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    • 2. 发明申请
    • DECOMPOSITION OF ALUMINUM NITRATE
    • 硝酸铝的分解
    • WO1981000401A1
    • 1981-02-19
    • PCT/US1980000552
    • 1980-05-09
    • REYNOLDS METALS CO
    • REYNOLDS METALS CODEWEY JRUSHING JSCOTT C
    • C01F07/30
    • C01F7/308C01P2004/51Y10S423/16
    • Method for the decomposition of aluminum nitrate crystals to alumina comprising the steps of: (a) melting the aluminum nitrate crystals; (b) evaporating from the melted crystals in a once through evaporator at the boiling temperature of the mixture and for a time sufficient to remove water and associated nitric acid and to provide a fluid having an alumina concentration of at least about 18% by weight; (c) decomposing the product of step (b) at a temperature of between about 150 and about 200`C and recovering the heat of condensation of the resultant vapors; (d) further decomposing the product of step (c) in a fluidized bed decomposer at a temperature of between about 300 and about 400`C to reduce the residual nitrate concentration in the product to between about5 and about 10 weight percent; (e) decomposing the product of step (d) in a fluidized bed decomposer at a temperature of between about 500 and about 800`C to reduce the residual nitrate concentration in the product to below about 3 percent by weight; and (f) calcining the product of step (e) at a temperature of at least about 1000`C.
    • 将硝酸铝晶体分解成氧化铝的方法包括以下步骤:(a)熔融硝酸铝晶体; (b)在混合物的沸腾温度下在一次性蒸发器中从熔融的晶体中蒸发出足够的时间以除去水和相关的硝酸,并提供氧化铝浓度至少为约18重量%的流体; (c)在约150至约200℃的温度下分解步骤(b)的产物并回收所得蒸气的冷凝热; (d)在流化床分解器中在约300至约400℃的温度下进一步分解步骤(c)的产物以将产物中的残留硝酸盐浓度降低至约5至约10重量%; (e)在流化床分解器中在约500至约800℃的温度下分解步骤(d)的产物以将产物中的残留硝酸盐浓度降低至低于约3重量%; 和(f)在至少约1000℃的温度下煅烧步骤(e)的产物。