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1. 发明授权

US4528379A Preparation of substituted thiadiazolyloxyacetamides 失效
标题翻译：取代的噻二唑氧基乙酰胺的制备
公开(公告)号：US4528379A
公开(公告)日：1985-07-09
申请号：US515084
申请日：1983-07-18
申请人： Reimer Colln , Karl H. Mohrmann
发明人： Reimer Colln , Karl H. Mohrmann
IPC分类号： A01N43/824 , A01N43/836 , C07D285/08 , C07D285/12 , C07D285/13 , C07D417/12
CPC分类号： C07D285/08 , C07D285/13
摘要： In a process for the preparation of a substituted thiadiazolyloxyacetamide of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is hydrogen, alkyl, alkenyl, alkenyl, alkinyl, optionally substituted cycloalkyl or cycloalkenyl, halogenoalkyl, alkoxyalkyl, alkoxy, aralkyl or optionally substituted aryl, orR.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, form an optionally substituted heterocyclic structure which can contain further hetero atoms,One of X and Y is a nitrogen atom and the other a C-R.sup.3 a grouping, andR.sup.3 is alkyl, alkoxy, alkylthio, alkylsulphonyl, halogenoalkyl, aralkyl, aralkoxy, aralkythio or optionally substituted aryl,wherein a substituted 5-halogenothiadiazole of the formula ##STR2## in which Hal is halogen, is reacted with a hydroxyacetamide of the formula ##STR3## in the presence of a base as an acid acceptor and, optionally in the presence of a diluent, the improvement which comprises employing lithium hydroxide or its hydrate as the base, and carrying out the reaction at a temperature between about -10.degree. C. and +60.degree. C. The end products are known herbicides.
摘要翻译：在制备式“IMAGE”的取代的噻二唑氧基乙酰胺的方法中，其中R 1和R 2各自独立地为氢，烷基，烯基，烯基，炔基，任选取代的环烷基或环烯基，卤代烷基，烷氧基烷基，烷氧基，芳烷基或任选取代芳基或R 1和R 2与它们所键合的氮原子一起形成可含有其它杂原子的任选取代的杂环结构，X和Y之一是氮原子，另一个是C-R 3a组，和 R 3是烷基，烷氧基，烷硫基，烷基磺酰基，卤代烷基，芳烷基，芳烷氧基，芳烷基或任选取代的芳基，其中Hal为卤素的式“IMAGE”的取代的5-卤代噻二唑与下式的羟基乙酰胺在作为酸受体的碱存在下，并且任选地在稀释剂的存在下，包括使用氢氧化锂或其水合物作为碱的改进，并在约-10℃至+ 60℃的温度下进行反应。最终产物是已知的除草剂。

2. 发明授权

US4960911A Process for the preparation of oxiranes 失效
标题翻译：环氧乙烷的制备方法
公开(公告)号：US4960911A
公开(公告)日：1990-10-02
申请号：US264463
申请日：1988-10-28
申请人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann , Wolf Reiser
发明人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann , Wolf Reiser
IPC分类号： A01N43/20 , C07D249/08 , C07D301/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/04 , C07D303/08
摘要： A process for the preparation of oxiranes is disclosed in which a ketone of the formula ##STR1## wherein Y represents chlorine or phenyl, X represents oxygen or CH.sub.2 and Z represents hydrogen or halogen is reacted with trimethylsulphonium methyl sulphate formed by treating dimethyl sulphide with dimethyl sulphate. The process is carried out in the presence of potassium hydroxide or sodium hydroxide powder in an inert organic diluent at 0.degree. to 60.degree. C. The products are useful as intermediates for the formation of plant growth regulants and fungicides.

3. 发明授权

US4992565A Preparation of oxiranes 失效
标题翻译：环氧乙烷的制备
公开(公告)号：US4992565A
公开(公告)日：1991-02-12
申请号：US512612
申请日：1990-04-12
申请人： Karl H. Mohrmann , Wolf Reiser , Siegfried W. Linke , Rudolf Zerbes
发明人： Karl H. Mohrmann , Wolf Reiser , Siegfried W. Linke , Rudolf Zerbes
IPC分类号： A01N43/20 , C07D249/08 , C07D301/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/04 , C07D303/08
摘要： A process for the preparation of an oxirane of the formula ##STR1## in which Y is chlorine or phenyl,X is oxygen or CH.sub.2, andZ is hydrogen or halogen, comprising reacting dimethyl sulphide with methyl bromide in the presence of an inert organic diluent thereby to produce trimethylsulphonium bromide of the formula(CH.sub.3).sub.3 S.sup..sym. Br.sup..crclbar.and reacting the trimethylsulphonium bromide with a ketone of the formula ##STR2## in the presence of a base and in the presence of an inert organic diluent, at a temperature between about 0.degree. C. and 60.degree. C. The end products are produced in high yield and are known intermediates for known fungicides.
摘要翻译：制备式“IMAGE”的环氧乙烷的方法，其中Y为氯或苯基，X为氧或CH 2，Z为氢或卤素，包括在惰性有机稀释剂存在下使二甲基硫醚与甲基溴反应从而产生式（CH3）3S（+）Br（ - ）的三甲基锍溴化物，并在碱的存在下和在惰性有机稀释剂的存在下，使溴化三甲基锍与式温度在约0℃至60℃之间。最终产物以高产率生产，是已知杀真菌剂的已知中间体。

