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1. 发明授权

US08741988B2 Use of cyclic carbonates in epoxy resin compositions 有权
标题翻译：在环氧树脂组合物中使用环状碳酸酯
公开(公告)号：US08741988B2
公开(公告)日：2014-06-03
申请号：US13158841
申请日：2011-06-13
申请人： Rainer Klopsch , Andreas Lanver , Achim Kaffee , Klaus Ebel , Miran Yu
发明人： Rainer Klopsch , Andreas Lanver , Achim Kaffee , Klaus Ebel , Miran Yu
IPC分类号： C08L63/00 , C08G59/00
CPC分类号： C08L63/00 , C08G59/00 , C08K5/04
摘要： The present invention relates to the use of cyclic carbonates of the formula I or a mixture thereof in epoxy resin compositions and also to epoxy resin compositions which comprise such cyclic carbonates. in which R1 and R2 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; R3 and R4 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group; or mixtures thereof, as additives in epoxy resin compositions.
摘要翻译：本发明涉及式I的环状碳酸酯或其混合物在环氧树脂组合物中的用途，还涉及包含这种环状碳酸酯的环氧树脂组合物。其中R1和R2彼此独立地是氢，C1-C6-烷基，C1-C4-烷氧基-C1-C4-烷基，C5-C6-环烷基，苯基，苯基-C1-C4-烷基，C2-C6- 烯基或C 2 -C 6炔基，或者R 1和R 2一起是C 3 -C 11 - 亚烷基; R 3和R 4彼此独立地是氢，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基，C 5 -C 6 - 环烷基，苯基，苯基-C 1 -C 4 - 烷基，C 2 -C 6 - 烯基或 C2-C6-炔基或R3和R4一起是C4-C6-亚烷基; 或其混合物，作为环氧树脂组合物中的添加剂。

2. 发明申请

US20110306702A1 USE OF CYCLIC CARBONATES IN EPOXY RESIN COMPOSITIONS 有权
标题翻译：循环碳酸酯在环氧树脂组合物中的应用
公开(公告)号：US20110306702A1
公开(公告)日：2011-12-15
申请号：US13158841
申请日：2011-06-13
申请人： Rainer KLOPSCH , Andreas Lanver , Achim Kaffee , Klaus Ebel , Miran Yu
发明人： Rainer KLOPSCH , Andreas Lanver , Achim Kaffee , Klaus Ebel , Miran Yu
IPC分类号： C08L63/10 , C09D163/10
CPC分类号： C08L63/00 , C08G59/00 , C08K5/04
摘要： The present invention relates to the use of cyclic carbonates of the formula I or a mixture thereof in epoxy resin compositions and also to epoxy resin compositions which comprise such cyclic carbonates. in which R1 and R2 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R1 and R2 together are a C3-C11-alkylene group; R3 and R4 independently of each other are hydrogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C5-C6-cycloalkyl, phenyl, phenyl-C1-C4-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, or R3 and R4 together are a C4-C6-alkylene group; or mixtures thereof, as additives in epoxy resin compositions.
摘要翻译：本发明涉及式I的环状碳酸酯或其混合物在环氧树脂组合物中的用途，还涉及包含这种环状碳酸酯的环氧树脂组合物。其中R1和R2彼此独立地是氢，C1-C6-烷基，C1-C4-烷氧基-C1-C4-烷基，C5-C6-环烷基，苯基，苯基-C1-C4-烷基，C2-C6- 烯基或C 2 -C 6炔基，或者R 1和R 2一起是C 3 -C 11 - 亚烷基; R 3和R 4彼此独立地是氢，C 1 -C 6 - 烷基，C 1 -C 4 - 烷氧基-C 1 -C 4 - 烷基，C 5 -C 6 - 环烷基，苯基，苯基-C 1 -C 4 - 烷基，C 2 -C 6 - 烯基或 C2-C6-炔基或R3和R4一起是C4-C6-亚烷基; 或其混合物，作为环氧树脂组合物中的添加剂。

