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    • 6. 发明申请
    • Covalent Bonding of Carboxylated Cellulose Fiber Webs
    • 羧基纤维素纤维网的共价键合
    • US20080000603A1
    • 2008-01-03
    • US11427470
    • 2006-06-29
    • Amar N. NeogiRichard A. JewellDavid W. ParkJohn A. Westland
    • Amar N. NeogiRichard A. JewellDavid W. ParkJohn A. Westland
    • D21F11/00D21C9/00
    • D21H11/20D21C9/005
    • Methods are provided for creating covalent bonding of webs by combining cellulosic fibers having a carboxyl content approximately greater than 7 meq/100 g with one or more crosslinking agents. In a first step, a carboxyl group is placed onto a fiber. In an embodiment, the fiber is then reacted with an oxazoline-functional polymer which has been combined with a polycarboxylate compound. Heat is applied to the treated web, and this enables formation of a cross-linked bridge in the form of a covalent bond. In an embodiment, the covalent bonding of the carboxylated cellulose pulp webs utilizes oxazoline-functional polymers and polyacrylic acid. The oxazoline polymer in combination with polyacrylic acid should form a network polymer with covalent bonds to the cellulose carboxyl groups. The non-woven web may be strengthhened by covalent bonding, thereby improving overall wet/dry strength of the final product.
    • 提供了通过将具有大于7meq / 100g的羧基含量的纤维素纤维与一种或多种交联剂组合来产生纤维网共价结合的方法。 在第一步中,将羧基置于纤维上。 在一个实施方案中,然后使纤维与已经与多羧酸盐化合物组合的恶唑啉官能聚合物反应。 将热量施加到处理过的纤维网上,这样可形成共价键形式的交联桥。 在一个实施方案中,羧化纤维素纸浆网的共价键合使用恶唑啉官能聚合物和聚丙烯酸。 恶唑啉聚合物与聚丙烯酸结合应形成与纤维素羧基具有共价键的网状聚合物。 可以通过共价键强化非织造纤维网,从而提高最终产品的整体湿/干强度。
    • 10. 发明授权
    • Surfaced cellulose composite panel and panel forming method
    • 浮雕纤维素复合板和面板成型方法
    • US5436069A
    • 1995-07-25
    • US110338
    • 1993-08-23
    • Jack G. WinterowdDavid W. ParkJ. Harry WirzRoland E. KreibichRoger M. ShantzTimit GhermayCharles C. Childress
    • Jack G. WinterowdDavid W. ParkJ. Harry WirzRoland E. KreibichRoger M. ShantzTimit GhermayCharles C. Childress
    • B27N7/00E04C2/10B32B5/20
    • B27N7/005E04C2/10Y10T428/249959Y10T428/249987Y10T428/249989Y10T428/31989
    • A method of producing a surfaced composite panel of cellulosic particulates, such as wood flakes, involves the application of polymer forming foamable material to at least one of the first and second major surfaces of the panel, contacting said at least one of the first and second surfaces with a pressure applying surface to apply pressure thereto, foaming the polymer forming foamable material while pressure is applied and curing the applied foam material to produce a polymeric coating on the panel with the desired surface, which is typically extremely smooth. One or both surfaces may be surface treated in this manner. A skin formed on the surface of the panel is believed to add to the strength and stiffness of the coating on the panel. A wide variety of foaming systems may be used to accomplish this surface treating. By avoiding sanding the surface treated panel, the skin remains intact. The resulting panel, in addition to being extremely smooth as desired, resists water penetration when subjected to water or high humidity conditions. The resulting panel is receptive to adhesives for purposes of securing overlaying materials such as vinyl, reduces formaldehyde emissions when a panel formed of the resin which emits formaldehydes is surface treated.
    • 生产纤维素颗粒如木屑的表面复合板的方法涉及将聚合物形成可发泡材料施加到面板的第一和第二主表面中的至少一个上,使所述第一和第二表面中的至少一个接触 具有压力施加表面以施加压力的表面,在施加压力的同时使聚合物形成发泡材料,并固化所施加的泡沫材料,以在面板上产生具有期望表面的聚合物涂层,其通常非常光滑。 一个或两个表面可以以这种方式进行表面处理。 认为在面板表面上形成的皮肤增加了面板上涂层的强度和刚度。 可以使用各种发泡系统来完成该表面处理。 通过避免打磨表面处理的面板,皮肤保持原样。 除了根据需要非常光滑之外,所得到的面板在经受水或高湿度条件时抗水渗透。 所得到的面板接受粘合剂,以便确保覆盖材料例如乙烯基,当由发出甲醛的树脂形成的面板进行表面处理时,减少甲醛释放。