题翻译：稳定的液体洗涤剂组合物具有增强的粘土污垢去污力和抗再沉积性能
公开(公告)号：US5049302A
公开(公告)日：1991-09-17
申请号：US254467
申请日：1988-10-06
申请人： Richard J. Holland , Ornie K. Bullard , Alicia V. York , Dieter Boeckh , Wolfgang Trieselt , Paul Diessel , Hans-Ulrich Jaeger
发明人： Richard J. Holland , Ornie K. Bullard , Alicia V. York , Dieter Boeckh , Wolfgang Trieselt , Paul Diessel , Hans-Ulrich Jaeger
IPC分类号： C11D1/83 , C11D3/00 , C11D3/22 , C11D3/37
CPC分类号： C11D1/83 , C11D3/0036 , C11D3/225 , C11D3/3788
摘要： A stable liquid detergent composition having improved clay soil detergency, clay soil anti-redeposition, oily soil anti-redeposition and soil release properties is disclosed. The detergent composition is comprised of an anionic surfactant, a nonionic surfactant, a hydrotrope, a graft copolymer of polyalkylene oxide and an ester monomer, and a nonionic cellulosic anti-redeposition agent. The graft copolymer is comprised of (a) a polyalkylene oxide based upon an alkylene oxide having from 2 to 4 carbon atoms having a molecular weight of 300 to 100,000 and, (b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms, and/or methyl or ethyl ester of acrylic or meth-acrylic acid in a weight ratio of (a):(b) of from 1:0.2 to 1:10. The nonionic cellulosic anti-redeposition agent is preferably hydroxypropyl methylcellulose. There is a synergism between the nonionic anti-redeposition agent and the graft polyol which imparts improved clay soil detergency, clay anti-deposition and oily soil anti-redeposition properties to the detergent composition.
摘要翻译：公开了一种稳定的液体洗涤剂组合物，其具有改进的粘土污垢去污力，粘土污垢抗再沉积，油性土壤抗再沉积和脱土性质。洗涤剂组合物由阴离子表面活性剂，非离子表面活性剂，水溶助长剂，聚环氧烷和酯单体的接枝共聚物和非离子纤维素抗再沉积剂组成。接枝共聚物包含（a）基于分子量为300至100,000的具有2至4个碳原子的烯化氧的聚亚烷基氧化物，和（b）至少一种衍生自饱和一元羧酸的乙烯基酯，其含有1 至（6）个碳原子，和/或丙烯酸或甲基丙烯酸的甲酯或乙酯，重量比（a）：（b）为1:0.2至1:10。非离子纤维素抗再沉积剂优选为羟丙基甲基纤维素。非离子抗再沉积剂和接枝多元醇之间存在协同作用，其赋予洗涤剂组合物改进的粘土污垢去污力，粘土抗沉积和油性土壤抗再沉积性能。

2. 发明授权

US4999869A Pre-treating textiles with dispersions of graft polymers based on polyalkylene oxides to impart soil release properties thereto 失效
标题翻译：用基于聚环氧烷的接枝聚合物的分散体预处理织物以赋予其去污性
公开(公告)号：US4999869A
公开(公告)日：1991-03-19
申请号：US417317
申请日：1989-10-05
申请人： Richard J. Holland , Alicia V. York , Ronald M. Ruppert
发明人： Richard J. Holland , Alicia V. York , Ronald M. Ruppert
IPC分类号： D06M15/53
CPC分类号： C11D3/3788 , D06M15/53
摘要： A process for the pre-treatment of textile surfaces which impart soil release properties, comprising contacting a textile with a dispersion graft copolymer of:(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000, is based on ethylene oxide, propylene oxide and/or butylene oxide and may be capped at one end through etherification, esterification, amidation or reaction with a isocyanate, and(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acidin a weight ratio (a):(b) of from 1:0.2 to 1:10 in an aqueous liquor.
摘要翻译：一种用于预处理纺织品表面的方法，其赋予污渍释放性能，包括使织物与分散接枝共聚物接触，所述分散体接枝共聚物为：（a）数均分子量为300至100,000的聚环氧烷，基于乙烯氧化物，环氧丙烷和/或环氧丁烷，并且可以通过醚化，酯化，酰胺化或与异氰酸酯的反应在一端封端，和（b）至少一种衍生自含有1至6个碳原子的饱和一元羧酸的乙烯基酯和 /或丙烯酸或甲基丙烯酸的甲基或乙酯在水溶液中的重量比（a）：（b）为1:0.2至1:10。