3. 发明申请

US20120101306A1 PROCESS FOR THE PREPARATION OF 1-METHYLCYCLOPENTANE DERIVATIVES 审中-公开
标题翻译：制备1-甲基环戊烷衍生物的方法
公开(公告)号：US20120101306A1
公开(公告)日：2012-04-26
申请号：US13278688
申请日：2011-10-21
申请人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
发明人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
IPC分类号： C07C41/14 , C07C1/20 , C07C5/29 , C07C29/04
CPC分类号： C07C1/20 , C07C5/29 , C07C29/04 , C07C41/06 , C07C2601/10 , Y02P20/127 , C07C13/12 , C07C35/06 , C07C43/184
摘要： Process for the preparation of 1-methylcyclopentene by thermal reaction of cyclohexanol or cyclohexene or mixtures of both compounds to give 1-methylcyclopentene, wherein the resulting by-products 3-methylcyclopentene and 4-methylcyclopentene (double-bond isomers of 1-methylcyclopentene) are returned to the reaction.
摘要翻译：通过环己醇或环己烯或两种化合物的混合物的热反应制备1-甲基环戊烯得到1-甲基环戊烯的方法，其中得到的副产物3-甲基环戊烯和4-甲基环戊烯（1-甲基环戊烯的双键异构体）是回到了反应。

4. 发明申请

US20120101307A1 PROCESS FOR THE PREPARATION OF 1-METHYL-1-ALKOXYCYCLOPENTANES 审中-公开
标题翻译：制备1-甲基-1-烷氧基环戊二烯的方法
公开(公告)号：US20120101307A1
公开(公告)日：2012-04-26
申请号：US13279915
申请日：2011-10-24
申请人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
发明人： Andreas LANVER , Klaus Ebel , Rainer Klopsch , Werner Bertleff , Richard Dehn , Joaquim Henrique Teles , Helmut Kronemayer , Marcus Georg Schrems
IPC分类号： C07C41/01
CPC分类号： C07C41/06 , C07C5/29 , C07C2521/08 , C07C2601/08 , C07C2601/10 , Y02P20/127 , C07C43/184 , C07C13/12
摘要： Process for the preparation of cyclopentane derivatives of the formula I in which R is a C1- to C10-alkyl group, which comprises reacting cyclohexanol or cyclohexene or mixtures of both compounds to give 1-methyl-1-cyclopentene (1st stage) and subsequently adding a C1- to C10-alkanol onto the double bond of the 1-methyl-1-cyclopentene (2nd stage).
摘要翻译：制备式Ⅰ的环戊烷衍生物的方法，其中R为C1-至C10烷基，其包括使环己醇或环己烯或两种化合物的混合物反应得到1-甲基-1-环戊烯（第一阶段），随后在1-甲基-1-环戊烯的双键中加入C 1〜C 10链烷醇（第2阶段）。

5. 发明授权

US08692025B2 Process for preparing M- or P-substituted phenylalkanols by alkylation 有权
标题翻译：通过烷基化制备M-或P-取代的苯基链烷醇的方法
公开(公告)号：US08692025B2
公开(公告)日：2014-04-08
申请号：US13503515
申请日：2010-10-14
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/29 , C07C29/32
CPC分类号： C07C29/32 , C07C29/56 , C07C45/29 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m- or p-substituted phenylalkanols of the formula (I) in which R1 is bonded to the phenyl ring in the m- or p-position and is C1-C5-alkyl, and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein an unsubstituted phenylalkanol of the formula (II) in which R2, R3, R4 and R5 have the meanings given under formula (I) is alkylated together with a C1-C5-alkyl halide of the formula (III) R1-Hal (III), in which R1 has the meaning given under formula (I) and Hal is halogen, in the presence of a Friedel-Crafts catalyst to give an m- or p-alkyl-substituted phenylalkanol of the formula (I), then the reaction mixture is worked-up and the desired m- or p-alkyl-substituted phenylalkanol of the formula (I) is separated off, the other formed by-products are returned to the reaction mixture and these are isomerized in the presence of a Friedel-Crafts catalyst to give the desired m- or p-alkyl-substituted phenylalkanol. From the m- or p-alkyl-substituted phenylalkanols of the formula (I), it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which play an interesting role as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间 - 或对 - 取代的苯烷醇的方法，其中R 1与m-或p-位上的苯环键合并且是C1-C5-烷基，R2 R 3，R 4和R 5彼此独立地为氢或甲基，其中R 2，R 3，R 4和R 5具有式（I）所示含义的式（II）的未取代的苯基烷醇与其中R 1具有式（I）所示含义，Hal为卤素的式（III）R1-Hal（Ⅲ）的C1-C5烷基卤化物，在Friedel-Crafts催化剂存在下，得到m- 或式（I）的对烷基取代的苯基链烷醇，然后将反应混合物处理并分离所需的式（I）的间 - 或对 - 烷基取代的苯基烷醇，另一个形成的副产物返回到反应混合物中，并将它们在Friedel-Crafts催化剂存在下异构化，得到所需的间 - 或对 - 烷基取代的苯基 kanol 从式（I）的间 - 或对 - 烷基取代的苯烷醇，可以通过氧化或脱氢形成作为有价值的产物，相应的醛作为香料和香气化学品起着重要的作用。

