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1. 发明专利

JP2000297064A INTERMEDIATE FOR PRODUCING POLYFUNCTIONAL PERHALOGENATED POLYORGANOSILOXANE 失效
公开(公告)号：JP2000297064A
公开(公告)日：2000-10-24
申请号：JP2000078199
申请日：2000-03-21
申请人： RHODIA CHIMIE SA
发明人： JOST PHILIPPE , KARRER PHILIPPE , MIGNANI GERARD , OLIER PHILIPPE
IPC分类号： C07C69/65 , C07F7/18 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37
摘要： PROBLEM TO BE SOLVED: To obtain a new compound containing a specific perhalogenated group, useful for producing a perhalogenated polyorganosiloxane(POS) suitable as a stain repulsive agent. SOLUTION: This (per)halogenated α-olefin compound is shown by formula I [Rq and R9 are each H or a 1-6C alkyl; R10 and R11 are each OH, a 1-6C alkoxy, a Z3-Rf (Z3 is a group of the formula O-CH2 or the like; Rf is a perhalogen) and at least one of R10 and R11 is Z3-Rf; i is 0-20], formula II or formula III such as a perfluoroalkyl compound IV. The compound of formula IV is obtained by reacting diethyl allylmalonate with C2F17, Ti(OEt)4 and dried toluene in a nitrogen atmosphere at 95 deg.C, removing ethanol in vacuum and further reacting the resultant substance with Ti(OEt)4. The compound of formula IV is reacted with a Si-H unit-containing silicone oil and allylsuccinic acid anhydride in the presence of a Karstedt catalyst to give a polyfunctional POS.

2. 发明申请

WO2004054941A3 METHOD FOR ENHANCING WATER-REPELLENCY TREATMENT OF MINERAL HYDRAULIC BINDER COMPOSITIONS AND COMPOSITIONS OBTAINABLE BY SAID METHOD AND THEIR USES 审中-公开
标题翻译：矿物液压组合物水分循环处理方法及采用方法及其用途获得的组合物
公开(公告)号：WO2004054941A3
公开(公告)日：2004-08-05
申请号：PCT/FR0303699
申请日：2003-12-12
申请人： RHODIA CHIMIE SA , CASTAING JEAN-CHRISTOPHE , BAKER GARY , JOST PHILIPPE
发明人： CASTAING JEAN-CHRISTOPHE , BAKER GARY , JOST PHILIPPE
IPC分类号： C04B24/08 , C04B40/00 , C04B28/02
CPC分类号： C04B24/085 , C04B40/0042 , C04B2103/0057 , C04B2103/65 , C04B14/02 , C04B24/26 , C04B28/02 , C04B24/163
摘要： The invention concerns a method for enhancing water-repellency treatment of mineral hydraulic binder compositions and compositions obtainable by said method and their uses in the building sector.
摘要翻译：本发明涉及一种增强矿物水硬性粘合剂组合物和通过所述方法获得的组合物的防水处理方法及其在建筑部门中的用途的方法。

3. 发明专利

AT260312T 未知
公开(公告)号：AT260312T
公开(公告)日：2004-03-15
申请号：AT96420252
申请日：1996-07-25
申请人： RHODIA CHIMIE SA
发明人： JOST PHILIPPE , KARRER PHILIPPE , MIGNANI GERARD , OLIER PHILIPPE
IPC分类号： C08L83/04 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37
摘要： Halogenated pref. fluorinated polyorganosiloxanes (POS) have the formula Ä(R )a1(Gf)b1SiO1/2Ü-ÄR GfSiO2/2Üp-ÄHR SiO2/2Üy 1-Ä(R )2SiO2/2Üy-Ä(R )a2(Gf)b2SiO1/2Ü (I) and (II). In the formulae, (i) a1 + b1 =3; a2 + b2 = 3; a2 = 2, 3; b1, b2, = 0, 1; p = 0-200 (1-90); y1 = 0-10 (0-5); y = 0-50 (0-25); with p + y1 + y = 5-200 (10-100) and (p/(p + y + y1 + 2)Ü x 100 ≥ 3 (pref. 5); (ii) p' = 1-9 (1-4.5); (iii) y1' = 0-0.5 pref. 0.25; (iv) y' = 0-5 (pref. 0.5); (v) R1-2 = 1-12C (1-6C) aryl, aralkyl, alkylaryl (opt. branched); (vi) (Gf)= -(Z1)h-(Z2)g-Ä(Z3)j-RfÜk with h = 0.1; g = 0.1; j = 0.1; and k = 1 or 2; ≥ 1 Gf gp. is present in POS p; Z1= -(CmH2m)-with m ≥ 2 and, if m = 2 then g > 0 in ≥ 1 Gf; Z2 = -W(-C(O)-)2, -CRa(-C(O)-)2, -W(OH)-, -ÄW-NH-COÜ-, -ÄW-C(O)-Ü-, -Si(R6)

