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    • 3. 发明授权
    • Electric storage battery with valve metal electrodes
    • 蓄电池带阀门金属电极
    • US4037032A
    • 1977-07-19
    • US683544
    • 1976-05-05
    • Antonio NidolaVittorio DE NoraPlacido M. Spaziante
    • Antonio NidolaVittorio DE NoraPlacido M. Spaziante
    • H01M2/02H01M4/66H01M4/86H01M4/92H01M10/36H01M12/08H01M6/16
    • H01M4/664H01M10/365H01M2/02H01M4/66H01M4/661
    • Electric storage batteries with titanium or other film forming metal anodes and cathodes are provided. The anodes are coated with mixed oxide coatings of a film forming metal oxide containing a platinum group metal oxide catalyst, which coatings may contain oxides of other metals to alter the breakdown voltage and increase the oxygen overpotential of the cathodes while preserving a low bromine and chlorine overpotential. The cathodes may be uncoated titanium or other film forming metals or film forming metals with a silver coating thereon. Bipolar film forming metal cathodes and anodes are provided carrying a mixed oxide coating on the cathodic face and either no coating or a silver coating on the anodic face. The invention is applicable to all types of electric storage batteries, either primary or secondary, and multiple batteries may be connected in series or in parallel to provide the desired amperage and voltage characteristics.
    • 提供具有钛或其它成膜金属阳极和阴极的蓄电池。 阳极用含有铂族金属氧化物催化剂的成膜金属氧化物的混合氧化物涂层涂覆,该涂层可以含有其它金属的氧化物,以改变击穿电压并增加阴极的氧超电势,同时保持低溴和氯 超电位 阴极可以是未涂覆的钛或其它成膜金属或其上具有银涂层的成膜金属。 提供双极成膜金属阴极和阳极,其在阴极表面上带有混合氧化物涂层,并且在阳极表面上没有涂层或银涂层。 本发明适用于所有类型的主要或次要的蓄电池,并且多个电池可以串联或并联连接以提供所需的电流和电压特性。
    • 4. 发明授权
    • Sintered electrodes with electrocatalytic coating
    • 具有电催化涂层的烧结电极
    • US4146438A
    • 1979-03-27
    • US774101
    • 1977-03-07
    • Vittorio de NoraPlacido M. SpazianteAntonio Nidola
    • Vittorio de NoraPlacido M. SpazianteAntonio Nidola
    • C25B11/04C25C3/12C25C7/02C25B11/08C25C5/04
    • C25B11/04C25C3/12C25C7/02
    • Sintered electrodes for electrolytic processes comprising a self-sustaining body or matrix of sintered powders of an oxycompound of at least one metal selected from the group consisting of titanium, tantalum, zirconium, vanadium, niobium, hafnium, aluminum, silicon, tin, chromium, molybdenum, tungsten, lead, manganese, beryllium, iron, cobalt, nickel, platinum, palladium, osmium, iridium, rhenium, technetium, rhodium, ruthenium, gold, silver, cadmium, copper, zinc, germanium, arsenic, antimony, bismuth, boron, scandium and metals of the lanthanide and actinide series and at least one electroconductive agent, the said electrodes being provided over at least a portion of their surface with at least one electrocatalyst for electrolysis reaction and bipolar electrodes, electrolytic cells containing said electrodes and electrolytic processes using the said electrodes as anodes and/or electrodes. Oxycompounds include oxides, multiple oxides, mixed oxides, oxyhalides and oxycarbides and mixtures thereof.PRIOR APPLICATION
    • 一种用于电解方法的烧结电极,其包含选自钛,钽,锆,钒,铌,铪,铝,硅,锡,铬等的至少一种金属的氧化合物的烧结粉末的自持体或基质, 钼,钨,铅,锰,铍,铁,钴,镍,铂,钯,锇,铱,铼,锝,铑,钌,金,银,镉,铜,锌,锗,砷,锑,铋, 硼,钪和金属的镧系元素和锕系和至少一种导电剂,所述电极在其至少一部分表面上提供至少一个用于电解反应的电催化剂和双极电极,含有所述电极和电解质的电解槽 使用所述电极作为阳极和/或电极的过程。 氧化合物包括氧化物,多重氧化物,混合氧化物,卤氧化物和碳氧化物及其混合物。
    • 6. 发明授权
    • Novel electrolysis method and apparatus
    • 新型电解法和设备
    • US4046653A
    • 1977-09-06
    • US580952
    • 1975-05-27
    • Oronzio de NoraVittorio DE NoraPlacido M. Spaziante
    • Oronzio de NoraVittorio DE NoraPlacido M. Spaziante
    • C25B1/26C25B9/06C25B1/24
    • C25B9/063C25B1/265
    • A novel process for the preparation of an alkali metal halate by electrolysis of an aqueous alkali metal halide solution comprising passing an alkali metal halide solution upwardly through a plurality of bipolar electrolysis units while passing an electrolysis current therethrough at a temperature of 90.degree. to 110.degree. C and at a current density to volume ratio of 15 to 30 A/liter to convert at least a portion of the alkali metal halide to alkali metal hypohalite, passing the resulting electrolyte while venting the hydrogen formed to a reaction zone whose volume is sufficient to provide a residence time to substantially complete the conversion of the alkali metal hypohalite to alkali metal halate and recovering the said halate from the electrolyte and an apparatus for performing the said process.
    • 一种用于通过电解碱金属卤化物水溶液来制备碱金属卤化物的新方法,包括使碱金属卤化物溶液向上通过多个双极电解单元,同时在90°至110°的温度通过电解电流。 并且当前的体积比为15-30A /升,以将至少一部分碱金属卤化物转化为碱金属次卤酸盐,使所得电解质通过,同时将形成的氢气排放到体积足够的反应区 提供停留时间以基本上完​​成碱金属次卤酸盐转化为碱金属卤化物并从电解质中回收所述卤酸盐和用于进行所述方法的设备。
    • 10. 发明授权
    • Molten salt electrolysis
    • 熔盐电解
    • US4187155A
    • 1980-02-05
    • US940277
    • 1978-09-07
    • Vittorio de NoraPlacido M. SpazianteAntonio Nidola
    • Vittorio de NoraPlacido M. SpazianteAntonio Nidola
    • C25C3/06C25C3/12C25C7/02C25B11/04
    • C25C7/025C25C3/06C25C3/12
    • A novel method of molten salt electrolysis and novel electrolytic cells for molten salt electrolysis wherein the anodes for the electrolysis are comprised of a self-sustaining matrix of sintered powders of at least one oxycompound such as oxides, multipleoxides, mixed oxides, oxyhalides and oxycarbides, of at least one metal selected from the group consisting of lanthanum, terbium, erbium, ytterbium, thorium, titanium, zirconium, hafnium, niobium, chromium and tantalum and at least one electroconductive agent, the said anode being provided over at least a portion of its surface with at least one electrocatalyst for the electrolysis reaction and bipolar electrodes for the said cells which electrodes are resistant to corrosion in molten salt electrolysis and have good electroconductive and good electrocatalytic activity.
    • 熔盐电解的新方法和用于熔盐电解的新型电解池,其中电解阳极由至少一种氧化合物如氧化物,多氧化物,混合氧化物,卤氧化物和碳氧化物的烧结粉末的自持基质组成, 的至少一种选自镧,铽,铒,镱,钍,钛,锆,铪,铌,铬和钽的金属和至少一种导电剂,所述阳极设置在至少一部分 其表面具有用于电解反应的至少一个电催化剂和用于所述电池的双极电极,该电极在熔融盐电解中具有耐腐蚀性并且具有良好的导电性和良好的电催化活性。