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1. 发明授权

US5792825A Silicone compounds containing sterically hindered cyclic amine functional groups which are useful for the light and thermal stabilization of polymers 失效
标题翻译：含有空间位阻环状胺官能团的硅氧烷化合物，可用于聚合物的光稳定和热稳定性
公开(公告)号：US5792825A
公开(公告)日：1998-08-11
申请号：US661692
申请日：1996-06-11
申请人： Philippe Karrer , Gerard Mignani , Bernard Pontini , Storet Isabelle
发明人： Philippe Karrer , Gerard Mignani , Bernard Pontini , Storet Isabelle
IPC分类号： C07D491/113 , C07F7/08 , C08F283/12 , C08G77/388 , C08G77/42 , C08L101/00 , C08G77/04
CPC分类号： C08G77/388 , C07F7/0879 , C08L101/00
摘要： The present invention relates to linear, cyclic or branched polyorganosiloxanes having, per molecule, at least three siloxy units, including at least one functional unit of formula: ##EQU1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical and X contains a secondary or tertiary cyclic amine functional group bonded to the silicon via an Si--A--C bond where A is a residue comprising a cyclic acetal group. X more specifically represents a monovalent group of formula: ##STR1## The present invention also relates to the use of such polyorganosiloxanes in polymers for improving in particular their photostabilization.
摘要翻译：本发明涉及每分子具有至少三个甲硅烷氧基单元的直链，环状或支化的聚有机基硅氧烷，其包括至少一个下式的官能单元：其中R 1表示C 1至C 4烷基或苯基，X包含仲或通过Si-AC键与硅键合的叔环胺官能团，其中A是包含环状缩醛基团的残基。 X更具体地表示下式的单价基团：（II）本发明还涉及这种聚有机硅氧烷在聚合物中的用途，特别是其改善光稳定性。

2. 发明授权

US5834613A Perhalogenated polyorganosiloxanes and the processes for their preparation 失效
标题翻译：全卤代聚有机硅氧烷及其制备方法
公开(公告)号：US5834613A
公开(公告)日：1998-11-10
申请号：US686400
申请日：1996-07-25
申请人： Philippe Jost , Philippe Karrer , Gerard Mignani , Philippe Olier
发明人： Philippe Jost , Philippe Karrer , Gerard Mignani , Philippe Olier
IPC分类号： C08L83/04 , C08G77/24 , C08G77/38 , C08G77/382 , C08G77/385 , C08G77/42 , C08L83/08 , C10M107/50 , C11D3/37 , C07F7/08 , C07F7/10
CPC分类号： C08G77/385 , C08G77/382
摘要： Chemically stable, perfluorinated, linear or cyclic polyorganosiloxanes (POS), and a process for the preparation thereof. Antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings and other compositions containing the perfluorinated POS are disclosed.
摘要翻译：化学稳定的全氟化，线性或环状聚有机硅氧烷（POS）及其制备方法。公开了消泡剂，降低表面张力的试剂，防污剂，抗粘合剂，润滑剂，疏油和/或疏水剂，包含全氟化POS的涂料和其它组合物。

3. 发明授权

US5733999A Silicone compounds containing a phenylenediamine functional group and their application in the protection of rubber materials against ozone 失效
标题翻译：含有苯二胺官能团的硅氧烷化合物及其在保护橡胶材料中抵抗臭氧的应用
公开(公告)号：US5733999A
公开(公告)日：1998-03-31
申请号：US644028
申请日：1996-05-09
申请人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
发明人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
IPC分类号： C08G77/26 , C08G77/28 , C08G77/388 , C08G77/42 , C08G77/44 , C08L21/00 , C07F7/08
CPC分类号： C08G77/388 , C08L21/00 , C08L7/00 , C08L9/00
摘要： The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si--(hydrocarbon linking unit)--N and/or Si--(hydrocarbon linking unit)--C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.
摘要翻译：本发明涉及基本上由直链，环状或支化的聚有机硅氧烷组成的化合物，其每分子具有至少3个甲硅烷氧基单元，包括至少一个下式的式（I）的硅氧烷基官能单元：（R1）aXSi（O）+ E， a / 2 + EE，其中R1表示C1-C4烷基或苯基，X含有N，N'-二 - 和/或三取代苯二胺官能团，通过Si - （烃连接单元）-N 和/或Si-（烃连接单元）-C键，a是选自0,1和2的数字。本发明还涉及这种化合物作为橡胶的抗臭氧剂，特别是用于轮胎的橡胶组合物的用途。

