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1. 发明授权

US5454974A Halobenzene liquid crystals 失效
标题翻译：卤代苯液晶
公开(公告)号：US5454974A
公开(公告)日：1995-10-03
申请号：US178180
申请日：1994-01-06
申请人： Arthur Boller , Richard Buchecker , Martin Schadt , Alois Villiger
发明人： Arthur Boller , Richard Buchecker , Martin Schadt , Alois Villiger
IPC分类号： C07C17/00 , C07C17/26 , C07C25/24 , C07C41/00 , C07C43/188 , C07C43/192 , C07C43/225 , C07C67/00 , C07C69/75 , C07C69/753 , C07C69/76 , C07C69/773 , C07C69/92 , C07C69/94 , C07C255/46 , C07D213/26 , C07D213/65 , C07D239/26 , C07D239/28 , C07D241/12 , C07D241/14 , C07D317/18 , C07D319/06 , C07D319/16 , C09K19/12 , C09K19/14 , C09K19/20 , C09K19/30 , C09K19/34 , G02F1/13
CPC分类号： C07D239/26 , C07C255/46 , C07C43/188 , C07C43/192 , C07C43/225 , C07D239/28 , C07D319/06 , C07D319/16 , C09K19/2007 , C09K19/3001 , C09K19/3402 , C09K19/3469 , C07C2101/14 , C09K2019/3422
摘要： Compounds of the formula ##STR1## wherein X.sup.1 denotes fluorine or chlorine and X.sup.2 denotes hydrogen, fluorine or chlorine; R.sup.1 is 3E-alkenyl, 4-alkenyl, 2E-alkenyloxy or 3-alkenyloxy; n stands for the number 0 or 1; one of the groups Y.sup.1 and Y.sup.2 is a single covalent bond, --COO--, --OOC--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O-- or --OCH.sub.2 -- and the other of the groups Y.sup.1 and Y.sup.2 is a single covalent bond; and rings A.sup.1 and A.sup.2 each individually are substituted or unsubstituted trans-1,4-cyclohexylene, in which optionally 2 non-adjacent CH.sub.2 groups are replaced by oxygen, or substituted or unsubstituted 1,4-phenylene, in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen; with the proviso that X.sup.2 denotes fluorine or chlorine and/or Y.sup.1 or Y.sup.2 denotes --CH.sub.2 O-- or --OCH.sub.2 -- when simultaneously X.sup.1 is fluorine and R.sup.1 is 3E-alkenyl,and their use for liquid crystalline mixtures and electro-optical purposes.
摘要翻译：式（Ⅰ）化合物其中X1表示氟或氯，X2表示氢，氟或氯; R1是3E-链烯基，4-烯基，2E-烯氧基或3-烯氧基; n代表数字0或1; Y1和Y2中的一个是单个共价键，-COO-，-OOC-，-CH 2 CH 2 - ， - CH 2 O-或-OCH 2 - ，而Y1和Y2中的另一个是单个共价键; 和环A1和A2各自各自为取代或未取代的反式-1,4-亚环己基，其中任选的两个不相邻的CH 2基团被氧取代，或取代或未取代的1,4-亚苯基，其中任选地1个CH基团或 2个CH基团被氮取代; 条件是当X 1是氟并且R 1是3E-烯基时，X 2表示氟或氯和/或Y 1或Y 2表示-CH 2 O-或-OCH 2 - ，并且它们用于液晶混合物和电光目的。

