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1. 发明授权

US5001295A Process for preparing dialkylnaphthalene 失效
标题翻译：制备二烷基萘的方法
公开(公告)号：US5001295A
公开(公告)日：1991-03-19
申请号：US494203
申请日：1990-03-15
申请人： Philip J. Angevine , Thomas F. Degnan , David O. Marler
发明人： Philip J. Angevine , Thomas F. Degnan , David O. Marler
IPC分类号： B01J29/04 , C07C2/12
CPC分类号： C07C2/12 , B01J29/04 , C07C2529/70
摘要： A catalytic process is provided for the preparation of dialkylnaphthalenes by alkylating a 2-alkylnaphthalene with an alkylating agent having an aliphatic group of from one to five carbon atoms, such as methanol. The catalyst comprises a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译：提供了通过用具有1至5个碳原子的脂族基团如甲醇的烷基化烷基化2-烷基萘来制备二烷基萘的催化方法。该催化剂包括合成沸石，其特征在于X射线衍射图包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83±0.14,6.18±0.12,6.00±0.10， 4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。

2. 发明授权

US4982040A Process for the catalytic disproportionation of methylnaphthalenes 失效
标题翻译：甲基萘催化歧化过程
公开(公告)号：US4982040A
公开(公告)日：1991-01-01
申请号：US454481
申请日：1989-12-21
申请人： Philip J. Angevine , Thomas F. Degnan , David O. Marler
发明人： Philip J. Angevine , Thomas F. Degnan , David O. Marler
IPC分类号： B01J29/86 , B01J29/04 , B01J29/70 , C07B61/00 , C07C2/12 , C07C6/12 , C07C15/24
CPC分类号： C07C6/123 , B01J29/04 , C07C2/12 , C07C2529/06 , C07C2529/70
摘要： A methylnaphthalene such as 2-methylnaphthalene undergoes catalytic disproportionation to naphthalene and a mixture of dimethylnaphthalene isomers, preferably containing substantial quantities of 2,6-dimethylnaphthalene, employing catalyst comprising zeolite characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译：使用包含沸石的催化剂，其特征在于X射线衍射图包括12.36+的平面d间距，甲基萘如2-甲基萘经历催化歧化萘和二甲基萘异构体的混合物，优选含有大量的2,6-二甲基萘， /-0.4,11.03 +/- 0.2,8.83±0.14 6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。

3. 发明授权

US5073655A Method for preparing diarylalkanes 失效
标题翻译：二芳基烷烃的制备方法
公开(公告)号：US5073655A
公开(公告)日：1991-12-17
申请号：US559242
申请日：1990-07-27
申请人： Philip J. Angevine , Ivy D. Johnson , David O. Marler , John P. McWilliams
发明人： Philip J. Angevine , Ivy D. Johnson , David O. Marler , John P. McWilliams
IPC分类号： B01J29/04 , C07C2/12
CPC分类号： B01J29/04 , C07C2/12 , C07C2529/70
摘要： Diarylalkanes are prepared by alkylating an aromatic hydrocarbon with an aromatic alkylation agent in the presence of a synthetic porous crystalline material catalyst composition. The aromatic hydrocarbon can be, for example, benzene, toluene, naphthalene, etc. The aromatic alkylating agent can be an aromatic compound with a hydroxy group, such as phenol, or benzyl alcohol, or an aromatic halide, aldehyde, ether, or an aromatic olefin such as styrene.
摘要翻译：二芳基烷烃通过在合成的多孔结晶材料催化剂组合物的存在下用芳族烷基化剂烷基化芳族烃来制备。芳族烃可以是例如苯，甲苯，萘等。芳族烷基化剂可以是具有羟基的芳香族化合物，例如苯酚或苄醇，或芳族卤化物，醛，醚或芳族烯烃如苯乙烯。

4. 发明授权

US5294330A Hydrocracking process with a catalyst comprising MCM-36 失效
标题翻译：含有MCM-36催化剂的加氢裂化工艺
公开(公告)号：US5294330A
公开(公告)日：1994-03-15
申请号：US929065
申请日：1992-08-12
申请人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Hye Kyung C. Timken
发明人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Hye Kyung C. Timken
IPC分类号： C10G47/16 , C10G47/00 , C10G47/12 , C10G47/20
CPC分类号： C10G47/16
摘要： There is provided a hydrocracking process with a catalyst comprising MCM-36.
摘要翻译：提供了含有MCM-36的催化剂的加氢裂化方法。

