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    • 1. 发明申请
    • Degradable additive for viscoelastic surfactant based fluid systems
    • 用于粘弹性表面活性剂的流体系统的可降解添加剂
    • US20050252659A1
    • 2005-11-17
    • US11159023
    • 2005-06-22
    • Philip SullivanJ. BrownJesse LeeGolchehreh Salamat
    • Philip SullivanJ. BrownJesse LeeGolchehreh Salamat
    • C09K8/68C09K8/70E21B43/267
    • C09K8/68C09K8/506C09K8/62C09K8/70C09K8/72C09K8/74C09K2208/26C09K2208/30Y10S507/902
    • A method is given for treating a subterranean formation penetrated by a wellbore with a viscosified fluid. The fluid contains a solid hydrolysable polyacid that upon dissolution and hydrolysis releases an acid that is a breaker for the viscosifying system. Suitable solid hydrolysable polyacids include polylactic acid and polyglycolic acid. The fluid also contains a pH control agent, present in an amount sufficient to neutralize any acid present in the solid hydrolysable polyacid before the injection and to neutralize any acid generated by the solid hydrolysable polyacid during the injection, so that the acid breaker is not available to break the fluid during the injection. In one embodiment the viscosifier is a viscoelastic surfactant fluid system and the solid hydrolysable polyacid is of a size selected to be a fluid loss additive, for example in fracturing or gravel packing. In another embodiment, the solid hydrolysable polyacid is used in particles sufficiently small that they enter the pores of the formation. In either case, the viscosifier is broken after the solid releases more acid than can be neutralized by the pH control agent.
    • 给出了用增稠液体处理井眼渗透的地层的方法。 流体包含固体可水解的多酸,其在溶解和水解时释放酸,该酸是用于增粘体系的断裂剂。 合适的固体可水解的多元酸包括聚乳酸和聚乙醇酸。 流体还含有pH控制剂,其量足以中和注射前固体可水解的多元酸中存在的任何酸,并且在注射期间中和由固体可水解的多元酸产生的任何酸,使得酸性破坏剂不可用 在注射期间打破流体。 在一个实施方案中,增粘剂是粘弹性表面活性剂流体系统,并且固体可水解的多元酸的尺寸被选择为流体损失添加剂,例如在压裂或砾石包装中。 在另一个实施方案中,固体可水解的多元酸以足够小的颗粒使用,使得它们进入地层的孔。 在任一种情况下,在固体释放比可以被pH控制剂中和的酸更多之后,粘稠剂被破坏。
    • 9. 发明授权
    • Carbon dioxide foamed fluids
    • 二氧化碳发泡流体
    • US07803744B2
    • 2010-09-28
    • US11858246
    • 2007-09-20
    • Yiyan ChenJesse LeeTimothy L. Pope
    • Yiyan ChenJesse LeeTimothy L. Pope
    • C09K8/518C09K8/60
    • C09K8/706B01F17/0085C09K8/516C09K8/703C09K8/74C09K2208/30Y10S507/904
    • An aqueous viscoelastic surfactant (VES) fluid foamed or energized with carbon dioxide, in which the VES is more compatible with the carbon dioxide, is made by the addition of one or more than one synergistic co-surfactant. The synergist co-surfactant includes quaternary amines and ethoxylated carboxylates having a hydrophobic chain shorter than the hydrophobic chain of the VES. Improved compatibility is evidenced for a given surfactant concentration either by formation and maintenance of a foam under conditions at which the foam could not otherwise have been formed or maintained, or by either higher viscosity of the foamed fluid at a given temperature or longer foam life at a given temperature or a higher temperature at which useful fluid viscosity can be generated or maintained for a useful time. The aqueous carbon dioxide foamed fluids may be used in acidizing, acid fracturing, gravel packing, diversion, and well cleanout.
    • 通过添加一种或多种协同辅助表面活性剂,可以制备VES与二氧化碳更相容的二氧化碳发泡或赋能的含水粘弹性表面活性剂(VES)流体。 增效剂助表面活性剂包括具有比VES的疏水链短的疏水链的季胺和乙氧基化羧酸盐。 对于给定的表面活性剂浓度,通过在泡沫不能形成或保持的条件下形成和维持泡沫,或通过在给定温度下较高粘度的发泡流体或更长的泡沫寿命来证明给定的表面活性剂浓度的改进的相容性 给定的温度或更高的温度,在该温度下可以产生或维持有用的时间。 二氧化碳水溶液发泡流体可用于酸化,酸压裂,砾石填充,分流和清洁。