2. 发明授权

US5413734A 4-cyano-3-fluorophenyl esters 失效
标题翻译： 4-氰基-3-氟苯基酯
公开(公告)号：US5413734A
公开(公告)日：1995-05-09
申请号：US250393
申请日：1994-05-27
申请人： Richard Buchecker , Martin Schadt
发明人： Richard Buchecker , Martin Schadt
IPC分类号： C07C255/55 , C07D239/26 , C07D319/06 , C09K19/20 , C09K19/30 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , C09K19/06
CPC分类号： C07D239/26 , C07C255/55 , C07D319/06 , C09K19/3068 , C09K19/3402 , C09K19/3469 , C09K19/42 , C09K19/46 , C09K2019/3422
摘要： Compounds of the formula ##STR1## wherein ring A is trans-1,4-cyclohexylene, 1,4-phenylene, pyrimidine-2,5-diyl or trans-1,3-dioxane-2,5-diyl; n is either 0 or 1; ring B stands for 1,4-phenylene or trans-1,4-cyclohexylene; and R.sup.1 is 3E-alkenyl or on a saturated ring also 1E-alkenyl, their manufacture, liquid crystalline mixtures which contain these compounds as well as their use for electro-optical purposes.
摘要翻译：式A的化合物其中环A是反式-1,4-亚环己基，1,4-亚苯基，嘧啶-2,5-二基或反式-1,3-二恶烷-2,5-二基; n为0或1; 环B代表1,4-亚苯基或反式-1,4-亚环己基; 并且R 1是3E-烯基或在饱和环上也是1E-烯基，它们的制造，含有这些化合物的液晶混合物以及它们用于电光目的。

3. 发明授权

US5335303A Quasi-phased matched optical waveguide frequency conversion element having a ferroelectric liquid crystalline material exhibiting a periodic structure 失效
标题翻译：具有表现出周期性结构的铁电液晶材料的准相位匹配光波导变换元件
公开(公告)号：US5335303A
公开(公告)日：1994-08-02
申请号：US102676
申请日：1993-08-05
申请人： Richard Buchecker , Xin H. Chen , Jurg Funfschilling , Rolf-Peter Herr , Martin Schadt , Klaus Schmitt
发明人： Richard Buchecker , Xin H. Chen , Jurg Funfschilling , Rolf-Peter Herr , Martin Schadt , Klaus Schmitt
IPC分类号： G02F1/35 , C07C229/34 , C07C229/56 , C07C229/64 , C07D239/26 , C08F12/26 , C08F16/28 , C08F18/22 , C08F20/36 , C09K3/00 , G02F1/141 , G02F1/355 , G02F1/361 , G02F1/37 , G02F1/377 , H01S3/109 , H03F7/00
CPC分类号： C07D239/26 , C07C229/64 , G02F1/3775 , G02F1/141 , G02F2001/3548
摘要： An optical frequency conversion element has a wave-guiding layer which consists of a .chi..sup.(2) -active ferroelectric liquid crystal. The monomeric or polymeric liquid crystal material has a periodic structure which permits the so-called quasi phase matching of a guided laser beam. The period length of the structure is equal to twice the coherence length l.sub.c =.pi./.DELTA..beta. of the material, whereby .DELTA..beta.=.beta..sub.o (2.omega.)-2.beta..sub.o (.omega.), with .omega.=angular frequency of the fundamental wave, 0=zero-order mode and .beta.=propagation constant of the mode.
摘要翻译：光变换元件具有由chi（2）活性铁电液晶构成的波导层。单体或聚合物液晶材料具有允许引导的激光束的所谓的准相位匹配的周期性结构。结构的周期长度等于材料的相干长度lc = pi / DELTAβ的两倍，其中ΔTA=ω（2ω）-2βo（ω），ω=基波的角频率，0 =零阶模式，β=模式的传播常数。

