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1. 发明申请

US20070141264A1 Stain resistant urethane-vinyl aqueous coating compositions 有权
标题翻译：耐污染的聚氨酯 - 乙烯基水性涂料组合物
公开(公告)号：US20070141264A1
公开(公告)日：2007-06-21
申请号：US10583266
申请日：2004-12-14
申请人： Rajasingham Satgurunathan , Gerardus Overbeek , Marc Roelands , Ronald Tennebroek , Roel Johannes Swaans , Gerhardus Roescher
发明人： Rajasingham Satgurunathan , Gerardus Overbeek , Marc Roelands , Ronald Tennebroek , Roel Johannes Swaans , Gerhardus Roescher
IPC分类号： C08F8/30 , B05D3/02
CPC分类号： C08G18/12 , C08G18/423 , C08G18/6216 , C08G18/6275 , C08G18/6659 , C08L33/00 , C09D175/06 , C08G18/3231 , C08L2666/04
摘要： An aqueous coating composition, which when in the form of a film exhibits an MVTR of ≦500 g/m2/24 h comprising 20 to 80 wt % of a polyurethane A with an acid value of 8 to 40 mg KOH/g and a hard segment content ≧40 wt %, a ring structure content ≧48 wt % and 80 to 20 wt % of a vinyl polymer B with a Tg≧20° C.
摘要翻译：一种水性涂料组合物，其当以膜的形式显示出MVTR为<= 500G / M 2/24小时，包含20-80重量％的酸值为8的聚氨酯A 至40mg KOH / g，硬链段含量≥40wt％，环结构含量≥48wt％和Tg = 20℃的乙烯基聚合物B的80-20wt％

2. 发明申请

US20060258801A1 Aqueous polymer compositions 审中-公开
标题翻译：水性聚合物组合物
公开(公告)号：US20060258801A1
公开(公告)日：2006-11-16
申请号：US10570163
申请日：2004-07-26
申请人： Emilio Martin , Gerardus Overbeek , Marc Roelands , Rajasingham Satgurunathan
发明人： Emilio Martin , Gerardus Overbeek , Marc Roelands , Rajasingham Satgurunathan
IPC分类号： C08G18/08 , C08K3/20
CPC分类号： C08G18/12 , C08G18/6692 , C09D175/04 , C08G18/3231 , C08L2666/20 , C08L2666/04
摘要： An aqueous coating composition comprising: (i) (10) to (80) wt % of a polyurethane A which exhibits a minimum film forming temperature of ≦ambient temperature and which comprises a polyurethane obtained by the reaction of: (a) an isocyanate-terminated pre-polymer formed from components which comprise: (1) 10 to 30 wt % of a polyisocyanate; (2) 0.1 to 10 wt % of a polyol of weight average molecular weight less than 500, containing ionic or potentially ionic water-dispersing groups, and having two or more isocyanate-reactive groups; (3) 0 to 15 wt % of a polyol containing non-ionic water dispersing groups having two or more isocyanate-reactive groups; (4) 40 to 80 wt % of a polyol other than (2) or (3), having two or more isocyanate-reactive groups; where (1), (2), (3) and (4) add up to 100%; and (b) an active-hydrogen chain extending compound; and (ii) 20 to 90 wt % of a polymer dispersion B which exhibits a minimum film forming temperature of above ambient temperature; wherein (i) and (ii) add up to 100%. Processes for manufacture of said composition and methods of application to substrates are also described.
摘要翻译：一种水性涂料组合物，其包含：（i）（10） - （80）wt％的聚氨酯A，其表现出最小成膜温度<=环境温度，并且其包含通过以下反应获得的聚氨酯：（a）异氰酸酯由包含以下组分的组分形成的终止预聚物：（1）10至30重量％的多异氰酸酯; （2）0.1〜10重量％的重均分子量小于500的多元醇，其含有离子或潜在离子性水分散基团，并且具有两个或多个异氰酸酯反应性基团; （3）含有2个以上异氰酸酯反应性基团的非离子性水分散基团的多元醇0〜15重量％（4）40〜80重量％的具有2个以上异氰酸酯反应性基团的（2）或（3）以外的多元醇; 其中（1），（2），（3）和（4）加起来为100％; 和（b）活性氢链增长化合物; 和（ii）20〜90重量％的表现出最高成膜温度高于环境温度的聚合物分散体B; 其中（i）和（ii）加起来为100％。还描述了用于制造所述组合物的方法和施加于基材的方法。

