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1. 发明授权

US5372875A Aqueous two-component polyurethane-forming compositions and a process for their preparation 失效
标题翻译：水性双组分聚氨酯形成组合物及其制备方法
公开(公告)号：US5372875A
公开(公告)日：1994-12-13
申请号：US14304
申请日：1993-02-05
申请人： Peter H. Markusch , Robin E. Tirpak , James W. Rosthauser
发明人： Peter H. Markusch , Robin E. Tirpak , James W. Rosthauser
IPC分类号： C08K7/14 , B32B27/40 , C08K3/20
CPC分类号： C08K7/14 , Y10T428/31551 , Y10T428/31601 , Y10T442/2992
摘要： The present invention is directed to a process for the preparation of an aqueous two-component polyurethane-forming composition bya) dispersing in water a polyisocyanate which has an isocyanate content of at least 12% by weight andb) also blending with water either before, during or after dispersing the polyisocyanate, a polyhydroxyl compound whichi) has a molecular weight of 62 to 10,000,ii) contains at least two hydroxyl groups,iii) is water soluble or water dispersible,iv) does not contain urea or urethane groups andv) is selected from the group of polyesters, polylactones, polycarbonates, polyethers, polythioethers, polyacetals, polyether esters, polyester amides and polyamides,wherein the equivalent ratio of isocyanate groups to aqueous groups is 0.8:1 to 6:1.The present invention is also directed to the aqueous composition prepared by this process and to its use as a binder for fiberglass.
摘要翻译：本发明涉及一种制备水性双组分聚氨酯形成组合物的方法，该方法是：a）在水中分散异氰酸酯含量为至少12重量％的多异氰酸酯，和b）还可以在水之前与水混合在分散多异氰酸酯之间或之后，分子量为62至10,000的多羟基化合物，ii）至少包含两个羟基，iii）是水溶性的或水分散的，iv）不含脲或氨基甲酸酯基团和v）选自聚酯，聚内酯，聚碳酸酯，聚醚，聚硫醚，聚缩醛，聚醚酯，聚酯酰胺和聚酰胺，其中异氰酸酯基与水基的当量比为0.8:1至6:1。本发明还涉及通过该方法制备的水性组合物及其作为玻璃纤维的粘合剂的用途。

2. 发明授权

US4701480A Stable, aqueous dispersions of polyurethane-ureas 失效
标题翻译：稳定的聚氨酯 - 脲类水性分散体
公开(公告)号：US4701480A
公开(公告)日：1987-10-20
申请号：US778836
申请日：1985-09-23
申请人： Peter H. Markusch , James W. Rosthauser , Robin E. Tirpak
发明人： Peter H. Markusch , James W. Rosthauser , Robin E. Tirpak
IPC分类号： C08G18/08 , C08G18/50 , C08G18/78 , C08J3/02 , C08L75/04
CPC分类号： C08G18/0819 , C08G18/5042 , C08G18/7818
摘要： The present invention is directed to a process for the preparation of aqueous polyurethane-urea dispersions with improved hydrolytic stability by(a) forming an aqueous polyurethane-urea dispersion, optionally by chain extending an aqueously dispersed isocyanate-terminated prepolymer, containing carboxylic acid groups neutralized with volatile organic bases,(b) converting the volatile, organic base-neutralized carboxylic acid groups to nonvolatile cation-neutralized carboxylate groups by adding alkali metal salts of organic or inorganic acids having a pKa greater than 0 to the aqueous polyurethane-urea dispersion of (a) in an amount sufficient to displace at least a portion of the volatile organic bases and, optionally,(c) removing the volatile organic bases by distillation, optionally under reduced pressure.The present invention is also directed to the products produced by this process.
摘要翻译：本发明涉及一种制备具有改善的水解稳定性的水性聚氨酯 - 尿素分散体的方法，该方法通过（a）形成水性聚氨酯 - 尿素分散体，任选地通过链延伸含有中和的羧酸基团的异氰酸酯封端预聚物挥发性有机碱，（b）通过将pKa大于0的有机或无机酸的碱金属盐加入到水性聚氨酯 - 尿素分散体中，将挥发性有机碱中和的羧酸基团转化成非挥发性阳离子中和的羧酸酯基团（a）的量足以使至少一部分挥发性有机碱取代，和任选地（c）任选地在减压下通过蒸馏除去挥发性有机碱。本发明还涉及通过该方法生产的产品。

3. 发明授权

US5358997A Reactive aqueous polyurea dispersions prepared by an emulsion polymerization process 失效
标题翻译：通过乳液聚合方法制备的反应性聚脲分散体
公开(公告)号：US5358997A
公开(公告)日：1994-10-25
申请号：US879828
申请日：1992-05-07
申请人： James W. Rosthauser , Robin E. Tirpak
发明人： James W. Rosthauser , Robin E. Tirpak
IPC分类号： C08G18/08 , C08G18/50 , C08G18/66 , C08G18/70 , C08J3/20 , C08K3/20 , C08L75/00
CPC分类号： C08G18/706 , C08G18/0819 , C08G18/0866 , C08G18/5024 , C08G18/6688
摘要： The present invention is directed to a process for the preparation of an aqueous polyurea dispersion containing blocked isocyanate groups and unreacted isocyanate-reactive groups by(I) dispersing in watera) a polyisocyanateb) a monofunctional blocking agent which is more reactive with isocyanate groups than water andc) an amine componentII) reacting the polyisocyanate with components b) and c) to form an aqueous polyurea dispersion.
摘要翻译：本发明涉及通过（I）分散在水中制备含有封端异氰酸酯基团和未反应异氰酸酯反应性基团的聚脲分散体水溶液的方法a）多异氰酸酯b）与异氰酸酯基团更具反应性的单官能封端剂并且c）胺组分II）使多异氰酸酯与组分b）和c）反应以形成聚脲分散体水溶液。

