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    • 8. 发明授权
    • Hydrolyzable titanyl sulphate solutions by decomposition of ternary raw
material mixtures
    • 通过三元原料混合物的分解可水解的硫酸氧钛溶液
    • US4304758A
    • 1981-12-08
    • US213540
    • 1980-12-05
    • Hilmar RieckWalter GutschePeter WoditschPeter Panek
    • Hilmar RieckWalter GutschePeter WoditschPeter Panek
    • C01G23/00C22B34/12C01G23/053
    • C22B34/125C01G23/008
    • A process for the preparation of a hydrolyzable titanyl sulphate solution comprising adding sulphuric acid having a concentration greater than about 86% to a ternary mixture of two slags and an ilmenite to bring the proportion by weight of H.sub.2 SO.sub.4 to TiO.sub.2 to from about 1.7:1 to 2.2:1 and adding water, dilute sulphuric acid or oleum in amount sufficient to bring the H.sub.2 SO.sub.4 concentration to from about 86 to 96%, thereby to form the titanyl sulphate solution, the first slag having a TiO.sub.2 content greater than about 80% and a Ti(III) content of about 22 to 40%, the second slag having a TiO.sub.2 content of about 60 to 80% and a Ti(III) content of about 5 to 15%, and the ilmenite having a ratio of Fe(III) to Fe(II) of from about 1:1 to 10:1, the slags and ilmenite being present in such proportions that the ternary mixture of raw materials obtained has a molar ratio of Ti(III) to Fe(III).gtoreq.1.4.
    • 一种制备可水解硫酸氧钛溶液的方法,其包括将浓度大于约86%的硫酸添加到两种炉渣和钛铁矿的三元混合物中,以使H 2 SO 4的重量比例从约1.7:1提高到约1.7:1至 2.2:1,并加入水,稀硫酸或发烟硫酸,其量足以使H 2 SO 4浓度达到约86%至96%,从而形成硫酸氧钛溶液,第一炉渣的TiO 2含量大于约80%,并且 Ti(III)含量为约22〜40%,第二炉渣的TiO 2含量为约60〜80%,Ti(III)含量为5〜15%左右,钛铁矿的Fe(III) 对于Fe(II)为约1:1至10:1,炉渣和钛铁矿以以下比例存在:获得的原料的三元混合物具有Ti(III)与Fe(III)的摩尔比> 1.4。