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1. 发明授权

US4746354A 4-nitro-1-phenylpyrazoles, composition containing them, and method of using them to combat unwanted vegetation 失效
标题翻译： 4-硝基-1-苯基吡唑，含有它们的组合物，以及使用它们来对付不需要的植被的方法
公开(公告)号：US4746354A
公开(公告)日：1988-05-24
申请号：US836268
申请日：1986-03-04
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Wolfgang Behrenz
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Wolfgang Behrenz
IPC分类号： A01N43/56 , C07D231/12 , C07D231/16
CPC分类号： C07D231/16
摘要： Herbicidally and insecticidally active 4-nitro-1-phenylpyrazoles of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, alkyl, cycloalkyl, hydroxyalkyl, alkoxyalkyl, alkylthioalkyl or halogenoalkyl,R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7 each independently is hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, alkylsulphinyl, alkylsulphonyl, alkoxycarbonyl, or --(X).sub.n --R.sup.8,X is oxygen, sulphur, sulphinyl or sulphonyl,n is 0 or 1, andR.sup.8 is halogenoalkyl.
摘要翻译： R1和R2各自独立地为氢，烷基，环烷基，羟基烷基，烷氧基烷基，烷硫基烷基或卤代烷基，R3，R4，R5，R6和R7各自独立地为除草和杀虫活性的4-硝基-1-苯基吡唑，或 - （X）n -R 8，X为氧，硫，亚磺酰基或磺酰基，n为0或1，并且R 8为卤代烷基，卤素，氰基，硝基，烷基，烷氧基，烷硫基，烷基亚磺酰基，烷基磺酰基，。

2. 发明授权

US4804398A 1-aryl-4-cyano-5-halogenopyrazoles, composition containing them, and method of using them as selective herbicides 失效
标题翻译： 1-芳基-4-氰基-5-卤代吡唑，含有它们的组合物，以及使用它们作为选择性除草剂的方法
公开(公告)号：US4804398A
公开(公告)日：1989-02-14
申请号：US57471
申请日：1987-06-03
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/16 , C07D231/22 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/16
摘要： Herbicidally active novel 1-phenyl-4-cyano-5-halogenopyrazoles of the formula ##STR1## in which R is hydrogen or alkyl,Hal is halogen, andAr is phenyl substituted at least once by a radical other than halogen.Intermediates of the formulas ##STR2## are also new.
摘要翻译：式“IMAGE”的除草活性新型1-苯基-4-氰基-5-卤代吡唑，其中R为氢或烷基，Hal为卤素，Ar为至少一个被卤素以外的基团取代的苯基。公式 + TR 的中间体也是新的。

3. 发明授权

US4747867A 1-aryl-4-cyano-5-halogenopyrazoles, composition containing them, and herbicidal method of using them 失效
标题翻译： 1-芳基-4-氰基-5-卤代吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4747867A
公开(公告)日：1988-05-31
申请号：US866050
申请日：1986-05-22
申请人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Uta Jensen-Korte , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/16 , C07D231/22 , C07D401/04
CPC分类号： C07D401/04 , A01N43/56 , C07D231/16
摘要： Herbicidally active 1-aryl-4-cyano-5-halogenopyrazoles of the formula ##STR1## in which R is hydrogen or alkyl,Hal is halogen, andAr is substituted phenyl or represents polysubstituted pyridyl.Intermediates of the formulas ##STR2## are also disclosed.
摘要翻译：其中R为氢或烷基，Hal为卤素，Ar为取代苯基或代表多取代吡啶基的除草活性1-芳基-4-氰基-5-卤代吡唑。还公开了公式 + TR 的中间体。