4. 发明授权

US5326497A Nitrogen heterocycles and liquid crystalline mixtures containing them 失效
标题翻译：含氮杂环和含有它们的液晶混合物
公开(公告)号：US5326497A
公开(公告)日：1994-07-05
申请号：US955633
申请日：1992-10-02
申请人： Richard Buchecker , Stephen Kelly , Martin Schadt
发明人： Richard Buchecker , Stephen Kelly , Martin Schadt
IPC分类号： C07D213/65 , C07D239/36 , C09K19/34 , G02F1/13 , C09K19/30 , C07D213/62 , C07D239/02 , C09K19/12
CPC分类号： C09K19/3469 , C09K19/3444
摘要： Compounds of the general formula ##STR1## wherein R.sup.1 is C.sub.5-12 -alkyl or C.sub.5-12 -alkenyl;R.sup.2 is C.sub.1-9 -alkyl or C.sub.2-9 -alkenyl; provided that at least one of groups R.sup.1 and R.sup.2 is alkenyl;X is a CH group or nitrogen;n is either 0 or 1;q is a whole number between 2 to 6 inclusive;r is either 0 or 1 provided that the sum of q and r at least 3,s is either 0 or 1; andp is either 1 or 2, provided that n is zero when p is 2;mixtures which contain these compounds as well as the use of these compounds for electro-optical purposes.
摘要翻译：其中R 1为C 5-12烷基或C 5-12链烯基的通式为其的化合物 R2是C1-9 - 烷基或C2-9 - 烯基; 基团R1和R2中的至少一个是烯基; X是CH基或氮; n为0或1; q是2到6之间的整数; r为0或1，条件是q和r之和至少为3，s为0或1; 并且p为1或2，条件是当p为2时n为零; 含有这些化合物的混合物以及这些化合物用于电光目的。

5. 发明授权

US5082589A Liquid crystalline esters 失效
标题翻译：液晶酯
公开(公告)号：US5082589A
公开(公告)日：1992-01-21
申请号：US485710
申请日：1990-02-27
申请人： Richard Buchecker , Hans-Jurgen Fromm , Stephen Kelly , Martin Schadt
发明人： Richard Buchecker , Hans-Jurgen Fromm , Stephen Kelly , Martin Schadt
IPC分类号： C07C69/773 , C09K19/30
CPC分类号： C07C255/00 , C09K19/3068
摘要： Compounds of the formula ##STR1## wherein m represents is the number of 0 to 1; A is a single convalent bond, --CH.sub.2 --CH.sub.2 --, --OCH.sub.2 --, --COO-- or --OOC--; rings B, C and D are 1,4-phenylene optionally substituted with cyano, halogen or lower alkyl; Y.sup.1 and Y.sup.2 are hydrogen or one of them also is cyano; and R.sup.1 and R.sup.2 each represents C.sub.1 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 alkenyl, either of which is optionally halogen-substituted, in which one CH.sub.2 group or two non-adjacent CH.sub.2 groups is/are optionally replaced by oxygen: with the provisos that at least one of R.sup.1 and R.sup.2 has a chiral carbon atom or R.sup.1 is straight-chain C.sub.4-18 -alkoxy and R.sup.2 is straight C.sub.3-18 -alkyl or a C--C double bond or both when A is --COO-- and at least one of R.sup.1 and R.sup.2 has a C--C double bond when A is a single covalent bond, their preparation, liquid crystalline mixtures containing these compounds and their use for electro-optical purposes are described.
摘要翻译：式（Ⅰ）化合物其中m表示0至1的数; A是单个共价键，-CH 2 -CH 2 - ， - OCH 2 - ， - COO-或-OOC-; 环B，C和D是任选被氰基，卤素或低级烷基取代的1,4-亚苯基; Y1和Y2是氢或其中之一也是氰基; 并且R 1和R 2各自表示任选被卤素取代的C 1 -C 18 - 烷基或C 2 -C 18烯基，其中一个CH 2基团或两个不相邻的CH 2基团任选被氧取代：条件是 R 1和R 2中的至少一个具有手性碳原子，或者R 1是直链C 4-18 - 烷氧基，并且R 2是直链C 3-8 - 烷基或CC双键，或者当A是-COO-时，当A是单一共价键时，R1和R2具有CC双键，其制备，含有这些化合物的液晶混合物及其用于电光目的的用途。

