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1. 发明授权

US06632909B2 Photocrosslinkable polymers 有权
标题翻译：可光交联聚合物
公开(公告)号：US06632909B2
公开(公告)日：2003-10-14
申请号：US09915574
申请日：2001-07-27
申请人： Richard Buchecker , Guy Marck , Andreas Schuster , Hubert Seiberle
发明人： Richard Buchecker , Guy Marck , Andreas Schuster , Hubert Seiberle
IPC分类号： C08F2210
CPC分类号： C08F246/00 , C08F2220/305 , C08F2220/365 , C09K19/3852 , G02F1/133711 , G02F1/133788
摘要： The present invention relates to polymers of the general formula I: in which M1, M1′, M2 denote a recurring monomer unit from the group: acrylate, methacrylate, 2-chloroacrylate, 2-phenylacrylate; w, w1, w2 are molar fractions of the comonomers with 0
摘要翻译：本发明涉及通式I的聚合物：其中 M <1 ，M <1> > <2 表示从丙烯酸酯，甲基丙烯酸酯，2-氯丙烯酸酯，2-苯基丙烯酸酯组成的重复单体单元; <2 是具有0 1 <1 AND 0＆LE; W 2 <= 0.5; S <1 和S <1' 彼此独立地表示直线 - 链或支链亚烷基 - （CH 2 ） D，D'独立地彼此独立地表示-O - ; X，X'，Y，Y'彼此独立地表示氢;彼此独立地表示氢; A，A'，B，B'表示亚苯基 C，C'是未取代的或任选被氟，氯，氰基，烷基，烷氧基或氟代烷氧基取代的苯基; K和K'彼此独立地表示氢，氟，氯，氰基; P / XT> Z，Z'，Z <1 ，Z <1' 彼此独立地表示单个共价键 t 表示1至4的整数; u表示1至3的整数; p，p'，n，n'彼此独立地表示0或1.本发明还涉及上述聚合物作为液晶的取向层及其在光学中的应用的用途组件。

2. 发明授权

US07514514B2 Photoactive copolymer 有权
标题翻译：光活性共聚物
公开(公告)号：US07514514B2
公开(公告)日：2009-04-07
申请号：US10451995
申请日：2001-12-28
申请人： Richard Buchecker , Guy Marck , Olivier Muller , Hubert Seiberle , Andreas Schuster
发明人： Richard Buchecker , Guy Marck , Olivier Muller , Hubert Seiberle , Andreas Schuster
IPC分类号： C08F120/54
CPC分类号： C08F246/00 , G02F1/133788
摘要： A novel photoactive copolymer and its use as orientation layers for liquid crystals and in the construction of unstructured and structured optical elements and multilayer systems. The copolymer contains side chains incorporating photoreactive groups and simultaneously side chains of general formula (I) wherein the total number of rings, including the number of rings in optionally present condensed systems is at least two and at most six; wherein the broken line symbolizes the point of linkage to the polymer main chain; and wherein the variables are defined in the disclosure.
摘要翻译：一种新型光敏共聚物及其作为液晶的取向层以及非结构化和结构化光学元件和多层体系的构建。该共聚物含有包含光反应基团和同时为通式（I）的侧链的侧链，其中环的总数，包括任选存在的缩合体系中的环数是至少2和至多6; 其中虚线表示与聚合物主链的连接点; 并且其中变量在本公开中被定义。

