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1. 发明授权

US5744655A Process to make 2,3-dihalopropanols 失效
标题翻译：制备2,3-二卤丙醇的方法
公开(公告)号：US5744655A
公开(公告)日：1998-04-28
申请号：US667526
申请日：1996-06-19
申请人： P. J. Thomas , R. Garth Pews , Paul C. Vosejpka , George J. Frycek
发明人： P. J. Thomas , R. Garth Pews , Paul C. Vosejpka , George J. Frycek
IPC分类号： C07C29/141 , C07C31/36 , C07C45/35 , C07C45/63 , C07D301/26 , C07C31/34
CPC分类号： C07D301/26 , C07C29/141 , C07C45/35 , C07C45/63 , Y02P20/582
摘要： A 2,3-dihalopropanol is made by reacting 2,3-dihalopropanal with a hydrogenating agent in the presence of a transition metal-containing catalyst, under conditions such that 2,3-dihalopropanol is formed. The reaction is particularly useful as Step (3) in a process to make epihalohydrin by: (1) reacting a 3-carbon hydrocarbon with an oxidizing agent to form acrolein; (2) reacting acrolein with a molecular halogen to form 2,3-dihalopropanal; (3) reducing 2,3-dihalopropanal to form 2,3-dihalopropanol; and (4) cyclizing 2,3-dihalopropanol to make epihalohydrin. The process produces epihalohydrin using only about one mole of halogen per mole of epihalohydrin. It also uses substantially less water than existing processes.
摘要翻译：在含过渡金属的催化剂存在下，在形成2,3-二卤丙醇的条件下，通过2,3-二卤代丙醛与氢化剂反应制备2,3-二卤丙醇。在通过以下步骤制备表卤代醇的方法中，作为步骤（3）特别有用：（1）使3-碳烃与氧化剂反应形成丙烯醛; （2）使丙烯醛与分子卤素反应形成2,3-二卤代丙醛; （3）还原2,3-二卤丙醛以形成2,3-二卤丙醇; 和（4）环化2,3-二卤丙醇以制备表卤代醇。该方法使用每摩尔表卤代醇仅使用约1摩尔卤素产生表卤代醇。它还使用比现有工艺少得多的水。

2. 发明授权

US5491155A Substituted thiadiazoles, compositions containing them and their use as antimicrobial and marine antifouling agents 失效
标题翻译：取代的噻二唑，含有它们的组合物及其作为抗微生物剂和海洋防污剂的用途
公开(公告)号：US5491155A
公开(公告)日：1996-02-13
申请号：US360497
申请日：1994-12-21
申请人： Ravi B. Shankar , R. Garth Pews , Duane R. Romer
发明人： Ravi B. Shankar , R. Garth Pews , Duane R. Romer
IPC分类号： A01N43/82 , A01N43/832 , C07D285/10 , C09D5/14 , C09D5/16 , A61K31/41
CPC分类号： C07D285/10 , A01N43/82 , C09D5/14 , C09D5/1625
摘要： Substituted thiadiazoles which correspond to the formula: ##STR1## wherein X and Y each independently represents --Br, --Cl, --OCH.sub.3, --SCN, --OCH.sub.2 SCN, --SCH.sub.2 SCN, --OCH.sub.2 CH.sub.2 SCN or --SCH.sub.2 CH.sub.2 SCN, provided that at least one of X or Y represents --SCN, --OCH.sub.2 SCN, --SCH.sub.2 SCN, --OCH.sub.2 CH.sub.2 SCN or --SCH.sub.2 CH.sub.2 SCN are disclosed.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
摘要翻译：对应于下式的取代的噻二唑：其中X和Y各自独立地表示-Br，-Cl，-OCH 3，-SCN，-OCH 2 SCN，-SCH 2 SCN，-OCH 2 CH 2 SCN或-SCH 2 CH 2 SCN，条件是X或 Y表示-SCN，-OCH 2 SCN，-SCH 2 SCN，-OCH 2 CH 2 SCN或-SCH 2 CH 2 SCN。已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性，并且使用含有这些化合物的组合物。