6. 发明授权

US5486310A Liquid crystalline mixtures having a chiral tilted smectic phase 失效
标题翻译：具有手性倾斜近晶相的液晶混合物
公开(公告)号：US5486310A
公开(公告)日：1996-01-23
申请号：US198669
申请日：1994-02-18
申请人： Richard Buchecker , Nina I. Chernova , Alexander V. Ivaschenko , Marina V. Loseva , Olga S. Petrashevich , Evgeniy P. Pozhidaev , Arnold Z. Rabinovich , Martin Schadt
发明人： Richard Buchecker , Nina I. Chernova , Alexander V. Ivaschenko , Marina V. Loseva , Olga S. Petrashevich , Evgeniy P. Pozhidaev , Arnold Z. Rabinovich , Martin Schadt
IPC分类号： C09K19/12 , C09K19/20 , C09K19/34 , C07C69/76 , C02F1/13
CPC分类号： C09K19/3441 , C09K19/126 , C09K19/2028
摘要： Optically active compounds of the formula ##STR1## wherein rings A, B and C each independently are unsubstituted or each are 1,4-phenylene substituted with at least one of halogen-, cyano-, methyl- or methoxy in which optionally 1 CH group or 2 CH groups is/are replaced by nitrogen; R.sup.1 is a radical of an optically active terpene alcohol after cleavage of the hydroxy group or a group --(CH.sub.2).sub.m --C*HX.sup.1 --R.sup.3 ; R.sup.2 is a radical of an optically active terpene alcohol after cleavage of the hydroxy group or a group --(CH.sub.2).sub.n --C*HX.sup.2 --R.sup.4 ; m and n each independently stand for the number 0 or 1: C* denotes a chiral carbon atom; X.sup.1 and X.sup.2 each independently are fluorine, chlorine, cyano, methyl or methoxy; R.sup.3 and R.sup.4 each independently denote a group R, phenyl or phenyl substituted with R, with the proviso that R.sup.3 is different from X.sup.1 and R.sup.4 is different from X.sup.2 ; R is an alkyl group in which optionally one methylene group is replaced by oxygen and/or optionally one group CH--CH is replaced by a group C.dbd.C; with the proviso that R.sup.1 and R.sup.2 are not simultaneously 2-alkyl when rings A, B and C together are p-terphenyl,as well as liquid crystalline mixtures and their use for electro-optical purposes.
摘要翻译：式I的光学活性化合物其中环A，B和C各自独立地是未取代的或各自是被至少一个卤素，氰基，甲基或甲氧基取代的1,4-亚苯基，其中任选地1个CH 基团或2个CH基团被氮取代; R1是羟基或 - （CH2）m-C * HX1-R3基团裂解后的光学活性萜烯醇基团; R2是羟基或 - （CH2）n-C * HX2-R4基团裂解后的光学活性萜烯醇基团; m和n各自独立代表数字0或1：C *表示手性碳原子; X1和X2各自独立地为氟，氯，氰基，甲基或甲氧基; R3和R4各自独立地表示基团R，苯基或被R取代的苯基，条件是R3不同于X1，R4不同于X2; R是一个烷基，其中任选的一个亚甲基被氧代替，和/或任选一个CH-CH被C = C组取代; 条件是当环A，B和C一起是对三联苯时，R1和R2不同时为2-烷基，以及液晶混合物及其用于电光目的。