3. 发明申请

US20050182180A1 Aqueous coating composition comprising non-crosslinkable oligomer(s) and dispersed polymer(s) 有权
标题翻译：包含不可交联的低聚物和分散的聚合物的水性涂料组合物，
公开(公告)号：US20050182180A1
公开(公告)日：2005-08-18
申请号：US10509223
申请日：2003-03-21
申请人： Emilio Martin , Jurgen Scheerder , Gerardus Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
发明人： Emilio Martin , Jurgen Scheerder , Gerardus Overbeek , Ronald Tennebroek , Tijs Nabuurs , Pablo Steenwinkel
IPC分类号： C09D167/00 , C09D175/04 , C08K3/20
CPC分类号： C09D167/00 , C09D175/04 , C08L2666/04
摘要： An aqueous coating composition comprising a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 min; a wet edge time of at least 10 min; a tack free time of ≦24 hrs and an equilibrium viscosity of 5,000 Pa·s.
摘要翻译：一种包含不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少为10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。

4. 发明申请

US20110086953A1 AQUEOUS AUTOXIDISABLE COATING COMPOSITION 审中-公开
标题翻译：水性自动涂料组合物
公开(公告)号：US20110086953A1
公开(公告)日：2011-04-14
申请号：US12918932
申请日：2009-03-31
申请人： Ronald Tennebroek , Gerardus Overbeek , Francisco Bergman , Mourad Aabich , Richard George Coogan , Roel Swaans
发明人： Ronald Tennebroek , Gerardus Overbeek , Francisco Bergman , Mourad Aabich , Richard George Coogan , Roel Swaans
IPC分类号： C08K5/3415 , B05D5/00 , B32B33/00 , C09D167/02
CPC分类号： C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要： An aqueous coating composition comprising an autoxidisable polyester resin having ≧30 wt % of fatty acid residues; a Tg in the range of from −60° C. to +35° C.; an acid value greater than 15 mg KOH/g and less than 75 mg KOH/g; a Mw in the range of from 2,500 to 100,000 g/mol; said composition having a co-solvent content less that 15 wt % by weight of total composition; a solids content >30 wt %; and when a film, a telegraphing value of less than 20 gloss units.
摘要翻译：一种水性涂料组合物，其包含具有≥30重量％脂肪酸残基的可自动氧化的聚酯树脂; Tg在-60℃至+ 35℃的范围内。酸值大于15mg KOH / g且小于75mg KOH / g; 在2500至100,000g / mol范围内的Mw; 所述组合物的共溶剂含量小于总组合物的15重量％; 固体含量> 30wt％; 而当一部电影，电报值小于20光泽单位。

5. 发明申请

US20060217483A1 Aqueous pigmented coating composition with improved open time comprising crosslinkable oligomer(s) and dispersed polymer(s) 有权
公开(公告)号：US20060217483A1
公开(公告)日：2006-09-28
申请号：US10551046
申请日：2004-03-22
申请人： Ronald Tennebroek , Tijs Nabuurs , Gerardus Overbeek , Jan Bouman
发明人： Ronald Tennebroek , Tijs Nabuurs , Gerardus Overbeek , Jan Bouman
IPC分类号： C09D5/02
CPC分类号： C09D125/14 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/3212 , C08G18/68 , C08G18/758 , C08K3/22 , C08L33/24 , C08L35/06 , C08L67/00 , C08L75/00 , C09D167/06 , C09D175/12 , C09D175/14 , C08G18/3231 , C08L2666/02 , C08L2666/20 , C08L2666/04
摘要： An aqueous coating composition with an improved open time comprising (a) a crosslinkable water-dispersible oligomer(s); (b) a dispersed polymer(s), (c) a pigment(s) with an oil absorption number ≦25 g oil/100 g pigment and optionally (d) a Newtonian-like thickener(s) and (e) a thixotropic thickener(s) wherein the weight ratio of (a):(b) is in the range of from 10:90 to 60:40; wherein (d)+(e)=0.1 to 10 wt % and wherein said composition when drying to form a coating has a tack-free time of ≦24 hours.

6. 发明申请

US20070219328A1 Free Radical Polymerisation Process for Making Macromonomers 审中-公开
标题翻译：制备大分子单体的自由基聚合方法
公开(公告)号：US20070219328A1
公开(公告)日：2007-09-20
申请号：US11587402
申请日：2005-04-25
申请人： Saskia Van Der Slot , Tijs Nabuurs , Alfred Jean Buckmann , Gerardus Overbeek
发明人： Saskia Van Der Slot , Tijs Nabuurs , Alfred Jean Buckmann , Gerardus Overbeek
IPC分类号： C08F4/06
CPC分类号： C08F4/26 , C08F2/22 , C08F2/38 , C08F220/14 , C08F265/06 , C08F290/062 , C09D151/00 , C09J151/00 , C08F2220/1825 , C08F220/06 , C08F220/58
摘要： Process for preparing a macromonomer using free radical-initiated aqueous emulsion polymerisation in a polymerisation reactor of at least one olefinically unsaturated monomer, which process employs a hydrophobic Co chelate complex as a CTA, a stabilising substance(s) for the emulsion polymerisation process and a monomer feed stage MF; wherein an aqueous pre-emulsified mixture A, comprising at least part of the Co chelate(s) employed, at least part of the stabilising substance(s) employed, and (i) a non-polymerisable organic solvent(s) and/or (ii) a polymerisable monomer(s) in unpolymerised or at least partially polymerised form, is contacted in the reactor with monomer(s) of feed stage MF at the beginning of and/or during the course of feed stage MF; and wherein in mixture A the weight ratio of (i) and/or (ii) to the stabilising substance(s) is in the range of from 10/1 to 1/10.
摘要翻译：在至少一种烯属不饱和单体的聚合反应器中使用自由基引发的水性乳液聚合制备大分子单体的方法，该方法使用疏水性Co螯合物络合物作为CTA，用于乳液聚合方法的稳定物质和单体进料级MF; 其中包含至少部分所述Co螯合物的至少一部分所用稳定物质的水性预乳化混合物A和（i）不可聚合的有机溶剂和/或（ii）未聚合或至少部分聚合形式的可聚合单体在反应器中在进料阶段MF的开始和/或期间在进料阶段MF的单体接触; 并且其中在混合物A中，（i）和/或（ii）与稳定物质的重量比在10/1至1/10的范围内。

