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1. 发明授权

US09458310B2 Modified polyethylene film compositions 有权
标题翻译：改性聚乙烯薄膜组合物
公开(公告)号：US09458310B2
公开(公告)日：2016-10-04
申请号：US13584137
申请日：2012-08-13
申请人： Pradeep P. Shirodkar , Jianya J. Cheng , Andy H. Tsou , Pamela J. Wright , Johannes M. Soulages
发明人： Pradeep P. Shirodkar , Jianya J. Cheng , Andy H. Tsou , Pamela J. Wright , Johannes M. Soulages
IPC分类号： C08L23/06 , C08J5/18 , C08L23/08 , C08F36/04 , C08C19/02 , C08G81/02 , C08C19/44 , C08G83/00 , C08L25/04
CPC分类号： C08L23/06 , C08C19/02 , C08C19/44 , C08F36/04 , C08G81/022 , C08G83/003 , C08G83/006 , C08J5/18 , C08J2323/06 , C08J2400/202 , C08L9/00 , C08L23/0815 , C08L25/04 , C08L2203/16 , C08F4/488 , C08L101/005
摘要： The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g′ value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.
摘要翻译：本发明涉及包含一种或多种乙烯聚合物和一种或多种树枝状烃聚合物改性剂的聚乙烯组合物，特别地，本发明还涉及包含一种或多种乙烯聚合物和一种或多种树枝状烃聚合物改性剂的聚乙烯共混物，其中改性剂具有：1）ag'值小于0.75; 2）层数为2以上的Cayley树拓扑; 和3）分支点之间的平均Mw为1,500g / mol以上。

2. 发明申请

US20130211008A1 Modified Polyethylene Film Compositions 有权
标题翻译：改性聚乙烯薄膜组合物
公开(公告)号：US20130211008A1
公开(公告)日：2013-08-15
申请号：US13584137
申请日：2012-08-13
申请人： Pradeep P. SHIRODKAR , Jianya J. Cheng , Andy H. Tsou , Pamela J. Wright , Johannes M. Soulages
发明人： Pradeep P. SHIRODKAR , Jianya J. Cheng , Andy H. Tsou , Pamela J. Wright , Johannes M. Soulages
IPC分类号： C08L23/06
CPC分类号： C08L23/06 , C08C19/02 , C08C19/44 , C08F36/04 , C08G81/022 , C08G83/003 , C08G83/006 , C08J5/18 , C08J2323/06 , C08J2400/202 , C08L9/00 , C08L23/0815 , C08L25/04 , C08L2203/16 , C08F4/488 , C08L101/005
摘要： The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g′ value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.
摘要翻译：本发明涉及包含一种或多种乙烯聚合物和一种或多种树枝状烃聚合物改性剂的聚乙烯组合物，特别是本发明还涉及包含一种或多种乙烯聚合物和一种或多种树枝状烃聚合物改性剂的聚乙烯共混物，其中改性剂具有：1）ag'值小于0.75; 2）层数为2以上的Cayley树拓扑; 和3）分支点之间的平均Mw为1,500g / mol以上。

3. 发明授权

US08487061B2 Star hydrocarbon polymer, process for making, and a polymer blend composition having same 有权
标题翻译：星形烃聚合物，制备方法和具有相同的聚合物共混组合物
公开(公告)号：US08487061B2
公开(公告)日：2013-07-16
申请号：US13109313
申请日：2011-05-17
申请人： Andy H. Tsou , Nikos Hadjichristidis , Pamela J. Wright , Johannes M. Soulages
发明人： Andy H. Tsou , Nikos Hadjichristidis , Pamela J. Wright , Johannes M. Soulages
IPC分类号： C08G77/08
CPC分类号： C08F36/06 , C08C19/02 , C08F36/04 , C08F4/48
摘要： Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.
摘要翻译：提供了制备饱和星形烃聚合物的方法。该方法具有以下步骤：（A）在甲硅烷基化催化剂存在下，用甲基二氯硅烷氢化甲硅烷基化硅，形成氯硅烷树枝状大分子; （B）在锂和/或有机锂引发剂的存在下逐步使氯硅烷树状聚合物与乙烯基溴化镁反应，以构建更高代的氯代硅烷树枝状聚合物; （C）在锂和/或有机锂引发剂存在下阴离子聚合的聚丁二烯以形成活性聚（丁二烯基）锂; （D）将活性聚（丁二烯基）锂连接到较高代树枝状聚合物以形成星形聚丁二烯; 和（E）氢化星形聚丁二烯以形成饱和星形烃聚合物。还提供了根据上述方法制备的饱和星形烃聚合物和基质乙烯聚合物和饱和星形烃聚合物的聚合物组合物。