4. 发明授权

US06555678B1 Method for preparing a regenerated cellulose fibre or yarn 失效
标题翻译：制备再生纤维素纤维或纱线的方法
公开(公告)号：US06555678B1
公开(公告)日：2003-04-29
申请号：US09530188
申请日：2000-09-25
申请人： Christian Allandrieu , Lucile Gambut , Philippe Karrer , Ties Karstens , Gerard Mignani , Armin Stein
发明人： Christian Allandrieu , Lucile Gambut , Philippe Karrer , Ties Karstens , Gerard Mignani , Armin Stein
IPC分类号： C08B1600
CPC分类号： D01F2/24 , D01F2/00
摘要： A method has been developed for making regenerated cellulose yarn. The method includes the steps of spinning a solution derived from cellulose or a cellulose derivative in a molten state through at least one extrusion die, then regenerating the cellulose by treating the resulting yarn, wherein a silylated cellulose derivative is prepared by reaction with a silylating agent; the silylated cellulose is extracted from the synthesis reaction medium; then spun through at least an extrusion die; and the resultant yarn treated with a desilylation agent to regenerate the cellulose and a siloxane. The resulting cellulose yarns or fibers may be used for making woven or knitted textile surfaces or non-woven surfaces. Said yarns or fibers are also useful as reinforcing fibers in elastomeric materials and more particularly, in tires.
摘要翻译：已经开发了用于制备再生纤维素纱线的方法。该方法包括以下步骤：通过至少一个挤出模头将来自纤维素或纤维素衍生物的溶液通过至少一个挤出模头纺丝，然后通过处理所得纱线再生纤维素，其中通过与甲硅烷基化试剂反应制备甲硅烷基化纤维素衍生物 ; 从合成反应介质中提取甲硅烷基化纤维素; 然后通过至少一个挤出模头旋转; 用脱甲基剂处理得到的纱线再生纤维素和硅氧烷。所得到的纤维素纱线或纤维可用于制造机织或针织织物表面或无纺织物表面。所述纱线或纤维也可用作弹性体材料中的增强纤维，更具体地，在轮胎中。

5. 发明授权

US5929166A Silicone compounds containing a phenylenediamine functional group and their application in the protection of rubber materials against ozone 失效
标题翻译：含有苯二胺官能团的硅氧烷化合物及其在保护橡胶材料中抵抗臭氧的应用
公开(公告)号：US5929166A
公开(公告)日：1999-07-27
申请号：US979498
申请日：1997-11-26
申请人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
发明人： Yves Bomal , Philippe Karrer , Jean-Manuel Mas , Gerard Mignani
IPC分类号： C08G77/26 , C08G77/28 , C08G77/388 , C08G77/42 , C08G77/44 , C08L21/00 , C08F8/30
CPC分类号： C08G77/388 , C08L21/00 , C08L7/00 , C08L9/00
摘要： The present invention relates to compounds composed essentially of a linear, cyclic or branched polyorganosiloxane having, per molecule, at least 3 siloxy units, including at least one siloxy functional unit of formula: ##STR1## where R.sup.1 represents a C.sub.1 to C.sub.4 alkyl or phenyl radical, X contains an N,N'-di- and/or trisubstituted phenylenediamine functional group, bonded to the silicon via an Si-(hydrocarbon linking unit)-N and/or Si-(hydrocarbon linking unit)-C bond, and a is a number chosen from 0, 1 and 2. The present invention also relates to the use of such compounds as antiozonants for rubbers and in particular for rubber compositions for tires.
摘要翻译：本发明涉及基本上由直链，环状或支化的聚有机硅氧烷组成的化合物，其每分子具有至少3个甲硅烷氧基单元，包括至少一个下式的甲硅烷氧基官能单元：其中R 1表示C 1至C 4烷基或苯基，X 含有通过Si-（烃连接单元）-N和/或Si-（烃连接单元）-C键与硅结合的N，N'-二 - 和/或三取代的苯二胺官能团，a是本发明还涉及这种化合物作为橡胶的抗臭氧剂，特别是用于轮胎的橡胶组合物的用途。