3. 发明申请

US20130096047A1 Surfactant Component And A Composition Including The Same 有权
标题翻译：表面活性剂组分和包含它的组合物
公开(公告)号：US20130096047A1
公开(公告)日：2013-04-18
申请号：US13805801
申请日：2011-06-10
申请人： Richard J. Holland , Mary A. Kinsella , Mark Thompson
发明人： Richard J. Holland , Mary A. Kinsella , Mark Thompson
IPC分类号： C11D3/00
CPC分类号： C11D3/0015 , C11D1/62 , C11D1/72 , C11D1/8255 , C11D1/8355
摘要： A surfactant component and a composition comprising the same are provided. The surfactant component comprises a first surfactant, a second surfactant, and water. The first surfactant comprises an alcohol alkoxylate having a high degree of alkoxylation of greater than 30 to 150. The first surfactant is present in an amount of from 1% to 50% by weight based on the total weight of the surfactant component. The second surfactant is present in an amount of at least 5% by weight based on the total weight of the surfactant component. Water is present in an amount of from 20% to 90% by weight based on the total weight of the surfactant component. The second surfactant enables higher concentrations of the first surfactant in water to be achieved without gelling than what has been accomplished to date.
摘要翻译：提供表面活性剂组分和包含其的组合物。表面活性剂组分包括第一表面活性剂，第二表面活性剂和水。第一表面活性剂包含烷氧基化程度高于30至150的醇烷氧基化物。基于表面活性剂组分的总重量，第一表面活性剂的存在量为1重量％至50重量％。基于表面活性剂组分的总重量，第二表面活性剂的存在量为至少5重量％。基于表面活性剂组分的总重量，水的存在量为20重量％至90重量％。第二种表面活性剂可以使水中的第一种表面活性剂的浓度达到最高，而不会凝胶化。

4. 发明授权

US06342474B1 Hard surface cleaner containing nonionic surfactants 有权
标题翻译：含有非离子表面活性剂的硬表面清洁剂
公开(公告)号：US06342474B1
公开(公告)日：2002-01-29
申请号：US09466291
申请日：1999-12-17
申请人： Charles O. Kerobo , Richard J. Holland , Michael C. Welch , Suzanne M. Gessner , Sonia J. Patterson
发明人： Charles O. Kerobo , Richard J. Holland , Michael C. Welch , Suzanne M. Gessner , Sonia J. Patterson
IPC分类号： C11D166
CPC分类号： C11D1/72 , C11D1/722 , C11D3/33 , C11D3/43 , C11D17/003
摘要： There is provided an aqueous hard surface cleaning composition comprising a) a water soluble organic solvent; b) a nonionic surfactant selected from the group consisting of an alcohol alkoxylate, an alcohol block alkoxylate, a polyxyethylene polyoxypropylene block surfactant, and mixtures thereof; and c) an effective amount up to about 5% by weight of a cleaning auxiliary selected from the group consisting of methylglycine diacetic acid, hydroxyethyl ethylenediamine triacetic acid, diethylenetriamine pentaacetic acid, ethylenediamine tetraacetic acid, nitilotriacetic acid, salts thereof, and mixtures thereof; and d) optionally, a thickening agent. The compositions are useful for cleaning hard surfaces with a minimum of wiping and scrubbing.
摘要翻译：提供一种含水硬质表面清洁组合物，其包含a）水溶性有机溶剂; b）选自醇烷氧基化物，醇嵌段烷氧基化物，聚亚乙基聚氧丙烯嵌段表面活性剂及其混合物的非离子表面活性剂; 和c）有效量，至多约5重量％的选自甲基甘氨酸二乙酸，羟乙基乙二胺三乙酸，二亚乙基三胺五乙酸，乙二胺四乙酸，硝基三乙酸，其盐及其混合物的清洁助剂的重量; andd）任选地，增稠剂。该组合物可用于清洁硬表面，同时进行擦拭和擦拭。