3. 发明授权

US06277502B1 Photocrosslinkable silane derivatives 失效
标题翻译：光可交联硅烷衍生物
公开(公告)号：US06277502B1
公开(公告)日：2001-08-21
申请号：US09016376
申请日：1998-01-30
申请人： Richard Buchecker , Guy Marck , Hubert Seiberle
发明人： Richard Buchecker , Guy Marck , Hubert Seiberle
IPC分类号： B32B900
CPC分类号： G02F1/133719 , C07F7/12 , C07F7/1804 , C09K19/406
摘要： The invention relates to novel crosslinkable, photoactive silane derivatives of the formula I mixtures of silane derivatives of the formula I and mixtures of silane derivatives of the formula I with uncrosslinkable silane derivatives as usually used for silanizing inorganic, oxide-containing surfaces. The invention furthermore relates to the use of silane derivatives of the formula I and of mixtures which contain at least one silane derivative of the formula I as orientation layers for liquid crystals and for the production of unstructured or structured optical elements and multilayer systems.
摘要翻译：本发明涉及新型的交联性光活性硅烷衍生物，其具有式I的硅烷衍生物和式I的硅烷衍生物与通常用于硅烷化无机，含氧化物的表面的不可交联的硅烷衍生物的混合物。本发明还涉及使用式I的硅烷衍生物和含有至少一种式I的硅烷衍生物的混合物作为液晶的取向层和用于生产非结构化或结构化的光学元件和多层体系的混合物。

4. 发明授权

US08557922B2 Photocrosslinkable materials 有权
标题翻译：光交联材料
公开(公告)号：US08557922B2
公开(公告)日：2013-10-15
申请号：US13616287
申请日：2012-09-14
申请人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
发明人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
IPC分类号： C08F14/18
CPC分类号： C08G73/10 , C07C69/92 , C07C205/42 , C07C205/57 , C07C205/59 , C07C219/32 , C07C229/60 , C07C229/64 , C08F2/46 , C09K19/0403 , C09K19/2007 , C09K19/2014 , C09K19/38 , C09K2019/0407 , G02F1/133723 , G02F1/133788 , Y10T428/10 , Y10T428/3154
摘要： A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.
摘要翻译：提出式（I）的二胺化合物以及基于这种化合物的聚合物，共聚物，聚酰胺酸，聚酰胺酸酯或聚酰亚胺。

5. 发明申请

US20100059709A1 PATTERNABLE LIQUID CRYSTAL POLYMER COMPRISING THIO-ETHER UNITS 有权
标题翻译：包含THIO-ETHER单位的方形液晶聚合物
公开(公告)号：US20100059709A1
公开(公告)日：2010-03-11
申请号：US12515918
申请日：2007-12-11
申请人： Thomas Bachels , Izabela Bury , Guy Marck , Hubert Seiberle , Peggy Studer , Stefano Tugulu
发明人： Thomas Bachels , Izabela Bury , Guy Marck , Hubert Seiberle , Peggy Studer , Stefano Tugulu
IPC分类号： C08G75/02 , C09K19/38
CPC分类号： C09K19/3804 , C09K19/38 , C09K19/54 , C09K2019/0448 , C09K2219/03
摘要： The present invention relates to a photo-polymerized, patterned or unpatterned liquid crystal polymer, especially a liquid crystal polymer film or a liquid crystal polymer network, comprising thio-ether units of formula (I) * covalent bond, which links the unit of formula (I) to the residue of the polymer wherein LC1 is selected from the group of liquid crystal residues, X1 is selected from the group of aliphatic organic residues, and n1 is an integer ≧0 and m1 is an integer ≧0; with the proviso that if n1 is 0, then m1 is >0, and if m1 is 0, then n1>0; which is prepared in an atmosphere containing oxygen, preferably with an amount of 0.1≦oxygen 50%, more preferably 1≦oxygen≦25%, most preferably in air; with the proviso that polymer dispersed liquid crystals are excluded. Further, this invention relates to a composition used for the preparation of that photo-polymerized liquid crystal polymer of the invention, to processes of the preparation of that liquid crystal polymer and to its use.
摘要翻译：本发明涉及光聚合，图案化或未图案化的液晶聚合物，特别是液晶聚合物膜或液晶聚合物网络，其包含式（I）*共价键的硫醚单元，其将式（I）所示的聚合物残基，其中LC1选自液晶残基，X1选自脂族有机残基，n1为整数≥0，m1为整数≥0; 条件是如果n1为0，则m1> 0，如果m1为0，则n1> 0; 其在含有氧气的气氛中制备，优选为0.1＆lt; NlE;氧气50％，更优选1＆amp; NlE;氧气＆amp; 25％，最优选在空气中; 条件是排除聚合物分散的液晶。此外，本发明涉及用于制备本发明的光聚合液晶聚合物的组合物，该液晶聚合物的制备方法及其用途。