5. 发明授权

US5281328A Hydrocracking with ultra large pore size catalysts 失效
标题翻译：用超大孔径催化剂加氢裂化
公开(公告)号：US5281328A
公开(公告)日：1994-01-25
申请号：US734850
申请日：1991-07-24
申请人： Thomas F. Degnan, Jr. , Kathleen M. Keville , David O. Marler , Dominick N. Mazzone
发明人： Thomas F. Degnan, Jr. , Kathleen M. Keville , David O. Marler , Dominick N. Mazzone
IPC分类号： B01J29/00 , B01J29/03 , B01J29/04 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/80 , C10G47/16 , C10G47/02 , C10G47/04
CPC分类号： B01J29/40 , B01J29/005 , B01J29/04 , B01J29/70 , B01J29/80 , C10G47/16 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/0308 , B01J29/084
摘要： A hydrocracking process uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material has pores of at least 13 .ANG. diameter arranged in a uniform manner and exhibits unusually large sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams (50 torr and 25.degree. C.). A preferred form of the catalyst has a hexagonal structure which exhibits a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrocracking catalysts based on these materials are capable of producing hydrocracked products of improved quality with lower nitrogen and aromatic content.
摘要翻译：加氢裂化方法使用基于超大孔结晶材料的催化剂。结晶材料具有均匀排列的至少13（Aangstroem）直径的孔，并且通过其大于约15克苯/ 100克（50托和25摄氏度）的苯吸附能力证明其具有非常大的吸附能力。催化剂的优选形式具有六角形结构，其显示可以以大于约18的d100值（Aangstroem）为指数的六方电子衍射图。基于这些材料的加氢裂化催化剂能够生产具有较低氮和芳族含量的改进质量的加氢裂化产物。

6. 发明授权

US5183557A Hydrocracking process using ultra-large pore size catalysts 失效
标题翻译：使用超大孔径催化剂的加氢裂化工艺
公开(公告)号：US5183557A
公开(公告)日：1993-02-02
申请号：US734983
申请日：1991-07-24
申请人： Thomas F. Degnan, Jr. , Kathleen M. Keville , Michael E. Landis , David O. Marler , Dominick N. Mazzone
发明人： Thomas F. Degnan, Jr. , Kathleen M. Keville , Michael E. Landis , David O. Marler , Dominick N. Mazzone
IPC分类号： B01J29/00 , B01J29/03 , B01J29/04 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/76 , B01J29/78 , B01J29/80 , C10G47/16
CPC分类号： B01J29/041 , B01J29/005 , B01J29/04 , B01J29/044 , B01J29/045 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/76 , B01J29/78 , B01J29/80 , C10G47/16 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/0308 , B01J29/084
摘要： A hydrocracking catalyst with improved distillate selectivity comprises, in addition to a metal component, a mesoporous crystalline material together with a molecular sieve component of relatively smaller pore size. The metal component of the catalyst is preferably associated with the high-surface area mesoporous component and high-metal loadings can be achieved in order to give good hydrogenation activity to the catalyst. The relatively smaller pore size component is preferably a large pore size zeolite such as zeolite Y or an intermediate pore size zeolite such as ZSM-5; this component provides a higher level of acidic functionality than the mesoporous component, achieving a functional separation in the hydrocracking process, permitting the metals loading and acidic activities to be optimized for good catalyst selectivity and activity. The catalysts enable the distillate selectivities comparable to amorphous catalyst to be achieved with improved conversion activity.
摘要翻译：具有改进的馏出物选择性的加氢裂化催化剂除了金属组分之外还包括介孔结晶材料以及具有相对较小孔径的分子筛组分。催化剂的金属组分优选与高表面积介孔组分相关，并且可以实现高金属负载量，以便为催化剂提供良好的氢化活性。相对较小的孔径成分优选为大孔分子沸石，例如沸石Y或中等孔径沸石如ZSM-5; 该组分提供比介孔组分更高水平的酸性官能度，在加氢裂化过程中实现功能性分离，允许金属负载和酸性活性被优化以获得良好的催化剂选择性和活性。催化剂使得能够通过改进的转化活性实现与无定形催化剂相当的馏出物选择性。

7. 发明授权

US5296428A Catalyst comprising MCM-36 and a hydrogenation/dehydrogenation component 失效
标题翻译：包含MCM-36和氢化/脱氢组分的催化剂
公开(公告)号：US5296428A
公开(公告)日：1994-03-22
申请号：US929070
申请日：1992-08-12
申请人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
发明人： Thomas F. Degnan , Kathleen M. Keville , Charles T. Kresge , David O. Marler , Brenda H. Rose , Wieslaw J. Roth , Kenneth G. Simons, deceased , Hye K. C. Timken , James C. Vartuli
IPC分类号： B01J21/16 , B01J29/04 , C01B33/36 , C01B39/02 , B01J21/06
CPC分类号： B01J29/049 , C01B39/026
摘要： There is provided a catalyst comprising MCM-36 and a hydrogenation/dehydrogenation component. A particular example of such a catalyst comprises MCM-36, nickel and tungsten.
摘要翻译：提供了包含MCM-36和氢化/脱氢组分的催化剂。这种催化剂的具体实例包括MCM-36，镍和钨。

