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1. 发明申请

US20120184692A1 METHOD FOR PREPARING LINEAR ALPHA-OLEFINS 有权
标题翻译：制备线性脂蛋白的方法
公开(公告)号：US20120184692A1
公开(公告)日：2012-07-19
申请号：US13386618
申请日：2010-05-28
申请人： Peter M. Fritz , Heinz Bölt , Andreas Meiswinkel , Carsten Taube , Florian Winkler , Volker Göke , Wolfgang Müller , Anina Wöhl , Richard Schneider , Uwe Rosenthal , Helmut Fritz , Bernd H. Müller , Normen Peulecke , Stephan Peitz , Bhaskar Reddy Aluri , MOhammed Al-Hazmi , Shahid Majeed Azam , Fuad Mosa , Abdullah Al-Dugathier
发明人： Peter M. Fritz , Heinz Bölt , Andreas Meiswinkel , Carsten Taube , Florian Winkler , Volker Göke , Wolfgang Müller , Anina Wöhl , Richard Schneider , Uwe Rosenthal , Helmut Fritz , Bernd H. Müller , Normen Peulecke , Stephan Peitz , Bhaskar Reddy Aluri , MOhammed Al-Hazmi , Shahid Majeed Azam , Fuad Mosa , Abdullah Al-Dugathier
IPC分类号： C08F2/38
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14 , C07C11/02
摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, poly-ethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stre con the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream prior to mixing with caustic is at least 1 second preferably at least 5 seconds, more preferably at least 10 seconds.
摘要翻译：本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，包括以下步骤：（i）将乙烯，溶剂和催化剂进料到低聚反应器中（ ii）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，线性α-烯烃，任选未反应的乙烯和催化剂的反应器出口流，（iv）给予至少一种选自由醇，聚乙二醇，聚乙二醇单醚，聚乙二醇二醚，多胺，胺，氨基醇和表面活性剂组成的组，（v）将反应器出口将该添加剂转移到催化剂失活和除去部分，和（vi ）用苛性碱使催化剂失活并从反应器出口流中除去失活的催化剂，其中添加剂在反应器外部的停留时间在与苛性碱混合之前的流量为至少1秒，优选至少5秒，更优选至少10秒。

2. 发明授权

US08809613B2 Method for preparing linear alpha-olefins 有权
标题翻译：线性α-烯烃的制备方法
公开(公告)号：US08809613B2
公开(公告)日：2014-08-19
申请号：US13386618
申请日：2010-05-28
申请人： Peter M. Fritz , Heinz Bölt , Andreas Meiswinkel , Carsten Taube , Florian Winkler , Volker Göke , Wolfgang Müller , Anina Wöhl , Richard Schneider , Uwe Rosenthal , Helmut Fritz , Bernd H. Müller , Normen Peulecke , Stephan Peitz , Bhaskar Reddy Aluri , Mohammed Al-Hazmi , Shahid Majeed Azam , Fuad Mosa , Abdullah Al-Dugathier
发明人： Peter M. Fritz , Heinz Bölt , Andreas Meiswinkel , Carsten Taube , Florian Winkler , Volker Göke , Wolfgang Müller , Anina Wöhl , Richard Schneider , Uwe Rosenthal , Helmut Fritz , Bernd H. Müller , Normen Peulecke , Stephan Peitz , Bhaskar Reddy Aluri , Mohammed Al-Hazmi , Shahid Majeed Azam , Fuad Mosa , Abdullah Al-Dugathier
IPC分类号： C07C2/08
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14 , C07C11/02
摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of a solvent and homogeneous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, optionally unreacted ethylene and catalyst from the reactor via a reactor outlet piping system, (iv) dosing at least one additive selected from the group consisting of alcohols, poly-ethylene glycols, polyethylene glycol monoethers, polyethylene glycol diethers, polyamines, amines, amino alcohols and surfactants, (v) transferring the reactor outlet stream containing the additive to a catalyst deactivation and removal section, and (vi) deactivating the catalyst with caustic and removing the deactivated catalyst from the reactor outlet stream, wherein the residence time of the additive in the reactor outlet stream prior to mixing with caustic is at least 1 second preferably at least 5 seconds, more preferably at least 10 seconds.
摘要翻译：本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，包括以下步骤：（i）将乙烯，溶剂和催化剂进料到低聚反应器中（ ii）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，线性α-烯烃，任选未反应的乙烯和催化剂的反应器出口流，（iv）给予至少一种选自由醇，聚乙二醇，聚乙二醇单醚，聚乙二醇二醚，多胺，胺，氨基醇和表面活性剂组成的组，（v）将含有添加剂的反应器出口流转移到催化剂失活和除去部分，和（vi ）用苛性碱使催化剂失活并从反应器出口流中除去失活的催化剂，其中添加剂在真空中的停留时间在与苛性碱混合之前的出口流量为至少1秒，优选至少5秒，更优选至少10秒。