6. 发明授权

US08574454B2 Patternable liquid crystal polymer comprising thio-ether units 有权
标题翻译：包含硫醚单元的可成形液晶聚合物
公开(公告)号：US08574454B2
公开(公告)日：2013-11-05
申请号：US12515918
申请日：2007-12-11
申请人： Thomas Bachels , Izabela Bury , Guy Marck , Hubert Seiberle , Peggy Studer , Stefano Tugulu
发明人： Thomas Bachels , Izabela Bury , Guy Marck , Hubert Seiberle , Peggy Studer , Stefano Tugulu
IPC分类号： C09K19/52 , C09K19/06 , C09K19/00 , G02F1/1333 , C08G75/04
CPC分类号： C09K19/3804 , C09K19/38 , C09K19/54 , C09K2019/0448 , C09K2219/03
摘要： The present invention relates to a photo-polymerized, patterned or unpatterned liquid crystal polymer, especially a liquid crystal polymer film or a liquid crystal polymer network, comprising thio-ether units of formula (I) * covalent bond, which links the unit of formula (I) to the residue of the polymer wherein LC1 is selected from the group of liquid crystal residues, X1 is selected from the group of aliphatic organic residues, and n1 is an integer ≧0 and m1 is an integer ≧0; with the proviso that if n1 is 0, then m1 is >0, and if m1 is 0, then n1>0; which is prepared in an atmosphere containing oxygen, preferably with an amount of 0.1≦oxygen≦50%, more preferably 1≦oxygen≦25%, most preferably in air; with the proviso that polymer dispersed liquid crystals are excluded. Further, this invention relates to a composition used for the preparation of that photo-polymerized liquid crystal polymer of the invention, to processes of the preparation of that liquid crystal polymer and to its use.
摘要翻译：本发明涉及光聚合，图案化或未图案化的液晶聚合物，特别是液晶聚合物膜或液晶聚合物网络，其包含式（I）*共价键的硫醚单元，其将式（I）所示的聚合物的残基，其中LC1选自液晶残基，X1选自脂族有机残基，n1为整数> = 0，m1为整数> = 0; 条件是如果n1为0，则m1> 0，如果m1为0，则n1> 0; 其在含有氧气的气氛中制备，优选以25％的0.1％氧气，更优选25％的氧气，最优选在空气中制备; 条件是排除聚合物分散的液晶。此外，本发明涉及用于制备本发明的光聚合液晶聚合物的组合物，该液晶聚合物的制备方法及其用途。

7. 发明授权

US08173749B2 Photocrosslinkable materials 有权
标题翻译：光交联材料
公开(公告)号：US08173749B2
公开(公告)日：2012-05-08
申请号：US12096719
申请日：2006-12-19
申请人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
发明人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
IPC分类号： C08F14/18
CPC分类号： C08G73/10 , C07C69/92 , C07C205/42 , C07C205/57 , C07C205/59 , C07C219/32 , C07C229/60 , C07C229/64 , C08F2/46 , C09K19/0403 , C09K19/2007 , C09K19/2014 , C09K19/38 , C09K2019/0407 , G02F1/133723 , G02F1/133788 , Y10T428/10 , Y10T428/3154
摘要： A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.
摘要翻译：提出式（I）的二胺化合物以及基于这种化合物的聚合物，共聚物，聚酰胺酸，聚酰胺酸酯或聚酰亚胺。

