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1. 发明授权

US4204981A Supported catalysts for the homo- and co-polymerization of .alpha.-olefines 失效
标题翻译：用于α-烯烃的均聚和共聚的负载型催化剂
公开(公告)号：US4204981A
公开(公告)日：1980-05-27
申请号：US947229
申请日：1978-09-29
申请人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi
发明人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi
IPC分类号： C08F4/62 , C08F10/00 , C08F4/02 , C08F4/64
CPC分类号： C08F10/00 , C08F2410/04
摘要： Ziegler catalytic system for the polymerization of olefins, formed by the combination of an organo-metallic compound and a compound of a heavy metal supported on a carrier.The carrier is an active complex obtained by reacting one or more alloys of metals chosen from Mg, Fe, Al, Ni, Cr and Zn, gaseous hydrogen chloride and one or more alcohols in the liquid or gaseous state, at a temperature of from 60.degree. to 300.degree. C., the said active complex having a content of free alcoholic hydroxyl groups of from 1 to 20% by weight, a chlorine content of from 15 to 70% by weight, a metal content of from 5 to 35% by weight, a porosity of from 0.1 to 1 cc/g and a surface area of from 1 to 200 m.sup.2 /g.
摘要翻译：用于烯烃聚合的齐格勒催化体系，通过有机金属化合物和负载在载体上的重金属化合物的组合形成。载体是通过使一种或多种选自Mg，Fe，Al，Ni，Cr和Zn的金属合金，气态氯化氢和一种或多种液体或气态的醇在60℃的温度下反应而获得的活性配合物将所述活性配合物的游离醇羟基含量为1至20重量％，氯含量为15至70重量％，金属含量为5至35质量％重量，0.1至1cc / g的孔隙率和1至200m 2 / g的表面积。

2. 发明授权

US4142990A Ziegler catalysts 失效
标题翻译： ZIEGLER催化剂
公开(公告)号：US4142990A
公开(公告)日：1979-03-06
申请号：US840184
申请日：1977-10-06
申请人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
发明人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
IPC分类号： C08F4/00 , C08F4/60 , C08F4/62 , C08F10/00 , C08F4/02 , C08F4/64
CPC分类号： C08F10/00
摘要： Ziegler catalytic system comprising an organo-metallic compound of a metal of Groups I to III of the Periodic Table and a compound of a heavy metal of Groups IV to VI supported on a carrier, the latter being an activated amorphous alumina or alumino-silicate containing from 0.3 to 30% by weight of salts of aluminum with oxygenated inorganic anions, or of a mixture of the latter with salts of aluminum with non-oxygenated inorganic anions, said inorganic anions being introduced into the amorphous alumina or alumino-silicate by contacting the latter with one or more acid solutions of the inorganic anions and the carrier being then activated by calcination at 250.degree. - 700.degree. C.

3. 发明授权

US4421674A Supported catalysts for the polymerization of ethylene 失效
标题翻译：用于乙烯聚合的负载催化剂
公开(公告)号：US4421674A
公开(公告)日：1983-12-20
申请号：US376727
申请日：1982-05-10
申请人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi , Roberto Catenacci
发明人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi , Roberto Catenacci
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/64 , C08F4/654 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00
摘要： A process for the preparation of a catalyst which is highly active in the polymerization of gaseous ethylene is described the process comprising the steps of spray drying an ethanolic solution of MgCl.sub.2 to obtain MgCl.sub.2 particles of from 3 to 100 microns in size and with a residual alcoholic OH-groups content of from 1.5% to 20% by wt., the MgCl.sub.2 in said particles having an X-ray spectrum with a maximum peak at 10.8 angstrom, reacting said particles with a titanium halide in liquid or vapor phase and mixing the obtained reaction product with an alkylaluminium or an alkylaluminium halide in such amount to obtain an atomic ratio Al:Ti of from 100:1 to 5,000:1.
摘要翻译：描述了一种制备在气态乙烯聚合中具有高活性的催化剂的方法，该方法包括以下步骤：喷雾干燥MgCl 2的乙醇溶液，得到尺寸为3至100微米的MgCl 2颗粒和残留的酒精 OH基含量为1.5％至20％重量，所述颗粒中的MgCl 2具有在10.8埃处具有最大峰的X射线光谱，使所述颗粒与液体或气相中的卤化钛反应，并将所得到的反应产物与烷基铝或卤化烷基卤化铝的反应产物的量为100：1至5,000：1的原子比Al:Ti。