4. 发明专利

ES2187630T3 未知
公开(公告)号：ES2187630T3
公开(公告)日：2003-06-16
申请号：ES96420251
申请日：1996-07-25
申请人： RHODIA CHIMIE SA
发明人： JOST PHILIPPE , KARRER PHILIPPE , MIGNANI GERARD , OLIER PHILIPPE
IPC分类号： C07C69/65 , C07F7/18 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37
摘要： Halogenated pref. fluorinated polyorganosiloxanes (POS) have the formula Ä(R )a(Gf)b(E)pSiO1/2Ü-ÄR GfSiO2/2Üz-ÄR ESiO2/2 Üe-ÄHR SiO2/2Üy1-Ä(R )2-SiO2/2Üy-Ä(R )a (Gf)b(E)p-SiO1/2Ü (I) and (II). In the formulae, (i) a + b + p = 3; a = 2, 3; b, p = 0, 1; z = 0- 200 (1-90); y1 = 0-10 (0-5); y = 0-50 (0-25); and e = 1-200 (1-90); with the conditions if z is not 0 then y + y1 + e =5-200 (10-100) and (z/(z + y + y1 + e + 2) x 100 ≥ 3 (pref. ≥ 5); if z = 0 then y=y1 +e = 5-50 and b > 0 in at least one alkoxy group; if e > 0 then z + y1 + y + e = 5-200 (pref. 10-100) and (z/(z + y + y1 + e + 2)) x 100 ≥ 3 (pref. ≥ 5); and if e = 0 then y + y1 + z = 5-100 and p > 0 in at least one group; (ii) z' = 1-9 (1-4.5); (iii) y1' = 0-0.5 (0.25); (iv) y' = 0-5 (0.5); (v) R1-2 = 1-12C (1-6C) aryl, aralkyl, alkylaryl (opt. branched); (vi) (Gf) = -(Z1)h-(Z2)g-Ä(Z3)j-RfÜk with h = 0.1;g = 0.1; j = 0.1; and k = 1 or 2; at least one Gf group is present in POS pref. 60% per mol.; Z1 = (CmH2m) with m ≥ 2 and, if m = 2 then g > 0 in at least one Gf; Z2 = -W(-C(O)-)2, -CRa(-C(O)-)2, -W(OH)-, -ÄW-NH-COÜ-, -ÄW-C(O)-Ü-, -Si(R ) = H or 1-6C alkyl; in each case, one free valency is attached to Rf and the other to hydroxyl or 1-6C alkoxy; W = cyclic or non-cyclic hydrocarbon radical pref. aliphatic, alkenyl or aromatic; Z3 = with n ≥ 1, U = S, NH, NHSO, and pref. O; and Rf = -CqF2q-CF3, q ≥ 0, or -CqF2q-H, q ≥ 1, or -NRrfSO2CqF2q-CF3, q ≥ 0, Rrf = H, aryl, 1-6C alkyl; or -NRrfSO2CqF2q-H, q ≥ 1; and (vii) E is a monofunctional group chosen from e.g. amine alkoxyl, acyl, acyloxy, hydroxy, trialkoxysilyl, amide, ester, phenyl, arylalkoxy, aryloxy or ether-hydroxy.