3. 发明授权

US09593055B2 Method for preparing linear alpha-olefins 有权
标题翻译：线性α-烯烃的制备方法
公开(公告)号：US09593055B2
公开(公告)日：2017-03-14
申请号：US12735585
申请日：2009-01-07
申请人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi , Syriac Palackal , Ayed Al-Ayed , Sultan Al-Otaibi , Mohammed Zahoor , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Florian Winkler , Uwe Rosenthal , Hans-Jörg Zander , Normen Peulecke , Bernd H. Müller , Karl-Heinz Hofmann , Helmut Fritz , Carsten Taube , Andreas Meiswinkel , Richard Schneider , Anina Woehl
发明人： Vugar Aliyev , Fuad Mosa , Mohammed Al-Hazmi , Syriac Palackal , Ayed Al-Ayed , Sultan Al-Otaibi , Mohammed Zahoor , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Florian Winkler , Uwe Rosenthal , Hans-Jörg Zander , Normen Peulecke , Bernd H. Müller , Karl-Heinz Hofmann , Helmut Fritz , Carsten Taube , Andreas Meiswinkel , Richard Schneider , Anina Woehl
IPC分类号： C07C2/02 , C07C2/04 , C07C2/08 , C07C2/30
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14
摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of solvent and homogenous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, ethylene, and catalyst from the reactor via a reactor outlet piping system, (iv) transferring the reactor outlet stream to a catalyst deactivation and removal step, and (v) deactivating and removing the catalyst from the reactor outlet stream, characterized in that at least one organic amine is added into the oligomerization reactor and/or into the reactor outlet piping system.
摘要翻译：本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，其包括以下步骤：（i）将乙烯，溶剂和催化剂加入到低聚反应器中，（ii ）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，直链α-烯烃，乙烯和催化剂的反应器出口流，（iv）将反应器出口流转移到催化剂失活和（v）从反应器出口流中去活化和除去催化剂，其特征在于将至少一种有机胺加入到低聚反应器和/或反应器出口管道系统中。

