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1. 发明授权

US5430209A Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen 失效
标题翻译：在同时燃烧氢气的情况下将烷烃催化脱氢成烯烃的方法
公开(公告)号：US5430209A
公开(公告)日：1995-07-04
申请号：US112287
申请日：1993-08-27
申请人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
发明人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
IPC分类号： C07C5/42 , C07C1/00 , C07C5/327
CPC分类号： C07C5/42 , C07C2529/44
摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilbrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor is then passed into a second reactor containing a reducible metal oxide which serves to selectively combust hydrogen in an oxidation/reduction (REDOX) reaction. This particular mode of operation is termed a separate reactor, REDOX mode.
摘要翻译：提供了用于烷烃的净催化氧化脱氢以产生烯烃的方法。该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。在本反应中，烷烃进料在第一反应器中通过平衡脱氢催化剂脱氢，然后将来自第一反应器的流出物进入含有可还原金属氧化物的第二反应器中，该可还原金属氧化物用于在氧化/还原（REDOX）反应。这种特定的操作模式被称为单独的反应器，REDOX模式。

2. 发明授权

US5527979A Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen 失效
标题翻译：在同时燃烧氢气的情况下将烷烃催化脱氢成烯烃的方法
公开(公告)号：US5527979A
公开(公告)日：1996-06-18
申请号：US423630
申请日：1995-04-17
申请人： Pradyot A. Agaskar , Robert K Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
发明人： Pradyot A. Agaskar , Robert K Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
IPC分类号： C07C5/333
CPC分类号： C07C5/3337 , C07C2529/44
摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilbrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor, along with oxygen, is then passed into a second reactor containing a metal oxide catalyst which serves to selectively catalyze the combustion of hydrogen. This particular mode of operation is termed a separate reactor, cofed oxygen mode. The equilibrium dehydrogenation catalyst may comprise platinum and the selective metal oxide combustion catalyst may contain bismuth, antimony, indium, molybdenum, or a mixture thereof.
摘要翻译：提供了用于烷烃的净催化氧化脱氢以产生烯烃的方法。该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。在本反应中，烷烃进料在第一反应器中通过平衡脱氢催化剂脱氢，然后将来自第一反应器的流出物与氧气一起进入含有金属氧化物催化剂的第二反应器，该反应器用于选择性催化燃烧氢气。这种特定的操作模式被称为单独的反应器，共模氧气模式。平衡脱氢催化剂可以包含铂，并且选择性金属氧化物燃烧催化剂可以含有铋，锑，铟，钼或它们的混合物。

3. 发明授权

US5563314A Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen 失效
公开(公告)号：US5563314A
公开(公告)日：1996-10-08
申请号：US423626
申请日：1995-05-25
申请人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
发明人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
IPC分类号： C07C5/333 , C07C5/42 , C07C1/00 , C07C5/327
CPC分类号： C07C5/3335 , C07C5/3337 , C07C5/42 , C07C2529/44
摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is dehydrogenated over an equilbrium dehydrogenation catalyst in a first reactor, and the effluent from the first reactor is then passed into a second reactor containing a reducible metal oxide which serves to selectively combust hydrogen in an oxidation/reduction (REDOX) reaction. This particular mode of operation is termed a separate reactor, REDOX mode.

