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1. 发明授权

US07553460B2 Process and apparatus for cracking hydrocarbon feedstock containing resid to improve vapor yield from vapor/liquid separation 有权
标题翻译：用于裂化含有渣油的烃原料以提高蒸气/液体分离产物的方法和装置
公开(公告)号：US07553460B2
公开(公告)日：2009-06-30
申请号：US11713505
申请日：2007-03-02
申请人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. Dinicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
发明人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. Dinicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
IPC分类号： B01J10/00 , B01J23/90 , B01J19/00
CPC分类号： C10G9/00 , C10G2400/20
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent. The process comprises at least two of the following conditions: (1) maintaining the bottoms under conditions to effect at least partial visbreaking; (2) reducing or eliminating partial vapor condensation during flashing by adding a heated vaporous diluent to dilute and superheat the vapor; (3) partially condensing the vapor within said flash/separation vessel by contacting with a condenser; (4) decoking internal surfaces and associated piping of the flash/separation vessel with air and steam; (5) utilizing a flash/separation vessel having an annular, inverted L-shaped baffle; and (6) regulating temperature in furnace tube banks used for heating by utilizing a desuperheater and/or an economizer. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，并冷却产物流出物。该方法包括以下条件中的至少两个：（1）在至少部分减粘裂化的条件下保持底部物质; （2）通过添加加热的蒸气稀释剂来稀释和过热蒸气来减少或消除闪蒸过程中的部分蒸气冷凝; （3）通过与冷凝器接触来部分冷凝所述闪蒸/分离容器内的蒸气; （4）用空气和蒸汽去除闪蒸/分离容器的内表面和相关管道; （5）利用具有环形的倒L形挡板的闪光/分离容器; 和（6）通过利用过热降温器和/或节能器来调节用于加热的炉管组中的温度。还提供了一种用于执行该过程的装置。

2. 发明授权

US07220887B2 Process and apparatus for cracking hydrocarbon feedstock containing resid 有权
公开(公告)号：US07220887B2
公开(公告)日：2007-05-22
申请号：US10851486
申请日：2004-05-21
申请人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
发明人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
IPC分类号： C07C4/04
CPC分类号： C10G51/06 , C10G9/00 , C10G9/007 , C10G9/36
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the bottoms are maintained under conditions to effect at least partial visbreaking. The visbroken bottoms may be steam stripped to recover the visbroken molecules while avoiding entrainment of the bottoms liquid. An apparatus for carrying out the process is also provided.

3. 发明授权

US07193123B2 Process and apparatus for cracking hydrocarbon feedstock containing resid to improve vapor yield from vapor/liquid separation 有权
标题翻译：用于裂化含有渣油的烃原料以提高蒸气/液体分离产物的方法和装置
公开(公告)号：US07193123B2
公开(公告)日：2007-03-20
申请号：US11134148
申请日：2005-05-20
申请人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. DiNicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
发明人： Richard C. Stell , Jennifer L. Bancroft , Arthur R. DiNicolantonio , Subramanian Annamalai , James N. McCoy , Paul F. Keusenkothen , George Stephens , John R. Messinger , James Mitchell Frye , Nick G. Vidonic , George J. Balinsky
IPC分类号： C07C4/04 , C07C4/02
CPC分类号： C10G9/00 , C10G2400/20
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent. The process comprises at least two of the following conditions: (1) maintaining the bottoms under conditions to effect at least partial visbreaking; (2) reducing or eliminating partial vapor condensation during flashing by adding a heated vaporous diluent to dilute and superheat the vapor; (3) partially condensing the vapor within said flash/separation vessel by contacting with a condenser; (4) decoking internal surfaces and associated piping of the flash/separation vessel with air and steam; (5) utilizing a flash/separation vessel having an annular, inverted L-shaped baffle; and (6) regulating temperature in furnace tube banks used for heating by utilizing a desuperheater and/or an economizer. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，并冷却产物流出物。该方法包括以下条件中的至少两个：（1）在至少部分减粘裂化的条件下保持底部物质; （2）通过添加加热的蒸气稀释剂来稀释和过热蒸气来减少或消除闪蒸过程中的部分蒸气冷凝; （3）通过与冷凝器接触来部分冷凝所述闪蒸/分离容器内的蒸气; （4）用空气和蒸汽去除闪蒸/分离容器的内表面和相关管道; （5）利用具有环形的倒L形挡板的闪光/分离容器; 和（6）通过利用过热降温器和/或节能器来调节用于加热的炉管组中的温度。还提供了一种用于执行该过程的装置。

