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    • 8. 发明授权
    • Cyclohexenone oxime ether/(glyphosates/gluphosinates) suspension concentrates
    • 环己烯酮肟醚/(草甘膦/草甘膦)悬浮浓缩物
    • US06383987B1
    • 2002-05-07
    • US09868072
    • 2001-08-02
    • Jürgen von der HeydeReiner KoberMatthias BratzRainer BerghausKarl-Friedrich JägerJürgen FriesAdolf Parg
    • Jürgen von der HeydeReiner KoberMatthias BratzRainer BerghausKarl-Friedrich JägerJürgen FriesAdolf Parg
    • A01N4380
    • A01N57/20A01N2300/00
    • A substantially water-free formulation of crop protection agents, comprising essentially a) a cyclohexenone oxime ether of the formula I  where R1=ethyl, propyl; R2=hydrogen or an equivalent of an agriculturally useful cation; R3=2-(thioethyl)propyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-(methylthio)cyclopropyl, 5-(isopropyl)isoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl; R4, R5=H, CH3, CO—OCH3; Alk=CH2CH2, CH2CH(CH3), CH2CH═CH, CH2CH═C(Cl), CH2CH2CH═CH; R6=H, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy, dihalophenoxy; b) N-phosphonamethylglycine, or an ester or salt thereof, DL-homoalanin-4-yl(methyl)phosphinic acid or its ammonium salt; c) from 20 to 80% by weight of an aprotic or weakly protic solvent in which the components a) and b) are suspended; d) if desired emulsifiers, surfactants, surface-active and/or activity-enhancing auxiliaries, is described.
    • 基本上无水的作物保护剂制剂,其基本上包括式I的环己烯酮肟醚,其中R 1 =乙基,丙基; R 2 =氢或相当于农业上可用的阳离子; R 3 = 2-(硫代乙基)丙基,四氢噻喃 吡啶-3-基,四氢噻喃-4-基,四氢吡喃-3-基,四氢吡喃-4-基,1-(甲硫基)环丙基,5-(异丙基)异恶唑-3-基,2,5-二甲基吡唑-3-基 ,2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R4,R5 = H,CH3,CO-OCH3; Alk = CH2CH2,CH2CH(CH3),CH2CH = CH,CH2CH = C( Cl),CH 2 CH 2 CH = CH; R 6 = H,苯基,卤代苯基,二卤代苯氧基,苯氧基,卤代苯氧基,二卤苯氧基; b)N-膦酰基甲基甘氨酸或其酯或盐,DL-高拉蛋白-4-基(甲基)次膦酸或其 铵盐; c)20至80重量%的非质子或弱质子溶剂,其中组分a)和b)悬浮; d)如果需要,乳化剂,表面活性剂,表面活性剂和/或活性增强助剂, 被描述。