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    • 3. 发明申请
    • METHOD FOR MAKING END COMPOUNDS FROM INTERNAL KETONES ISSUED FROM THE DECARBOXYLATIVE KETONIZATION OF FATTY ACIDS OR FATTY ACID DERIVATIVES
    • 从脂肪酸或脂肪酸衍生物的脱羧酮化反应中得到的来自内酮的终化合物的制备方法
    • WO2018087181A1
    • 2018-05-17
    • PCT/EP2017/078665
    • 2017-11-08
    • RHODIA OPERATIONS
    • BACK, OlivierLEROY, RémyMARION, Philippe
    • C07C45/48C07C49/04
    • Method (M) for the preparation of an end compound from an internal ketone, said method comprising: - synthesizing the internal ketone by a process (P) for the decarboxylative ketonization of a fatty acid, a fatty acid derivative or a mixture thereof in a liquid phase with a metal compound as catalyst in the substantial absence of added solvent, wherein the fatty acid, fatty acid derivative or mixture thereof is added in sequential steps, the first step taking place at a temperature sequentially at a temperature from 100°C to 270°C, - causing the internal ketone to react in accordance with a single or multiple chemical reaction scheme involving at least one reagent other than the internal ketone, wherein at least one product of the chemical reaction scheme is the end compound that is not further caused to be chemically converted into another compound.
    • (M),用于由内酮制备末端化合物,所述方法包括: - 通过用于脂肪酸脱羧酮化的方法(P)合成内酮,脂肪酸 酸衍生物或其混合物在金属化合物作为催化剂的液相中在基本不存在添加的溶剂的情况下进行,其中脂肪酸,脂肪酸衍生物或其混合物以连续的步骤添加,第一步在相继的温度下进行 在100℃至270℃的温度下,使内部酮根据涉及除内部酮之外的至少一种试剂的单个或多个化学反应方案反应,其中化学反应方案的至少一种产物 是最终化合物,它不会进一步化学转化成另一种化合物。