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1. 发明申请

US20140316035A1 HYDROPHOBICALLY ASSOCIATING COPOLYMERS 审中-公开
标题翻译：疏水性共聚物
公开(公告)号：US20140316035A1
公开(公告)日：2014-10-23
申请号：US14323324
申请日：2014-07-03
申请人： ROLAND REICHENBACH-KLINKE , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Marcus Rösch , Bjorn Langlotz
发明人： ROLAND REICHENBACH-KLINKE , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Marcus Rösch , Bjorn Langlotz
IPC分类号： C08F220/58 , C08F220/60 , C04B16/04
CPC分类号： C08F220/58 , C04B16/04 , C04B2103/0052 , C04B2103/0053 , C08F220/26 , C08F220/56 , C08F220/60 , C08F228/02 , C08F230/02 , C08F2220/585 , C09K8/588 , E21B43/16
摘要： Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要翻译：包含新型疏水缔合单体的水溶性疏水缔合共聚物。单体包含烯属不饱和基团和具有嵌段结构的聚醚基团，其包含基本上由环氧乙烷基团组成的亲水性聚环氧烷嵌段，以及末端疏水性聚环氧烷嵌段，其由具有至少4个，优选至少5个碳原子。

2. 发明授权

US09163103B2 Hydrophobically associating copolymers 有权
标题翻译：疏水缔合共聚物
公开(公告)号：US09163103B2
公开(公告)日：2015-10-20
申请号：US14323324
申请日：2014-07-03
申请人： Roland Reichenbach-Klinke , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Marcus Rösch , Bjorn Langlotz
发明人： Roland Reichenbach-Klinke , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Marcus Rösch , Bjorn Langlotz
IPC分类号： C04B24/26 , C04B24/38 , C08F220/58 , C08F220/26 , C08F220/56 , C08F228/02 , C08F230/02 , C09K8/588 , E21B43/16 , C04B16/04 , C08F220/60 , C04B103/00
CPC分类号： C08F220/58 , C04B16/04 , C04B2103/0052 , C04B2103/0053 , C08F220/26 , C08F220/56 , C08F220/60 , C08F228/02 , C08F230/02 , C08F2220/585 , C09K8/588 , E21B43/16
摘要： Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要翻译：包含新型疏水缔合单体的水溶性疏水缔合共聚物。单体包含烯属不饱和基团和具有嵌段结构的聚醚基团，其包含基本上由环氧乙烷基团组成的亲水性聚环氧烷嵌段，以及末端疏水性聚环氧烷嵌段，其由具有至少4个，优选至少5个碳原子。

3. 发明申请

US20100331510A1 HYDROPHOBICALLY ASSOCIATING COPOLYMERS 有权
标题翻译：疏水性共聚物
公开(公告)号：US20100331510A1
公开(公告)日：2010-12-30
申请号：US12783877
申请日：2010-05-20
申请人： Roland Reichenbach-Klinke , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Markus Rösch , Björn Langlotz
发明人： Roland Reichenbach-Klinke , Thomas Pfeuffer , Kati Schmidt , Thomas Ostrowski , Reinhold J. Leyrer , Yulia Fogel , Stefan Friedrich , Peter Gaeberlein , Andrea Orleans , Manfred Schuhbeck , Marcus Guzmann , Markus Rösch , Björn Langlotz
IPC分类号： C08F230/02 , C08F216/12 , C08F220/26 , C08F220/00 , C08F228/02 , C08F220/56
CPC分类号： C08F220/58 , C04B16/04 , C04B2103/0052 , C04B2103/0053 , C08F220/26 , C08F220/56 , C08F220/60 , C08F228/02 , C08F230/02 , C08F2220/585 , C09K8/588 , E21B43/16
摘要： Water-soluble, hydrophobically associating copolymers which comprise new types of hydrophobically associating monomers. The monomers comprise an ethylenically unsaturated group and a polyether group with block structure comprising a hydrophilic polyalkylene oxide block which consists essentially of ethylene oxide groups, and a terminal, hydrophobic polyalkylene oxide block which consists of alkylene oxides with at least 4, preferably at least 5 carbon atoms.
摘要翻译：包含新型疏水缔合单体的水溶性疏水缔合共聚物。单体包含烯属不饱和基团和具有嵌段结构的聚醚基团，其包含基本上由环氧乙烷基团组成的亲水性聚环氧烷嵌段，以及末端疏水性聚环氧烷嵌段，其由具有至少4个，优选至少5个碳原子。