3. 发明授权

US5466707A Dimercapto-1,3-dithiolo-2-one or thione maleimides, compositions containing them and their use as antimicrobial and marine antifouling agents 失效
标题翻译：二巯基-1,3-二硫代-2-酮或硫酮马来酰亚胺，含有它们的组合物及其作为抗微生物剂和海洋防污剂的用途
公开(公告)号：US5466707A
公开(公告)日：1995-11-14
申请号：US360490
申请日：1994-12-21
申请人： Weishi W. Wu , Ravi B. Shankar , Duane R. Romer , R. Garth Pews
发明人： Weishi W. Wu , Ravi B. Shankar , Duane R. Romer , R. Garth Pews
IPC分类号： A01N43/90 , C07D495/14 , C09D5/14 , C09D5/16 , A01N43/72 , C07D513/14
CPC分类号： C07D495/14 , A01N43/90 , C09D5/14 , C09D5/1625
摘要： Various 4,5-dimercapto-1,3-dithiolo-2-one or thione maleimides corresponding to the formula ##STR1## wherein R represents --H, phenyl, benzyl, phenethyl, a C.sub.1 -C.sub.10 straight or branched chain alkyl radical, a C.sub.3 -C.sub.10 cycloalkyl radical, a C.sub.1 -C.sub.10 straight or branched chain alkoxy radical, a C.sub.3 -C.sub.10 cycloalkoxy, an ester of the formula --CH.sub.2 CH.sub.2 O--C(O)--R.sup.1, wherein R.sup.1 represents a C.sub.1 -C.sub.5 straight or branched chain alkyl radical or a C.sub.3 -C.sub.5 cycloalkyl radical and Z represents oxygen or sulfur are disclosed.These compounds have been found to exhibit antimicrobial and marine antifouling activity in industrial and commercial applications and compositions containing these compounds are so employed.
摘要翻译：对应于式“IMAGE”的各种4,5-二巯基-1,3-二硫代-2-酮或硫酮马来酰亚胺，其中R表示-H，苯基，苄基，苯乙基，C1-C10直链或支链烷基， C 3 -C 10环烷基，C 1 -C 10直链或支链烷氧基，C 3 -C 10环烷氧基，式-CH 2 CH 2 O-C（O）-R 1的酯，其中R 1表示C 1 -C 5直链或支链烷基自由基或C3-C5环烷基，Z表示氧或硫。已经发现这些化合物在工业和商业应用中表现出抗微生物和海洋防污性，并且使用含有这些化合物的组合物。

4. 发明授权

US5349095A Process for preparing hydroxyalkylbenzocyclobutenes 失效
标题翻译：制备羟烷基苯并环丁烯的方法
公开(公告)号：US5349095A
公开(公告)日：1994-09-20
申请号：US982213
申请日：1992-11-25
申请人： P. J. Thomas , R. Garth Pews
发明人： P. J. Thomas , R. Garth Pews
IPC分类号： C07C29/14 , C07C33/34 , C07C45/00 , C07C45/51 , C07C49/792
CPC分类号： C07C49/792 , C07C29/14 , C07C33/34 , C07C45/004 , C07C45/513 , C07C2101/06
摘要： A process for preparing a substituted or unsubstituted 3- or 4-hydroxyalkylbenzocyclobutene compound comprises reducing a corresponding 3- or 4-formyl or ketobenzocyclobutene compound with a hydride at a temperature below that at which dimerization or oligomerization of the formyl- or ketobenzocycloutene compound or the thus-produced hydroxyalkylbenzocyclobutene compound is a significant side reaction, for a time sufficient to convert the formyl- or ketobenzocyclobutene compound to the hydroxyalkylbenzocyclobutene compound. In a two-step process, formylbenzocyclobutenes are prepared from bromobenzocyclobutenes in 90% yield or from benzocyclobutenes in a 70% yield, and then converted to hydroxymethylbenzocyclobutenes for an overall yield of about 85% from a bromobenzocyclobutene or of about 65% from a benzocyclobutene. In a two-step process, ketobenzocyclobutenes from bromobenzocyclobutene Grignard reagents and an N-alkanoyl- or N-aroyl-2-methylaziridine are converted to hydroxyalkylbenzocyclobutenes in high yields.
摘要翻译：取代或未取代的3-或4-羟基烷基苯并环丁烯化合物的方法包括在低于甲酰基或酮基苯并环丁烯化合物的二聚或低聚的温度下用氢化物还原相应的3-或4-甲酰基或酮基苯并环丁烯化合物或因此产生的羟烷基苯并环丁烯化合物是足够将甲酰基或酮基苯并环丁烯化合物转化为羟烷基苯并环丁烯化合物的显着副反应。在两步法中，甲酰基苯并环丁烯由90％产率的溴代苯并环丁烯或70％产率的苯并环丁烯制备，然后从溴代苯并环丁烯转化为羟甲基苯并环丁烯，总产率为约85％，或从苯并环丁烯转化为约65％。在两步法中，来自溴苯并环丁烯格氏试剂和N-烷酰基或N-芳酰基-2-甲基氮丙啶的酮基苯并环丁烯以高产率转化为羟基烷基苯并环丁烯。

