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1. 发明授权

US5573992A Process for the calcination/activation of V/P/O catalyst 失效
标题翻译： V / P / O催化剂的煅烧/活化方法
公开(公告)号：US5573992A
公开(公告)日：1996-11-12
申请号：US330762
申请日：1994-10-28
申请人： Rashmikant M. Contractor , Donald I. Garnett , Harold S. Horowitz , Arthur W. Sleight
发明人： Rashmikant M. Contractor , Donald I. Garnett , Harold S. Horowitz , Arthur W. Sleight
IPC分类号： B01J27/198 , B01J37/08 , C07C51/215
CPC分类号： C07C51/215 , B01J23/002 , B01J27/198 , B01J2523/00
摘要： An improved process for calcination and activation of a catalyst containing mixed oxides of vanadium and phosphorus (V/P/O) comprising the steps of calcining a hydrated V/P/O or V/P/O- SiO.sub.2 catalyst precursor at a temperature range of 375.degree. to 400.degree. C. for sufficient time to dehydrate said catalyst precursor while simultaneously and continuously controlling the oxygen level such as to maintain the Vox in the range of 3.825 to 4.175; and then activating the dehydrated catalyst precursor by further heating at a range of 340.degree. to 500.degree. C. in the presence of a gaseous atmosphere containing n-butane at a partial pressure not exceeding 0.20 atm while simultaneously and continuously controlling the oxygen level such as to maintain the Vox in the range of 3.95 to 4.15. Such a V/P/O catalyst is useful in the preparation of maleic anhydride from n-butane.
摘要翻译：一种用于煅烧和活化含有钒和磷的混合氧化物（V / P / O）的催化剂的改进方法，包括在温度范围下煅烧水合V / P / O或V / P / O-SiO 2催化剂前体的步骤在375℃至400℃下充分时间使所述催化剂前体脱水，同时并连续地控制氧水平，以维持Vox在3.825至4.175的范围内; 然后在含有正丁烷的气态气氛存在下，在不超过0.20atm的压力的条件下，在340〜500℃的范围内进一步加热活化脱水催化剂前体，同时连续地控制氧水平，例如以维持Vox在3.95至4.15的范围内。这种V / P / O催化剂可用于从正丁烷制备马来酸酐。

2. 发明授权

US4278563A Copper chloride containing catalysts for the preparation of furan compounds 失效
标题翻译：含氯化铜的催化剂用于制备呋喃化合物
公开(公告)号：US4278563A
公开(公告)日：1981-07-14
申请号：US109263
申请日：1980-01-18
申请人： Joseph M. Fremont , Donald I. Garnett
发明人： Joseph M. Fremont , Donald I. Garnett
IPC分类号： B01J27/08 , C07D307/36 , B01J27/10
CPC分类号： B01J27/08 , C07D307/36
摘要： A process for preparing a furan compound by contacting a diolefin such as butadiene with a catalyst at a low pressure and a low temperature is provided. In this process, a diolefin, an oxygen-containing gas and water containing HCl are contacted with a catalyst which is a support having deposited thereon copper chloride, an alkali metal chloride and at least one of palladium chloride and iodide, usually cuprous iodide. Temperature of the reaction is usually in the range of about 80.degree.-125.degree. C. and the pressure is usually in the range of about 1-5 atmospheres. Cyclic operation between furan production and catalyst oxidation is also provided.
摘要翻译：提供了通过使二烯烃如丁二烯与催化剂在低压和低温下接触来制备呋喃化合物的方法。在该方法中，将二烯烃，含氧气体和含HCl的水与作为其上沉积有氯化铜，碱金属氯化物和氯化钯和碘化物中的至少一种（通常为碘化亚铜）的载体的催化剂接触。反应温度通常在约80℃-125℃的范围内，压力通常在约1-5个大气压的范围内。还提供呋喃生产和催化剂氧化之间的循环操作。