8. 发明授权

US5264116A Production of lubricants by hydrocracking and hydroisomerization 失效
标题翻译：通过加氢裂化和加氢异构化生产润滑剂
公开(公告)号：US5264116A
公开(公告)日：1993-11-23
申请号：US734999
申请日：1991-07-24
申请人： Minas R. Apelian , Thomas F. Degnan, Jr. , David O. Marler , Dominick N. Mazzone
发明人： Minas R. Apelian , Thomas F. Degnan, Jr. , David O. Marler , Dominick N. Mazzone
IPC分类号： B01J29/04 , C10G47/16 , C10G47/02 , C10G47/04 , C10G47/20
CPC分类号： C10G47/16 , B01J29/04
摘要： A process for producing high quality lubricants by the hydrocracking and hydroisomerization of petroleum waxes uses a catalyst which is based on an ultra-large pore crystalline material. The crystalline material exhibits unusually large pores of at least 13 .ANG. diameter and a high sorption capacity demonstrated by its benzene adsorption capacity of greater than about 15 grams benzene/100 grams at 50 torr and 25.degree. C. The crystalline material is characterized by an X-ray diffraction pattern with at least one d-spacing greater than about 18 .ANG. and in a particularly preferred form, a hexagonal arrangement of pores of at least 13 .ANG. diameter which can be indexed with a d.sub.100 value greater than about 18 .ANG.. The hydrocracking catalysts based on these materials are capable of producing lube products with a high VI of at least 120 and usually higher, values of 135 and higher e.g. 143. the lube products are produced in good yield from feeds which may contain down to about 30 percent wax content, although wax contents of at least 50 percent are preferred for the highest quality products. The catalysts achieve this result without the use of fluorine or other promoters.
摘要翻译：通过石油蜡的加氢裂化和加氢异构化生产高品质润滑剂的方法使用基于超大孔结晶材料的催化剂。结晶材料表现出非常大的至少13安格姆直径的孔，并且在50托和25℃下其苯吸附能力大于约15克苯/ 100克证明了高吸附能力。结晶材料的特征在于X 具有至少一个d-间距大于约18的射线衍射图案，并且在特别优选的形式中，具有至少13个ANGSTROM直径的孔的六边形排列，其可以以大于约18的d100值进行索引。基于这些材料的加氢裂化催化剂能够生产具有至少120的高VI，通常较高的值135和更高的润滑油产品，例如， 143.润滑油产品从饲料中以良好的产率生产，其可含有至多约30％的蜡含量，尽管至少50％的蜡含量对于最高质量的产品是优选的。催化剂在不使用氟或其它促进剂的情况下实现该结果。