4. 发明授权

US08865639B2 Use of a copolymer as thickener in liquid detergents having lower graying tendency 有权
标题翻译：在具有较低变灰趋势的液体洗涤剂中使用共聚物作为增稠剂
公开(公告)号：US08865639B2
公开(公告)日：2014-10-21
申请号：US13578469
申请日：2011-02-11
申请人： Christofer Arisandy , Kati Schmidt , Reinhold J. Leyrer
发明人： Christofer Arisandy , Kati Schmidt , Reinhold J. Leyrer
IPC分类号： C11D3/37 , C11D17/00
CPC分类号： C11D17/003 , C11D3/3765
摘要： The invention relates to copolymers which contain a) at least 15% by weight units of an ethylenically unsaturated carboxylic acid, b) at least 15% by weight units of a C4-C8-alkylacrylats, c) less than 5% by weight units of methyl methacrylate, and are used as thickeners in liquid textile detergents. The copolymers can additionally contain units of a non-ionic ethylenically unsaturated surfactant monomer that are incorporated by polymerization. The thickeners are characterized by high thickening action, high shear thinning and low graying of the laundry after the washing process.
摘要翻译：本发明涉及含有a）至少15重量％单元的烯属不饱和羧酸的共聚物，b）至少15重量％的C 4 -C 8烷基丙烯酸酯单元，c）小于5重量％甲基丙烯酸甲酯，并用作液体织物洗涤剂中的增稠剂。共聚物可另外含有通过聚合引入的非离子型烯属不饱和表面活性剂单体的单元。增稠剂的特征在于洗涤过程后衣物的高增稠作用，高剪切变稀和低灰度。

5. 发明申请

US20130040870A1 USE OF A COPOLYMER AS THICKENER IN LIQUID DETERGENTS HAVING LOWER GRAYING TENDENCY 有权
标题翻译：在具有较低灰度倾向的液体洗涤剂中使用共聚物作为增稠剂
公开(公告)号：US20130040870A1
公开(公告)日：2013-02-14
申请号：US13578469
申请日：2011-02-11
申请人： Christofer Arisandy , Kati Schmidt , Reinhold J. Leyrer
发明人： Christofer Arisandy , Kati Schmidt , Reinhold J. Leyrer
IPC分类号： C08F220/18 , C11D17/00 , C08F220/20
CPC分类号： C11D17/003 , C11D3/3765
摘要： The invention relates to copolymers which contain a) at least 15% by weight units of an ethylenically unsaturated carboxylic acid, b) at least 15% by weight units of a C4-C8-alkylacrylats, c) less than 5% by weight units of methyl methacrylate, and are used as thickeners in liquid textile detergents. The copolymers can additionally contain units of a non-ionic ethylenically unsaturated surfactant monomer that are incorporated by polymerization. The thickeners are characterized by high thickening action, high shear thinning and low graying of the laundry after the washing process.
摘要翻译：本发明涉及含有a）至少15重量％单元的烯属不饱和羧酸的共聚物，b）至少15重量％的C 4 -C 8烷基丙烯酸酯单元，c）小于5重量％甲基丙烯酸甲酯，并用作液体织物洗涤剂中的增稠剂。共聚物可另外含有通过聚合引入的非离子型烯属不饱和表面活性剂单体的单元。增稠剂的特征在于洗涤过程后衣物的高增稠作用，高剪切变稀和低灰度。

6. 发明授权

US08232356B2 Method for producing a thickener dispersion 有权
标题翻译：生产增稠剂分散体的方法
公开(公告)号：US08232356B2
公开(公告)日：2012-07-31
申请号：US12681856
申请日：2008-11-13
申请人： Reinhold J. Leyrer , Kati Schmidt
发明人： Reinhold J. Leyrer , Kati Schmidt
IPC分类号： C08F2/24
CPC分类号： C08F2/22 , A61K8/04 , A61K8/8152 , A61K8/86 , A61K2800/48 , C08F220/06 , C08F220/18 , C08F222/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F265/06 , C08F267/02 , C08L51/003 , C11D3/3765 , C08L2666/02
摘要： A method is described for producing an aqueous thickener dispersion from a monomer composition made of at least one ethylenically unsaturated carboxylic acid and at least one ethylenically unsaturated hydrophobic monomer, (i) an at least partially polymerized pre-emulsion being produced from 10 to 80 wt.-% of said monomer composition, and (ii) the residual quantity of said monomer composition being added completely to the at least partially polymerized pre-emulsion and initiating a radical polymerization. The monomer composition preferably also comprises an associative monomer. The method avoids disadvantages of batch polymerization, such as inadequate batch-to-batch reproducibility and safety problems.
摘要翻译：描述了从由至少一种烯键式不饱和羧酸和至少一种烯属不饱和疏水单体制成的单体组合物制备水性增稠剂分散体的方法，（i）至少部分聚合的预乳液由10至80wt 所述单体组合物的％，和（ii）所述单体组合物的残留量完全添加到至少部分聚合的预乳液中并引发自由基聚合。单体组合物优选还包含缔合单体。该方法避免了批次聚合的缺点，例如批次间重复性不足和安全问题。

