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    • 8. 发明申请
    • USE OF METAL COMPLEX COMPOUNDS AS OXIDATION CATALYSTS
    • 使用金属复合化合物作为氧化催化剂
    • WO2005061688A1
    • 2005-07-07
    • PCT/GB2004/005297
    • 2004-12-17
    • RECKITT BENCKISER N.V.RECKITT BENCKISER (UK) LIMITEDGERET, Laurence
    • GERET, Laurence
    • C11D3/395
    • C11D3/3723C11D3/3932
    • An automatic dishwasher detergent formulation comprising: -a) a metal complex compound of formula: (I) [L n Me m X p ] z Y q wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q = z/(charge Y), and L is a ligand of formula: (II) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; -COOR 12 or -SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -SR 13 , -SO 2 R 13 or -OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; -NR 14 R 15 ; -(C 1 -C 6 alkylene)-NR 14 R 15 ; -N ® R 14 R 15 R 16 ; -(C 1 -C 6 alkylene)-N ® R 14 R 15 R 16 ; -N(R 13 )-(C 1 -C 6 alkylene)-NR 14 R 15 ; -N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; -N(R 13 )-(C 1 -C 6 alkylene)- N ® R 14 R 15 R 16 , -N[(C 1 -C 6 alkylene)-N ® R 14 R 15 R 16 ] 2 ; -N(R 13 )-N-R 14 R 15 or -N(R 13 )-N ® R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independ-ently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heteroatoms; with the proviso that (i) at least one of the substituents R 1 -R 11 contains a quaternized nitrogen atom which is not directly bonded to one of the three pyridine rings A, B or C and that (ii) Y is neither I - nor CI - in the case that Me is Mn(II), R 1 -R 5 and R 7 -R 11 are hydrogen and R 6 is: (A) as catalysts for oxidation reactions; and b) a sulphonated polymer.
    • 一种自动洗碗机洗涤剂配方,其包含:a)式(I)的金属络合物:其中Me是锰,钛,铁,钴,镍或铜,X是配位基或桥键基, n和m各自独立地为具有1至8的整数,p为0至32的整数,z为金属络合物的电荷,Y为抗衡离子,q为 = Z /(电荷Y),L为式(II)的配体,其中R1,R2,R3,R4,R5,R6,R7,R8,R9,R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基; -COOR 12或-SO 3 R 12,其中R 12在各种情况下为氢,阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13,-SO 2 R 13或-OR 13,其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -NR14R15; - (C 1 -C 6亚烷基)-NR 14 R 15; -N <(R)> R14R15R16; - (C 1 -C 6亚烷基)-N <(R)> R14R15R16; -N(R13) - (C 1 -C 6亚烷基)-NR 14 R 15; -N [(C1-C6亚烷基)-NR 14 R 15] 2; -N(R 13) - (C 1 -C 6亚烷基)-N(R)R 14 R 15 R 16,-N [(C 1 -C 6亚烷基)-N R 2 R 15 R 16] 2; -N(R 13)-N-R 14 R 15或-N(R 13)-N(R)> R 14 R 15 R 16,其中R 13如上所定义,R 14,R 15和R 16各自独立地为氢或未取代的 或取代的C 1 -C 18烷基或芳基,或R 14和R 15与它们键合的氮原子一起形成未取代或取代的可含有其它杂原子的5-,6-或7-元环; 条件是(i)至少一个取代基R 1 -R 11含有不直接与三个吡啶环A,B或C之一键合的季铵化氮原子,(ii)Y不是I - 在Me是Mn(II)的情况下,R1-R5和R7-R11是氢,R6是:(A)作为氧化反应的催化剂; 和b)磺化聚合物。