7. 发明授权

US5327273A Bistable ferroelectric liquid crystal display cell 失效
标题翻译：双稳态铁电液晶显示单元
公开(公告)号：US5327273A
公开(公告)日：1994-07-05
申请号：US46468
申请日：1993-04-12
申请人： Leonid A. Beresnev , Richard Buchecker , Nina I. Chernova , Vladimir G. Chigrinov , Jurg Funfschilling , Marina V. Loseva , Yury P. Panarin , Fvgeniy P. Pozhidaev , Martin Schadt
发明人： Leonid A. Beresnev , Richard Buchecker , Nina I. Chernova , Vladimir G. Chigrinov , Jurg Funfschilling , Marina V. Loseva , Yury P. Panarin , Fvgeniy P. Pozhidaev , Martin Schadt
IPC分类号： C09K19/02 , C09K19/58 , G02F1/13
CPC分类号： C09K19/588 , C09K19/0225 , C09K19/58
摘要： A bistable ferroelectric liquid crystal display cell utilizes two plates, a chiral ferroelectric smectic liquid crystal sandwiched between the plates, and an electrode for applying an electrical field to the plates. The chiral ferroelectric smectic liquid crystal has a structure which is influenced by the action of an electric field so that its optical anisotropy changes. By using a first polarizer connected to one of the plates and a second polarizer connected to the other plate, the unique bistable ferroelectric display produces dark parallel stripes when the polarizers are in a cross position relative to each other.
摘要翻译：双稳态铁电液晶显示元件利用夹在板之间的两个板，手征铁电晶界液晶和用于向板施加电场的电极。手性铁电层状液晶具有受电场作用影响的结构，使得其光学各向异性发生变化。通过使用连接到其中一个板的第一偏振器和连接到另一个板的第二偏振器，当偏振器相对于彼此处于交叉位置时，独特的双稳态铁电显示器产生暗的平行条纹。

8. 发明授权

US4830470A Liquid crystalline esters 失效
标题翻译：液晶酯
公开(公告)号：US4830470A
公开(公告)日：1989-05-16
申请号：US52659
申请日：1987-05-20
申请人： Richard Buchecker , Hans-Jurgen Fromm , Stephen Kelly , Martin Schadt
发明人： Richard Buchecker , Hans-Jurgen Fromm , Stephen Kelly , Martin Schadt
IPC分类号： C07C69/76 , C07C67/00 , C07C67/08 , C07C69/773 , C07C69/90 , C07C69/92 , C07C69/94 , C07C253/00 , C07C253/30 , C07C255/46 , C07C255/49 , C07C255/53 , C07C255/55 , C07C255/57 , C09K19/20 , C09K19/30 , G02F1/13
CPC分类号： C07C255/00 , C09K19/3068
摘要： Compounds of the formula ##STR1## wherein m represents is the number 0 or 1; A is a single covalent bond, --CH.sub.2 --CH.sub.2 --, --OCH.sub.2 --, --COO-- or --OOC--; rings B, C and D are 1,4-phenylene optionally substituted with cyano, halogen or lower alkyl; Y.sup.1 and Y.sup.2 are hydrogen or one of them also is cyano; and R.sup.1 and R.sup.2 each represents C.sub.1 -C.sub.18 -alkyl or C.sub.2 -C.sub.18 alkenyl, either of which is optionally halogen-substituted, in which one CH.sub.2 group or two non-adjacent CH.sub.2 groups is/are optionally replaced by oxygen; with the provisos that at least one of R.sup.1 and R.sup.2 has a chiral carbon atom or a C--C double bond or both when A is --COO-- and at least one of R.sup.1 and R.sup.2 has a C--C double bond when A is a single covalent bond, their preparation, liquid crystalline mixtures containing these compounds and their use for electro-optical purposes are described.
摘要翻译：式（Ⅰ）化合物其中m代表0或1; A是单个共价键，-CH 2 -CH 2 - ， - OCH 2 - ， - COO-或-OOC-; 环B，C和D是任选被氰基，卤素或低级烷基取代的1,4-亚苯基; Y1和Y2是氢或其中之一也是氰基; 并且R 1和R 2各自表示任选被卤素取代的C 1 -C 18 - 烷基或C 2 -C 18烯基，其中一个CH 2基团或两个不相邻的CH 2基团任选被氧代替; 条件是当A是-COO-时，R 1和R 2中的至少一个具有手性碳原子或CC双键，当A是单个共价键时，R 1和R 2中的至少一个具有CC双键，描述了它们的制备方法，含有这些化合物的液晶混合物及其用于电光学目的的用途。