5. 发明授权

US5709852A Ethylene oxide/propylene oxide/ethylene oxide (EO/PO/EO) triblock copolymer carrier blends 失效
标题翻译：环氧乙烷/环氧丙烷/环氧乙烷（EO / PO / EO）三嵌段共聚物载体共混物
公开(公告)号：US5709852A
公开(公告)日：1998-01-20
申请号：US568604
申请日：1995-12-05
申请人： Sridhar Gopalkrishnan , Richard J. Holland , John J. Burke , Kathleen M. Guiney
发明人： Sridhar Gopalkrishnan , Richard J. Holland , John J. Burke , Kathleen M. Guiney
IPC分类号： A61K8/90 , A61K31/74 , A61Q11/00 , A61Q15/00 , A61Q19/10
CPC分类号： A61Q15/00 , A61K8/90 , A61Q11/00 , A61Q19/10
摘要： A stable non-aqueous carrier for personal care compositions comprising: a) about 80-98% by weight of a non-ionic liquid triblock EO/PO/EO copolymer of MW=1000-5000; b) about 2-20% by weight of a non-ionic solid triblock EO/PO/EO copolymer of MW=4000-16,000.
摘要翻译：一种用于个人护理组合物的稳定的非水性载体，其包含：a）约80-98重量％的MW = 1000-5000的非离子液体三嵌段EO / PO / EO共聚物; b）约2-20重量％的MW = 4000-16,000的非离子固体三嵌段EO / PO / EO共聚物。

6. 发明授权

US5156906A Method of pretreating fabrics in impart soil release properties thereto 失效
标题翻译：预处理织物赋予其去污性的方法
公开(公告)号：US5156906A
公开(公告)日：1992-10-20
申请号：US767732
申请日：1991-09-30
申请人： Richard J. Holland
发明人： Richard J. Holland
IPC分类号： D06M15/333 , D06M15/507 , D06M15/53
CPC分类号： D06M15/333 , D06M15/507 , D06M15/53 , D06M2101/06 , D06M2101/32 , D06M2101/34 , Y10T442/2279
摘要： A method of pretreating fabrics and textiles to impart soil release properties involves contacting the fabrics with a graft copolymer of polyoxyethylene terephthalate/polyethylene terephthalate with vinyl acetate or vinyl propionate.
摘要翻译：预处理织物和纺织品以赋予污垢释放性质的方法包括使织物与聚对苯二甲酸乙二醇酯/聚对苯二甲酸乙二醇酯与乙酸乙烯酯或丙酸乙烯酯的接枝共聚物接触。

