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    • 1. 发明申请
    • AMINOPHOSPHINATE POLYMERS
    • 氨基磷酸酯聚合物
    • WO2006032896A1
    • 2006-03-30
    • PCT/GB2005/003658
    • 2005-09-22
    • RHODIA UK LIMITEDOTTER, GrahamZAFAR, ShaziaWOODWARD, Gary
    • OTTER, GrahamZAFAR, ShaziaWOODWARD, Gary
    • C08G79/04C08L85/02
    • C08G79/04C09D185/02
    • The present invention provides an aminophosphinate mid functional co-polymer, or oligomer thereof, a method for its manufacture and a number of applications for it. The aminophosphinate co-polymer is of the formula (I): (A) a -[PO(OX)CR’ 2 NR(R’’NR) m CR’ 2 -] n PO(OX)-(A) b ; wherein: X is hydrogen or any suitable cation; each of the R groups, which may be the same or different, and each of the R’ groups, which may be the same or different, is hydrogen, an optionally substituted alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or alkoxyalkyl group of 1-20 carbon atoms each of which may be optionally substituted once or more than once, R’’ is an alkane group, substituted alkane group or heterocyclic group; and wherein A is derived from any suitable monomer, a and b are the same and each is an integer from 1 to 1000 or a and b are different and one is zero or an integer from 1 to 1000 and the other is an integer from 1 to 1000, m is zero or from 1 to 100, and n is zero or from 1 to 100.
    • 本发明提供氨基膦酸酯中间官能共聚物或其低聚物,其制备方法和多种应用。 氨基磷酸酯共聚物具有式(I):(A)a - [PO(OX)CR'2 NR(R“NR) 米 CR' 2 - ] 名词 PO(OX) - (A) b'/ SUB>; 其中:X是氢或任何合适的阳离子; 可以相同或不同的R基团中的每一个和可以相同或不同的R'基团各自为氢,任选取代的烷基,环烷基,烯基,芳基,芳烷基,烷芳基或烷氧基烷基 1-20个碳原子,每个碳原子可以任选被一次或多于一次取代,R“是烷烃基,取代的烷烃基或杂环基; 并且其中A衍生自任何合适的单体,a和b相同,并且各自为1至1000的整数或a和b不同,1为0或1至1000的整数,而另一个为1的整数 至1000,m为0或1至100,n为0或1至100。
    • 3. 发明授权
    • AMINOPHOSPHINATE POLYMERS
    • 氨基膦酸酯聚合物
    • EP1791893B1
    • 2009-11-04
    • EP05790835.2
    • 2005-09-22
    • Rhodia UK Limited
    • OTTER, GrahamZAFAR, ShaziaWOODWARD, Gary
    • C08G79/04C08L85/02
    • C08G79/04C09D185/02
    • The present invention provides an aminophosphinate mid functional co-polymer, or oligomer thereof, a method for its manufacture and a number of applications for it. The aminophosphinate co-polymer is of the formula (I): (A) a -[PO(OX)CR' 2 NR(R''NR) m CR' 2 -] n PO(OX)-(A) b ; wherein: X is hydrogen or any suitable cation; each of the R groups, which may be the same or different, and each of the R' groups, which may be the same or different, is hydrogen, an optionally substituted alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or alkoxyalkyl group of 1-20 carbon atoms each of which may be optionally substituted once or more than once, R'' is an alkane group, substituted alkane group or heterocyclic group; and wherein A is derived from any suitable monomer, a and b are the same and each is an integer from 1 to 1000 or a and b are different and one is zero or an integer from 1 to 1000 and the other is an integer from 1 to 1000, m is zero or from 1 to 100, and n is zero or from 1 to 100.