4. 发明授权

US5530171A Process for the catalytic dehydrogenation of alkanes to alkenes with simultaneous combustion of hydrogen 失效
标题翻译：在同时燃烧氢气的情况下将烷烃催化脱氢成烯烃的方法
公开(公告)号：US5530171A
公开(公告)日：1996-06-25
申请号：US423629
申请日：1995-04-17
申请人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
发明人： Pradyot A. Agaskar , Robert K. Grasselli , James N. Michaels , P. Thomas Reischman , David L. Stern , John G. Tsikoyiannis
IPC分类号： B01J23/06 , B01J23/08 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/20 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/745 , B01J23/88 , B01J27/199 , B01J29/44 , C07C5/333 , C07C5/42 , C07C11/02
CPC分类号： C07C5/42 , C07C2523/42 , C07C2523/44
摘要： There is provided a process for the net catalytic oxidative dehydrogenation of alkanes to produce alkenes. The process involves simultaneous equilibrium dehydrogenation of alkanes to alkenes and combustion of the hydrogen formed to drive the equilibrium dehydrogenation reaction further to the product alkenes. In the present reaction, the alkane feed is passed into a reactor containing both an equilibrium dehydrogenation catalyst and a reducible metal oxide, whereby the alkane is dehydrogenated and the hydrogen produced is simultaneously and selectively combusted in oxidation/ reduction (REDOX) reaction with the reducible metal oxide. This particular mode of operation is termed a same reactor, REDOX mode. The equilibrium dehydrogenation catalyst may comprise platinum and the reducible metal oxide may contain bismuth, antimony, indium, or molybdenum, or a mixture thereof.
摘要翻译：提供了用于烷烃的净催化氧化脱氢以产生烯烃的方法。该方法包括将烷烃同时平衡脱氢至烯烃，形成氢气的燃烧以进一步促进产物烯烃的平衡脱氢反应。在本反应中，将烷烃进料通入含有平衡脱氢催化剂和可还原金属氧化物的反应器中，由此烷烃脱氢，产生的氢气与氧化/还原（REDOX）反应同时并选择性燃烧，可还原金属氧化物。这种特定的操作模式称为相同的反应器，REDOX模式。平衡脱氢催化剂可以包含铂，并且可还原的金属氧化物可以含有铋，锑，铟或钼，或其混合物。

5. 发明授权

US5550308A Vanadium (IV)-containing nasicon materials 失效
标题翻译：含铑（IV）的鼻子材料
公开(公告)号：US5550308A
公开(公告)日：1996-08-27
申请号：US312580
申请日：1994-09-27
申请人： Pradyot A. Agaskar , Robert K. Grasselli
发明人： Pradyot A. Agaskar , Robert K. Grasselli
IPC分类号： C07D307/60 , B01J27/198 , C01B25/45 , C01B33/00 , C07C5/09 , C07D307/34
CPC分类号： B01J23/002 , B01J27/198 , C01B25/45 , B01J2523/00
摘要： The present invention provides a composition of matter having the formulaA.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3 O.sub.10-15wherein A is Nb or Ta, B is Sb, C is Ti or Sn, and 0.ltoreq.x,y.ltoreq.1, a composition of matter having the formulaM.sub.z A.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3 O.sub.10-15wherein M is selected from the group consisting of Cu, Ag, Na, K, and Cs, A is Nb or Ta, B is Sb, C is Ti or Sn, and 0.ltoreq.x,y,z .ltoreq.1, a composition of matter having the formulaM.sub.z A.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3-n Si.sub.n O.sub.10-15wherein M is selected from the group consisting of Cu, Ag, Bi, Na, K, Rb, and Cs, A is Nb or Ta, B is Sb or As, C is Ti, Zr, Sn, or Ge, and 0.ltoreq.x,z.ltoreq.1, 0
摘要翻译：本发明提供具有式A x B 1-x V y C 1-y P 3 O 10-15的物质组成，其中A是Nb或Ta，B是Sb，C是Ti或Sn，0