5. 发明授权

US5149768A Hydroxy-functional poly(ether sulfonamides) as thermoplastic barrier resins 失效
标题翻译：作为热塑性阻隔树脂的羟基官能聚（醚磺酰胺）
公开(公告)号：US5149768A
公开(公告)日：1992-09-22
申请号：US718684
申请日：1991-06-21
申请人： Jerry E. White , Anthony P. Haag , R. Garth Pews
发明人： Jerry E. White , Anthony P. Haag , R. Garth Pews
IPC分类号： C08G59/40 , C08G59/44 , C08G75/00 , C08G75/30
CPC分类号： C08G59/444 , C09J2459/00 , C09J2463/00 , Y10T428/1379 , Y10T428/1383 , Y10T428/31511
摘要： Hydroxy-functional poly(ether sulfonamides) prepared by polymerizing an N,N'-dialkyl or N,N'-diaryldisulfonamide with a diepoxide in the presence of a suitable catalyst exhibit high barrier properties. These are suitable for use in the manufacture of articles such as rigid containers and flexible films exhibiting high barrier to oxygen.
摘要翻译：通过在合适的催化剂存在下通过用二环氧化物聚合N，N'-二烷基或N，N'-二芳基二磺酰胺制备的羟基官能的聚（醚磺酰胺）显示出高阻隔性。这些适用于制造诸如刚性容器和表现出高的阻氧性的柔性膜的制品。

6. 发明授权

US5041674A Process and intermediates for the preparation of 2,6-difluoroaniline 失效
标题翻译：制备2,6-二氟苯胺的方法和中间体
公开(公告)号：US5041674A
公开(公告)日：1991-08-20
申请号：US537975
申请日：1990-06-14
申请人： R. Garth Pews , James A. Gall
发明人： R. Garth Pews , James A. Gall
IPC分类号： C07C209/36 , C07C211/52
CPC分类号： C07C211/52 , C07C209/365
摘要： 1-Chloro-3,5-difluorobenzene is chlorinated to give 4,6-difluoro-1,2,3-trichlorobenzene which in turn is nitrated and reduced to the corresponding novel aniline, 2,6-difluoro-3,4,5-trichloroaniline. Further reduction of this aniline provides 2,6-difluoroaniline with high selectivity.
摘要翻译：氯化1-氯-3,5-二氟苯，得到4,6-二氟-1,2,3-三氯苯，然后将其硝化并还原成相应的新型苯胺，2,6-二氟-3,4,5 三氯苯胺该苯胺的进一步还原提供了高选择性的2,6-二氟苯胺。