4. 发明申请

US20110046429A1 Method for preparing linear alpha-olefins 有权
标题翻译：线性α-烯烃的制备方法
公开(公告)号：US20110046429A1
公开(公告)日：2011-02-24
申请号：US12735585
申请日：2009-01-07
申请人： Vugar Aliyev , Fuda Mosa , Mohammed Al-Hazmi , Syriac Palackal , Ayed Al-ayed , Sultan Al-Otaibi , Mohammed Zahoor , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Florian Winkler , Uwe Rosenthal , Hans-Jörg Zander , Normen Peulecke , Bernd H. Müller , Karl-Heinz Hofmann , Helmut Fritz , Carsten Taube , Andreas Meiswinkel , Richard Schneider , Anina Woehl
发明人： Vugar Aliyev , Fuda Mosa , Mohammed Al-Hazmi , Syriac Palackal , Ayed Al-ayed , Sultan Al-Otaibi , Mohammed Zahoor , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Florian Winkler , Uwe Rosenthal , Hans-Jörg Zander , Normen Peulecke , Bernd H. Müller , Karl-Heinz Hofmann , Helmut Fritz , Carsten Taube , Andreas Meiswinkel , Richard Schneider , Anina Woehl
IPC分类号： C07C2/02
CPC分类号： C07C2/30 , C07C2531/025 , C07C2531/04 , C07C2531/14
摘要： The present invention relates to a method for preparing linear alpha-olefins (LAO) by oligomerization of ethylene in the presence of solvent and homogenous catalyst, comprising the steps of: (i) feeding ethylene, solvent and catalyst into an oligomerization reactor, (ii) oligomerizing the ethylene in the reactor, (iii) removing a reactor outlet stream comprising solvent, linear alpha-olefins, ethylene, and catalyst from the reactor via a reactor outlet piping system, (iv) transferring the reactor outlet stream to a catalyst deactivation and removal step, and (v) deactivating and removing the catalyst from the reactor outlet stream, characterized in that at least one organic amine is added into the oligomerization reactor and/or into the reactor outlet piping system.
摘要翻译：本发明涉及通过在溶剂和均相催化剂存在下使乙烯低聚制备线性α-烯烃（LAO）的方法，其包括以下步骤：（i）将乙烯，溶剂和催化剂加入到低聚反应器中，（ii ）使反应器中的乙烯低聚，（iii）通过反应器出口管道系统从反应器中除去包含溶剂，直链α-烯烃，乙烯和催化剂的反应器出口流，（iv）将反应器出口流转移到催化剂失活和（v）从反应器出口流中去活化和除去催化剂，其特征在于将至少一种有机胺加入到低聚反应器和/或反应器出口管道系统中。

5. 发明申请

US20110054233A1 METHOD FOR OLIGOMERIZATION OF ETHYLENE AND REACTOR SYSTEM THEREFOR 审中-公开
标题翻译：乙烯和其反应器体系低级化的方法
公开(公告)号：US20110054233A1
公开(公告)日：2011-03-03
申请号：US12735267
申请日：2008-12-18
申请人： Fuad Mousa , Mohammed Al-Hazmi , Abdullah Al-Thauyyan , Mohammed Al-Musned , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Andreas Meiswinkel , Carsten Taube , Richard Schneider , Florian Winkler , Helmut Fritz , Karl-Heinz Hofmann , Hans-Jörg Zander , Peter Ulbrich , Jan Segatz
发明人： Fuad Mousa , Mohammed Al-Hazmi , Abdullah Al-Thauyyan , Mohammed Al-Musned , Wolfgang Müller , Peter M. Fritz , Heinz Bölt , Anton Wellenhofer , Andreas Meiswinkel , Carsten Taube , Richard Schneider , Florian Winkler , Helmut Fritz , Karl-Heinz Hofmann , Hans-Jörg Zander , Peter Ulbrich , Jan Segatz
IPC分类号： C07C2/08 , B01J19/00
CPC分类号： B01J19/18 , B01J19/1806 , C07C2/22 , C07C11/04 , C07C2521/06 , C07C2531/14 , Y02P20/52
摘要： The present invention relates to a method and a reactor system, for the oligomerization of ethylene, comprising oligomerizing ethylene in a reactor in the presence of a solvent and a catalyst composition to produce a liquid product stream comprising linear alpha-olefins, solvent and catalyst composition, and deactivating and extracting the catalyst composition in said liquid product stream by mixing it with a polar phase in a dynamic mixing device having rotor and stator elements comprising concentric tool rings.
摘要翻译：本发明涉及用于乙烯低聚的方法和反应器系统，其包括在溶剂和催化剂组合物存在下在反应器中使乙烯低聚以产生包含线性α-烯烃，溶剂和催化剂组合物的液体产物流并且通过在具有包括同心工具环的转子和定子元件的动态混合装置中将其与极性相混合来使所述液体产物流中的催化剂组合物失活和萃取。

