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    • 1. 发明申请
    • THERMOTROPIC POLYMERS
    • 热致PLASTICS
    • WO2014096222A3
    • 2014-11-13
    • PCT/EP2013077443
    • 2013-12-19
    • QUARZWERKE GMBHFRAUNHOFER GES ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E V
    • ZILLES JÖRG ULRICHKRUBER DIRKSEEBOTH ARNOMÜHLING OLAFRUHMANN RALF
    • C09K9/02
    • C08L33/14C08L25/14C09K9/02Y10T428/2982
    • Polymer particles having a mean primary particle diameter d50 between 50 nm and 10 pm based on the total weight, containing: A. 10 to 100% by weight of a polymer phase A, obtainable by free-radical copolymerization of an oil-in-water miniemulsion having a monomer mixture as oil phase, containing i) 30 to 99.9% by weight of one or more monoethylenically unsaturated monomers II having at least one C12—C48-n-alkyl side chain, ii) 0 to 60% by weight of one or more monoethylenically unsaturated monomers II having at least one C1—C11-n-alkyl and/or one C3—C48-i-alkyl side chain, iii) 0.1 to 20% by weight of one or more monomers III having at least two non-conjugated ethylenic double bonds, iv) 0 to 69.9% by weight of one or more (hetero)aromatic, monoethylenically unsaturated monomers IV, v) 0 to 40% by weight of one or more other monoethylenically unsaturated monomers V; and B. 0 to 90% by weight of a polymer phase B, obtainable by subsequent free-radical graft copolymerization, in the presence of the polymer phase A obtained after stage A), of a monomer mixture containing i) 0 to 100% by weight of one or more monomers VI from the group of the C1—C10-alkyl (meth)acrylates, ii) 0 to 100% by weight of one or more (hetero)aromatic, monoethylenically unsaturated monomers VII, iii) 0 to 50% by weight of one or more other monoethylenically unsaturated monomers VIII, where the percentages by weight of the monomer mixtures used in the respective stages add up to 100% by weight.
    • 具有纳米和pm之间50 10的平均初级粒径d50用含有总重量相对于聚合物粒子:A.从10到100重量聚合物相A,由含有单体混合物作为油相的油包水微乳液的自由基共聚获得的%I )30至99.9重量%的一种或多种单烯属不饱和单体的%I与至少一种C12-C48正烷基侧链,II)0至60重量具有至少一个C1的一种或多种单烯属不饱和单体II的% -C11正烷基和/或C3-C48-异AIkylseitenkette,III)为0.1至20重量的一种或多种单体III具有至少两个非共轭烯属双键,静脉内)从0到69.9%的 重量的一种或多种(杂)芳族的,单烯属不饱和单体Ⅳ的%,v)0至40重量的一种或多种其它单烯属不饱和单体的v%; 和B. 0至90重量的聚合物相B的%,通过在聚合物相的存在随后的自由基接枝共聚根据阶段A)从0单体混合物包含:i)至100重量%的一种或多种单体的%选自VI的获得 C1-C10烷基(甲基)丙烯酸酯,ⅱ)0至100重量的一种或多种(杂的%)芳族的,单烯属不饱和单体VII,III)0至50重量的一种或多种其它单烯不饱和% VIII的单体,其特征在于,按重量计在各阶段使用的单体混合物的百分比合计为100重量%。
    • 4. 发明专利
    • Thermotropic polymers
    • NZ709079A
    • 2020-04-24
    • NZ70907913
    • 2013-12-19
    • QUARZWERKE GMBH
    • ZILLES JÖRG ULRICHKRUBER DIRKSEEBOTH ARNOMÜHLING OLAFRUHMANN RALF
    • C09K9/02
    • Polymer particles having a mean primary particle diameter d50 between 50 nm and 10 pm based on the total weight, containing: A. 10 to 100% by weight of a polymer phase A, obtainable by free-radical copolymerization of an oil-in-water miniemulsion having a monomer mixture as oil phase, containing i) 30 to 99.9% by weight of one or more monoethylenically unsaturated monomers II having at least one C12-C48-n-alkyl side chain, ii) 0 to 60% by weight of one or more monoethylenically unsaturated monomers II having at least one C1-C11-n-alkyl and/or one C3-C48-i-alkyl side chain, iii) 0.1 to 20% by weight of one or more monomers III having at least two non-conjugated ethylenic double bonds, iv) 0 to 69.9% by weight of one or more (hetero)aromatic, monoethylenically unsaturated monomers IV, v) 0 to 40% by weight of one or more other monoethylenically unsaturated monomers V; and B. 0 to 90% by weight of a polymer phase B, obtainable by subsequent free-radical graft copolymerization, in the presence of the polymer phase A obtained after stage A), of a monomer mixture containing i) 0 to 100% by weight of one or more monomers VI from the group of the C1-C10-alkyl (meth)acrylates, ii) 0 to 100% by weight of one or more (hetero)aromatic, monoethylenically unsaturated monomers VII, iii) 0 to 50% by weight of one or more other monoethylenically unsaturated monomers VIII, where the percentages by weight of the monomer mixtures used in the respective stages add up to 100% by weight.