5. 发明专利

ES2156402T3 未知
公开(公告)号：ES2156402T3
公开(公告)日：2001-06-16
申请号：ES97943006
申请日：1997-09-26
申请人： RHODIA CHIMIE SA
发明人： FEDER MICHEL , JOST PHILIPPE , LETOFFE MICHEL , DUCHAMP MARIE-CECILE
IPC分类号： C08J3/03 , C08L83/04 , C08L83/06 , C09D183/04 , C09J183/04
摘要： The invention concerns silicon dispersions hardenable by cross-linking and useable particularly as putty, paint or film coating. The aim of the invention is to provide an aqueous silicon dispersion capable of cross-linking by water elimination into an elastomer with suitable mechanical properties and having a high cohesive and adhesive force on supports of different kinds and eliminating the drawbacks of known dispersions, in particular concerning safety/toxicity (VOC content) and facility for use. This aim is achieved by the dispersion characterised in that it contains hydroxylated condensable constituents and is free from hydrolyzable substituents (Sofh) capable of being transformed into VOC, it is free from VOC and polyvinyl alcohol and it contains an alpha , omega -diOH POS (A), an adherence promoter (B) with Fas = NH2 functions and OH functions, and optionally: a catalyst (C) [tin salts], a surfactant (D), a cross-linking agent (E) (MDT hydroxylated POS resin), fillers (F), a dispersing agent (G), a plasticizer (H), an antifungal agent (I), an antifoaming agent (J), a stabiliser (K) or a base (L). The invention is useful for putty or film coatings prepared with this dispersion.

6. 发明专利

DK0792322T3 未知
公开(公告)号：DK0792322T3
公开(公告)日：1999-11-01
申请号：DK95940317
申请日：1995-11-15
申请人： RHODIA CHIMIE SA
发明人： PEIGNIER MICHEL , JOST PHILIPPE , GAY MICHEL , PRIOU CHRISTIAN
IPC分类号： C08L83/06 , C07F7/08 , C07F7/21 , C08G77/38 , C08G77/392 , C08L83/08
摘要： The present invention relates to multifunctionalized alkoxy, the alkoxy functionality Y being introduced onto a suitable polyhydrooorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the functionality W by a hydrosilylation reaction from the olefinic compound from which W derives. The multifunctionalized alkoxy polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions and as silica covering agents in silicone compositions containing fillers.

7. 发明专利

ES2133834T3 未知
公开(公告)号：ES2133834T3
公开(公告)日：1999-09-16
申请号：ES95940318
申请日：1995-11-15
申请人： RHODIA CHIMIE SA
发明人： JOST PHILIPPE , PEIGNIER MICHEL , PRIOU CHRISTIAN
IPC分类号： C08L83/06 , C07F7/08 , C07F7/21 , C08G77/38 , C08G77/385 , C08G77/395 , C08G77/50 , C08L83/08 , C09D183/06 , C09D183/08
摘要： The present invention relates to multifunctionalized polyorganosiloxanes comprising, per molecule at least one functional siloxy unit Y having C1-C5 alkoxy radical and at least one other functional siloxy unit W having an halogenated or polyhalogenated alkyl, aralkyl or aryl; polyether ether; epoxidized alkyl; alkoxyalkyl; hydroxylated, carbonylated or esterified alkyl; phenol; and alkoxysilyl; and optionally at least one siloxy unit having a SiH group. The alkoxy functionality Y is introduced onto a suitable polyhydroorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the non-hydrogen functionality W by a hydrosilylation reaction from the olefinic compound from which W derives. The multifunctionalized polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions.

8. 发明专利

FR2861398A1 Oxidation of thiocarbonylthio end groups in polymers made by radical polymerisation in presence of thiocarbonylthio agents, involves treatment with ozone-containing gas in order to stabilise the polymer 未知
公开(公告)号：FR2861398A1
公开(公告)日：2005-04-29
申请号：FR0312338
申请日：2003-10-22
申请人： RHODIA CHIMIE SA
发明人： ZARD SAMIR , SIRE BEATRICE , JOST PHILIPPE
IPC分类号： C08F8/06 , C08F293/00
摘要： A method for the partial or complete oxidation of one or more thiocarbonylthio end groups of a polymer obtained by radical polymerisation controlled by reversible addition-fragmentation with the aid of thiocarbonylthio reagents, involves contacting the polymer with ozone-containing gas so that the ozone reacts with the thiocarbonylthio groups. An independent claim is also included for polymers obtained by this method.