4. 发明授权

US4898954A Process for the preparation of oxiranes 失效
标题翻译：环氧乙烷的制备方法
公开(公告)号：US4898954A
公开(公告)日：1990-02-06
申请号：US772066
申请日：1985-09-03
申请人： Karl H. Mohrmann , Wolf Reiser , Siegfried W. Linke , Rudolf Zerbes
发明人： Karl H. Mohrmann , Wolf Reiser , Siegfried W. Linke , Rudolf Zerbes
IPC分类号： A01N43/20 , A01N43/22 , C07D249/08 , C07D301/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/04 , C07D303/08
摘要： A process for the preparation of oxiranes is disclosed in which trimethylsulphonium methyl sulphate, formed by treating dimethyl sulphide with dimethyl sulphate in the presence of tert.-butanol, is reacted, without previous isolation, with a ketone in the presence of a base and in the presence of tert.-butanol. The resultant oxiranes are useful in the preparation of plant growth regulants and fungicides.
摘要翻译：公开了制备环氧乙烷的方法，其中通过在叔丁醇存在下用硫酸二甲酯处理二甲基硫化物而形成的三甲基锍甲基硫酸酯在没有事先分离的情况下与酮在碱的存在下反应，并在存在叔丁醇。所得的环氧乙烷可用于制备植物生长调节剂和杀真菌剂。

5. 发明授权

US4886892A Process for the preparation of oxiranes 失效
标题翻译：环氧乙烷的制备方法
公开(公告)号：US4886892A
公开(公告)日：1989-12-12
申请号：US7078
申请日：1987-01-27
申请人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann
发明人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann
IPC分类号： A01N43/20 , C07D249/08 , C07D301/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/04 , C07D303/08
摘要： A process for the preparation of oxiranes is disclosed in which a ketone of the formula ##STR1## wherein Y represents chlorine or phenyl, X represents oxygen or CH.sub.2 and Z represents hydrogen or halogen is reacted with trimethylsulphonium methyl sulphate formed by treating dimethyl sulphide with dimethyl sulphate. The process is carried out in the presence of potassium hydroxide or sodium hydroxide powder in an inert organic diluent at 0.degree. to 60.degree. C. The products are useful as intermediates for the formation of plant growth regulants and fungicides.
摘要翻译：公开了一种制备环氧乙烷的方法，其中Y表示氯或苯基，X表示氧或CH 2且Z表示氢或卤素的通式（III）的酮与三甲基锍甲基硫酸盐反应，硫酸二甲酯与硫酸二甲酯。该方法在氢氧化钾或氢氧化钠粉末存在下，在惰性有机稀释剂中，0℃至60℃下进行。该产物可用作形成植物生长调节剂和杀真菌剂的中间体。

6. 发明授权

US4632999A Process for the preparation of oxiranes 失效
标题翻译：环氧乙烷的制备方法
公开(公告)号：US4632999A
公开(公告)日：1986-12-30
申请号：US789987
申请日：1985-10-22
申请人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann , Wolf Reiser
发明人： Rudolf Zerbes , Siegfried W. Linke , Karl H. Mohrmann , Wolf Reiser
IPC分类号： A01N43/20 , C07D249/08 , C07D301/02 , C07D303/04 , C07D303/08 , C07D303/22 , C07D521/00
CPC分类号： C07D303/22 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/04 , C07D303/08
摘要： A process for the preparation of an oxirane of the formula ##STR1## in which Y represents chlorine or phenyl, X represents oxygen or Ch.sub.2 and Z represents hydrogen or halogen, which comprises containing dimethyl sulphoxide with dimethyl sulphate whereby to form trimethyloxosulphonium methyl sulphate of the formula(CH.sub.3).sub.3 SO.sup..sym. CH.sub.3 SO.sub.4.sup.63 (II)and thereafter, without isolating said trimethyloxosulphonium methyl sulphate, contacting the same with a ketone of the formula ##STR2## in which X, Y and Z have the meanings indicated above, in the presence of a base and in the presence of an inert organic diluent, at a temperature between 0.degree. C. and 60.degree. C.
摘要翻译：制备式（I）的环氧乙烷的方法，其中Y表示氯或苯基，X表示氧或Ch2，Z表示氢或卤素，其包含含二甲基亚砜与二甲基硫酸盐，由此形成三甲基锍甲基式（CH3）3SO（+）CH3SO463（II）的硫酸盐，然后不分离所述三羟甲基硫酸甲基硫酸盐，将其与式（III）的酮接触，其中X，Y和Z的含义在碱存在下，在惰性有机稀释剂存在下，在0℃至60℃的温度下进行。

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