6. 发明授权

US5354722A Vanadium (IV)-containing NASICON materials 失效
标题翻译：含钒（IV）的NASICON材料
公开(公告)号：US5354722A
公开(公告)日：1994-10-11
申请号：US50794
申请日：1993-04-22
申请人： Pradyot A. Agaskar , Robert K. Grasselli
发明人： Pradyot A. Agaskar , Robert K. Grasselli
IPC分类号： C07D307/60 , B01J27/198 , C01B25/45 , C01B33/00 , C01B25/37
CPC分类号： B01J23/002 , B01J27/198 , C01B25/45 , B01J2523/00
摘要： The present invention provides a composition of matter having the formulaA.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3 O.sub.10-15wherein A is Nb or Ta, B is Sb, C is Ti or Sn, and 0.ltoreq.x,y.ltoreq.1, a composition of matter having the formulaM.sub.z A.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3 O.sub.10-15wherein M is selected from the group consisting of Cu, Ag, Na, K, and Cs, A is Nb or Ta, B is Sb, C is Ti or Sn, and 0.ltoreq.x,y,z.ltoreq.1, a composition of matter having the formulaM.sub.z A.sub.x B.sub.1-x V.sub.y C.sub.1-y P.sub.3-n Si.sub.n O.sub.10-15wherein M is selected from the group consisting of Cu, Ag, Bi, Na, K, Rb, and Cs, A is Nb or Ta, B is Sb or As, C is Ti, Zr, Sn, or Ge, and 0.ltoreq.x,z.ltoreq.1, 0
摘要翻译：本发明提供具有式AxB1-xVyC1-yP3O10-15的物质组合物，其中A为Nb或Ta，B为Sb，C为Ti或Sn，0为x，y为1，组成具有式MzAxB1-xVyC1-yP3O10-15的物质，其中M选自Cu，Ag，Na，K和Cs，A为Nb或Ta，B为Sb，C为Ti或Sn，0为具有式MzAxB1-xVyC1-yP3-nSinO10-15的物质组合物，其中M选自Cu，Ag，Bi，Na，K，Rb，而Cs，A为Nb或Ta，B为Sb或As，C为Ti，Zr，Sn或Ge，0为x，z = 1,0

7. 发明授权

US5348631A Method and apparatus for synthesizing lead .beta.-diketonates 失效
标题翻译：用于合成铅β-二酮化合物的方法和装置
公开(公告)号：US5348631A
公开(公告)日：1994-09-20
申请号：US73113
申请日：1993-06-07
申请人： Seshu B. Desu , May Nyman , Pradyot A. Agaskar
发明人： Seshu B. Desu , May Nyman , Pradyot A. Agaskar
IPC分类号： C07F7/24 , B01J19/10 , C01G21/06 , C07C45/77 , C07C49/92 , C23C16/40 , C01G21/00
CPC分类号： C07C45/77 , B01J19/10 , C01G21/06 , C07C49/92 , C01P2002/82 , C01P2002/86 , C01P2002/88 , C01P2002/89 , C01P2006/34
摘要： A method and apparatus for the synthesis of .beta.-diketonates such as Pb(fod).sub.2 and Pb(thd).sub.2 for use as precursors in metalorganic chemical vapor deposition processes. Lead oxide and a medium of pentane and a protonated ligand (H-fod or H-thd) are combined in a flask and subjected to reaction-promoting ultrasonic waves. The flask is immersed in a water bath to maintain a constant cool temperature, and the flask may include one or more arms for cooling and circulation of the medium during the reaction.
摘要翻译：用于合成β-二酮酸盐如Pb（fod）2和Pb（thd）2的方法和装置，用作金属有机化学气相沉积工艺中的前体。将氧化铅和戊烷和质子化配体（H-fod或H-thd）的培养基合并在烧瓶中并进行反应促进超声波。将烧瓶浸在水浴中以保持恒定的冷却温度，并且烧瓶可以包括用于在反应期间冷却和循环介质的一个或多个臂。

8. 发明授权

US5824835A Isoparaffin-olefin alkylation process 失效
标题翻译：异链烷烃烯烃烷基化方法
公开(公告)号：US5824835A
公开(公告)日：1998-10-20
申请号：US383152
申请日：1995-02-03
申请人： Pradyot A. Agaskar , Tracy J. Huang
发明人： Pradyot A. Agaskar , Tracy J. Huang
IPC分类号： B01J29/70 , C07C2/58 , B01J29/06
CPC分类号： C07C2/58 , B01J29/7007 , C07C2529/70
摘要： The present invention provides a process for alkylating an olefin with an isoparaffin comprising contacting an olefin-containing feed with an isoparaffin-containing feed with a solid catalyst comprising zeolite Beta having a silica:alumina ratio in the as-synthesized state of less than about 18.
摘要翻译：本发明提供了一种用异链烷烃烷基化烯烃的方法，包括使含烯烃的进料与含异链烷烃的进料与含有二氧化硅：氧化铝比的固体催化剂接触，所述固体催化剂具有小于约18的合成状态的二氧化硅：氧化铝比。