6. 发明授权

US08686193B2 Method for producing M-substituted phenylalkanols by means of isomerization 失效
标题翻译：通过异构化制备M取代的苯基链烷醇的方法
公开(公告)号：US08686193B2
公开(公告)日：2014-04-01
申请号：US13503488
申请日：2010-10-19
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/51 , C07C29/56 , C07C47/22 , A61K8/18
CPC分类号： C07C29/56 , C07C45/29 , C11B9/0061 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m-substituted phenylalkanols of the formula (I) in which R1 is C1-C5-alkyl and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein a p-substituted phenylalkanol of the formula (II) in which R1, R2, R3, R4 and R5 having the meanings given under formula (I), is isomerized in the presence of a Friedel-Crafts catalyst to give an m-substituted phenylalkanol of the formula (I). From the m-substituted phenylalkanols of the formula (I) it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which are known as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间位取代的苯基烷醇的方法，其中R 1为C 1 -C 5 - 烷基且R 2，R 3，R 4和R 5彼此独立地为氢或甲基，其中a 式（II）的对取代的苯基链烷醇，其中具有式（I）给出的含义的R 1，R 2，R 3，R 4和R 5在Friedel-Crafts催化剂存在下异构化得到m-取代的苯基烷醇式（I）。从式（I）的间位取代的苯基烷醇可以通过氧化或脱氢形成作为有价值的产物，相应的醛被称为香料和芳香化学品。

7. 发明授权

US08367875B2 Process for the preparation of m-substituted alkyltoluenes by isomerization with ionic liquids as catalysts 有权
标题翻译：通过用离子液体作为催化剂异构化制备间取代的烷基甲苯的方法
公开(公告)号：US08367875B2
公开(公告)日：2013-02-05
申请号：US13024786
申请日：2011-02-10
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/45 , C07C5/22
CPC分类号： C07C45/62 , C07C5/2732 , C07C45/74 , C07C2527/126 , C07C15/02 , C07C47/228 , C07C47/232
摘要： The invention relates to a process for the preparation of m-substituted alkyltoluenes of the formula (I) in which R1 is C1-C5-alkyl, wherein a p-substituted alkyltoluene of the formula (II) in which R1 has the meaning given under formula (I), is isomerized in the presence of ionic liquids to give an m-substituted alkyltoluene of the formula (I). The m-substituted alkyltoluenes obtainable according to the invention are starting compounds for the preparation of fragrances and aroma substances.
摘要翻译：本发明涉及一种制备其中R 1为C 1 -C 5 - 烷基的式（I）的间位取代的烷基甲苯的方法，其中式（II）的对取代烷基甲苯其中R 1具有下面给出的含义式（I）的化合物在离子液体的存在下异构化，得到式（I）的间位取代的烷基甲苯。根据本发明可获得的m取代的烷基甲苯是用于制备香料和香料物质的起始化合物。

8. 发明申请

US20120209031A1 METHOD FOR PRODUCING M-SUBSTITUTED PHENYLALKANOLS BY MEANS OF ISOMERIZATION 失效
标题翻译：通过异构化制备M取代的苯乙醇的方法
公开(公告)号：US20120209031A1
公开(公告)日：2012-08-16
申请号：US13503488
申请日：2010-10-19
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C29/56 , C07C47/228 , C07C45/51
CPC分类号： C07C29/56 , C07C45/29 , C11B9/0061 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m-substituted phenylalkanols of the formula (I) in which R1 is C1-C5-alkyl and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein a p-substituted phenylalkanol of the formula (II) in which R1, R2, R3, R4 and R5 having the meanings given under formula (I), is isomerized in the presence of a Friedel-Crafts catalyst to give an m-substituted phenylalkanol of the formula (I). From the m-substituted phenylalkanols of the formula (I) it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which are known as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间位取代的苯基烷醇的方法，其中R 1为C 1 -C 5 - 烷基，R 2，R 3，R 4和R 5彼此独立地为氢或甲基，其中a 式（II）的对取代的苯基链烷醇，其中具有式（I）给出的含义的R 1，R 2，R 3，R 4和R 5在Friedel-Crafts催化剂存在下异构化得到m-取代的苯基烷醇式（I）。从式（I）的间位取代的苯基烷醇可以通过氧化或脱氢形成作为有价值的产物，相应的醛被称为香料和芳香化学品。