9. 发明专利

DK0755960T3 未知
公开(公告)号：DK0755960T3
公开(公告)日：2003-03-24
申请号：DK96420251
申请日：1996-07-25
申请人： RHODIA CHIMIE SA
发明人： KARRER PHILIPPE , MIGNANI GERARD , JOST PHILIPPE , OLIER PHILIPPE
IPC分类号： C07C69/65 , C07F7/18 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37
摘要： Halogenated pref. fluorinated polyorganosiloxanes (POS) have the formula Ä(R )a(Gf)b(E)pSiO1/2Ü-ÄR GfSiO2/2Üz-ÄR ESiO2/2 Üe-ÄHR SiO2/2Üy1-Ä(R )2-SiO2/2Üy-Ä(R )a (Gf)b(E)p-SiO1/2Ü (I) and (II). In the formulae, (i) a + b + p = 3; a = 2, 3; b, p = 0, 1; z = 0- 200 (1-90); y1 = 0-10 (0-5); y = 0-50 (0-25); and e = 1-200 (1-90); with the conditions if z is not 0 then y + y1 + e =5-200 (10-100) and (z/(z + y + y1 + e + 2) x 100 ≥ 3 (pref. ≥ 5); if z = 0 then y=y1 +e = 5-50 and b > 0 in at least one alkoxy group; if e > 0 then z + y1 + y + e = 5-200 (pref. 10-100) and (z/(z + y + y1 + e + 2)) x 100 ≥ 3 (pref. ≥ 5); and if e = 0 then y + y1 + z = 5-100 and p > 0 in at least one group; (ii) z' = 1-9 (1-4.5); (iii) y1' = 0-0.5 (0.25); (iv) y' = 0-5 (0.5); (v) R1-2 = 1-12C (1-6C) aryl, aralkyl, alkylaryl (opt. branched); (vi) (Gf) = -(Z1)h-(Z2)g-Ä(Z3)j-RfÜk with h = 0.1;g = 0.1; j = 0.1; and k = 1 or 2; at least one Gf group is present in POS pref. 60% per mol.; Z1 = (CmH2m) with m ≥ 2 and, if m = 2 then g > 0 in at least one Gf; Z2 = -W(-C(O)-)2, -CRa(-C(O)-)2, -W(OH)-, -ÄW-NH-COÜ-, -ÄW-C(O)-Ü-, -Si(R ) = H or 1-6C alkyl; in each case, one free valency is attached to Rf and the other to hydroxyl or 1-6C alkoxy; W = cyclic or non-cyclic hydrocarbon radical pref. aliphatic, alkenyl or aromatic; Z3 = with n ≥ 1, U = S, NH, NHSO, and pref. O; and Rf = -CqF2q-CF3, q ≥ 0, or -CqF2q-H, q ≥ 1, or -NRrfSO2CqF2q-CF3, q ≥ 0, Rrf = H, aryl, 1-6C alkyl; or -NRrfSO2CqF2q-H, q ≥ 1; and (vii) E is a monofunctional group chosen from e.g. amine alkoxyl, acyl, acyloxy, hydroxy, trialkoxysilyl, amide, ester, phenyl, arylalkoxy, aryloxy or ether-hydroxy.

10. 发明专利

ES2132749T3 未知
公开(公告)号：ES2132749T3
公开(公告)日：1999-08-16
申请号：ES95940317
申请日：1995-11-15
申请人： RHODIA CHIMIE SA
发明人： GAY MICHEL , JOST PHILIPPE , PEIGNIER MICHEL , PRIOU CHRISTIAN
IPC分类号： C08L83/06 , C07F7/08 , C07F7/21 , C08G77/38 , C08G77/392 , C08L83/08
摘要： The present invention relates to multifunctionalized alkoxy, the alkoxy functionality Y being introduced onto a suitable polyhydrooorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the functionality W by a hydrosilylation reaction from the olefinic compound from which W derives. The multifunctionalized alkoxy polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions and as silica covering agents in silicone compositions containing fillers.

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