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    • 3. 发明申请
    • Hydrophobic Thermoplastic Polyurethane
    • 疏水热塑性聚氨酯
    • US20090192262A1
    • 2009-07-30
    • US12356557
    • 2009-01-21
    • Donald A. MeltzerJacques P.E.J. Horrion
    • Donald A. MeltzerJacques P.E.J. Horrion
    • C08L75/04C08G18/32C08L23/00
    • C08G18/3206C08G18/36C08K5/053C08K5/098C08L23/02C08L23/06C08L23/10C08L23/22C08L75/00C08L2205/08C08L2666/20
    • The present invention discloses a semicrystalline, thermoplastic polyurethane which is comprised of the reaction product of (1) a hydrophobic polyol, (2) a polyisocyanate, and (3) a linear chain extender containing 5 carbon atoms or 7 to 12 carbon atoms; wherein the hydrophobic polyol has a number average molecular weight which is within the range of about 1,000 to about 4,000; wherein the semicrystalline, thermoplastic polyurethane has a weight average molecular weight which is within the range of 50,000 to 1,000,000; and wherein the semicrystalline, thermoplastic polyurethane has a melting point which is within the range of 80° C. to 150° C. This hydrophobic thermoplastic polyurethane offers a unique array of characteristics that are highly desirable for utilization in manufacturing a variety of products. For instance, it can be used in overmolding soft grips onto consumer products, in adhesives, and in protective coatings.
    • 本发明公开了一种半结晶的热塑性聚氨酯,其由(1)疏水性多元醇,(2)多异氰酸酯和(3)含有5个碳原子或7至12个碳原子的直链增链剂的反应产物组成; 其中所述疏水性多元醇的数均分子量在约1,000至约4000的范围内; 其中所述半结晶热塑性聚氨酯具有在50,000至1,000,000范围内的重均分子量; 并且其中所述半结晶的热塑性聚氨酯具有在80℃至150℃的范围内的熔点。该疏水性热塑性聚氨酯提供了独特的特征阵列,其非常适用于制造各种产品。 例如,它可以用于将软握把覆盖在消费品,粘合剂和保护涂层中。
    • 5. 发明申请
    • Thermoplastic Polyurethane For Printing Blankets
    • 印刷毯用热塑性聚氨酯
    • US20110168043A1
    • 2011-07-14
    • US12987386
    • 2011-01-10
    • Donald A. MeltzerJoseph J. Vontorcik, JR.
    • Donald A. MeltzerJoseph J. Vontorcik, JR.
    • B41N1/00
    • B41N10/04B41N2210/02B41N2210/04B41N2210/14
    • The present invention provides an offset printing blanket or sleeve including one or more layers that are made with a soft thermoplastic polyurethane composition that provides excellent compression set and excellent resistance to apolar solvents, such as naphthenic mineral spirits. The subject invention more specifically reveals a printing blanket comprising: a base layer; a compressible layer, and a printing surface layer, wherein the compressible layer and/or the printing surface layer is comprised of a thermoplastic polyurethane composition, wherein the thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender; wherein the polyester polyol intermediate comprises an intermediate derived from at least one dialkylene glycol and at least one dicarboxylic acid or an ester or anhydride thereof. It is particularly beneficial to utilize the thermoplastic polyurethane composition in the printing surface layer.
    • 本发明提供了一种胶版印刷橡皮布或套筒,其包括由软的热塑性聚氨酯组合物制成的一层或多层,其提供优异的压缩永久变形性和对非极性溶剂如环烷烃矿物油的优异的耐受性。 本发明更具体地揭示了一种印刷毯,包括:基层; 可压缩层和印刷表面层,其中所述可压缩层和/或所述印刷表面层由热塑性聚氨酯组合物组成,其中所述热塑性聚氨酯组合物通过使(a)至少一种聚酯多元醇中间体与(b) 至少一种二异氰酸酯和(c)至少一种扩链剂; 其中所述聚酯多元醇中间体包含衍生自至少一种二亚烷基二醇和至少一种二羧酸或其酯或酸酐的中间体。 在印刷表面层中使用热塑性聚氨酯组合物是特别有益的。
    • 6. 发明授权
    • High moisture vapor transmissive polyurethanes
    • 高湿透气聚氨酯
    • US08637629B2
    • 2014-01-28
    • US13223338
    • 2011-09-01
    • Donald A. Meltzer
    • Donald A. Meltzer
    • C08G18/00
    • C08G18/0895C08G18/4833C08G18/4837C08G18/6674C08G18/7671Y10T442/20Y10T442/3854Y10T442/674
    • The present invention relates generally to polyurethane compositions; and more preferably to thermoplastic polyurethane compositions. In one embodiment, the polyurethane compositions of the present invention have high moisture vapor transmission rates and are suitable for film applications (e.g., breathable films). In one embodiment, the polyurethane compositions of the present invention are prepared from the reaction of a mixed polyol component, a polyisocyanate component, a chain extender, and optionally at least one suitable catalyst, wherein the mixed polyol component is formed by a combination of one or more poly(ethylene oxide) polyols and one or more copolymer polyols, where the resulting mixed polyol component comprises from about 3 to about 30 weight percent of a copolymer polyol and about 70 to 97 weight percent of poly(ethylene oxide) polyol.