4. 发明授权

US4196097A Ziegler catalysts 失效
标题翻译：齐格勒催化剂
公开(公告)号：US4196097A
公开(公告)日：1980-04-01
申请号：US839958
申请日：1977-10-06
申请人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
发明人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
IPC分类号： C08F4/60 , C08F4/62 , C08F10/00 , C08F4/02
CPC分类号： C08F10/00
摘要： A Ziegler catalytic system comprising an organometallic compound of a metal of Groups I to III of the Periodic Table and a compound of a heavy metal of Groups IV to VI supported on a carrier, the latter being an activated amorphous alumina or alumino-silicate containing from 0.3 to 30% by weight of salts of metals of Groups IIb, IIIa, VIb and VIII with oxygenated inorganic anions, or of a mixture of the latter with salts of said metals of Groups IIb, IIIa, VIb and VIII with non-oxygenated inorganic anions, said salts being introduced into the carrier by contacting the latter with one or more solutions of said salts and the carrier being then activated by calcination at 250.degree.-700.degree. C.
摘要翻译：齐格勒催化体系，其包含元素周期表第I至III族金属的有机金属化合物和负载在载体上的第Ⅳ至Ⅵ族重金属的化合物，后者是活化的无定形氧化铝或铝硅酸盐，其含有 0.3至30重量％的IIb，IIIa，VIb和VIII族金属与含氧无机阴离子的盐，或后者与IIb，IIIa，VIb和VIII族金属的盐与无氧无机阴离子的盐阴离子，所述盐通过使所述盐与所述盐的一种或多种溶液接触而引入载体中，然后通过在250-700℃下煅烧使载体活化。

5. 发明授权

US4347162A Catalyst for the polymerization of alpha-olefins 失效
标题翻译： α-烯烃聚合催化剂
公开(公告)号：US4347162A
公开(公告)日：1982-08-31
申请号：US241288
申请日：1981-03-06
申请人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi , Roberto Catenacci
发明人： Renzo Invernizzi , Ferdinando Ligorati , Maurizio Fontanesi , Roberto Catenacci
IPC分类号： C08F4/60 , C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： Ziegler catalytic system formed of an organometallic compound of a metal of Group I, II or III of the Periodic System in combination with a transition metal compound supported on a carrier.The carrier is prepared by reacting magnesium chloride with an aliphatic alcohol and a fluorine-containing compound at 100.degree.-200.degree. C. to obtain an active complex comprising 2-15 wt. % of fluorine and 0.4-11 wt. % of alcoholic hydroxyl groups.The catalytic system may be used for the polymerization of alpha-olefins.
摘要翻译：齐格勒催化体系由元素周期系I，II或III族金属的有机金属化合物与负载在载体上的过渡金属化合物组合形成。载体是通过在100-200℃下使氯化镁与脂族醇和含氟化合物反应制得的，得到包含2-15wt。氟的百分比和0.4-11重量％％的醇羟基。催化体系可用于α-烯烃的聚合。