6. 发明申请

US20160130204A1 PROCESS AND PLANT FOR PREPARATION OF ONE OR MORE REACTION PRODUCTS 有权
标题翻译：制备一种或多种反应产物的方法和设备
公开(公告)号：US20160130204A1
公开(公告)日：2016-05-12
申请号：US14933535
申请日：2015-11-05
申请人： Andreas Peschel , Helmut Fritz , Thomas Bartesch , Johannes Fendt
发明人： Andreas Peschel , Helmut Fritz , Thomas Bartesch , Johannes Fendt
IPC分类号： C07C41/01 , C01B3/36
CPC分类号： C07C41/01 , C01B3/36 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/06 , C01B2203/1241 , C01B2203/141 , C01B2203/148 , C07C41/09 , Y02P20/129 , C07C43/043
摘要： A process for preparing one or more reaction products, in which a first methane-rich feed stream is subjected to a partial oxidation process and/or an autothermal reforming process and a second methane-rich feed stream is subjected to a steam reforming process, in which a first synthesis gas-containing output stream is formed from the first methane-rich feed stream and a second synthesis gas-containing output stream is formed from the second methane-rich feed stream and these synthesis gas streams are used to form a collective synthesis gas stream and fluid from the collective synthesis gas stream is subjected to a molecular weight-increasing reaction in a synthesis feed stream to obtain a synthesis output stream comprising carbon dioxide and the reaction product(s). At least one carbon dioxide-rich first recycle stream is formed from fluid from the synthesis output stream and fluid from the first recycle stream is subjected to the steam reforming process.
摘要翻译：制备一种或多种反应产物的方法，其中使第一富甲烷进料流经受部分氧化过程和/或自热重整过程和第二富甲烷进料流进行蒸汽重整过程，其由第一富含甲烷的进料流形成第一合成气体输出流，并且由第二富甲烷进料流形成第二合成气输出流，并且使用这些合成气流形成集合合成将气流和来自集体合成气流的流体在合成进料流中进行分子量增加反应，以获得包含二氧化碳和反应产物的合成输出流。来自合成输出流的流体形成至少一种富含二氧化碳的第一再循环流，并且来自第一再循环流的流经受蒸汽重整过程。

7. 发明申请

US20080041764A1 METHOD AND APPARATUS FOR STEAM DEALKYLATION IN A PLANT FOR THE CATALYTIC SPLITTING OF HYDROCARBONS 审中-公开
标题翻译：用于烃类催化分解的植物中蒸汽处理的方法和装置
公开(公告)号：US20080041764A1
公开(公告)日：2008-02-21
申请号：US11840892
申请日：2007-08-17
申请人： Helmut Fritz , Volker Goeke
发明人： Helmut Fritz , Volker Goeke
IPC分类号： C10G45/08
CPC分类号： C07C4/20 , B01J23/44 , B01J23/464 , C07C2521/04 , C07C2521/10 , C07C2523/26 , C07C2523/44 , C07C2523/46 , C10G2400/26 , C10G2400/30 , Y02P20/52 , C07C15/04
摘要： A method and apparatus for treating a fraction consisting predominantly of hydrocarbons having at least seven carbon atoms (C7+ fraction) as produced in a plant for the catalytic splitting of hydrocarbon-containing feedstock, is disclosed. Following hydration, the C7+ fraction is taken to steam dealkylation where the usable products benzene and hydrogen are produced.
摘要翻译：公开了一种用于处理主要由具有至少七个碳原子的烃（C 7+分馏分）组成的级分的方法和装置，其在用于烃类原料的催化裂解的设备中产生。水合后，将C 7+ H 2 O分馏得到蒸馏脱烷基，其中制得苯和氢。