7. 发明申请

US20100210771A1 METHOD FOR PRODUCING A THICKENER DISPERSION 有权
标题翻译：生产较稠化剂分散体的方法
公开(公告)号：US20100210771A1
公开(公告)日：2010-08-19
申请号：US12681856
申请日：2008-11-13
申请人： Reinhold J. Leyrer , Kati Schmidt
发明人： Reinhold J. Leyrer , Kati Schmidt
IPC分类号： C08K5/06 , C08L33/00 , C08L33/10 , C08L33/08
CPC分类号： C08F2/22 , A61K8/04 , A61K8/8152 , A61K8/86 , A61K2800/48 , C08F220/06 , C08F220/18 , C08F222/06 , C08F265/00 , C08F265/02 , C08F265/04 , C08F265/06 , C08F267/02 , C08L51/003 , C11D3/3765 , C08L2666/02
摘要： A method is described for producing an aqueous thickener dispersion from a monomer composition made of at least one ethylenically unsaturated carboxylic acid and at least one ethylenically unsaturated hydrophobic monomer, (i) an at least partially polymerized pre-emulsion being produced from 10 to 80 wt.-% of said monomer composition, and (ii) the residual quantity of said monomer composition being added completely to the at least partially polymerized pre-emulsion and initiating a radical polymerization. The monomer composition preferably also comprises an associative monomer. The method avoids disadvantages of batch polymerization, such as inadequate batch-to-batch reproducibility and safety problems.
摘要翻译：描述了从由至少一种烯键式不饱和羧酸和至少一种烯属不饱和疏水单体制成的单体组合物制备水性增稠剂分散体的方法，（i）至少部分聚合的预乳液由10至80重量％所述单体组合物的％，和（ii）所述单体组合物的残留量完全添加到至少部分聚合的预乳液中并引发自由基聚合。单体组合物优选还包含缔合单体。该方法避免了批次聚合的缺点，例如批次间重复性不足和安全问题。

8. 发明授权

US07776237B2 Polymer dispersion with a colour effect 有权
标题翻译：聚合物色散具有色彩效果
公开(公告)号：US07776237B2
公开(公告)日：2010-08-17
申请号：US10553793
申请日：2004-05-04
申请人： Xu He , Reinhold J. Leyrer , Holger Schöpke
发明人： Xu He , Reinhold J. Leyrer , Holger Schöpke
IPC分类号： B05D5/06 , C09D5/36 , C09D7/14 , C09D5/02 , C09D151/10 , C08F2/22 , C08F265/00
CPC分类号： C08L51/003 , B05D3/0254 , B05D5/06 , C08F257/02 , C08F265/00 , C08F265/04 , C08F265/06 , C08F291/00 , C09D151/003 , Y10S525/902 , C08L2666/02
摘要： Process for improving the brilliance of color and the stability of a colored polymer system, which is composed of a matrix and of discrete polymer particles distributed in accordance with a defined spatial lattice structure in the matrix, and which is obtained by filming of an emulsion polymer with core/shell structure, which comprises using an emulsion polymer obtainable by polymerizing monomers in at least one first stage (core monomers), then polymerizing monomers in at least one further, second stage (transition stage), and finally polymerizing monomers in a third stage (shell monomers), where, based on the percentage constitution of the monomer mixtures of the three stages, at most 30% by weight of the monomers of the first stage are identical with those of the third stage, and 5% of the monomers of the second stage are identical with, respectively, those of the first and those of the third stage, and not more than 60% by weight of the monomers of the 2nd stage here are monomers absent in the 1st stage and also absent in the 3rd stage.
摘要翻译：用于提高颜色亮度和着色聚合物体系的稳定性的方法，其由基质和根据基质中限定的空间格子结构分布的离散聚合物颗粒组成，并且其通过将乳液聚合物具有核/壳结构，其包括使用可通过在至少一个第一阶段（核心单体）中聚合单体获得的乳液聚合物，然后在至少一个第二阶段（过渡阶段）中聚合单体，最后在第三阶段中聚合单体阶段（壳单体），其中基于三个阶段的单体混合物的百分比构成，至多30重量％的第一阶段的单体与第三阶段的单体相同，并且5％的单体第二阶段的单体分别与第一阶段和第三阶段的相同，并且不超过60重量％的第二阶段的单体是单体a 在第一阶段也没有在第三阶段。

