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    • 3. 发明授权
    • Processing of (Bi,Pb)SCCO superconductor in wires and tapes
    • (Bi,Pb)SCCO超导体在电线和磁带中的处理
    • US06311386B1
    • 2001-11-06
    • US09358245
    • 1999-07-21
    • Qi LiEric R. PodtburgPatrick John WalshWilliam L. CarterGilbert N. Riley, Jr.Martin W. RupichElliott ThompsonAlexander Otto
    • Qi LiEric R. PodtburgPatrick John WalshWilliam L. CarterGilbert N. Riley, Jr.Martin W. RupichElliott ThompsonAlexander Otto
    • H01L3929
    • C04B35/4521C04B35/4525C04B35/65H01L39/2419H01L39/248Y10S505/739Y10S505/74Y10S505/742Y10T29/49014
    • A novel process of the production and processing of high quality, high Tc (Bi,Pb)SCCO superconductors starts with fabrication of a precursor article including selected intermediate phases with desired chemical and structural properties. The precursor fabrication includes introducing the reacted mixture having a dominant amount of the tetragonal BSCCO phase into a metal sheath, and sealing the reacted mixture within said sheath, heating the mixture at a second selected processing temperature in an inert atmosphere with a second selected oxygen partial pressure for a second selected time period, the second processing temperature and the second oxygen partial pressure being cooperatively selected to form a dominant amount of an orthorhombic BSCCO phase in the reacted mixture. The sealed sheath is deformed to form an elongated precursor article of a desired texture; and thereafter heated at a third selected processing temperature in an inert atmosphere with a third selected oxygen partial pressure for a third selected time period. The third processing temperature and third oxygen partial pressure are cooperatively selected to convert at least a portion of the orthorhombic BSCCO phase to the final superconducting BSCCO material.
    • 高品质,高Tc(Bi,Pb)SCCO超导体的生产和加工的新工艺首先制造包含所需化学和结构性质的选定中间相的前体制品。 前体制备包括将具有显着量的四边形BSCCO相的反应混合物引入金属护套中,并将反应的混合物密封在所述护套内,在第二选择的加工温度下在惰性气氛中加热第二选择的氧部分 第二选择时间段的压力,第二加工温度和第二氧分压协同选择以形成反应混合物中正交BSCCO相的显着量。 密封的鞘被变形以形成具有所需纹理的细长的前体制品; 然后在具有第三选择的氧分压的惰性气氛中在第三选择的处理温度下加热第三选定时间段。 协调选择第三加工温度和第三氧分压以将正交BSCCO相的至少一部分转化为最终超导BSCCO材料。