4. 发明授权

US4814001A 5-imido-pyrazole compounds, herbicidal compositions and use 失效
标题翻译： 5-亚氨基 - 吡唑化合物，除草组合物和用途
公开(公告)号：US4814001A
公开(公告)日：1989-03-21
申请号：US190603
申请日：1988-05-05
申请人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/40 , C07D401/04 , C07D401/14 , C07D403/04
CPC分类号： C07D401/04 , C07D231/40 , C07D401/14 , C07D403/04
摘要： Herbicidal and plant growth-regulating novel 5-acylamino-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl or optionally substituted cycloalkyl,Ar represents in each case optionally substituted phenyl or pyridyl,X represents oxygen or sulphur,A represents a straight-chain or branched optionally substituted alkylene bridge,n represents the numbers 0 or 1 andY represents cyano or the grouping ##STR2## wherein X.sup.1 represents oxygen or sulphur andR.sup.3 represents hydroxyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, amino, alkylamino, dialkylamino, alkenylamino, dialkenylamino, alkyl-alkenylamino or a --OM radical,whereinM represents one equivalent of the cation of an inorganic or organic base.Intermediates therefor of the formula ##STR3## are also new.
摘要翻译：除草剂和植物生长调节新型式（IMAGE）的5-酰基氨基 - 吡唑，其中R1代表氢，卤素或硝基，R2代表氢，烷基，烯基，炔基或任选取代的环烷基，Ar表示在任何情况下任选取代的苯基或吡啶基，X表示氧或硫，A表示直链或支链任选取代的亚烷基桥，n表示数字0或1，Y表示氰基或分子式，其中X1表示氧或硫，R3表示羟基，烷氧基，烯氧基，炔氧基，烷硫基，氨基，烷基氨基，二烷基氨基，烯基氨基，二烷基氨基，烷基 - 烯基氨基或-OM基团，其中M表示无机或有机碱的一当量阳离子。具有公式的中间体也是新的。

5. 发明授权

US4812165A Substituted 1-arylpyrazoles, compositions and use 失效
标题翻译：取代的1-芳基吡唑，组合物和用途
公开(公告)号：US4812165A
公开(公告)日：1989-03-14
申请号：US164673
申请日：1988-03-07
申请人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Harry Strang
发明人： Otto Schallner , Reinhold Gehring , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen , Harry Strang
IPC分类号： A01N43/56 , C07D231/40 , C07D401/04 , A01N43/40 , C07D231/16
CPC分类号： C07D401/04 , A01N43/56 , C07D231/40
摘要： Herbicidal and plant growth-regulating compounds of the formula ##STR1## in which R.sup.1 represents hydrogen or nitro,R.sup.2 represents hydrogen, alkyl or a radical ##STR2## A.sup.1 and A.sup.2 independently of each other each represent a divalent alkylene radical,Y represents halogen, hydroxyl, optionally substituted alkoxy, optionally substituted aryloxy or a radical ##STR3## R.sup.3 represents hydrogen, alkyl, alkoxy, amino, alkylamino, dialkylamino or in each case optionally substituted aryl, aryloxy or arylamino,Ar represents in each case optionally substituted phenyl or pyridyl andn represents a number 1, 2, 3 or 4.
摘要翻译：式（Ⅰ）的除草剂和植物生长调节化合物其中R 1表示氢或硝基，R 2表示氢，烷基或基团A 1和A 2彼此独立地表示二价亚烷基，Y 代表卤素，羟基，任选取代的烷氧基，任选取代的芳氧基或基团。R 3表示氢，烷基，烷氧基，氨基，烷基氨基，二烷基氨基或在各种情况下任选取代的芳基，芳氧基或芳基氨基，Ar表示在任何情况下任选取代苯基或吡啶基，n表示数字1,2,3或4。

6. 发明授权

US4772310A 5-acylamino-pyrazole derivatives, composition containing them, and their use as herbicides and plant growth 失效
标题翻译： 5-酰基氨基 - 吡唑衍生物，含有它们的组合物及其作为除草剂和植物生长的用途
公开(公告)号：US4772310A
公开(公告)日：1988-09-20
申请号：US52671
申请日：1987-05-19
申请人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Jorg Stetter , Otto Schallner , Reinhold Gehring , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/40 , C07D401/04 , C07D401/14 , C07D403/04
CPC分类号： C07D401/04 , C07D231/40 , C07D401/14 , C07D403/04
摘要： Herbicidal and plant growth-regulating novel 5-acylamino-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen, alkyl, alkenyl, alkinyl or optionally substituted cycloalkyl,Ar represents in each case optionally substituted phenyl or pyridyl,X represents oxygen or sulphur,A represents a straight-chain or branched optionally substituted alkylene bridge,n represents the numbers 0 or 1 andY represents cyano or the grouping ##STR2## wherein X.sup.1 represents oxygen or sulphur andR.sup.3 represents hydroxyl, alkoxy, alkenyloxy, alkynyloxy, alkylthio, amino, alkylamino, dialkylamino, alkenylamino, dialkenylamino, alkyl-alkenylamino or a --OM radical,wherein M represents one equivalent of the cation of an inorganic or organic base.Intermediates therefor of the formula ##STR3## are also new.
摘要翻译：除草剂和植物生长调节新型式（IMAGE）的5-酰基氨基 - 吡唑，其中R1代表氢，卤素或硝基，R2代表氢，烷基，烯基，炔基或任选取代的环烷基，Ar表示在任何情况下任选取代的苯基或吡啶基，X表示氧或硫，A表示直链或支链任选取代的亚烷基桥，n表示数字0或1，Y表示氰基或分子式，其中X1表示氧或硫，R3表示羟基，烷氧基，烯氧基，炔氧基，烷硫基，氨基，烷基氨基，二烷基氨基，烯基氨基，二烷基氨基，烷基 - 烯基氨基或-OM基团，其中M表示无机或有机碱的一当量阳离子。具有公式的中间体也是新的。