3. 发明授权

US08258638B1 Energy generation using continental shelf mass 有权
标题翻译：使用大陆架质量的能源生产
公开(公告)号：US08258638B1
公开(公告)日：2012-09-04
申请号：US13433707
申请日：2012-03-29
申请人： Donald I. Garnett
发明人： Donald I. Garnett
IPC分类号： H02P9/04
CPC分类号： F03B17/00 , F03B13/06 , Y02E10/20 , Y02E10/22 , Y02E60/17 , Y02P90/50
摘要： A system and method for generating electrical energy from continental shelf mass involves moving continental shelf mass onto a conveyor at a first elevation at or near sea level. The mass is moved on the conveyor system to a second elevation well below sea level. Ideally, the second elevation is the bottom of a continental trench. The conveyor is then used to convey a liquid, preferably seawater, to a third elevation higher than the first elevation. The liquid is then passed into a reservoir and through a hydroelectric generator. The conveyor system may include a bucket chain enclosed in a pipeline.
摘要翻译：用于从大陆架组件产生电能的系统和方法包括在海平面处或附近的第一高度将大陆架质量移动到输送机上。质量在输送系统上移动到海平面以下的第二高度。理想情况下，第二个高程是大陆沟底部。输送机然后用于将液体（优选海水）输送到比第一高度高的第三高度。然后将液体进入储存器并通过水力发电机。输送系统可包括封闭在管道中的铲斗链。

4. 发明授权

US4410713A Preparation of furan compounds 失效
标题翻译：呋喃化合物的制备
公开(公告)号：US4410713A
公开(公告)日：1983-10-18
申请号：US372559
申请日：1982-04-28
申请人： Donald I. Garnett
发明人： Donald I. Garnett
IPC分类号： B01J31/00 , C07B61/00 , C07D307/36
CPC分类号： C07D307/36
摘要： Process comprising contacting and reacting a substituted or unsubstituted diolefin polyperoxide, for example, butadienepolyperoxide, with an acidic aqueous medium containing cuprous and cupric ions and a water-soluble agent which forms a water-soluble complex with cuprous ions, and recovering furan or a substituted furan from the reaction mixture.
摘要翻译：方法包括使取代或未取代的二烯烃聚过氧化物例如丁二烯过氧化物与含有亚铜和铜离子的酸性含水介质和与亚硝酸根离子形成水溶性络合物的水溶性试剂接触和反应，并回收呋喃或取代的呋喃从反应混合物中。

5. 发明授权

US4268421A Preparation of furan compounds 失效
标题翻译：呋喃化合物的制备
公开(公告)号：US4268421A
公开(公告)日：1981-05-19
申请号：US128112
申请日：1980-03-07
申请人： Donald I. Garnett , Marvin L. Peterson
发明人： Donald I. Garnett , Marvin L. Peterson
IPC分类号： B01J27/08 , C07D307/36 , B01J27/10
CPC分类号： B01J27/08 , C07D307/36 , Y02P20/582
摘要： A process for preparing a furan compound by the catalytic oxidation of a diolefin such as butadiene or a halo-substituted alkene is provided. In this process, the starting material is contacted with an aqueous medium having a pH less than about 2 containing (1) iodide ion, (2) a mixture of cuprous and cupric ions, and (3) a solubilizing agent for cuprous ion such as an alkali metal halide. Optionally, an oxygen-containing gas such as air can also be contacted with the aqueous medium. In one embodiment, the starting material is contacted with an aqueous solution of the aforesaid ingredients in one reaction zone to prepare furan and a portion of the solution is passed to a second reaction zone where cuprous ion is oxidized to cupric ion with air and then the air-treated solution returned to the first reaction zone.
摘要翻译：提供了通过二烯烃如丁二烯或卤代烯烃的催化氧化制备呋喃化合物的方法。在该方法中，使原料与含有（1）碘离子的pH小于约2的水性介质接触，（2）亚铜和铜离子的混合物，和（3）用于亚铜离子的增溶剂，例如碱金属卤化物。任选地，诸如空气的含氧气体也可以与水性介质接触。在一个实施方案中，将原料与上述成分的水溶液在一个反应区中接触以制备呋喃，并将一部分溶液通入第二反应区，其中亚硝酸根被空气氧化成铜离子，然后空气处理的溶液返回到第一反应区。