9. 发明授权

US08557000B2 Complete liquefication of lignocellulosic agrowaste to form liquid biofuels 有权
标题翻译：木质纤维素农药的完全液化形成液体生物燃料
公开(公告)号：US08557000B2
公开(公告)日：2013-10-15
申请号：US12866350
申请日：2009-02-04
申请人： Pradyot A. Agaskar
发明人： Pradyot A. Agaskar
IPC分类号： C10L1/00 , C12P17/04 , C12P7/10 , C12P7/22
CPC分类号： C12P7/10 , C10G1/002 , C10G2300/1014 , C10L1/023 , C10L2290/10 , C10L2290/30 , C10L2290/543 , C10L2290/544 , C12P7/22 , Y02E50/16 , Y02E50/17 , Y02P30/20
摘要： A process for converting lignocellulosic materials which are field residues such as cotton stalks and corn stover, process residues such as sugarcane bagasse and sweet sorghum bagasse, woody parts of energy crops such as switchgrass and miscanthus, forest residues or byproducts of the wood processing industries such as sawdust from sawmills to a liquid biofuel by a series of processing steps wherein the feed materials are hydrolysed in three stages and withdrawn as three product streams each consisting of solubilized fragments of one of the three major components of the feed materials and a set of concurrently operating processing steps wherein each of the three product streams is transformed through chemical or biochemical processes into products, such as pure lignin and ethanol, that have a high calorific value and process wherein these products with high calorific value are combined to form a liquid biofuel.
摘要翻译：用于转化木质纤维素材料的方法，这些木质纤维素材料是诸如棉花秸秆和玉米秸秆的残留物，甘蔗渣和甜高粱甘蔗渣等过程残渣，诸如柳枝稷和芒草的能量作物的木质部分，木材加工业的森林残留物或副产品，通过一系列加工步骤将锯木厂从锯木厂转移到液体生物燃料，其中进料以三个阶段水解并作为三个产物流排出，每个产物流由进料的三个主要成分之一的溶解碎片组成，操作处理步骤，其中三个产物流中的每一个通过化学或生物化学过程转化成具有高发热量和过程的产物，例如纯木质素和乙醇，其中将这些具有高热值的产物组合以形成液体生物燃料。

10. 发明授权

US5593727A Production of films of SiO.sub.2 by chemical vapor deposition 失效
标题翻译：通过化学气相沉积生产SiO2膜
公开(公告)号：US5593727A
公开(公告)日：1997-01-14
申请号：US148391
申请日：1993-11-08
申请人： Seshu B. Desu , Chien-Hsiung Peng , Tian Shi , Pradyot A. Agaskar
发明人： Seshu B. Desu , Chien-Hsiung Peng , Tian Shi , Pradyot A. Agaskar
IPC分类号： C01B33/00 , C08G77/12 , C23C16/00
CPC分类号： C08G77/12 , C01B33/00
摘要： The chemical vapor deposition of hydridospherosiloxane to generate films of SiO.sub.2 at low temperatures on substrates that cannot withstand high temperatures. The chemical vapor deposition process synthesized compounds with the general formula,(HSiO.sub.3/2).sub.n,with n being an even number ranging from 8 to a very large number. More particularly, it relates to the vapor deposition of oligomeric hydrogensilsesquioxanes, henceforth referred to as hydridospherosiloxanes. The hydridospherosiloxanes are used directly in a chemical vapor deposition reactor to generate films of SiO.sub.2 at low temperatures on substrates that cannot withstand high temperatures. Hydridospherosiloxanes and soluble hydrogensilsesquioxane resin are produced having the formula(HSiO.sub.3/2).sub.n,where n is an even integer greater than 8.
摘要翻译：化学气相沉积氢化间苯二甲硅氧烷以在不能承受高温的基材上在低温下产生SiO 2膜。化学气相沉积工艺合成具有通式（HSiO3 / 2）n的化合物，其中n为8至非常大的偶数。更具体地说，本发明涉及低聚氢倍半硅氧烷的气相沉积，此后称为氢化间苯二甲硅氧烷。氢化间苯二甲硅氧烷直接用于化学气相沉积反应器，以在低温下在不能承受高温的基材上产生SiO 2膜。产生具有式（HSiO3 / 2）n的氢化间苯二酚硅烷和可溶性倍半硅氧烷树脂，其中n是大于8的偶数整数。

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