4. 发明授权

US07588737B2 Process and apparatus for cracking hydrocarbon feedstock containing resid 有权
标题翻译：含有渣油的烃原料裂解方法和装置
公开(公告)号：US07588737B2
公开(公告)日：2009-09-15
申请号：US11522137
申请日：2006-09-15
申请人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
发明人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
IPC分类号： B01J10/00 , C07C4/02
CPC分类号： C10G51/06 , C10G9/00 , C10G9/007 , C10G9/36
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the bottoms are maintained under conditions to effect at least partial visbreaking. The visbroken bottoms may be steam stripped to recover the visbroken molecules while avoiding entrainment of the bottoms liquid. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，以及冷却产物流出物，其中底部保持在至少部分减粘裂化的条件下。脱硫塔底物可以蒸汽汽提以回收分解的分子，同时避免夹带底部液体。还提供了一种用于执行该过程的装置。

5. 发明授权

US07993435B2 Process and apparatus for cracking hydrocarbon feedstock containing resid 有权
标题翻译：含有渣油的烃原料裂解方法和装置
公开(公告)号：US07993435B2
公开(公告)日：2011-08-09
申请号：US11521961
申请日：2006-09-15
申请人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
发明人： Richard C. Stell , George J. Balinsky , James N. McCoy , Paul F. Keusenkothen
IPC分类号： B01D47/00 , B01D3/00 , B01D3/06 , B01D3/08 , B01D3/10 , B01D3/28 , B01D3/34 , B01D3/38 , C10G7/00 , C10G7/02 , F28C3/06
CPC分类号： C10G51/06 , C10G9/00 , C10G9/007 , C10G9/36
摘要： A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent, wherein the bottoms are maintained under conditions to effect at least partial visbreaking. The visbroken bottoms may be steam stripped to recover the visbroken molecules while avoiding entrainment of the bottoms liquid. An apparatus for carrying out the process is also provided.
摘要翻译：一种用于裂化含有渣油的烃原料的方法，包括：加热原料，将加热的原料与流体和/或初级稀释蒸汽流混合以形成混合物，使混合物闪蒸形成气相和液相，并除去液相，分离和裂化气相，以及冷却产物流出物，其中底部保持在至少部分减粘裂化的条件下。脱硫塔底物可以蒸汽汽提以回收分解的分子，同时避免夹带底部液体。还提供了一种用于执行该过程的装置。

6. 发明申请

US20130156656A1 Integrated Process For Steam Cracking 有权
标题翻译：蒸汽裂解综合工艺
公开(公告)号：US20130156656A1
公开(公告)日：2013-06-20
申请号：US13768640
申请日：2013-02-15
申请人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. Dinicolantonio , John J. Waldrop
发明人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. Dinicolantonio , John J. Waldrop
IPC分类号： B01J10/00
CPC分类号： B01J10/005 , C10B55/00 , C10B55/10 , C10G9/005 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker™, visbreaker and catalytic hydrovisbreaker) where at least 30 wt % of the vacuum resid is converted to material boiling below 1050° F. (566° C.); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt % olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
摘要翻译：本发明涉及一种用于裂化含有真空渣油的烃原料的方法和系统，该方法和系统包括：（a）在热转化反应器（例如延迟焦化器，流体焦化器，Flexicoker TM，减粘裂化器和催化脱硫剂），其中至少30重量％的真空渣油转化成沸点低于1050°F（566℃）的材料; （b）将所述热转化残渣引入蒸汽/液体分离器，所述分离器整合成蒸汽裂解炉，形成气相和液相; （c）将所述气相通过所述蒸汽裂解炉中的辐射炉; 和（d）从离开辐射炉的材料（基于离开辐射炉的总烃材料的重量）回收至少30重量％的烯烃。