7. 发明授权

US4764202A 5-dichloroacetamido-4-nitro-1-aryl-pyrazoles, composition containing them, and herbicidal and plant growth regulating method of using them 失效
标题翻译： 5-二氯乙酰氨基-4-硝基-1-芳基吡唑，含有它们的组合物，以及使用它们的除草和植物生长调节方法
公开(公告)号：US4764202A
公开(公告)日：1988-08-16
申请号：US934067
申请日：1986-11-24
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Albrecht Marhold , Hans-Joachim Santel , Robert R. Schmidt , Klaus Lurssen
IPC分类号： A01N43/56 , C07D231/16 , C07D231/38 , C07D231/40
CPC分类号： C07C243/00 , A01N43/56 , C07D231/38 , C07D231/40
摘要： 5-Dichloracetamido-4-nitro-1-aryl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, fluorine, chlorine or bromine,R.sup.2 represents hydrogen, fluorine or chlorine,R.sup.3 represents halogen, halogenoalkyl, halogenoalkoxy, halogenoalkylthio or halogenoalkylsulphonyl,R.sup.4 represents hydrogen, fluorine, or chlorine, andR.sup.5 represents fluorine, chlorine or bromine, but in the case in which R.sup.1 and R.sup.5 simultaneously represent chlorine and in addition R.sup.2 and R.sup.4 simultaneously represent hydrogen, R.sup.3 does not represent chlorine or trifluoromethyl,exhibit herbicidal and plant growth-regulating properties. Novel intermediates therefor are also shown.
摘要翻译：其中R 1表示氢，氟，氯或溴，R 2表示氢，氟或氯，R 3表示卤素，卤代烷基，卤代烷氧基，卤代烷硫基或卤代烷基磺酰基的5-二氯乙酰氨基-4-硝基-1-芳基吡唑，R4代表氢，氟或氯，R5代表氟，氯或溴，但在R1和R5同时代表氯的情况下，R2和R4同时代表氢，R3不代表氯或三氟甲基，除草和植物生长调节性质。还显示了其新型中间体。

8. 发明授权

US4758673A 1-aryl-5-halopyrazoles 失效
标题翻译： 1-芳基-5- halopyrazoles
公开(公告)号：US4758673A
公开(公告)日：1988-07-19
申请号：US16599
申请日：1987-02-19
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , C07D231/14 , C07D231/16 , C07D231/22 , C07D231/32 , C07D231/38
CPC分类号： C07D231/16
摘要： 1-Aryl-pyrazoles of the general formula ##STR1## in which Hal represents halogen,R.sup.1 and R.sup.3 independently of one another represent cyano, nitro, halogen, alkyl, alkoxy, alkoxycarbonyl, halogenoalkyl, halogenoalkoxy or a radical --S(O).sub.n --R.sup.6 andR.sup.2, R.sup.4 and R.sup.5 independently of one another and independently of R.sup.1 and R.sup.3 represent the same radicals as R.sup.1 and R.sup.3, and additionally represent hydrogen,and whereinR.sup.6 represents alkyl, halogenoalkyl, amino, alkylamino or dialkylamino and n-represents the number 0, 1 or 2 are disclosed.These compounds can be nitrated to form herbicially effective 1-aryl-4-nitropyrazoles.
摘要翻译：通式其中Hal表示卤素，R 1和R 3独立地为1芳基吡唑类另一个代表氰基，硝基，卤素，烷基，烷氧基，烷氧基羰基，卤代烷基，卤代烷氧基或基团-S（O）N -R 6和R2，R4和R5彼此独立地且独立的R1和R3代表相同的基团作为R 1和R 3，并另外代表氢，且其中R 6代表烷基，卤代烷基，氨基，烷基氨基或二烷基氨基和n表示号0，1或2。这些化合物可以被硝化以形成herbicially有效的1-芳基-4-硝基吡唑。

