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    • 2. 发明申请
    • 1,3-OXAZIN-4-ONE DERIVATIVES AS HERBICIDES
    • 1,3-氧杂-4-酮衍生物作为除草剂
    • WO1997000865A1
    • 1997-01-09
    • PCT/EP1996002616
    • 1996-06-18
    • RHONE-POULENC AGRICULTURE LTD.MITSUBISHI CHEMICAL CORPORATIONCRAMP, Michael, ColinUSUI, YoshihiroHAYASHIZAKI, Keiichi
    • RHONE-POULENC AGRICULTURE LTD.MITSUBISHI CHEMICAL CORPORATION
    • C07D265/06
    • C07D265/06A01N43/86
    • 1,3-oxazin-4-ones of formula (I), wherein R represents phenyl optionally substituted; R represents: a straight- or branched-chain alkyl having from one to ten carbon atoms which is substituted by one or more groups R which may be the same or different; a straight- or branched-chain optionally halogenated alkenyl or alkynyl group having up to ten carbon atoms; or a group selected from cyano, -CHO, -COR , -CO2H, -CO2R , -COSR , -CONR R , -CH=NOH, -CH=NOR , -CH=NOCOR , -CH=NNR R , -CH2CN, -CH2NO2 and oxiranyl; R represents phenyl optionally susbtituted or R represents a first five to seven membered heteroaromatic ring; said first ring being optionally fused and said first ring being linked to the nitrogen atom of the group NR via one of the ring carbon atoms; R and R independently represent lower alkyl; W represents -NR -; R represents hydrogen, lower alkyl, haloalkyl, alkenyl, alkynyl, -COR or -CO2R ; and their use as herbicides.
    • (I)的1,3-恶嗪-4-酮,其中R 1表示任选取代的苯基; R 2表示:具有1至10个碳原子的直链或支链烷基,其被一个或多个可以相同或不同的基团R 8取代; 具有至多10个碳原子的直链或支链任选卤代的烯基或炔基; 或选自氰基,-CHO,-COR 7,-CO 2 H,-CO 2 R 7,-COSR 7,-CONR 9 R 10,-CH = NOH,-CH = NOR -CH = NOCOR 7,-CH = NNR 9 R 10,-CH 2 CN,-CH 2 NO 2和环氧乙烷基; R 3表示任选被取代的苯基,或R 3表示第一个五元至七元杂芳环; 所述第一环任选地稠合,并且所述第一环通过环碳原子连接到基团NR 6的氮原子; R 4和R 5独立地表示低级烷基; W表示-NR 6 - ; R 6代表氢,低级烷基,卤代烷基,烯基,炔基,-COR 7或-CO 2 R 7; 及其作为除草剂的用途。
    • 4. 发明申请
    • 1,3-OXAZIN-4-ONE DERIVATES AS HERBICIDES, PROCESS AND INTERMEDIATES FOR THEIR PREPARATION
    • 作为除草剂的1,3-氧化物-4-酮衍生物,其制备方法和中间体
    • WO1997040041A1
    • 1997-10-30
    • PCT/EP1997001733
    • 1997-04-08
    • RHONE-POULENC AGRICULTURE LTD.MITSUBISHI CHEMICAL CORPORATIONHAYASHIZAKI, KeiichiUSUI, YoshihiroWHITE, Catherine, Jacqueline
    • RHONE-POULENC AGRICULTURE LTD.MITSUBISHI CHEMICAL CORPORATION
    • C07D413/04
    • C07D413/04A01N43/86C07D265/06
    • 1,3-oxazin-4-ones of formula (I) wherein W represents -NR ; R represents thiophene optionally substituted by one to three groups which may be the same or different selected from halogen, hydroxy, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, -S(O)nR , -CO2R , COR , cyano, nitro and phenoxy; R represents hydrogen, lower alkyl, lower haloalkyl, alkoxyalkyl, lower alkenyl, lower haloalkenyl, alkoxyalkenyl, -CHO, -COR , -CO2R , -CH2NO2, and lower alkyl which is substituted by a group selected from -S(O)mR and -OCOR ; R represents phenyl optionally substituted by one to five groups which may be the same or different selected from halogen, lower alkyl, lower haloalkyl, lower alkoxy, lower haloalkoxy, -S(O)nR , -CO2R ,-COR , cyano, nitro, -OH, phenoxy, -NR R and -SF5; or a cycloalkyl group containing from three to six carbon atoms, optionally substituted by lower alkyl, lower haloalkyl or one or more halogen atoms which may be the same or different; R and R independently represent lower alkyl; and their use as herbicides.