    • 本发明一般涉及聚氨酯组合物; 更优选热塑性聚氨酯组合物。 在一个实施方案中,本发明的聚氨酯组合物具有高的水蒸汽透过率,并且适用于薄膜应用(例如透气薄膜)。 在一个实施方案中,本发明的聚氨酯组合物由混合的多元醇组分,多异氰酸酯组分,扩链剂和任选的至少一种合适的催化剂的反应制备,其中混合的多元醇组分由一种 或更多的聚(环氧乙烷)多元醇和一种或多种共聚物多元醇,其中所得混合多元醇组分包含约3至约30重量%的共聚物多元醇和约70至97重量%的聚(环氧乙烷)多元醇。
    • 7. 发明授权
    • Soft thermoplastic elastomer composition
    • 软质热塑性弹性体组合物
    • US08273845B2
    • 2012-09-25
    • US12542012
    • 2009-08-17
    • Donald A. MeltzerGilbert T. MontaguePatrick E. MosierJacques P. E. J. Horrion
    • Donald A. MeltzerGilbert T. MontaguePatrick E. MosierJacques P. E. J. Horrion
    • C08G18/32C08K5/10
    • C08G18/36C08G18/3206C08G18/3215C08K5/01
    • The present invention relates to a soft, semicrystalline, thermoplastic elastomer composition which is comprised of (I) a hydrophobic thermoplastic block copolymer which is comprised of (I) the reaction product of (1) a hydrophobic polyol or polyamine, (2) a polyisocyanate or an aromatic dicarboxylic acid, and (3) a chain extender containing 2 to 20 carbon atoms, or the reaction product of (1) a hydrophobic polyol or polyamine, and (2) a carboxyl terminated telechelic polyamide sequence; wherein the hydrophobic polyol or polyamine has a number average molecular weight in the range of from 1,000 to 4,000 Daltons; wherein the hydrophobic thermoplastic block copolymer has a weight average molecular weight in the range of 50,000 to 1,000,000 Daltons; and (II) from 1 to 80 weight percent of a mineral oil, wherein the soft, semicrystalline, thermoplastic elastomer composition has a Shore A hardness which is within the range of 20 to 80.
    • 本发明涉及一种软的半结晶的热塑性弹性体组合物,其包含(I)疏水性热塑性嵌段共聚物,其包含(I)(1)疏水多元醇或多胺的反应产物,(2)多异氰酸酯 或芳族二羧酸,和(3)含有2〜20个碳原子的扩链剂,或(1)疏水多元醇或多胺的反应产物和(2)羧基封端的遥爪聚酰胺序列; 其中所述疏水多元醇或多胺的数均分子量在1,000至4,000道尔顿范围内; 其中所述疏水性热塑性嵌段共聚物的重均分子量在50,000至1,000,000道尔顿范围内; 和(II)1至80重量%的矿物油,其中所述软的半结晶的热塑性弹性体组合物具有在20至80的范围内的肖氏A硬度。
    • 9. 发明申请
    • High Moisture Vapor Transmissive Polyurethanes
    • 高湿度透射聚氨酯
    • US20110312237A1
    • 2011-12-22
    • US13223338
    • 2011-09-01
    • Donald A. Meltzer
    • Donald A. Meltzer
    • B32B5/02C08G18/66B32B27/12C08G18/22C08G18/24C08G18/32C08G18/18
    • C08G18/0895C08G18/4833C08G18/4837C08G18/6674C08G18/7671Y10T442/20Y10T442/3854Y10T442/674
    • The present invention relates generally to polyurethane compositions; and more preferably to thermoplastic polyurethane compositions. In one embodiment, the polyurethane compositions of the present invention have high moisture vapor transmission rates and are suitable for film applications (e.g., breathable films). In one embodiment, the polyurethane compositions of the present invention are prepared from the reaction of a mixed polyol component, a polyisocyanate component, a chain extender, and optionally at least one suitable catalyst, wherein the mixed polyol component is formed by a combination of one or more poly(ethylene oxide) polyols and one or more copolymer polyols, where the resulting mixed polyol component comprises from about 3 to about 30 weight percent of a copolymer polyol and about 70 to 97 weight percent of poly(ethylene oxide) polyol.
    • 本发明一般涉及聚氨酯组合物; 更优选热塑性聚氨酯组合物。 在一个实施方案中,本发明的聚氨酯组合物具有高的水蒸汽透过率,并且适用于薄膜应用(例如透气薄膜)。 在一个实施方案中,本发明的聚氨酯组合物由混合的多元醇组分,多异氰酸酯组分,扩链剂和任选的至少一种合适的催化剂的反应制备,其中混合的多元醇组分由一种 或更多的聚(环氧乙烷)多元醇和一种或多种共聚物多元醇,其中所得混合多元醇组分包含约3至约30重量%的共聚物多元醇和约70至97重量%的聚(环氧乙烷)多元醇。