9. 发明授权

US4734125A 5-acylamido-1-aryl-pyrazoles, composition containing them and herbicidal method of using them 失效
标题翻译： 5-酰基酰氨基-1-芳基吡唑，含有它们的组合物和使用它们的除草方法
公开(公告)号：US4734125A
公开(公告)日：1988-03-29
申请号：US1471
申请日：1987-01-08
申请人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Otto Schallner , Jorg Stetter , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N43/56 , A01N47/02 , C07D231/40 , C07D401/04 , C07D231/38
CPC分类号： C07D401/04 , A01N43/56 , A01N47/02 , C07D231/40
摘要： Herbicidally active 5-acylamido-1-aryl-pyrazoles of the formula ##STR1## in which R.sup.1 represents hydrogen, halogen or nitro,R.sup.2 represents hydrogen or alkyl,X represents oxygen or sulphur,Y represents oxygen, sulphur, a sulphinyl group or a sulphonyl group,A represents a straight-chain or branched, optionally substituted alkylene bridge,Ar.sup.1 represents in each case optionally substituted aryl or heteroaryl, andAr.sup.2 represents in each case optionally substituted phenyl or pyridyl.
摘要翻译：式“IMAGE”的除草活性5-酰基酰氨基-1-芳基 - 吡唑，其中R1表示氢，卤素或硝基，R2表示氢或烷基，X表示氧或硫，Y表示氧，硫，亚磺酰基或磺酰基，A表示直链或支链的任选取代的亚烷基桥，Ar 1在每种情况下表示任选取代的芳基或杂芳基，Ar 2表示各自为任选取代的苯基或吡啶基。

10. 发明授权

US4734122A Substituted 5-acylamino-1-phenylpyrazoles composition containing them, and herbicidal method of using them 失效
标题翻译：含有它们的取代的5-酰基氨基-1-苯基吡唑组合物和使用它们的除草方法
公开(公告)号：US4734122A
公开(公告)日：1988-03-29
申请号：US743459
申请日：1985-06-11
申请人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
发明人： Reinhold Gehring , Jorg Stetter , Otto Schallner , Ludwig Eue , Hans-Joachim Santel , Robert R. Schmidt
IPC分类号： A01N47/18 , A01N47/22 , A01N47/36 , C07D231/40 , A01N43/56
CPC分类号： C07D231/40 , A01N47/18 , A01N47/22 , A01N47/36
摘要： 5-acylamino-1-phenylpyrazole herbicides of the formula ##STR1## in which R represents cyano, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, aminocarbonyl, alkylaminocarbonyl, alkenylaminocarbonyl or alkinylaminocarbonyl,R.sup.1 represents alkyl, alkenyl, alkinyl, alkoxyalkyl, alkylthioalkyl, halogenoalkyl, cycloalkyl or optionally substituted aryl, and, in the case in which Y represents the ##STR2## group, also represents hydrogen, X represents oxygen or sulphur,Y represents oxygen, sulphur or the ##STR3## group, whereinZ represents hydrogen, alkyl, alkoxy, alkenyl, alkinyl or optionally substituted aryl,R.sup.2 represents hydrogen or the radical ##STR4## and R.sup.3, R.sup.4, R.sup.5, R.sup.6 and R.sup.7, which are identical or different, represent hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylsulphonyl, alkoxycarbonyl or a radical --(X').sub.n --R.sup.8,whereinX' represents oxygen, sulphur, sulphinyl or sulphonyl,n represents 0 or 1 andR.sup.8 represents halogenoalkyl, with the proviso that at least one of the radicals R.sup.3, R.sup.4, R.sup.5, R.sup.6 or R.sup.7 represents a radical --(X').sub.n --R.sup.8, but R does not represent cyano when R.sup.5 represents trifluoromethyl.
摘要翻译：其中R代表氰基，烷氧基羰基，烯氧基羰基，烷氧基羰基，氨基羰基，烷基氨基羰基，链烯基氨基羰基或烷基氨基羰基，R1代表烷基，烯基，炔基，烷氧基烷基，烷硫基烷基，卤代烷基，环烷基或并且在Y代表基团的情况下也表示氢，X表示氧或硫，Y表示氧，硫或基团，其中Z表示氢，烷基，烷氧基，烯基，炔基或任选取代的芳基，R 2表示氢或基团，且R 3，R 4，R 5，R 6和R 7相同或不同，表示氢，卤素，氰基，硝基，烷基，烷氧基，烷基磺酰基，或基团 - （X'）n -R 8，其中X'表示氧，硫，亚磺酰基或磺酰基，n表示0或1，并且R 8表示卤代烷基，条件是至少一个碱基 R 3，R 4，R 5，R 6或R 7表示基团 - （X'）n -R 8，但当R 5表示三氟甲基时，R不表示氰基。

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