4. 发明申请

US20120296046A1 STAR HYDROCARBON POLYMER, PROCESS FOR MAKING, AND A POLYMER BLEND COMPOSITION HAVING SAME 有权
标题翻译：星形聚合物，制备方法和具有相同性能的聚合物混合组合物
公开(公告)号：US20120296046A1
公开(公告)日：2012-11-22
申请号：US13109313
申请日：2011-05-17
申请人： Andy H. Tsou , Nikos Hadjichristidis , Pamela J. Wright , Johannes M. Soulages
发明人： Andy H. Tsou , Nikos Hadjichristidis , Pamela J. Wright , Johannes M. Soulages
IPC分类号： C08L23/08 , C08F4/48
CPC分类号： C08F36/06 , C08C19/02 , C08F36/04 , C08F4/48
摘要： Provided is a process for making a saturated star hydrocarbon polymer. The process has the following steps: (A) hydrosilylating tetraethylene silicon with methyldichlorosilane in the presence of a hydrosilylating catalyst to form a chlorosilane dendrimer; (B) reacting the chlorosilane dendrimer with vinylmagnesium bromide in the presence of a lithium and/or organolithium initiator stepwise to build a higher generation chlorosilane dendrimer; (C) anionically polymerizing polybutadiene in the presence of a lithium and/or organolithium initiator to form living poly(butadienyl)lithium; (D) attaching the living poly(butadienyl)lithium to the higher generation dendrimer to form a star polybutadiene; and (E) hydrogenating the star polybutadiene to form the saturated star hydrocarbon polymer. There is also provided a saturated star hydrocarbon polymer made according to the above process and a polymer composition of a matrix ethylene polymer and the saturated star hydrocarbon polymer.
摘要翻译：提供了制备饱和星形烃聚合物的方法。该方法具有以下步骤：（A）在甲硅烷基化催化剂存在下，用甲基二氯硅烷氢化甲硅烷基化硅，形成氯硅烷树枝状大分子; （B）在锂和/或有机锂引发剂的存在下逐步使氯硅烷树状聚合物与乙烯基溴化镁反应，以构建更高代的氯代硅烷树枝状聚合物; （C）在锂和/或有机锂引发剂存在下阴离子聚合的聚丁二烯以形成活性聚（丁二烯基）锂; （D）将活性聚（丁二烯基）锂连接到较高代树枝状聚合物以形成星形聚丁二烯; 和（E）氢化星形聚丁二烯以形成饱和星形烃聚合物。还提供了根据上述方法制备的饱和星形烃聚合物和基质乙烯聚合物和饱和星形烃聚合物的聚合物组合物。

5. 发明申请

US20120157633A1 PROCESS FOR MAKING A SATURATED DENDRITIC HYDROCARBON POLYMER 有权
标题翻译：制备饱和的聚碳酸酯聚合物的方法
公开(公告)号：US20120157633A1
公开(公告)日：2012-06-21
申请号：US13329559
申请日：2011-12-19
申请人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Pamela J. Wright , Suzzy Chen Hsi Ho , Paul Edward Schuenzel
发明人： David John Lohse , Nikos Hadjichristidis , Andy Haishung Tsou , Pamela J. Wright , Suzzy Chen Hsi Ho , Paul Edward Schuenzel
IPC分类号： C08F8/32 , C08F255/00
CPC分类号： C08L9/00 , C08C19/02 , C08F36/04 , C08G83/002 , C08L19/00 , C08L23/06 , C08L2207/07 , C08F4/486
摘要： A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.
摘要翻译：制备基本上饱和的树枝状烃聚合物的方法。该方法具有以下步骤：（a）在阴离子条件下在第一有机单锂引发剂的存在下聚合一定量的第一链烯二烯单体以产生具有锂化链端的直链聚二烯二醇; （b）在四甲基乙二胺的存在下使直链多聚二烯与一定量的第二有机单锂引发剂反应，形成多元化的聚链二烯; （c）使多元化多聚二烯与一定量的第二链烯二烯单体反应以形成支链聚二烯; （d）用支链聚链二烯重复步骤（b）和（c）一次或多次以制备树枝状聚二烯; 和（e）氢化树枝状聚亚烷基二醇以形成基本饱和的树枝状烃聚合物。

