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    • 1. 发明授权
    • Composition and use of the composition for the extraction of metals from
aqueous solution
    • 用于从水溶液中萃取金属的组合物的组成和用途
    • US4978788A
    • 1990-12-18
    • US281078
    • 1988-12-08
    • Raymond F. DaltonJohn L. Leng
    • Raymond F. DaltonJohn L. Leng
    • C22B3/00B01D11/04C01G3/00C22B3/26C22B3/30C22B15/00
    • C22B3/0032C01G3/003C22B3/0017Y02P10/234Y10S210/912Y10S423/14
    • A composition for use in extracting copper values from aqeous solutions of metal salts which comprises one more o-hydroxyaryloximes containing at least 5 aliphatic or alicyclic carbon atoms which are strong metal extractants which, in 0.2 molar solution in an aliphatic hydrocarbon solution loaded with 50% of the theoreticl uptake of copper, will be in equilibrium with 0.1 molar solution of copper as copper perchlorate at a pH less than 1; and one or more branched chain aliphatic or aromatic-aliphatic alcohols containing 14 to 30 carbon atoms or aliphatic or aliphatic-aromatic esters containing 10 to 30 carbon atoms, wherein the ratio of the number of methyl carbon atoms to the number of non-methyl carbon atoms is higher than 1:5, and which is selected from the group consisting of highly branched isohexadecyl alcohol, highly branched isooctadecyl alcohol and a diester of 2,2,4-trimethyl-1,3-pentanediol; and wherein the weight ratio of A to B is in the range 10:1 to 1:3.
    • 一种用于从金属盐的金属溶液中提取铜值的组合物,其包含一个以上含有至少5个脂族或脂环族碳原子的邻羟基肟,其是强金属萃取剂,其在装载有50%的脂肪族烃溶液的0.2摩尔溶液中, 的理论吸收铜,将在pH小于1时与0.1当量的高氯酸铜的0.1摩尔溶液平衡; 和含有14〜30个碳原子的一个或多个支链脂肪族或芳香族 - 脂肪族醇或含有10〜30个碳原子的脂肪族或脂肪族 - 芳香族酯,其中甲基碳原子数与非甲基碳数 原子高于1:5,并且选自高度支化的异十六烷醇,高度支化的十六烷基醇和2,2,4-三甲基-1,3-戊二醇的二酯; 并且其中A与B的重量比在10:1至1:3的范围内。
    • 3. 发明授权
    • Composition and use of the composition for the extraction of metals from
aqueous solution
    • 用于从水溶液中萃取金属的组合物的组成和用途
    • US5176843A
    • 1993-01-05
    • US532578
    • 1990-06-04
    • Raymond F. DaltonJohn L. Leng
    • Raymond F. DaltonJohn L. Leng
    • C01B31/16C01G3/00C22B3/26C22B3/30
    • C01G3/003C22B3/0017C22B3/0032Y02P10/234Y10S423/14
    • A composition for use in extracting copper values from aqueous solutions of metal salts which comprises:A. one or more o-hydroxyaryloximes containing at least 5 aliphatic or alicyclic carbon atoms which are strong metal extractants which, in 0.2 molar solution in an aliphatic hydrocarbon solution when loaded with 50% of the theoretical uptake of copper, will be in equilibrium with a 0.1 molar solution of copper as copper perchlorate at a pH less than 1;B. one or more branched chain aliphatic or aromatic-aliphatic alcohol containing 14 to 30 carbon atoms or aliphatic or aliphatic-aromatic esters containing 10 to 30 carbon atoms in which the ratio of the number of methyl carbon atoms to the number of non-methyl carbon atoms is higher than 1:5 and which is selected from the group consisting of highly branched hexadecyl alcohol, highly branched isooctadecyl alcohol and a diester of 2,2,4-trimethyl -1,3-pentanediol; andC. one or more o-hydroxyarylketoximes which are weak metal extractants and which, in 0.2 molar solution in an aliphatic hydrocarbon solution when loaded with 50% of the theoretical uptake of copper, will be in equilibrium with a 0.1 molar solution for copper as copper perchlorate at a pH of 1.2 or higher; wherein the weight ratio of component A to component B is in the range 10:1 to 1:3.
    • 一种用于从金属盐水溶液中提取铜值的组合物,其包含:A.一种或多种含有至少5个脂族或脂环族碳原子的邻羟基亚胺,其为强金属萃取剂,其在脂族烃溶液中的0.2摩尔溶液 当负载了理论吸收铜的50%时,将在pH小于1时与0.1当量高氯酸铜的铜溶液平衡; B.一种或多种含有14至30个碳原子的支链脂族或芳族脂族醇或含有10至30个碳原子的脂族或脂族 - 芳族酯,其中甲基碳原子数与非甲基数 碳原子高于1:5,并且选自高度支化的十六烷醇,高度支化的十八烷基醇和2,2,4-三甲基-1,3-戊二醇的二酯; 和C.一种或多种作为弱金属萃取剂的邻羟基芳基酮肟,并且当负载50%理论吸收铜的脂族烃溶液中的0.2摩尔溶液将与0.1摩尔铜溶液平衡时 高氯酸铜,pH值在1.2以上; 其中组分A与组分B的重量比在10:1至1:3的范围内。