    • 式(I)的1,3-恶嗪-4-酮,其中W表示-NR 6; R 1表示噻吩任选被一至三个可以相同或不同的选自卤素,羟基,低级烷基,低级卤代烷基,低级烷氧基,低级卤代烷氧基,-S(O)n R 7,-CO 2 R COR 7,氰基,硝基和苯氧基; R 2表示氢,低级烷基,低级卤代烷基,烷氧基烷基,低级烯基,低级卤代烯基,烷氧基烯基,-CHO,-COR 7,-CO 2 R 7,-CH 2 NO 2,以及被基团取代的低级烷基 选自-S(O)mR 7和-OCOR 7; R 3表示任选被一至五个可以相同或不同的选自以下的基团取代的苯基:卤素,低级烷基,低级卤代烷基,低级烷氧基,低级卤代烷氧基,-S(O)nR 7,-CO 2 R 7 COR 7,氰基,硝基,-OH,苯氧基,-NR 8 R 9和-SF 5; 或含有3至6个碳原子的环烷基,任选被低级烷基,低级卤代烷基或一个或多个可以相同或不同的卤素原子取代; R 4和R 5独立地表示低级烷基; 及其作为除草剂的用途。
    • 9. 发明申请
    • PIGMENT COMPOSITION FOR LIQUID TONER, METHOD OF MANUFACTURING THE SAME AND LIQUID TONER MANUFACTURING METHOD
    • 液体色粉的颜料组合物,其制造方法和液体制备方法
    • WO1997049007A1
    • 1997-12-24
    • PCT/JP1997002114
    • 1997-06-19
    • MITSUBISHI CHEMICAL CORPORATIONMITSUBISHI HEAVY INDUSTRIES, LTD.HISASHI, HideyukiMATSUGI, AkihiroSUDA, YasuharuKUNO, HiroakiMAKINO, Katsuaki
    • MITSUBISHI CHEMICAL CORPORATIONMITSUBISHI HEAVY INDUSTRIES, LTD.
    • G03G09/12
    • G03G9/125G03G9/122
    • A pigment composition for liquid toner which is prepared by dissolving/dispersing carbon black and a resin in a nonaqueous solvent. One of (1) carbon black containing not more than 10 ppm of grit and not more than 0.1 wt.% of ash, (2) carbon black in which the quotient of the division of the total quantity of oxygen determined on the basis of a 1500 DEG volatile component by the specific surface area is 0.20-0.40 mg/m , and (3) carbon black in which the content of polycyclic aromatic hydrocarbons in a liquid extracted by using monochlorobenzene is not more than 30 ppm, is used as the carbon black. The pigment composition is manufactured by kneading a pigment and a resin, freeze-pulverizing the resultant product, and then dissolving/dispersing the powder in a nonaqueous solvent. Thus a pigment composition for liquid toner enabling excellent image characteristics, especially, image characterisitics with a sufficiently high printing density, and a pigment composition for liquid toner exerting little influence upon a living body even if it is inhaled and having excellent image characteristics are provided.
    • 通过将炭黑和树脂溶解/分散在非水溶剂中而制备的用于液体调色剂的颜料组合物。 (1)炭黑中含有不大于10ppm的砂粒和不超过0.1重量%的灰分,(2)炭黑,其中基于a确定的氧气总量除数的商 1500份挥发性成分的比表面积为0.20-0.40mg / m 2,(3)使用一氯苯萃取的液体中多环芳烃的含量不超过30ppm的碳黑 作为炭黑。 颜料组合物通过捏合颜料和树脂,将所得产物冷冻粉碎,然后将粉末溶解/分散在非水溶剂中来制备。 因此,提供了具有优异的图像特性,特别是具有足够高的印刷密度的图像特征的液体调色剂用颜料组合物,以及即使吸入并且具有优异的图像特性对活体几乎没有影响的液体调色剂的颜料组合物。
    • 10. 发明申请
    • MEDIA FOR THE TISSUE CULTURE OF PLANTS AND METHOD OF CULTURE WITH THE SAME
    • 植物组织培养基及其培养方法
    • WO1997048271A1
    • 1997-12-24
    • PCT/JP1997002088
    • 1997-06-18
    • NISSHINBO INDUSTRIES INC.MITSUBISHI CHEMICAL CORPORATIONHASEGAWA, OsamuTADOKORO, FumihikoTAKAHASHI, Nobumitsu
    • NISSHINBO INDUSTRIES INC.MITSUBISHI CHEMICAL CORPORATION
    • A01H04/00
    • A01H4/001
    • Materials for media to be used for efficiently effecting the proliferation and acclimatization of plants to be tissue-cultured to thereby give mature seedlings; a process for producing these materials; and a culture method characterized by using these media. The tissue culture media are characterized by containing vermiculite having an average grain size of 0.1 to 10 mm and cellulose fibers having an average fiber length of 0.01 to 5 mm. In the culture method, the above medium is used in a light-transmittable container at least partly covered with a porous film having a gas permeability (air permeability: JIS P 8117) of, preferably, 1 to 50 sec/100 ml. By using a medium produced by molding a mixture of a specific vermiculite with cellulose fibers, the culture can be efficiently carried out with good handling characteristics and good rooting and growth can be achieved. Thus, good seedlings can be obtained by a single culture without resort to acclimatization. Moreover, these seedlings can be transplanted and grown as such in the soil for raising the same outside without damaging the roots. Combined use of the medium with a gas-permeable container makes these effects further remarkable.
    • 用于有效影响待组织培养的植物的增殖和驯化的培养基的材料,从而产生成熟的幼苗; 一种生产这些材料的方法; 以及使用这些培养基的培养方法。 组织培养基的特征在于含有平均粒径为0.1〜10mm的蛭石和平均纤维长度为0.01〜5mm的纤维素纤维。 在培养方法中,将上述培养基用于至少部分被透气性(透气度:JIS P 8117)的多孔膜覆盖的透光性容器中,优选为1〜50秒/ 100ml。 通过使用通过将特定蛭石的混合物与纤维素纤维成型而制备的介质,可以有效地进行培养,具有良好的处理特性,并且可以实现良好的生根和生长。 因此,通过单一培养可以获得良好的幼苗,而不需要适应环境。 此外,这些幼苗可以在土壤中移植和生长,以便在不损害根部的情况下提高相同的外部。 将介质与气体渗透性容器结合使用,使这些效果更加显着。