6. 发明授权

US07402636B1 Method and apparatus for decreasing polymer deposition 有权
标题翻译：降低聚合物沉积的方法和装置
公开(公告)号：US07402636B1
公开(公告)日：2008-07-22
申请号：US11728324
申请日：2007-03-23
申请人： Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人： Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
IPC分类号： C08F2/12 , C08F4/52
CPC分类号： C08F10/10 , C08F2/005 , C08F2/14 , C08F210/10 , Y10S526/92 , C08F236/08
摘要： The disclosure provides a slurry polymerization system and method to decrease polymer deposition on reactor surfaces using an oxygenate such as alcohol (16) supplied to the polymerization medium (32) separate from the catalyst feed (34).
摘要翻译：本公开提供了一种使用供应到与催化剂进料（34）分离的聚合介质（32）的含氧化合物（16）来减少反应器表面上的聚合物沉积的淤浆聚合系统和方法。

7. 发明授权

US6111027A Adhesives comprising copolymers of macromonomers and unsaturated acids or anhydrides 有权
标题翻译：包含大分子单体和不饱和酸或酸酐的共聚物的粘合剂
公开(公告)号：US6111027A
公开(公告)日：2000-08-29
申请号：US164801
申请日：1998-10-01
申请人： Pamela J. Wright , Dennis George Peiffer , Kenneth Lewtas , Quoc Luvinh , Joseph Jacques Ripet , Anne Vera Macedo
发明人： Pamela J. Wright , Dennis George Peiffer , Kenneth Lewtas , Quoc Luvinh , Joseph Jacques Ripet , Anne Vera Macedo
IPC分类号： C10M145/10 , C08F8/00 , C08F20/16 , C08F210/16 , C08F255/00 , C08F267/00 , C08F283/00 , C08F290/04 , C08F290/06 , C08L23/08 , C09J123/08 , C09J123/24 , C09J151/00 , C09J151/06 , C10L1/196 , C10L1/198 , C10L1/236 , C10L1/238 , C10L1/30 , C10L10/00 , C10M145/16 , C10M149/06 , C10N30/02 , C10N40/25 , C08F210/00
CPC分类号： C10L1/2366 , C08F255/00 , C08F283/008 , C08F290/04 , C08F290/06 , C09J123/0815 , C09J123/0869 , C09J151/06 , C10L1/1966 , C10L1/198 , C10L1/2364 , C10L1/2368 , C10L1/238 , C10L1/303 , C10L10/00 , C10M145/16 , C10M149/06 , C08F210/16 , C08F2800/20 , C08L23/0815 , C08L23/0869 , C08L2314/06 , C10M2209/086 , C10M2217/024 , C10M2217/06
摘要： This invention relates to an adhesive composition comprising a copolymer comprising units derived from one or more macromonomers and an unsaturated acid or an unsaturated anhydride wherein the weight average molecular weight of the copolymer is at least twice the weight average molecular weight of the macromonomer, the melt index of the copolymer is 1 dg/min or more, and wherein the macromonomer:(1) has a weight average molecular weight between 500 and 100,000;(2) has at least 30% terminal unsaturation; and(3) comprises a copolymer of ethylene and at least one .alpha.-olefin, and/or a copolymer of propylene and ethylene or an .alpha.-olefin.
摘要翻译：本发明涉及包含共聚物的粘合剂组合物，其包含衍生自一种或多种大分子单体的单元和不饱和酸或不饱和酸酐，其中共聚物的重均分子量为大分子单体的重均分子量的至少两倍，熔体共聚物的指数为1dg / min以上，其中大分子单体：（1）的重均分子量为500〜100,000; （2）具有至少30％的末端不饱和度; 和（3）包括乙烯和至少一种α-烯烃的共聚物，和/或丙烯与乙烯或α-烯烃的共聚物。