7. 发明授权

US5006151A Substituted oxirane compounds 失效
标题翻译：取代的环氧乙烷化合物
公开(公告)号：US5006151A
公开(公告)日：1991-04-09
申请号：US464253
申请日：1990-01-12
申请人： R. Garth Pews
发明人： R. Garth Pews
IPC分类号： A01N43/20 , A01N47/12 , A01N47/34 , C07D303/46
CPC分类号： A01N43/20 , A01N47/12 , A01N47/34 , C07D303/46
摘要： Herbicidal compositions and methods utilizing novel substituted oxirane compounds as active ingredients are disclosed.
摘要翻译：公开了利用新的取代的环氧乙烷化合物作为活性成分的除草组合物和方法。

8. 发明授权

US4996323A Process for the preparation of 3,5,6-trichloropyridin-2-ol 失效
标题翻译：制备3,5,6-三氯吡啶-2-醇的方法
公开(公告)号：US4996323A
公开(公告)日：1991-02-26
申请号：US350961
申请日：1989-05-12
申请人： R. Garth Pews
发明人： R. Garth Pews
IPC分类号： B01J23/72 , B01J27/122 , C07B61/00 , C07C253/30 , C07C255/17 , C07C255/19 , C07D213/64
CPC分类号： C07D213/64 , C07C255/19
摘要： The preparation of 3,5,6-trichloropyridin-2-ol from trichloroacetyl chloride and acrylonitrile is improved by separately conducting the individual addition, cyclization and aromatization steps. By separating the steps, water and HCl, by-products of the latter steps, can be precluded from interfering with the earlier steps. The individual process steps have also been improved.

9. 发明授权

US4937396A Preparation of 3,4-difluorobenzotrifluoride 失效
标题翻译：制备3,4-二氟三氟甲苯
公开(公告)号：US4937396A
公开(公告)日：1990-06-26
申请号：US276711
申请日：1988-11-28
申请人： R. Garth Pews , Jack C. Little , James A. Gall
发明人： R. Garth Pews , Jack C. Little , James A. Gall
IPC分类号： C07C17/20 , C07C255/50
CPC分类号： C07C255/50 , C07C17/208
摘要： 3,4-Difluorobenzotrifluoride is prepared by contacting a 3,4-dihalobenzotrifluoride with an effective amount of KF or CsF in a polar aprotic solvent at an elevated temperature under substantially anhydrous conditions. The product can be removed as it is formed or the reaction may be run at the autogenous pressures generated by the reaction mixture in a sealed reactor.
摘要翻译：通过在极性非质子溶剂中在高温下在基本上无水的条件下使3,4-二卤代三氟甲苯与有效量的KF或CsF接触来制备3,4-二氟三氟甲苯。产物可以在其形成时被除去，或者反应可以在密封反应器中由反应混合物产生的自生压力下进行。

10. 发明授权

US4681943A 1-acyl-1-(2-pyridinyl)semicarbazides 失效
标题翻译： 1-酰基-1-（2-吡啶基）氨基脲
公开(公告)号：US4681943A
公开(公告)日：1987-07-21
申请号：US840359
申请日：1986-03-17
申请人： Charles E. Whitten , R. Garth Pews
发明人： Charles E. Whitten , R. Garth Pews
IPC分类号： C07D213/77 , C07D401/04 , C07D213/75
CPC分类号： C07D213/77 , C07D401/04
摘要： 5-Alkyl-1-(2-pyridinyl)-1H-1,2,4-triazol-3-ols are prepared in good yield by reacting an appropriate 1-acyl-1-(2-pyridinyl)-semicarbazide with a base in the presence of a non-nucleophilic solvent. The compounds so prepared are intermediates used in the preparation of insecticides. The starting semicarbazide materials are novel compounds.
摘要翻译：通过使适当的1-酰基-1-（2-吡啶基） - 氨基脲与碱反应，以良好的收率制备5-烷基-1-（2-吡啶基）-1H-1,2,4-三唑-3-醇在非亲核溶剂的存在下。如此制备的化合物是用于制备杀虫剂的中间体。起始氨基脲材料是新型化合物。

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