7. 发明申请

US20050004300A1 Aqueous crosslinkable coating compositions based on vinyl fluoropolymer 失效
标题翻译：基于乙烯基含氟聚合物的水性交联涂料组合物
公开(公告)号：US20050004300A1
公开(公告)日：2005-01-06
申请号：US10485572
申请日：2002-07-22
申请人： Gerardus Overbeek , Jurgen Scheerder , Tijs Nabuurs
发明人： Gerardus Overbeek , Jurgen Scheerder , Tijs Nabuurs
IPC分类号： C08G18/48 , C08G18/62 , C08G18/70 , C08L61/20 , C09D133/16 , C09D175/04 , C08L1/00 , B05D1/00
CPC分类号： C09D175/04 , C08G18/4833 , C08G18/6279 , C08G18/706 , C08L61/20 , C09D133/16 , C08L2666/14
摘要： Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerised constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from −50 to 90° C. and (B) at least one hydroxyl-reactive crosslinker material.
摘要翻译：适用于防涂鸦和重载应用的水性可交联涂料组合物包括：（A）包含至少一种乙烯基含氟聚合物的含水聚合物乳液，其包含作为其聚合的构成单体（i）具有式（1）的含氟单体，其中R 1是CH 3或H，R 2是全氟化的C 1-5烷基，n是1,2,3或4，（ii）羟基官能单体和（iii）a 羧酸官能单体，其中乙烯基含氟聚合物的玻璃化转变温度Tg在-50至90℃的范围内，和（B）至少一种羟基反应性交联剂材料。

8. 发明申请

US20070238824A1 Aqueous Vinyl Oligomer and Vinyl Polymer Compositions 审中-公开
标题翻译：乙烯基低聚物和乙烯基聚合物组合物
公开(公告)号：US20070238824A1
公开(公告)日：2007-10-11
申请号：US11578117
申请日：2005-03-18
申请人： Yvonne Smak , Gerardus Overbeek , Debby Geus-De Groot , Jacobus Griffioen , Paulus Honen , Alfred Buckmann
发明人： Yvonne Smak , Gerardus Overbeek , Debby Geus-De Groot , Jacobus Griffioen , Paulus Honen , Alfred Buckmann
IPC分类号： C08F265/02 , C08F2/00 , C09D151/00 , C08F257/02
CPC分类号： C08F257/02 , C08F265/02 , C09D151/003 , C08F220/10
摘要： An aqueous composition comprising i) at least a crosslinkable vinyl oligomer (A) with a weight average molecular weight in the range of from 1000 to 80,000 Daltons obtained by the bulk polymerisation of vinyl monomers ii) at least a vinyl polymer (B) with a weight average molecular weight ≧5000 Daltons, obtained by polymerisation in the presence of vinyl oligomer (A) of vinyl monomers where the ratio of vinyl oligomer (A) to vinyl polymer (B) is in the range of from 5:95 to 95:5; where polymer (B) is more hydrophobic than vinyl oligomer (A); and where the weight average molecular weight of vinyl polymer (B) is more than the weight average molecular weight of vinyl oligomer (A).
摘要翻译：一种水性组合物，其包含i）至少一种通过乙烯基单体的本体聚合获得的至少一种重均分子量在1000至80,000道尔顿范围内的交联性乙烯基低聚物（A）。ii）至少一种乙烯基聚合物（B）与在乙烯基单体的乙烯基低聚物（A）存在下，乙烯基低聚物（A）与乙烯基聚合物（B）的比率在5:95至95的范围内，通过聚合获得的重均分子量> = 5000道尔顿：5; 其中聚合物（B）比乙烯基低聚物（A）更疏水; 并且其中乙烯基聚合物（B）的重均分子量大于乙烯基低聚物（A）的重均分子量。

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