6. 发明授权

US06369186B1 Cross-linkable compositions containing functionalized silicon fluids and use of these compositions for preparing polyurethane films 失效
标题翻译：含有官能化硅液的可交联组合物和这些组合物用于制备聚氨酯膜的用途
公开(公告)号：US06369186B1
公开(公告)日：2002-04-09
申请号：US09297856
申请日：1999-07-19
申请人： Paul Branlard , Nathalie Guennouni , Philippe Karrer , Gérard Mignani
发明人： Paul Branlard , Nathalie Guennouni , Philippe Karrer , Gérard Mignani
IPC分类号： C08G7704
CPC分类号： C08J5/18 , C08G18/10 , C08G18/4063 , C08G18/61 , C08J2375/04 , C09D175/04
摘要： The invention concerns a novel cross-linkable composition and its use for preparing novel polyurethane films. The cross-linkable composition comprises (a) 20 to 50 wt. % of polyisocyanate, (b) 50 to 80 wt. % of acrylic oligomer containing hydroxyl groupings whose content in weight relative to the acrylic oligomer is between 2.5 and 4.5% and (c) 1 to 10 wt. % of a silicon fluid of formula (1).
摘要翻译：本发明涉及一种新的可交联组合物及其用于制备新型聚氨酯膜的用途。可交联组合物包含（a）20至50wt。％的多异氰酸酯，（b）50〜80重量％含有羟基的丙烯酸低聚物的含量相对于丙烯酸低聚物的重量比为2.5〜4.5％，（c）为1〜10重量％％的式（1）的硅液。

7. 发明授权

US06855842B1 Intermediates for making a bezofuran or benzothiophene derivative nitrated in position 5 and uses thereof 失效
标题翻译：制备在5号位置硝化的吩噻吩或苯并噻吩衍生物的中间体及其用途
公开(公告)号：US06855842B1
公开(公告)日：2005-02-15
申请号：US10110441
申请日：2000-10-23
申请人： Thierry Schlama , Armand Mettling , Philippe Karrer
发明人： Thierry Schlama , Armand Mettling , Philippe Karrer
IPC分类号： C07B61/00 , C07C67/31 , C07C69/712 , C07C69/734 , C07C201/08 , C07C205/37 , C07C205/44 , C07C319/14 , C07C319/20 , C07C323/52 , C07D307/79 , C07D333/54 , C07C69/76
CPC分类号： C07D307/79 , C07C67/31 , C07C201/12 , C07C205/37 , C07D333/54 , C07C69/712
摘要： The invention concerns novel nitroaromatic compounds of general formula (I′) wherein: R, R′1, R2, Z and n are as defined in claim 1. The invention also concerns a method for preparing nitroaromatic compounds nitrated in position 4. The invention further concerns the use of said compounds for preparing heterocyclic benzofuran or benzothiophene derivatives nitrated in position 5. The invention concerns particularly the preparation of 2-alkyl-5-nitrobezofuran.
摘要翻译：本发明涉及通式（I'）的新型硝基芳族化合物，其中：R 1，R 1，R 2，Z和n如权利要求1中所定义。本发明还涉及在位置4中硝化的硝基芳族化合物的制备方法。还涉及所述化合物用于制备在5位硝化的杂环苯并呋喃或苯并噻吩衍生物的用途。本发明特别涉及2-烷基-5-硝基吩呋呋喃的制备。