9. 发明授权

US5358628A Production of high viscosity index lubricants 失效
标题翻译：生产高粘度指数润滑剂
公开(公告)号：US5358628A
公开(公告)日：1994-10-25
申请号：US898615
申请日：1992-06-15
申请人： Minas R. Apelian , Charles L. Baker, Jr. , Thomas F. Degnan , David O. Marler , Dominick N. Mazzone , Dennis E. Walsh
发明人： Minas R. Apelian , Charles L. Baker, Jr. , Thomas F. Degnan , David O. Marler , Dominick N. Mazzone , Dennis E. Walsh
IPC分类号： B01J29/18 , B01J29/70 , B01J29/74 , C10G45/64 , C10G49/12 , C10G65/12 , C10G69/02
CPC分类号： B01J29/7415 , B01J29/18 , B01J29/7007 , C10G65/12 , B01J2229/36 , B01J2229/37 , C10G2400/10
摘要： Petroleum wax feeds are converted to high Viscosity Index lubricants by a two-step hydrocracking-hydroisomerization process in which the wax feed is initially subjected to hydrocracking under mild conditions with a conversion to non-lube range products of no more than about 30 weight percent of the feed. The hydrocracking is carried out at a hydrogen pressure of at least 1000 psig using an amorphous catalyst which preferentially removes the aromatic components present in the initial feed. The hydrocracked effluent is then subjected to hydroisomerization in a second step using a low acidity dicarboxylic acid-treated zeolite Beta or mordenite catalyst which effects a preferential isomerization on the paraffin components to less waxy, high V.I. isoparaffins. The second stage may be operated at high pressure by cascading the first stage product into the second stage or at a lower pressure, typically from 200 to 1000 psig. The second stage catalyst is preferably a noble metal containing zeolite Beta catalyst which is treated with oxalic acid to give a low Alpha Value, typically below 10. The second stage is carried out at relatively low temperature, typically from 600.degree. to 650.degree. F. with a 650.degree. F.+ conversion in the range of 10 to 20 weight percent of the second stage feed but with high selectivity for isomerization of the paraffins. A final dewaxing step to target pour point may be used with relatively low loss, typically no more than 15 weight percent, during this dewaxing. The final products typically have V.I. values in excess of 130 and usually in the range of 140 to 155 and are characterized by exceptional stability.
摘要翻译：石油蜡进料通过两步加氢裂化加氢异构化方法转化为高粘度指数润滑剂，其中蜡进料最初在温和条件下进行加氢裂化，转化为非润滑范围产物的不超过约30重量％饲料。加氢裂化在至少1000psig的氢气压力下进行，使用优选除去初始进料中存在的芳族组分的无定形催化剂。然后使用低酸度二羧酸处理的沸石β-或丝光沸石催化剂，将加氢裂化的流出物在第二步骤中进行加氢异构化，其对石蜡组分进行优先异构化，以降低蜡，高V.I。异链烷烃第二阶段可以通过将第一阶段产品级联到第二阶段或通常为200至1000psig的较低压力下在高压下操作。第二阶段催化剂优选是含贵金属的沸石β催化剂，其用草酸处理以得到低α值，通常低于10。第二阶段在相对较低的温度下进行，通常为600至650°F。 +转化率在第二阶段进料的10至20重量％的范围内，但对于链烷烃的异构化具有高选择性。在该脱蜡过程中，目标倾点的最终脱蜡步骤可以使用相当低的损失，通常不超过15重量％。最终产品通常有V.I. 值超过130，通常在140至155的范围内，并且具有出色的稳定性。

10. 发明授权

US5290744A Hydrocracking process using ultra-large pore size catalysts 失效
标题翻译：使用超大孔径催化剂的加氢裂化工艺
公开(公告)号：US5290744A
公开(公告)日：1994-03-01
申请号：US956196
申请日：1992-10-05
申请人： Thomas F. Degnan Jr. , Kathleen M. Keville , Michael E. Landis , David O. Marler , Dominick N. Mazzone
发明人： Thomas F. Degnan Jr. , Kathleen M. Keville , Michael E. Landis , David O. Marler , Dominick N. Mazzone
IPC分类号： B01J29/00 , B01J29/03 , B01J29/04 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/76 , B01J29/78 , B01J29/80 , C10G47/16
CPC分类号： B01J29/041 , B01J29/005 , B01J29/04 , B01J29/044 , B01J29/045 , B01J29/08 , B01J29/40 , B01J29/70 , B01J29/76 , B01J29/78 , B01J29/80 , C10G47/16 , B01J2229/26 , B01J2229/36 , B01J2229/42 , B01J29/0308 , B01J29/084
摘要： A hydrocracking catalyst with improved distillate selectivity comprises, in addition to a metal component, a mesoporous crystalline material together with a molecular sieve component of relatively smaller pore size. The metal component of the catalyst is preferably associated with the high-surface area mesoporous component and high-metal loadings can be achieved in order to give good hydrogenation activity to the catalyst. The relatively smaller pore size component is preferably a large pore size zeolite such as zeolite Y or an intermediate pore size zeolite such as ZSM-5; this component provides a higher level of acidic functionality than the mesoporous component, achieving a functional separation in the hydrocracking process, permitting the metals loading and acidic activities to be optimized for good catalyst selectivity and activity. The catalysts enable the distillate selectivities comparable to amorphous catalyst to be achieved with improved conversion activity.
摘要翻译：具有改进的馏出物选择性的加氢裂化催化剂除了金属组分之外还包括介孔结晶材料以及具有相对较小孔径的分子筛组分。催化剂的金属组分优选与高表面积介孔组分相关，并且可以实现高金属负载量，以便为催化剂提供良好的氢化活性。相对较小的孔径成分优选为大孔分子沸石，例如沸石Y或中等孔径沸石如ZSM-5; 该组分提供比介孔组分更高水平的酸性官能度，在加氢裂化过程中实现功能性分离，允许金属负载和酸性活性被优化以获得良好的催化剂选择性和活性。催化剂使得能够通过改进的转化活性实现与无定形催化剂相当的馏出物选择性。

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