9. 发明授权

US5478497A Tetracyclic compounds and liquid crystalline mixtures containing them 失效
标题翻译：四环化合物和含有它们的液晶混合物
公开(公告)号：US5478497A
公开(公告)日：1995-12-26
申请号：US383698
申请日：1995-02-01
申请人： Richard Buchecker , Martin Schadt , Alois Villiger
发明人： Richard Buchecker , Martin Schadt , Alois Villiger
IPC分类号： C07C69/75 , C07C13/28 , C07C25/18 , C07C43/174 , C07C69/94 , C07C255/50 , C07D213/26 , C07D213/30 , C07D239/26 , C07D319/06 , C09K19/30 , C09K19/34 , C09K19/42 , G02F1/13
CPC分类号： C07D239/26 , C07C25/18 , C07C43/1747 , C07D319/06 , C09K19/3003 , C09K19/3028 , C09K19/3402 , C09K19/3441 , C09K19/3444 , C09K19/3469 , C07C2101/14 , C09K2019/327 , C09K2019/3422
摘要： Compounds of the formula ##STR1## wherein rings A, B and C, Z.sup.1, Z.sup.2, Z.sup.3, R.sup.1, R.sup.2 and R.sup.3 are defined in the specification, their manufacture, liquid crystalline mixtures which contain such compounds and the use of these compounds for electro-optical purposes.
摘要翻译：其中环A，B和C，Z 1，Z 2，Z 3，R 1，R 2和R 3在本说明书中定义，其制备，含有这些化合物的液晶混合物以及这些化合物用于电光目的。

10. 发明授权

US5399689A Chlorophenylalkoxyalkyl compounds 失效
标题翻译：氯苯基烷氧基烷基化合物
公开(公告)号：US5399689A
公开(公告)日：1995-03-21
申请号：US17353
申请日：1993-02-11
申请人： Richard Buchecker , Martin Schadt , Haruyoshi Takatsu
发明人： Richard Buchecker , Martin Schadt , Haruyoshi Takatsu
IPC分类号： C07C43/174 , C07C43/176 , C07D239/26 , C07D309/06 , C07D319/06 , C07D405/12 , C09K19/12 , C09K19/30 , C09K19/34 , C09K19/42 , C09K19/44 , G02F1/13 , C07C43/168 , C07D241/12 , C07D403/06
CPC分类号： C07D239/26 , C07C43/1742 , C07C43/1747 , C07C43/176 , C07D309/06 , C09K19/12 , C09K19/3003 , C09K19/3402 , C09K19/3444 , C09K19/3469 , C07C2101/14 , C09K2019/3422
摘要： The present invention is concerned with novel chlorophenylalkoxyalkyl compounds of the general formula ##STR1## wherein R denotes an alkyl residue with 1 to 12 carbon atoms; n is a whole number of 2 to 7, ring A denotes trans-1,4-cyclohexylene or 1,4-phenylene; m is either 0 or 1; ring B is trans-1,4-cyclohexylene, 1,4-phenylene in which optionally one CH group or two non-adjacent CH groups is/are replaced by nitrogen or, when m stands for 1, also trans-1,3-dioxane-2,5-diyl; Y.sup.1 and Y.sup.2 each independently represent a single covalent bond or --CH.sub.2 CH.sub.2 --; and X denotes hydrogen, fluorine or chlorine, their manufacture, liquid crystalline mixtures which contain these compounds, their production and use for electro-optical purposes.
摘要翻译：本发明涉及通式“IMAGE”I的新型氯苯基烷氧基烷基化合物，其中R表示具有1至12个碳原子的烷基; n为2〜7的整数，环A为反式-1,4-亚环己基或1,4-亚苯基; m为0或1; 环B是反式-1,4-亚环己基，其中任选一个CH基团或两个不相邻的CH基团被1,4-亚苯基取代，或者当m代表1时，也可以是反式-1,3- 二恶烷-2,5-二基; Y1和Y2各自独立地表示单个共价键或-CH2CH2-; X表示氢，氟或氯，它们的制造，含有这些化合物的液晶混合物，它们的生产和用于电光目的。

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