9. 发明申请

US20120209030A1 PROCESS FOR PREPARING M- OR P-SUBSTITUTED PHENYLALKANOLS BY ALKYLATION 有权
标题翻译：通过烷基化制备M取代或P-取代的苯基甘露醇的方法
公开(公告)号：US20120209030A1
公开(公告)日：2012-08-16
申请号：US13503515
申请日：2010-10-14
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/29 , C07C29/32
CPC分类号： C07C29/32 , C07C29/56 , C07C45/29 , C07C33/20 , C07C47/228
摘要： The invention relates to a process for the preparation of m- or p-substituted phenylalkanols of the formula (I) in which R1 is bonded to the phenyl ring in the m- or p-position and is C1-C5-alkyl, and R2, R3, R4 and R5, independently of one another, are hydrogen or methyl, wherein an unsubstituted phenylalkanol of the formula (II) in which R2, R3, R4 and R5 have the meanings given under formula (I) is alkylated together with a C1-C5-alkyl halide of the formula (III) R1-Hal (III), in which R1 has the meaning given under formula (I) and Hal is halogen, in the presence of a Friedel-Crafts catalyst to give an m- or p-alkyl-substituted phenylalkanol of the formula (I), then the reaction mixture is worked-up and the desired m- or p-alkyl-substituted phenylalkanol of the formula (I) is separated off, the other formed by-products are returned to the reaction mixture and these are isomerized in the presence of a Friedel-Crafts catalyst to give the desired m- or p-alkyl-substituted phenylalkanol. From the m- or p-alkyl-substituted phenylalkanols of the formula (I), it is possible to form, by oxidation or dehydrogenation, as products of value, the corresponding aldehydes, which play an interesting role as fragrances and aroma chemicals.
摘要翻译：本发明涉及一种制备式（I）的间 - 或对 - 取代的苯烷醇的方法，其中R 1与m-或p-位上的苯环键合并且是C1-C5-烷基，R2 R 3，R 4和R 5彼此独立地为氢或甲基，其中R 2，R 3，R 4和R 5具有式（I）所示含义的式（II）的未取代的苯基烷醇与其中R 1具有式（I）所示含义，Hal为卤素的式（III）R1-Hal（Ⅲ）的C1-C5烷基卤化物，在Friedel-Crafts催化剂存在下，得到m- 或式（I）的对烷基取代的苯基链烷醇，然后将反应混合物处理并分离所需的式（I）的间 - 或对 - 烷基取代的苯基烷醇，另一个形成的副产物返回到反应混合物中，并将它们在Friedel-Crafts催化剂存在下异构化，得到所需的间 - 或对 - 烷基取代的苯基 kanol 从式（I）的间 - 或对 - 烷基取代的苯烷醇，可以通过氧化或脱氢形成作为有价值的产物，相应的醛作为香料和香气化学品起着重要的作用。

10. 发明申请

US20110196176A1 PROCESS FOR THE PREPARATION OF M-SUBSTITUTED ALKYLTOLUENES BY ISOMERIZATION WITH IONIC LIQUIDS AS CATALYSTS 有权
标题翻译：通过与作为催化剂的离子液体异构化制备M取代的烷基甲苯的方法
公开(公告)号：US20110196176A1
公开(公告)日：2011-08-11
申请号：US13024786
申请日：2011-02-10
申请人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
发明人： Andreas Lanver , Klaus Ebel , Karl Beck , Ralf Pelzer , Jörg Botzem , Ulrich Griesbach
IPC分类号： C07C45/45 , C07C5/22
CPC分类号： C07C45/62 , C07C5/2732 , C07C45/74 , C07C2527/126 , C07C15/02 , C07C47/228 , C07C47/232
摘要： The invention relates to a process for the preparation of m-substituted alkyltoluenes of the formula (I) in which R1 is C1-C5-alkyl, wherein a p-substituted alkyltoluene of the formula (II) in which R1 has the meaning given under formula (I), is isomerized in the presence of ionic liquids to give an m-substituted alkyltoluene of the formula (I). The m-substituted alkyltoluenes obtainable according to the invention are starting compounds for the preparation of fragrances and aroma substances.
摘要翻译：本发明涉及一种制备其中R 1为C 1 -C 5 - 烷基的式（I）的间位取代的烷基甲苯的方法，其中式（II）的对取代烷基甲苯其中R 1具有下面给出的含义式（I）的化合物在离子液体的存在下异构化，得到式（I）的间位取代的烷基甲苯。根据本发明可获得的m取代的烷基甲苯是用于制备香料和香料物质的起始化合物。

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