8. 发明申请

US20060136841A1 Entry of data in a data processing system 有权
标题翻译：在数据处理系统中输入数据
公开(公告)号：US20060136841A1
公开(公告)日：2006-06-22
申请号：US11304963
申请日：2005-12-15
申请人： Helmut Fritz
发明人： Helmut Fritz
IPC分类号： G06F17/00
CPC分类号： G06F3/0485 , G06F3/0481
摘要： A method and a system for entering data (12-15) in a data processing system is provided. In this case, the data is entered in a number of steps, with a view being displayed at a step in a display region of a display means, with the entering and/or display taking place in subsequent steps at least partially as a function of the data entered in one or a number of preceding steps. To design the step-by-step entering of data in a more user friendly manner, it is proposed to simultaneously display the views of a number of consecutive steps in the display region.
摘要翻译：提供了一种用于在数据处理系统中输入数据（12-15）的方法和系统。在这种情况下，以多个步骤输入数据，其中显示在显示装置的显示区域中的步骤，其中进入和/或显示在后续步骤中至少部分地作为在一个或多个前面的步骤中输入的数据。为了以更友好的方式设计数据的逐步输入，建议同时在显示区域中显示多个连续步骤的视图。

9. 发明授权

US07055105B2 Drop-enabled tabbed dialogs 有权
公开(公告)号：US07055105B2
公开(公告)日：2006-05-30
申请号：US10035478
申请日：2001-10-25
申请人： Helmut Windl , Helmut Fritz , Larry Constantine
发明人： Helmut Windl , Helmut Fritz , Larry Constantine
IPC分类号： G09G5/00
CPC分类号： G06F3/0486 , G06F3/0483 , Y10S715/964 , Y10S715/965 , Y10S715/966
摘要： The mouse cursor is moved over the register of a register dialog once a drop-and-drag action has been initiated, then the register under the mouse cursor is automatically moved to the foreground after a variable time interval, and the contents can thus be seen. Process of making the item visible is initiated just by locating the mouse over the register of the concealed registered dialog. The invention can be extended to normal mouse movements (that is to say that other than drag drop.) Dropping an object on to a drop destination in a concealed register of a register dialog for drag and drop actions and drag and drop between the registers of a tabbed dialog or the pages of a workbook (such as the various tables in Excel, for example.)

10. 发明授权

US09718751B2 Process and plant for preparation of one or more reaction products 有权
公开(公告)号：US09718751B2
公开(公告)日：2017-08-01
申请号：US14933535
申请日：2015-11-05
申请人： Andreas Peschel , Helmut Fritz , Thomas Bartesch , Johannes Fendt
发明人： Andreas Peschel , Helmut Fritz , Thomas Bartesch , Johannes Fendt
IPC分类号： C07C41/01 , C07C41/09 , C01B3/36 , C07C43/04
CPC分类号： C07C41/01 , C01B3/36 , C01B2203/0233 , C01B2203/0244 , C01B2203/025 , C01B2203/06 , C01B2203/1241 , C01B2203/141 , C01B2203/148 , C07C41/09 , Y02P20/129 , C07C43/043
摘要： A process for preparing one or more reaction products, in which a first methane-rich feed stream is subjected to a partial oxidation process and/or an autothermal reforming process and a second methane-rich feed stream is subjected to a steam reforming process, in which a first synthesis gas-containing output stream is formed from the first methane-rich feed stream and a second synthesis gas-containing output stream is formed from the second methane-rich feed stream and these synthesis gas streams are used to form a collective synthesis gas stream and fluid from the collective synthesis gas stream is subjected to a molecular weight-increasing reaction in a synthesis feed stream to obtain a synthesis output stream comprising carbon dioxide and the reaction product(s). At least one carbon dioxide-rich first recycle stream is formed from fluid from the synthesis output stream and fluid from the first recycle stream is subjected to the steam reforming process.

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