7. 发明申请

US20120006723A1 Integrated Process For Steam Cracking 有权
标题翻译：蒸汽裂解综合工艺
公开(公告)号：US20120006723A1
公开(公告)日：2012-01-12
申请号：US12833556
申请日：2010-07-09
申请人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. Dinicolantonio , John J. Waldrop
发明人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. Dinicolantonio , John J. Waldrop
IPC分类号： C10B55/00 , B01J8/08 , B01J8/00
CPC分类号： B01J10/005 , C10B55/00 , C10B55/10 , C10G9/005 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker™, visbreaker and catalytic hydrovisbreaker) where at least 30 wt % of the vacuum resid is converted to material boiling below 1050° F. (566° C.); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt % olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
摘要翻译：本发明涉及一种用于裂化含有真空渣油的烃原料的方法和系统，该方法和系统包括：（a）在热转化反应器（例如延迟焦化器，流体焦化器，Flexicoker TM，减粘裂化器和催化脱硫剂）中对真空渣油进行第一热转化），其中至少30重量％的真空渣油转化成沸点低于1050°F（566℃）的材料; （b）将所述热转化残渣引入蒸汽/液体分离器，所述分离器整合成蒸汽裂解炉，形成气相和液相; （c）将所述气相通过所述蒸汽裂解炉中的辐射炉; 和（d）从离开辐射炉的材料（基于离开辐射炉的总烃材料的重量）回收至少30重量％的烯烃。

8. 发明授权

US08399729B2 Integrated process for steam cracking 有权
标题翻译：蒸汽开裂综合工艺
公开(公告)号：US08399729B2
公开(公告)日：2013-03-19
申请号：US12833556
申请日：2010-07-09
申请人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. DiNicolantonio , John J. Waldrop
发明人： S. Mark Davis , Richard C. Stell , Jiunn-Shyan Liou , Stephen H. Brown , Paul F. Keusenkothen , Arthur R. DiNicolantonio , John J. Waldrop
IPC分类号： C07C4/04
CPC分类号： B01J10/005 , C10B55/00 , C10B55/10 , C10G9/005 , C10G9/007 , C10G9/36 , C10G51/023 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： This invention relates to a process and system for cracking hydrocarbon feedstock containing vacuum resid comprising: (a) subjecting a vacuum resid to a first thermal conversion in a thermal conversion reactor (such as delayed coker, fluid coker, Flexicoker™, visbreaker and catalytic hydrovisbreaker) where at least 30 wt % of the vacuum resid is converted to material boiling below 1050° F. (566° C.); (b) introducing said thermally converted resid to a vapor/liquid separator, said separator being integrated into a steam cracking furnace, to form a vapor phase and liquid phase; (c) passing said vapor phase to the radiant furnace in said steam cracking furnace; and (d) recovering at least 30 wt % olefins from the material exiting the radiant furnace (based upon the weight of the total hydrocarbon material exiting the radiant furnace).
摘要翻译：本发明涉及一种用于裂化含有真空渣油的烃原料的方法和系统，该方法和系统包括：（a）在热转化反应器（例如延迟焦化器，流体焦化器，Flexicoker TM，减粘裂化器和催化脱硫剂）中对真空渣油进行第一热转化），其中至少30重量％的真空渣油转化成沸点低于1050°F（566℃）的材料; （b）将所述热转化残渣引入蒸汽/液体分离器，所述分离器整合成蒸汽裂解炉，形成气相和液相; （c）将所述气相通过所述蒸汽裂解炉中的辐射炉; 和（d）从离开辐射炉的材料（基于离开辐射炉的总烃材料的重量）回收至少30重量％的烯烃。