7. 发明授权

US08916512B2 Surfactant component and a composition including the same 有权
标题翻译：表面活性剂组分和包含它们的组合物
公开(公告)号：US08916512B2
公开(公告)日：2014-12-23
申请号：US13805801
申请日：2011-06-10
申请人： Richard J. Holland , Mary A. Kinsella , Mark Thompson
发明人： Richard J. Holland , Mary A. Kinsella , Mark Thompson
IPC分类号： C11D1/72 , C11D1/825 , C11D1/835 , C11D3/00 , C11D1/62
CPC分类号： C11D3/0015 , C11D1/62 , C11D1/72 , C11D1/8255 , C11D1/8355
摘要： A surfactant component and a composition comprising the same are provided. The surfactant component comprises a first surfactant, a second surfactant, and water. The first surfactant comprises an alcohol alkoxylate having a high degree of alkoxylation of greater than 30 to 150. The first surfactant is present in an amount of from 1% to 50% by weight based on the total weight of the surfactant component. The second surfactant is present in an amount of at least 5% by weight based on the total weight of the surfactant component. Water is present in an amount of from 20% to 90% by weight based on the total weight of the surfactant component. The second surfactant enables higher concentrations of the first surfactant in water to be achieved without gelling than what has been accomplished to date.
摘要翻译：提供表面活性剂组分和包含其的组合物。表面活性剂组分包括第一表面活性剂，第二表面活性剂和水。第一表面活性剂包含烷氧基化程度高于30至150的醇烷氧基化物。基于表面活性剂组分的总重量，第一表面活性剂的存在量为1重量％至50重量％。基于表面活性剂组分的总重量，第二表面活性剂的存在量为至少5重量％。基于表面活性剂组分的总重量，水的存在量为20重量％至90重量％。第二种表面活性剂可以使水中的第一种表面活性剂的浓度达到最高，而不会凝胶化。

8. 发明授权

US06342206B1 Aqueous gels comprising ethoxylated polyhydric alcohols 失效
标题翻译：包含乙氧基化多元醇的水性凝胶
公开(公告)号：US06342206B1
公开(公告)日：2002-01-29
申请号：US09472471
申请日：1999-12-27
申请人： Sridhar Gopalkrishnan , Richard J. Holland , James S. Dailey , Kathleen M. Guiney
发明人： Sridhar Gopalkrishnan , Richard J. Holland , James S. Dailey , Kathleen M. Guiney
IPC分类号： A61K716
CPC分类号： A61K8/042 , A61K8/22 , A61K8/25 , A61K8/39 , A61K8/731 , A61K8/8147 , A61K8/86 , A61K8/90 , A61Q5/00 , A61Q11/00 , A61Q19/00
摘要： There is provided according to the present invention an aqueous gel composition, comprising a) an ethoxylated polyhydric alcohol which comprises a reaction product of an alcohol having 3 to 6 hydroxy groups with ethylene oxide; and b) a gelling agent selected from the group consisting of a polyoxyethylene/polyoxypropylene/polyoxyethylene triblock surfactant having a molecular weight of from 4,000 to 16,000, and wherein the weight of the polyoxyethylene blocks is from 55% to 90% of the weight of the triblock surfactant; a crosslinked polyacrylic thickener; cellulose derivatives; hydrated silicas; and mixtures thereof. When the gelling agent is the triblock surfactants, the ethoxylated polyhydric alcohol comprises the reaction product of the polyhydric alcohol and up to 5 mole equivalents of ethylene oxide per mole equivalent of hydroxyl group in the alcohol.
摘要翻译：根据本发明提供一种水性凝胶组合物，其包含a）乙氧基化多元醇，其包含具有3至6个羟基的醇与环氧乙烷的反应产物; 和b）选自分子量为4,000至16,000的聚氧乙烯/聚氧丙烯/聚氧乙烯三嵌段表面活性剂的胶凝剂，其中聚氧乙烯嵌段的重量为三嵌段重量的55％至90％表面活性剂交联聚丙烯酸增稠剂; 纤维素衍生物; 水合二氧化硅; 当胶凝剂是三嵌段表面活性剂时，乙氧基化多元醇包含多元醇的反应产物和醇中每摩尔当量羟基高达5摩尔当量的环氧乙烷。