6. 发明授权

US4243593A Preparation of furan compounds 失效
标题翻译：呋喃化合物的制备
公开(公告)号：US4243593A
公开(公告)日：1981-01-06
申请号：US109264
申请日：1980-01-18
申请人： Joseph M. Fremont , Donald I. Garnett
发明人： Joseph M. Fremont , Donald I. Garnett
IPC分类号： B01J27/08 , C07D307/36
CPC分类号： B01J27/08 , C07D307/36
摘要： A process for preparing a furan compound by contacting a diolefin such as butadiene with a catalyst at a low pressure and a low temperature is provided. In this process, a diolefin, an oxygen-containing gas and water containing HCl are contacted with a catalyst which is a support having deposited thereon copper chloride, and alkali metal chloride and at least one of palladium chloride and iodide, usually cuprous iodide. Temperature of the reaction is usually in the range of about 80.degree.-125.degree. C. and the pressure is usually in the range of about 1-5 atmospheres. Cyclic operation between furan production and catalyst oxidation is also provided.
摘要翻译：提供了通过使二烯烃如丁二烯与催化剂在低压和低温下接触来制备呋喃化合物的方法。在该方法中，将二烯烃，含氧气体和含HCl的水与作为其上沉积有氯化铜的载体的催化剂和碱金属氯化物以及氯化钯和碘化物中的至少一种（通常为碘化亚铜）接触。反应温度通常在约80℃-125℃的范围内，压力通常在约1-5个大气压的范围内。还提供呋喃生产和催化剂氧化之间的循环操作。

7. 发明授权

US4180687A Reaction of formaldehyde in butynediol 失效
标题翻译：甲醛在丁炔二醇中的反应
公开(公告)号：US4180687A
公开(公告)日：1979-12-25
申请号：US899297
申请日：1978-04-24
申请人： Harry O. Burrus , Donald I. Garnett
发明人： Harry O. Burrus , Donald I. Garnett
IPC分类号： C07C29/17 , C07C29/88 , C07C33/046 , C07C29/24 , C07C33/04
CPC分类号： C07C29/88 , C07C29/172 , C07C33/046
摘要： Formaldehyde in crude BYD, can be reacted to a polymeric substance in the presence of NaOH or Na.sub.2 CO.sub.3 at high temperatures.
摘要翻译：粗BYD中的甲醛可在NaOH或Na 2 CO 3存在下在高温下与聚合物反应。

8. 发明授权

US4172838A Preparation of furan compounds 失效
标题翻译：呋喃化合物的制备
公开(公告)号：US4172838A
公开(公告)日：1979-10-30
申请号：US935389
申请日：1978-08-21
申请人： Donald I. Garnett , Marvin L. Peterson
发明人： Donald I. Garnett , Marvin L. Peterson
IPC分类号： B01J27/06 , B01J27/08 , C07D307/36
CPC分类号： C07D307/36 , Y02P20/582
摘要： A process for preparing a furan compound by the catalytic oxidation of a diolefin such as butadiene or a halo-substituted alkene is provided. In this process the starting material is contacted with an aqueous medium having a pH less than about 2 containing (1) iodide ion, (2) a mixture of cuprous and cupric ions, and (3) a solubilizing agent for cuprous ion such as an alkali metal halide. Optionally, an oxygen-containing gas such as air can also be contacted with the aqueous medium. In one embodiment, the starting material is contacted with an aqueous solution of the aforesaid ingredients in one reaction zone to prepare furan and a portion of the solution is passed to a second reaction zone where curpous ion is oxidized to cupric ion with air and then the air-treated solution returned to the first reaction zone.
摘要翻译： {PG，1]提供了通过二烯烃如丁二烯或卤代烯烃的催化氧化制备呋喃化合物的方法。在该方法中，起始材料与含有（1）碘离子的pH小于约2的水性介质接触，（2）亚铜和铜离子的混合物，和（3）用于亚铜离子的增溶剂，例如碱金属卤化物。任选地，诸如空气的含氧气体也可以与水性介质接触。在一个实施方案中，将原料与上述成分的水溶液在一个反应区中接触以制备呋喃，并将一部分溶液通入第二反应区，其中将螯合离子用空气氧化成铜离子，然后空气处理的溶液返回到第一反应区。

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