8. 发明授权

US07893176B2 Polydispersity-controlled isoolefin polymerization with polymorphogenates 有权
标题翻译：多分散控制的异烯烃聚合与多形态
公开(公告)号：US07893176B2
公开(公告)日：2011-02-22
申请号：US11728306
申请日：2007-03-23
申请人： Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
发明人： Timothy D. Shaffer , Michael F. McDonald , David Y. Chung , Robert N. Webb , Deborah J. Davis , Pamela J. Wright
IPC分类号： C08F4/28 , C08F2/14 , C08F10/10
CPC分类号： C08F210/12 , C08F2/04 , C08F2/12 , C08F236/08 , C08F2500/04 , C08F4/00
摘要： The disclosure provides for a process and polymerization system to produce isoolefin polymers (72) utilizing polymorphogenates (16, 26) in the catalyst system to control polydispersity (MWD). The disclosure also provides a catalyst system (20) comprising a plurality of active catalyst complex species (34) formed by combination of a Lewis acid (24), an initiator (22) and a polymorphogenate (26), as well as polymers made using the catalyst system or process. The polymorphogenate (16, 26) can promote or mimic the formation of different active catalyst complex species (34) having different polymerization rates, i.e. different rates of propagation, chain transfer, or termination, as observed by different polydispersities resulting from the presence of relatively different proportions of the polymorphogenate.
摘要翻译：本公开提供了一种方法和聚合体系，以在催化剂体系中利用多形态（16,26）来产生异构烯烃聚合物（72）以控制多分散性（MWD）。本公开还提供了催化剂体系（20），其包含通过路易斯酸（24），引发剂（22）和多形态（26）的组合形成的多种活性催化剂络合物（34），以及使用催化剂体系或工艺。聚异构体（16,26）可以促进或模拟具有不同聚合速率的不同活性催化剂复合物（34）的形成，即不同的传播速率，链转移或终止，如通过相对存在导致的不同多分散性所观察到的不同比例的多形态。

9. 发明申请

US20090062484A1 Method for Reducing Depositions in Polymerization Vessels 有权
标题翻译：降低聚合容器沉积的方法
公开(公告)号：US20090062484A1
公开(公告)日：2009-03-05
申请号：US12179375
申请日：2008-07-24
申请人： Timothy D. Shaffer , Pamela J. Wright , J. Davis Deborah , Michael F. McDonald
发明人： Timothy D. Shaffer , Pamela J. Wright , J. Davis Deborah , Michael F. McDonald
IPC分类号： C08F2/01
CPC分类号： C08F210/12 , C08F2/01 , C08F2/14 , C08F236/08 , C08F2500/02 , C08F2500/03
摘要： The method of polymerization includes the steps of a) providing a catalyst system, b) providing at least one monomer or comonomer mixture in a reaction vessel, c) introducing the catalyst into the reaction vessel, and d) polymerizing the at least one monomer or comonomer mixture to produce an isoolefin polymer. The catalyst may be soluble in the diluent used for polymerization. The polymerization contact surfaces of the reaction vessel have an arithmetic average surface roughness of less than 0.3 μm (12 microinches).
摘要翻译：聚合方法包括以下步骤：a）提供催化剂体系，b）在反应容器中提供至少一种单体或共聚单体混合物，c）将催化剂引入反应容器中，和d）聚合至少一种单体或共聚单体混合物以产生异烯烃聚合物。催化剂可溶于用于聚合的稀释剂中。反应容器的聚合接触表面的算术平均表面粗糙度小于0.3μm（12微英寸）。

10. 发明授权

US06194622B1 Method for inhibiting hydrate formation 失效
标题翻译：抑制水合物形成的方法
公开(公告)号：US06194622B1
公开(公告)日：2001-02-27
申请号：US09266387
申请日：1999-03-11
申请人： Dennis G. Peiffer , Christine A. Costello , Lawrence D. Talley , Pamela J. Wright
发明人： Dennis G. Peiffer , Christine A. Costello , Lawrence D. Talley , Pamela J. Wright
IPC分类号： C07C720
CPC分类号： C07C7/20 , C09K8/52 , C09K2208/22 , Y10S585/95
摘要： A method for inhibiting the formation of gas hydrates in a petroleum fluid having hydrate-forming constituents is claimed. More specifically, the method can be used to treat a petroleum fluid, such as natural gas conveyed in a pipe, to inhibit the formation of a hydrate flow restriction in the pipe. The hydrate inhibitors used for practicing the method comprise substantially water soluble homopolymers and copolymers of surfactant monomers, wherein the surfactant monomer unit may be represented by the formula: where R1 and R2 independently are hydrogen or a methyl group, M is a metal cation, n is a number sufficient to produce a number average molecular weight between 1000 and 6,000,000, and o is a number from 1 to 5.
摘要翻译：要求保护在具有水合物形成成分的石油液体中抑制气体水合物形成的方法。更具体地，该方法可用于处理石油流体，例如在管道中输送的天然气，以抑制管道中的水合物流动限制的形成。用于实施该方法的水合物抑制剂包含基本上水溶性表面活性剂单体的均聚物和共聚物，其中表面活性剂单体单元可以由下式表示：其中R1和R2独立地是氢或甲基，M是金属阳离子，n 是足以产生1000至600,000之间的数均分子量的数，o是1至5的数。

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