9. 发明申请

US20110180456A1 Integrated Process and System for Steam Cracking and Catalytic Hydrovisbreaking with Catalyst Recycle 审中-公开
标题翻译：用催化剂回收利用蒸汽裂解和催化加氢脱硫的综合工艺和系统
公开(公告)号：US20110180456A1
公开(公告)日：2011-07-28
申请号：US12692222
申请日：2010-01-22
申请人： Stephen Mark Davis , Paul F. Keusenkothen , Jonathan Martin Mcconnachie , Larry L. Iaccino , Richard C. Stell
发明人： Stephen Mark Davis , Paul F. Keusenkothen , Jonathan Martin Mcconnachie , Larry L. Iaccino , Richard C. Stell
IPC分类号： C10G65/10 , B01J8/00
CPC分类号： C10G47/06 , C10G45/60 , C10G69/06 , C10G2300/302
摘要： This invention relates to a process for cracking hydrocarbon feedstock containing resid comprising: (a) heating a hydrocarbon feedstock containing resid; (b) adding molecular hydrogen to said heated feedstock to form a mixture stream; (c) adding a catalyst containing metal-sulfide particles to said heated feedstock and/or said mixture stream; (d) reacting said mixture in a catalytic hydrovisbreaking reactor under conditions of temperature, pressure and residence time sufficient to catalytically hydrovisbreak at least a portion of said resid into hydrovisbroken hydrocarbon components; (e) passing said reacted mixture stream into a high pressure separator and separating hydrogen from said reacted mixture; (f) passing said reacted mixture through a knockout drum to remove catalyst and unreacted or uncracked resid as a bottoms stream; and (g) passing said catalytically hydrovisbroken hydrocarbon components into a steam cracking furnace and thermally cracking said hydrocarbon components to form light olefins, alternately the knockout drum of step (f) is integrated into the steam cracking furnace of step (g).
摘要翻译：本发明涉及一种用于裂化含有残渣的烃原料的方法，包括：（a）加热含有渣油的烃原料; （b）向所述加热的原料中加入分子氢以形成混合物流; （c）向所述加热的原料和/或所述混合物流中加入含有金属硫化物颗粒的催化剂; （d）使所述混合物在催化加氢脱硫反应器中在温度，压力和停留时间的条件下反应，足以将至少一部分所述残余物催化裂解成含水分解烃组分; （e）使所述反应的混合物流进入高压分离器并从所述反应的混合物中分离氢; （f）使所述反应的混合物通过敲除鼓以除去作为塔底物流的催化剂和未反应或未裂化的残渣; 和（g）将所述催化氢裂解烃组分通入蒸汽裂解炉中并热裂化所述烃组分以形成轻质烯烃，或者将步骤（f）的脱模鼓整合到步骤（g）的蒸汽裂解炉中。

10. 发明授权

US08083931B2 Upgrading of tar using POX/coker 有权
标题翻译：使用POX /焦化器升级焦油
公开(公告)号：US08083931B2
公开(公告)日：2011-12-27
申请号：US11881063
申请日：2007-07-25
申请人： James N. McCoy , Paul F. Keusenkothen , Alok Srivastava , James E Graham
发明人： James N. McCoy , Paul F. Keusenkothen , Alok Srivastava , James E Graham
IPC分类号： C10G57/00 , C10G27/04
CPC分类号： C10G51/023 , C10G55/04
摘要： The invention is directed to a process wherein a feedstock or stream comprising steam cracker tar is passed to a vacuum pipestill. A deasphalted cut of tar is obtained as an overhead (or sidestream) and a heavy tar asphaltenic product is obtained as bottoms. In preferred embodiments, at least a portion of the bottoms product is sent to a partial oxidation unit (POX) wherein syn gas may be obtained as a product, and/or at least a portion of the bottoms product is used to produce a light product stream in a coker unit, such as coker naphtha and/or or coker gas oil. In another preferred embodiment at least a portion of the overheads product is added to refinery fuel oil pools and in yet another preferred embodiment at least a portion of the overheads product is mixed with locally combusted materials to lower soot make. Two or more of the aforementioned preferred embodiments may be combined.
摘要翻译：本发明涉及一种方法，其中将包含蒸汽裂解焦油的原料或料流送入真空管道。作为塔顶（或侧流）获得焦油的脱沥青馏分，并且作为底部获得重质焦油沥青产物。在优选的实施方案中，将底部产物的至少一部分送至部分氧化单元（POX），其中可以获得产物的合成气，和/或至少部分底部产物用于生产轻质产物在焦化装置中，例如焦化石脑油和/或焦化瓦斯油。在另一个优选的实施方案中，将至少一部分塔顶馏出产物加入到炼油厂燃料油池中，在另一个优选的实施方案中，塔顶产物的至少一部分与局部燃烧的材料混合以降低烟灰。上述优选实施例中的两个或更多个可以组合。

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