9. 发明授权

US5467622A Handle lock for reciprocally movable operator handle 失效
标题翻译：手柄用于可往复操作的手柄
公开(公告)号：US5467622A
公开(公告)日：1995-11-21
申请号：US236430
申请日：1994-04-29
申请人： James A. Becker , Ronald J. Fritsch , Richard J. Holland , Robert F. Klobuchar
发明人： James A. Becker , Ronald J. Fritsch , Richard J. Holland , Robert F. Klobuchar
IPC分类号： E05B13/00 , E05B67/38 , H01H9/28 , G05G5/02
CPC分类号： E05B13/002 , E05B67/383 , H01H9/283 , Y10S70/30 , Y10S70/63 , Y10T70/5739 , Y10T70/5779
摘要： A plate pivotally mounted to a padlock hasp adjacent a reciprocally movable operator handle is pivotable from a stored position to one covering the opening of the hasp, the plate having a hole aligned with the opening and smaller than the opening to receive the shackle of a single, scissors-type safety lockout and maintain the shackle in position to block movement of the operator handle to an operated position. The hole is preferably rectangular to conform to the flat, thin shape of the safety lockout shackle to maintain the shackle properly oriented. An additional round hole for a smaller diameter padlock shackle may be provided in said plate.
摘要翻译：枢转地安装到与可往复运动的操作手柄相邻的挂锁搭扣的板可以从存储位置枢转到覆盖搭扣的开口的一个，该板具有与开口对准的孔并且小于开口以接收单个的钩环，剪刀型安全锁定，并将卸扣保持在适当位置，以阻止操作手柄移动到操作位置。该孔优选地是矩形的，以符合安全锁定钩环的平坦的薄形状，以保持卸扣适当地定向。可以在所述板中提供用于较小直径的挂锁钩环的附加圆孔。

10. 发明授权

US5186856A Aqueous prewash stain remover compositions with efficacy on tenacious oily stains 失效
标题翻译：水性预洗去污剂组合物，具有强力油性污渍的功效
公开(公告)号：US5186856A
公开(公告)日：1993-02-16
申请号：US892295
申请日：1992-06-02
申请人： Richard J. Holland
发明人： Richard J. Holland
IPC分类号： C11D1/44 , C11D1/72 , C11D1/825 , C11D3/20 , C11D3/30 , C11D3/33 , C11D3/37
CPC分类号： C11D3/30 , C11D1/8255 , C11D3/2086 , C11D3/33 , C11D3/3707 , C11D1/44 , C11D1/72
摘要： An aqueous laundry prewash stain remover composition, has on a weight basis 0.1 to 20% of at least one chelating agent from the group of citric acid, tartaric acid, and ethylene diamine tetracetic acid; 0.1 to 40% of a mixture of nonionic surfactants from the group of ethoxylated alcohols and propoxylated alcohols; 0.1 to 10% of propoxylated ethylenediamine known as N,N,N',N'-tetrakis (2-hydroxypropyl) ethylenediamine; 0.1 to 5% of alpha-olefin epoxide modified polyether thickener; 0.1 to 19.9% of an additional chelant from the group of isoserine diacetate and Beta-alanine diacetate; with the remainder of the composition being water. The composition provides enhanced stain removal on both oil and water-borne stains on a variety of fabrics. These formulations are solvent free, freeze/thaw stable, and do not precipitate on standing at room temperature.
摘要翻译：含水衣物预洗去污剂组合物的重量基于0.1-20％的来自柠檬酸，酒石酸和乙二胺四乙酸的至少一种螯合剂; 0.1至40％的来自乙氧基化醇和丙氧基化醇的非离子表面活性剂的混合物; 0.1〜10％称为N，N，N'，N'-四（2-羟丙基）乙二胺的丙氧基化乙二胺; 0.1〜5％的α-烯烃环氧改性聚醚增稠剂; 0.1〜19.9％的来自二酸二脂肪酸二钠和β-丙氨酸二乙酸酯的附加螯合剂; 其余组合物为水。该组合物在各种织物上的油和水性污渍上提供增强的去污。这些制剂是无溶剂的，冷冻/解冻稳定的，并且在室温下静置时不沉淀。

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