6. 发明授权

US4506027A Method of preparing a supported Ziegler-catalyst for the polymerization of alpha-olefins 失效
标题翻译：制备用于α-烯烃聚合的负载齐格勒催化剂的方法
公开(公告)号：US4506027A
公开(公告)日：1985-03-19
申请号：US550422
申请日：1983-11-10
申请人： Renzo Invernizzi , Ferdinando Ligorati
发明人： Renzo Invernizzi , Ferdinando Ligorati
IPC分类号： C08F4/00 , C08F4/02 , C08F4/60 , C08F4/62 , C08F4/64 , C08F10/00 , C08F10/02
CPC分类号： C08F10/00 , Y10S526/904
摘要： Method of preparing a supported Ziegler-catalyst active in the polymerization of alpha-olefins to polymers particularly suited to working by blow-moulding, by reacting:(A) an organometallic compound of aluminium, and(B) the product of the reaction of titanium and vanadium halides with a solid support obtained by the spray drying of magnesium chloride in a mixed solution of ethanol and methanol, the support containing both ethanolic and methanolic alcoholic hydroxyl groups.
摘要翻译：通过使（A）铝的有机金属化合物和（B）钛的反应产物反应，制备在α-烯烃聚合中活性的负载的齐格勒 - 催化剂的方法，特别适用于通过吹塑加工和通过在乙醇和甲醇的混合溶液中喷雾干燥氯化镁获得的固体支持物的钒卤化物，该载体含有乙醇和甲醇的醇羟基。

7. 发明授权

US4481342A Method of preparing low-density ethylene copolymers 失效
标题翻译：制备低密度乙烯共聚物的方法
公开(公告)号：US4481342A
公开(公告)日：1984-11-06
申请号：US498370
申请日：1983-05-26
申请人： Renzo Invernizzi , Ferdinando Ligorati
发明人： Renzo Invernizzi , Ferdinando Ligorati
IPC分类号： C08F4/00 , C08F2/14 , C08F2/18 , C08F4/60 , C08F4/654 , C08F210/00 , C08F210/16 , C08F4/02 , C08F210/02
CPC分类号： C08F210/16
摘要： Method for the copolymerization of ethylene with C.sub.4 -C.sub.8 alpha-olefins by means of a suspension method in an organic liquid, at a temperature of from 50.degree. C. to 70.degree. C., at a pressure of less than about 10 bar, on a Ziegler catalyst constituted by:(a) an alkylaluminum or alkylaluminum halide;(b) the product of the reaction of a halogenated derivative of titanium with a support material; the support material being the solid, spheroidal product of the spray drying of a solution of magnesium chloride in ethanol containing at least one additional compound chosen from the following classes:aliphatic, cycloaliphatic or aromatic liquid hydrocarbons with a boiling point higher than that of ethanol at atmospheric pressure;polar, organic hydroxy or ester compounds which are solid or liquid with a boiling point higher than that of ethanol at atmospheric pressure; the solid, spheroidal, spray-dried product also having the following characteristics:particle form: spherical with a size of from 1 to 100 microns.Apparent density of the particles: from 0.1 to 1 g/ml;alcoholic hydroxyl group content: from 1.5 to 20% by weight;surface area: from 10 to 100 m.sup.2 /g;porosity from 1.2 to 3.5 ml/g;pore radius: from 1,000 to 65,000 Angstroms.
摘要翻译：乙烯与C 4 -C 8α-烯烃通过悬浮法在有机液体中，在50℃至70℃的温度，小于约10巴的压力下共聚合的方法，齐格勒催化剂由以下组成：（a）烷基铝或卤化烷基铝; （b）钛的卤化衍生物与载体材料的反应产物; 载体材料是将氯化镁在乙醇中的溶液喷雾干燥的固体，球形产物，其含有至少一种选自以下类别的另外的化合物：沸点高于乙醇的脂族，脂环族或芳族液体烃气压; 在大气压下沸点高于乙醇的固体或液体的极性有机羟基或酯化合物; 固体，球状，喷雾干燥的产品也具有以下特征：颗粒形式：具有1至100微米尺寸的球形。颗粒的表观密度：0.1至1g / ml; 醇羟基含量：1.5〜20重量％; 表面积：10〜100m2 / g; 孔隙率为1.2〜3.5ml / g; 孔半径：从1000到65000埃。

