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1. 发明授权

US06632953B1 Production of optically active phospholanes 失效
标题翻译：生产光学活性磷脂
公开(公告)号：US06632953B1
公开(公告)日：2003-10-14
申请号：US09700521
申请日：2000-11-15
申请人： Rainer Stürmer , Armin Börner , Jens Holz , Gudrun Voss
发明人： Rainer Stürmer , Armin Börner , Jens Holz , Gudrun Voss
IPC分类号： C07F9535
CPC分类号： B01J31/1875 , B01J31/2295 , B01J31/2423 , B01J31/2433 , B01J31/2476 , B01J2231/32 , B01J2231/44 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B53/00 , C07F9/6568 , C07F9/65683 , C07F15/008
摘要： Phospolanes and diphospholanes of the general formula I where: is H, C1-C6-aryl, alkylaryl, SiR32, R2 is alkyl or aryl, A is H, C1-C6-alkyl, aryl, Cl or B is a linker with 1-5 C atoms between the two P atoms, and their use as catalyst in asymmetric synthesis.
摘要翻译：具有通式I的磷光体和二磷脂：其中：其中：H，C 1 - 芳基，烷基芳基，烷基或芳基，烷基芳基，烷基芳基，烷基芳基，烷基芳基，烷基芳基， A是H，C 1 -C 6 - 烷基，芳基，Cl或B是具有1 -5个C原子在两个P原子之间，并且它们在不对称合成中用作催化剂

2. 发明授权

US07612240B2 Halophospholanes and their preparation 失效
标题翻译： Halophospholanes及其制备
公开(公告)号：US07612240B2
公开(公告)日：2009-11-03
申请号：US12091410
申请日：2006-10-04
申请人： Armin Börner , Jens Holz , Juan Almena , Renat Kadyrov , Axel Monsees , Thomas Riermeier
发明人： Armin Börner , Jens Holz , Juan Almena , Renat Kadyrov , Axel Monsees , Thomas Riermeier
IPC分类号： C07F9/02
CPC分类号： C07F9/65683 , B01J31/2433
摘要： The present invention is directed to a process for preparing compounds of the general formula (I). Compounds of the general formula (I) are advantageous precursors for preparing phospholane catalysts, especially bisphospholane catalysts. The invention therefore likewise provides for the use of the substances in question for preparing these catalysts.
摘要翻译：本发明涉及制备通式（I）化合物的方法。通式（I）的化合物是制备磷脂催化剂，特别是双
磷脂催化剂的有利前体。因此，本发明同样提供了所讨论的物质用于制备这些催化剂的用途。

3. 发明授权

US09982001B2 Bisphosphites having an unsymmetric central biaryl unit 有权
公开(公告)号：US09982001B2
公开(公告)日：2018-05-29
申请号：US14958143
申请日：2015-12-03
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Armin Börner , Detlef Selent
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Armin Börner , Detlef Selent
IPC分类号： C07F9/6574 , C07C45/50 , C07F15/00 , C07F15/06
CPC分类号： C07F9/65744 , C07C45/50 , C07F9/65746 , C07F15/0033 , C07F15/0046 , C07F15/0073 , C07F15/06 , C07C47/02
摘要： Bisphosphites having an unsymmetric central biaryl unit.