8. 发明授权

US07491752B2 Photoactive materials 有权
标题翻译：光敏材料
公开(公告)号：US07491752B2
公开(公告)日：2009-02-17
申请号：US10484260
申请日：2002-07-15
申请人： Guy Marck , Hubert Seiberle , Mohammed Ibn-Elhaj
发明人： Guy Marck , Hubert Seiberle , Mohammed Ibn-Elhaj
IPC分类号： C08F2/46 , C08J3/28 , C09K11/06 , C09K19/00 , C09K17/18
CPC分类号： C08F246/00 , G02F1/133788 , Y10S522/904 , Y10T428/10 , Y10T428/1005 , Y10T428/1018 , Y10T428/1023 , Y10T428/31504
摘要： Photoreactive dendrimers comprising a core portion, branching units and terminal groups, wherein at least one terminal group and/or branching unit is a photoreactive group and wherein the photo reactive groups include preferably cinnamates, coumarins, benzylidenephthalimidines, benzylideneacetophenones, diphenylacetylenes stilbazoles, uracyl, quinolinone, maleinimides, or cinnamylidene acetic acid derivatives and are able to undergo photocyclization, in particular [2+2]-photocyclization.
摘要翻译：光反应性树枝状聚合物，其包含核心部分，支化单元和末端基团，其中至少一个末端基团和/或支化单元是光反应性基团，并且其中所述光反应性基团优选包括肉桂酸酯，香豆素，亚苄基邻苯二甲酰亚胺，亚苄基苯乙酮，二苯基乙炔茋，尿嘧啶，喹啉酮，马来酰亚胺或肉桂亚乙酸衍生物，并且能够进行光环化，特别是[2 + 2] - 光环化。

9. 发明授权

US06649230B1 Photoactive polymers 有权
标题翻译：光活性聚合物
公开(公告)号：US06649230B1
公开(公告)日：2003-11-18
申请号：US09958043
申请日：2001-10-03
申请人： Hubert Seiberle , Guy Marck , Olivier Muller
发明人： Hubert Seiberle , Guy Marck , Olivier Muller
IPC分类号： C08F24600
CPC分类号： C08F246/00 , G02F1/133711 , G02F1/133723 , G02F1/133788 , Y10T428/1005 , Y10T428/1014 , Y10T428/1018 , Y10T428/1023 , Y10T428/1027
摘要： A photoactive polymer of the general formula I: in which: P is a photoactive group which can photoisomerise and/or photodimerise; B represents an aromatic or alicyclic group, or B further represents a nitrogen atom or —CR2—; A, C, D each independently of the other represents an aromatic or alicyclic group; M represents a repeating monomer unit in a homo- or copolymer; S1, S2, S3, S4, S5 represent a single covalent bond or a spacer unit; n1, n2 are each independently a positive integer up to 2 with the proviso that n1+n2≦2; R1 is a hydrogen atom, or a straight-chain or branched alkyl residue wherein R2 represents a hydrogen atom or lower alkyl. The photoactive polymers may be used as orientation layers for liquid crystals and in the construction of unstructured and structured optical elements and multi-layer systems.
摘要翻译：一种通式I的光敏聚合物，其中：P是可以光异构化和/或光二聚的光敏基团; B代表芳族或脂环族基团，或B进一步代表氮原子或-CR 2 - ; A， C，D各自独立地表示芳族或脂环族基团; M表示均聚物或共聚物中的重复单体单元; S 1，S 2，S 3，S 4， 5>表示单个共价键或间隔单元; n 1，n 2各自独立地为直至2的正整数，条件是n 1 + n 2 = 2; R 1 >是氢原子，或其中R 2表示氢原子或低级烷基的直链或支链烷基残基。光活性聚合物可用作液晶的取向层，以及在非结构化和结构化的光学元件的结构中和多层系统。

10. 发明授权

US08329823B2 Photocrosslinkable materials 有权
公开(公告)号：US08329823B2
公开(公告)日：2012-12-11
申请号：US13308879
申请日：2011-12-01
申请人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
发明人： Thomas Bachels , Zoubair Mohammed Cherkaoui , Guy Marck , Olivier Muller , Joachim Reichardt , Andreas Schuster , Hubert Seiberle , Peggy Studer , Thomas Peglow , Jean-Francois Eckert
IPC分类号： C08F14/18
CPC分类号： C08G73/10 , C07C69/92 , C07C205/42 , C07C205/57 , C07C205/59 , C07C219/32 , C07C229/60 , C07C229/64 , C08F2/46 , C09K19/0403 , C09K19/2007 , C09K19/2014 , C09K19/38 , C09K2019/0407 , G02F1/133723 , G02F1/133788 , Y10T428/10 , Y10T428/3154
摘要： A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.

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