8. 发明授权

US4148755A Ziegler catalysts 失效
标题翻译：齐格勒催化剂
公开(公告)号：US4148755A
公开(公告)日：1979-04-10
申请号：US840188
申请日：1977-10-06
申请人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
发明人： Ferdinando Ligorati , Renzo Invernizzi , Carlo Collu , Maurizio Fontanesi
IPC分类号： C08F4/62 , C08F10/00 , C08F4/02 , C08F4/64
CPC分类号： C08F10/00
摘要： Ziegler catalytic system comprising an organo-metallic compound of a metal of Groups I to III of the Periodic System and a compound of a heavy metal of Groups IV to VI supported on an alumina carrier, the latter being an activated amorphous alumina containing from 0.3 to 30% by weight of salts of aluminum with oxygenated inorganic anions, or of a mixture of the latter with salts of aluminum with non-oxygenated inorganic anions, said carrier being prepared by precipitating an alumina gel at a pH value of 7-10, introducing the inorganic anions into said gel, drying said gel and calcining the resulting amorphous alumina at 250.degree.-700.degree. C.
摘要翻译：齐格勒催化体系，其包含周期性体系中第I至III族金属的有机金属化合物和负载在氧化铝载体上的第Ⅳ至Ⅵ族重金属的化合物，后者为活性无定形氧化铝，其含有0.3至 30重量％的铝与含氧无机阴离子的盐或后者与非盐氧化无机阴离子的盐的混合物，所述载体通过沉淀pH值为7-10的氧化铝凝胶制备，引入将无机阴离子进入所述凝胶，干燥所述凝胶并煅烧所得到的无定形氧化铝在250-700℃。

9. 发明授权

US5320995A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US5320995A
公开(公告)日：1994-06-14
申请号：US957512
申请日：1992-10-05
申请人： Luciano Luciani , Mario Polesello , Federico Milani , Renzo Invernizzi , Giovanni Soverini
发明人： Luciano Luciani , Mario Polesello , Federico Milani , Renzo Invernizzi , Giovanni Soverini
IPC分类号： C08F4/652 , C08F4/635 , C08F4/655 , C08F10/00 , C08F110/00
CPC分类号： C08F10/00
摘要： A catalyst for the polymerization of olefins, containing magnesium, chlorine, aluminium and at least one transition metal, in a dispersed or emulsified form within an inert diluent, is obtained by:contacting, in an inert diluent, a magnesium dialkyl and aluminium trichloride, in a molar ratio equal or almost equal to 2/1, at a temperature lower than 105.degree. C. to obtain a catalyst precursor in a suspended form, or at a temperature higher than 105.degree. C. to form a catalyst precursor in the form of a colloidal emulsion, in the diluent used; andcontacting said suspended or emulsified precursor with at least one compound of a transition metal to form a catalyst in the form of a suspension or emulsion respectively.
摘要翻译：通过在惰性稀释剂中将分散或乳化形式的含有镁，氯，铝和至少一种过渡金属的烯烃聚合的催化剂在惰性稀释剂中接触二烷基铝和三氯化铝，摩尔比等于或几乎等于2/1，在低于105℃的温度下，得到悬浮形式的催化剂前体，或在高于105℃的温度下形成催化剂前体，形式为的胶体乳液; 并使所述悬浮或乳化的前体与至少一种过渡金属化合物接触以分别形成悬浮液或乳液形式的催化剂。

10. 发明授权

US5189000A Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it 失效
标题翻译：用于烯烃不饱和化合物的聚合和共聚的支持催化剂和使用它的（CO）聚合方法
公开(公告)号：US5189000A
公开(公告)日：1993-02-23
申请号：US673272
申请日：1991-03-21
申请人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
发明人： Francesco Masi , Renzo Invernizzi , Antonio Carbonaro , Lorenzo Costa , Angelo Moalli
IPC分类号： C08F4/658 , B01J20060101 , C07F20060101 , C08F20060101 , C08F2/00 , C08F4/00 , C08F4/02 , C08F4/60 , C08F4/61 , C08F4/617 , C08F4/62 , C08F4/622 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F210/16
CPC分类号： C08F10/00
摘要： A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

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