    • 7. 发明专利
    • THERMOTROPIC POLYMERS
    • SG10201704213XA
    • 2017-06-29
    • SG10201704213X
    • 2013-12-19
    • QUARZWERKE GMBH
    • ZILLES JÖRG ULRICHKRUBER DIRKSEEBOTH ARNOMÜHLING OLAFRUHMANN RALF
    • Polymer particles having a mean primary particle diameter d50 between 50 nm and 10 pm based on the total weight, containing: A. 10 to 100% by weight of a polymer phase A, obtainable by free-radical copolymerization of an oil-in-water miniemulsion having a monomer mixture as oil phase, containing i) 30 to 99.9% by weight of one or more mono-ethylenically unsaturated monomers II having at least one C12-C48-n-alkyl side chain, ii) 0 to 60% by weight of one or more mono-ethylenically unsaturated monomers II having at least one C1-C11-n-alkyl and/or one C3-C48-i-alkyl side chain, iii) 0.1 to 20% by weight of one or more monomers III having at least two non-conjugated ethylenic double bonds, iv) 0 to 69.9% by weight of one or more (hetero)aromatic, mono-ethylenically unsaturated monomers IV, v) 0 to 40% by weight of one or more other mono-ethylenically unsaturated monomers V; and B. 0 to 90% by weight of a polymer phase B, obtainable by subsequent free-radical graft copolymerization, in the presence of the polymer phase A obtained after stage A), of a monomer mixture containing i) 0 to 100% by weight of one or more monomers VI from the group of C1-C10-alkyl(meth)acrylates, ii) 0 to 100% by weight of one or more (hetero)aromatic, mono-ethylenically unsaturated monomers VII, iii) 0 to 50% by weight of one or more other mono-ethylenically unsaturated monomers VIII, where the percentages by weight of the monomer mixtures used in the respective stages add up to 100% by weight.
    • 9. 发明专利
    • Polímeros termotropos
    • ES2743035T3
    • 2020-02-18
    • ES13811530
    • 2013-12-19
    • QUARZWERKE GMBH
    • ZILLES JÖRG ULRICHKRUBER DIRKSEEBOTH ARNOMÜHLING OLAFRUHMANN RALF
    • C08L25/14C09K9/02C08L33/14
    • Partícula polimérica con un diámetro de partícula primaria medio de entre 50 nm y 10 mm que contiene con respecto al peso total: A. 10 a 100 % en peso de una fase polimérica A, que se obtiene mediante copolimerización por radicales de una miniemulsión de aceite en agua con una mezcla de monómeros como fase oleosa que contiene i) 30 a 99,9 % en peso de uno o varios monómeros I monoetilénicamente insaturados con al menos una cadena lateral de n-alquilo-C12-C48, ii) 0 a 60 % en peso de uno o varios monómeros II monoetilénicamente insaturados con al menos una cadena lateral de n-alquilo-C1-C11 y/o de i-alquilo-C3-C46, iii) 0,1 a 20 % en peso de uno o varios monómeros III con al menos dos dobles enlaces etilénicos no conjugados, iv) 0 a 69,9 % en peso de uno o varios monómeros IV (hetero)aromáticos monoetilénicamente insaturados, v) 0 a 40 % en peso de uno o varios otros monómeros V monoetilénicamente insaturados; y B. 0 a 90 % en peso de una fase polimérica B, que se obtiene mediante subsiguiente copolimerización por radicales por injerto en la presencia de la fase polimérica A de una mezcla de monómeros obtenida de acuerdo con la etapa A) que contiene i) 0 a 100 % en peso de uno o varios monómeros VI del grupo de los alquil-C1-C10-(met)acrilatos, ii) 0 a 100 % en peso de uno o varios monómeros VII (hetero)aromáticos monoetilénicamente insaturados, iii) 0 a 50 % en peso de uno o varios otros monómeros VIII monoetilénicamente insaturados, en la que los porcentajes en peso de las mezclas de monómeros usadas en las respectivas etapas se suman para obtener el 100 % en peso, en la que cuando está presente una fase polimérica B, la fase poliméricas A forma un núcleo interno y la fase polimérica B forma una cubierta exterior.
    • 10. 发明专利
    • THERMOTROPIC POLYMERS
    • ZA201503614B
    • 2017-09-27
    • ZA201503614
    • 2015-05-21
    • FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E VQUARZWERKE GMBH
    • RUHMANN RALFMÜHLING OLAFSEEBOTH ARNOKRUBER DIRKZILLES JÖRG ULRICH
    • Polymer particles having a mean primary particle diameter d50 between 50 nm and 10 pm based on the total weight, containing: A. 10 to 100% by weight of a polymer phase A, obtainable by free-radical copolymerization of an oil-in-water miniemulsion having a monomer mixture as oil phase, containing i) 30 to 99.9% by weight of one or more mono-ethylenically unsaturated monomers II having at least one C12-C48-n-alkyl side chain, ii) 0 to 60% by weight of one or more mono-ethylenically unsaturated monomers II having at least one C1-C11-n-alkyl and/or one C3-C48-i-alkyl side chain, iii) 0.1 to 20% by weight of one or more monomers III having at least two non-conjugated ethylenic double bonds, iv) 0 to 69.9% by weight of one or more (hetero)aromatic, mono-ethylenically unsaturated monomers IV, v) 0 to 40% by weight of one or more other mono-ethylenically unsaturated monomers V; and B. 0 to 90% by weight of a polymer phase B, obtainable by subsequent free-radical graft copolymerization, in the presence of the polymer phase A obtained after stage A), of a monomer mixture containing i) 0 to 100% by weight of one or more monomers VI from the group of C1-C10-alkyl(meth)acrylates, ii) 0 to 100% by weight of one or more (hetero)aromatic, mono-ethylenically unsaturated monomers VII, iii) 0 to 50% by weight of one or more other mono-ethylenically unsaturated monomers VIII, where the percentages by weight of the monomer mixtures used in the respective stages add up to 100% by weight.