9. 发明授权

US07767748B2 Aqueous polymer dispersions containing amphiphilic block copolymers, method for producing said dispersions and the use thereof 失效
标题翻译：含有两亲性嵌段共聚物的水性聚合物分散体，所述分散体的制造方法及其用途
公开(公告)号：US07767748B2
公开(公告)日：2010-08-03
申请号：US10586682
申请日：2005-02-08
申请人： Reinhold J. Leyrer , Ingolf Kuehn , Darijo Mijolovic
发明人： Reinhold J. Leyrer , Ingolf Kuehn , Darijo Mijolovic
IPC分类号： C08F2/16 , A61K9/16 , C07C37/00
CPC分类号： C08F2/24
摘要： Aqueous polymer dispersions which are obtainable by emulsion polymerization of ethylenically unsaturated monomers in an aqueous medium in the presence of free radical polymerization initiators and stabilizers, amphiphilic polymers which comprise one or more hydrophobic units (A) and one or more hydrophilic units (B) being used as the stabilizer before, during or after the polymerization, and the hydrophobic units (A) being formed from a polyisobutene block, at least 50 mol % of whose polyisobutene macromolecules have terminally arranged doubled bonds, processes for the preparation of the aqueous polymer dispersions by polymerizing ethylenically unsaturated monomers in the presence of free radical initiators and said amphiphilic polymers, which are used before, during or after the polymerization, and the use of the resulting aqueous polymer dispersions as associative thickeners in paper coating slips, in textile production, as thickeners for textile print pastes, in the pharmaceutical and cosmetics sector, for surface coatings, for detergents and cleaning agents, in foods and as oil field chemicals.
摘要翻译：在自由基聚合引发剂和稳定剂的存在下，通过在水性介质中的烯属不饱和单体的乳液聚合可获得的聚合物水分散体，包含一个或多个疏水单元（A）和一个或多个亲水单元（B）的两亲性聚合物是在聚合之前，期间或之后用作稳定剂，并且疏水单元（A）由聚异丁烯嵌段形成，其至少50摩尔％的聚异丁烯大分子具有末端排列的双键，制备聚合物水分散体的方法通过在自由基引发剂和在聚合之前，期间或之后使用的所述两亲性聚合物的存在下聚合烯属不饱和单体，以及在纺织品生产中使用所得水性聚合物分散体作为纸涂布纸中的缔合增稠剂，如纺织印花糊剂增稠剂，制药业a 化妆品行业，用于表面涂料，洗涤剂和清洁剂，食品和油田化学品。

10. 发明申请

US20090188054A1 Aqueous polymer dispersions containing alkenyl succinic acid anhydrides, methods for the production thereof, and use of the same 审中-公开
标题翻译：含有烯基琥珀酸酐的聚合物水分散体，其制备方法及其用途
公开(公告)号：US20090188054A1
公开(公告)日：2009-07-30
申请号：US10585339
申请日：2005-01-14
申请人： Rainer Dyllick-Brenzinger , Reinhold J. Leyrer , Andreas Brockmeyer , Markus Schmid , Roland Ettl
发明人： Rainer Dyllick-Brenzinger , Reinhold J. Leyrer , Andreas Brockmeyer , Markus Schmid , Roland Ettl
IPC分类号： C08F220/40 , D06M15/51
CPC分类号： D06M13/13 , C08F2/22 , C08F2/44 , C14C9/00 , D06M13/203 , D21H17/16 , D21H21/16
摘要： Aqueous alkenylsuccinic anhydride-containing polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkenylsuccinic anhydrides, processes for the preparation of such polymer dispersions by polymerizing hydrophobic monomers by a miniemulsion polymerization method in the presence of at least one alkenylsuccinic anhydride and, if appropriate, an alkyldiketene, and use of the resulting aqueous alkenylsuccinic anhydride-containing polymer dispersions as engine and surface sizes for paper and for imparting water repellency to leather, natural and/or synthetic fibers and textiles.
摘要翻译：含有烯基琥珀酸酐的聚合物分散体，其可通过在烯基琥珀酸酐的存在下的疏水性单烯属不饱和单体的细乳液聚合获得，通过在至少一种烯基琥珀酸存在下通过微乳液聚合法聚合疏水单体来制备这种聚合物分散体的方法酸酐，如果合适的话，可以使用烷基染料，使用得到的含有链烯基琥珀酸酐的聚合物分散液作为纸张的引擎和表面尺寸，并赋予皮革，天然和/或合成纤维和纺织品防水性。

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