    • 本发明提供氨基次膦酸盐中间体官能共聚物或其低聚物,其制备方法及其许多应用。 氨基次膦酸盐共聚物具有式(I):(A)a- [PO(OX)CR'2NR(R'NR)mCR'2-] nPO(OX) - (A)b; 其中:X是氢或任何合适的阳离子; 每个R基团可以相同或不同,并且每个R'基团可以相同或不同,为氢,任选取代的烷基,环烷基,烯基,芳基,芳烷基,烷芳基或烷氧烷基 1-20个碳原子,其中每个可任选被取代一次或多次,R“是链烷基,取代的烷烃基或杂环基; 并且其中A衍生自任何合适的单体,a和b相同并且各自为1至1000的整数或a和b不同且一个为零或1至1000的整数且另一个为1的整数 至1000,m是0或1至100,并且n是0或1至100。
    • 4. 发明公开
    • AMINOPHOSPHINATE POLYMERS
    • 氨基膦酸酯聚合物
    • EP1791893A1
    • 2007-06-06
    • EP05790835.2
    • 2005-09-22
    • Rhodia UK Limited
    • OTTER, GrahamZAFAR, ShaziaWOODWARD, Gary
    • C08G79/04C08L85/02
    • C08G79/04C09D185/02
    • The present invention provides an aminophosphinate mid functional co-polymer, or oligomer thereof, a method for its manufacture and a number of applications for it. The aminophosphinate co-polymer is of the formula (I): (A)a-[PO(OX)CR’2NR(R’’NR)mCR’2-]nPO(OX)-(A)b; wherein: X is hydrogen or any suitable cation; each of the R groups, which may be the same or different, and each of the R’ groups, which may be the same or different, is hydrogen, an optionally substituted alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or alkoxyalkyl group of 1-20 carbon atoms each of which may be optionally substituted once or more than once, R’’ is an alkane group, substituted alkane group or heterocyclic group; and wherein A is derived from any suitable monomer, a and b are the same and each is an integer from 1 to 1000 or a and b are different and one is zero or an integer from 1 to 1000 and the other is an integer from 1 to 1000, m is zero or from 1 to 100, and n is zero or from 1 to 100.
    • 本发明提供氨基次膦酸盐中间体官能共聚物或其低聚物,其制备方法及其许多应用。 氨基次膦酸盐共聚物具有式(I):(A)a- [PO(OX)CR'2NR(R'NR)mCR'2-] nPO(OX) - (A)b; 其中:X是氢或任何合适的阳离子; 每个R基团可以相同或不同,并且每个R'基团可以相同或不同,为氢,任选取代的烷基,环烷基,烯基,芳基,芳烷基,烷芳基或烷氧烷基 1-20个碳原子,其中每个可任选被取代一次或多次,R“是链烷基,取代的烷烃基或杂环基; 并且其中A衍生自任何合适的单体,a和b相同并且各自为1至1000的整数或a和b不同且一个为零或1至1000的整数且另一个为1的整数 至1000,m是0或1至100,并且n是0或1至100。
    • 5. 发明公开
    • MONODONOR PHOSPHONITE LIGANDS
    • EP1763399A1
    • 2007-03-21
    • EP05757629.0
    • 2005-07-04
    • Rhodia UK Limited
    • DOCHERTY, Gordon, FindlayWOODWARD, GaryWILLS, MartinXU, Yingjian
    • B01J31/18C07F9/6571
    • B01J31/1865
    • The invention provides the use of a metal complex, which is a complex of one or more metal atoms or ions with one or more ligands, as a catalyst in an organic transformation selected from hydrogenation of carbon-­heteroatom double bonds, hydroformylation, dialkylzinc additions to aldehydes, hydrocarboxylation, allylic substitution, oxidation, epoxidation, dihydroxylation, Diels-Alder cycloadditions, dipolar cycloadditions and rearrangement reactions, wherein one or more of the ligands is a ligand of formula (1), wherein the bridge group is an organic functional group, and the R group is a substituted phenyl group, wherein the R group has only one substituent at the ortho position, and wherein a carbon atom of the R group bonds the R group to the P atom. Also provided are monodonor ligands of formula (1) wherein the bridge group is an unsubstituted or substituted binaphthyl group and the R group is a substituted phenyl group, wherein the substituents are selected from halogen, nitro, alkynyl and sulfonic acid groups and unsubstituted or substituted alkyl, aryl, amino and vinyl groups, and wherein the R group has only one substituent at the ortho position, and wherein a carbon atom of the R group bonds the R group to the P atom.
    • 本发明提供了一种金属络合物作为催化剂在选自碳 - 杂原子双键的氢化,加氢甲酰化,二烷基锌加成至二氧化钛的有机转化中作为催化剂的用途,所述金属络合物是一种或多种金属原子或离子与一种或多种配体的络合物 其中一个或多个配体是式(1)的配体,其中所述桥基是有机官能团,其中所述桥基是有机官能团,其中所述桥基是有机官能团, 并且R基团是取代的苯基,其中R基团在邻位上仅具有一个取代基,并且其中R基团的碳原子将R基团键合到P原子上。 还提供了式(1)的单元配体,其中桥基为未取代或取代的联萘基,且R基为取代的苯基,其中取代基选自卤素,硝基,炔基和磺酸基,以及未取代或取代的 烷基,芳基,氨基和乙烯基,并且其中R基团在邻位上只有一个取代基,并且其中R基团的碳原子将R基团键合到P原子上。