4. 发明授权

US06570033B2 Bisphosphite compounds and their metal complexes 有权
标题翻译：二亚磷酸酯化合物及其金属络合物
公开(公告)号：US06570033B2
公开(公告)日：2003-05-27
申请号：US09984263
申请日：2001-10-29
申请人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
发明人： Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
IPC分类号： C07F908
CPC分类号： C07F9/65746 , C07C45/50 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： A bisphosphite of the formula I wherein R1, R2, R3 and R4 are each hydrogen, an aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon or heterocyclic or aliphatic-heterocyclic group having from 1 to 50 carbon atoms, F, Cl, Br, I, —CF3, —OR7, —COR7, —CO2R7, —CO2M, —SR7, —SO2R7, —SOR7, —SO3R7, —SO3M, —CO2NR7R8, NR7R8, N═CR7R8, NH2, where R1 to R4 are identical or different and may be covalently linked to one another; R7 and R8 are each hydrogen, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and may be identical or different; M is an alkali metal, alkaline earth metal, ammonium or phosphonium ion; Q is a substituted or unsubstituted divalent aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms where HO-Q-OH is a diol; W and X are each a substituted or unsubstituted aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms which may be identical or different or covalently linked to one another, provided that when the phosphite oxygens linked to W and X are each linked to an aromatic ring, then they are linked to different aromatic rings, metal complexes thereof, and a method for the hydroformylation of olefins.
摘要翻译：式I的二亚磷酸酯，其中R 1，R 2，R 3和R 4各自为氢，具有1至50个碳原子的脂族，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃或杂环或脂族杂环基，F，Cl，Br，I，-CF 3，-OR 7，-COR 7，-CO 2 R 7，-CO 2 M，-SR 7，-SO 2 R 7，-SOR 7，-SO 3 R 7，-SO 3 M，-CO 2 NR 7 R 8，NR 7 R 8，N = CR 7 R 8，NH 2，其中R 1至R 4相同或不同并且可以彼此共价连接; R 7和R 8各自为氢，具有1至25个碳原子的取代或未取代的脂族或芳族烃基，并且可以相同或不同; M 是碱金属，碱土金属，铵或鏻离子; Q是具有1至50个碳原子的取代或未取代的二价脂族，脂环族，脂族 - 脂环族，芳族，脂族 - 芳族烃，杂环或脂族杂环基团，其中 HO-Q-OH是二醇; W和X各自是取代或未取代的脂族基，脂环族，脂族 - 脂环族，芳族，芳族 - 芳族，脂族 - 芳族烃，具有1至50个碳原子的杂环或脂族 - 杂环基，其可以相同或不同或共价连接，条件是当亚磷酸酯连接到W和X各自连接到芳香环，然后它们连接到不同的芳环，其金属络合物和烯烃的加氢甲酰化方法。

5. 发明授权

US07009068B2 Phosphite compounds and the metal complexes thereof 失效
标题翻译：亚磷酸酯化合物及其金属络合物
公开(公告)号：US07009068B2
公开(公告)日：2006-03-07
申请号：US10485817
申请日：2002-08-07
申请人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
发明人： Reinhard Schmutzler , Ion Neda , Christine Kunze , Armin Börner , Detlef Selent , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese
IPC分类号： C07F9/02
CPC分类号： C07F15/0073 , B01J23/464 , B01J31/185 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65746 , C07C47/02
摘要： Phosphites of the formula I or II and their metal complexes, their preparation and the use of the phosphites as ligands in catalytic reactions, in particular in processes for the hydroformylation of olefins, are described.
摘要翻译：描述了式I或II的亚磷酸酯及其金属络合物，它们的制备和在催化反应中亚磷酸酯作为配体的用途，特别是在烯烃的加氢甲酰化方法中。

6. 发明授权

US06818770B2 Phosphinine compounds and metal complexes thereof 失效
标题翻译：膦化合物及其金属络合物
公开(公告)号：US06818770B2
公开(公告)日：2004-11-16
申请号：US09989077
申请日：2001-11-21
申请人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
发明人： Detlef Selent , Armin Börner , Renat Kadyrov , Cornelia Borgmann , Dieter Hess , Klaus-Diether Wiese , Dirk Röttger
IPC分类号： C07F928
CPC分类号： C07F15/06 , B01J31/185 , B01J31/187 , B01J31/1885 , B01J2231/321 , B01J2531/821 , B01J2531/822 , B01J2531/828 , B01J2531/845 , C07C45/50 , C07F9/65846 , C07F15/0046 , C07F15/0073 , C07F15/0086 , C07C47/02
摘要： Phosphinines of formula (I) can be combined with metal salts to prepare hydroformylation catalysts. The phosphinine complexes have two phosphorus centers that may be substituted with a variety of hetero atoms or alkyl substituents to modify the ligand characteristics of the phosphinine. Phosphinine metal complexes are employed under normal hydroformylation reaction conditions. The preparatory routes to the phosphinine ligands of formula (I) allow for their convenient synthesis.
摘要翻译：式（I）的膦可以与金属盐组合以制备加氢甲酰化催化剂。次膦酸络合物具有可以被各种杂原子或烷基取代基取代的两个磷中心，以改变次膦酸的配体特性。在正常加氢甲酰化反应条件下使用膦酸金属络合物。通式（I）的次膦酸配体的准备途径允许其方便的合成。

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