8. 发明申请

US20050113596A1 Intermediates for the production of a benzofuran or benzothiophene type derivative nitrated in the 5 position, and use thereof 审中-公开
标题翻译：用于生产在5位硝化的苯并呋喃或苯并噻吩型衍生物的中间体及其用途
公开(公告)号：US20050113596A1
公开(公告)日：2005-05-26
申请号：US10972575
申请日：2004-10-25
申请人： Thierry Schlama , Armand Mettling , Philippe Karrer
发明人： Thierry Schlama , Armand Mettling , Philippe Karrer
IPC分类号： C07B61/00 , C07C67/31 , C07C69/712 , C07C69/734 , C07C201/08 , C07C205/37 , C07C205/44 , C07C319/14 , C07C319/20 , C07C323/52 , C07D307/79 , C07D333/54 , C07C323/22 , C07C25/53
CPC分类号： C07D307/79 , C07C67/31 , C07C201/12 , C07C205/37 , C07D333/54 , C07C69/712
摘要： The invention concerns novel nitroaromatic compounds of general formula (I′) wherein: R, R′1, R2, Z and n are as defined in claim 38. The invention also concerns a method for preparing nitroaromatic compounds nitrated in position 4. The invention further concerns the use of said compounds for preparing heterocyclic benzofuran or benzothiophene derivatives nitrated in position 5. The invention concerns particularly the preparation of 2-alkyl-5-nitrobezofuran
摘要翻译：本发明涉及通式（I'）的新型硝基芳族化合物，其中：R，R'1，R2，Z和n如权利要求38中所定义。本发明还涉及制备位置4中硝化芳族化合物的方法。本发明进一步关于所述化合物用于制备位置5中硝化的杂环苯并呋喃或苯并噻吩衍生物的用途。本发明特别涉及2-烷基-5-硝基吩呋呋喃的制备

9. 发明授权

US06184329B2 Polyfunctional, perhalogenated polyorganosiloxanes and methods for preparation thereof 失效
标题翻译：多官能，全卤代聚有机硅氧烷及其制备方法
公开(公告)号：US06184329B2
公开(公告)日：2001-02-06
申请号：US08687044
申请日：1996-07-25
申请人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
发明人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
IPC分类号： C08G7724
CPC分类号： C08G77/382 , C08G77/385
摘要： Chemicaly stable, perflourinated, linear or cyclic polyorganosiloxanes (POS), and a process for the preparation thereof. Antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings and other compositions containing the perfluorinated POS are disclosed.
摘要翻译：化学稳定的，全氟化的，直链或环状的聚有机硅氧烷（POS）及其制备方法。公开了消泡剂，降低表面张力的试剂，防污剂，抗粘合剂，润滑剂，疏油和/或疏水剂，包含全氟化POS的涂料和其它组合物。

10. 发明授权

US06197987B1 Polyfunctional perhalogenated polyorganosiloxanes and the processes for their preparation 失效
标题翻译：多官能全卤代聚有机硅氧烷及其制备方法
公开(公告)号：US06197987B1
公开(公告)日：2001-03-06
申请号：US09247099
申请日：1999-02-09
申请人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
发明人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
IPC分类号： C07F708
CPC分类号： C08G77/382 , C08G77/385
摘要： The present invention relates to chemically stable, polyfunctional, perfluorinated polyorganosiloxanes (POS) comprising on the one hand fluorinated lateral grafts resulting from the hydrosilylation of perfluorinated olefins with SiH units and having alkyl and/or alkyl ester linkages but not ether linkages, and on the other hand other, non-perfluorinated functional units E capable of giving them diverse and varied physical and chemical properties and opening up avenues in numerous applications. Examples of these POS according to the invention are those of the following formula: According to another of its features, the invention relates to a process for the preparation of these polyfunctional perfluorinated POS. Applications: antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings etc.
摘要翻译：本发明涉及化学稳定的，多官能的全氟化聚有机硅氧烷（POS），其一方面包含由全氟化烯烃与SiH单元的氢化硅烷化并具有烷基和/或烷基酯键而不是醚键产生的氟化侧向接枝，另一方面是其他非全氟化功能单元E，其能够给予它们多种多样的变化的物理和化学性质，并且在许多应用中开辟了途径。根据本发明的这些POS的实例是下式的那些：根据其另一个特征本发明涉及制备这些多官能全氟化POS的方法。应用：消泡剂，降低表面张力的试剂，防污剂，抗粘合剂，润滑剂，疏油和/或疏水剂，涂料等。

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