4. 发明授权

US5367017A Aqueous polyurea dispersions prepared by an emulsion polymerization process 失效
标题翻译：通过乳液聚合方法制备的水性聚脲分散体
公开(公告)号：US5367017A
公开(公告)日：1994-11-22
申请号：US877686
申请日：1992-05-01
申请人： James W. Rosthauser , Robin E. Tirpak
发明人： James W. Rosthauser , Robin E. Tirpak
IPC分类号： C08G18/08 , C08G18/50 , C08G18/66 , C08G18/70 , C08G18/80 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/6685 , C08G18/0819 , C08G18/5024 , C08G18/706 , C08G18/8064
摘要： The present invention is directed to a aqueous polyurea dispersion for the preparation of an aqueous polyurea dispersion byI) dispersing in water at an NCO:NH equivalent ratio of 0.5:1.0 to 2.0:1.0a) a polyisocyanate which has an average functionality of 1.5 to 4.0 and an isocyanate content of at least 12% by weight andb) a polyamine component containingi) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups and a molecular weight of at least 1000 andii) 30 to 70 mole percent of a polyamine having at least two primary and/or secondary amino groups, a molecular weight of less than 400 and at least one anionic or potential anionic group andII) allowing the polyisocyanate and polyamine component to react to form an aqueous polyurea dispersion.The present invention is also directed to the aqueous polyurea dispersion prepared by this aqueous polyurea dispersion.
摘要翻译：本发明涉及一种用于制备聚脲水分散体的水性聚脲分散体，其通过I）以0.5: 1.0至2.0:1.0的NCO:NH当量比分散在水中，a）多异氰酸酯的平均官能度为1.5 至4.0，异氰酸酯含量为至少12重量％，b）多胺组分，其含有i）30至70摩尔％的具有至少两个伯和/或仲氨基并且分子量至少为1000的多胺;以及 ii）30-70摩尔％的具有至少两个伯和/或仲氨基，分子量小于400和至少一个阴离子或潜在阴离子基团的多胺，和II）允许多异氰酸酯和多胺组分与形成聚脲水分散体。本发明还涉及由该聚脲分散体水溶液制备的聚脲水溶液。

5. 发明授权

US5296160A Aqueous dispersions of blocked polyisocyanates 失效
标题翻译：封端多异氰酸酯的水分散体
公开(公告)号：US5296160A
公开(公告)日：1994-03-22
申请号：US734708
申请日：1991-07-23
申请人： Robin E. Tirpak , James W. Rosthauser
发明人： Robin E. Tirpak , James W. Rosthauser
IPC分类号： C07C263/18 , C07C265/14 , C08G18/08 , C08G18/70 , C08G18/79 , C08G18/80 , C08L75/00 , C08L75/04 , C09K3/00
CPC分类号： C08G18/792 , C07C263/18 , C08G18/0866 , C08G18/283 , C08G18/706 , C08G18/8061 , C08G18/8077
摘要： The present invention is directed to a process for the preparation of an aqueous dispersion of a blocked polyisocyanate by reacting an aqueously dispersed polyisocyanate having an isocyanate content of at least 12% by weight, based on the weight of the polyisocyanate, with a monofunctional blocking agent which is more reactive with isocyanate groups than water at an equivalent ratio of monofunctional blocking groups to isocyanate groups of 0.5:1 to 2:1. The present invention is also directed to the aqueously dispersed blocked polyisocyanates prepared by this process and to compositions containing these polyisocyanates and an isocyanate-reactive compound.
摘要翻译：本发明涉及一种制备封端多异氰酸酯的水性分散体的方法，该方法是使具有异氰酸酯含量至多12重量％（以多异氰酸酯的重量计）的异氰酸酯含量与单官能封端剂其与异氰酸酯基团的反应性高于水，其中单官能封端基团与异氰酸酯基团的当量比为0.5:1至2:1。本发明还涉及通过该方法制备的高分散的封闭多异氰酸酯和含有这些多异氰酸酯和异氰酸酯反应性化合物的组合物。

6. 发明授权

US5300556A Process for the preparation of aqueous dispersions containing both blocked polyisocyanates and polyhydroxyl compounds 失效
标题翻译：制备含有封端多异氰酸酯和多羟基化合物的水性分散体的方法
公开(公告)号：US5300556A
公开(公告)日：1994-04-05
申请号：US977330
申请日：1992-11-17
申请人： Robin E. Tirpak , James W. Rosthauser
发明人： Robin E. Tirpak , James W. Rosthauser
IPC分类号： C08G18/08 , C08G18/70 , C08G18/80 , C08J3/00 , C08G18/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/807 , C08G18/0804 , C08G18/0866 , C08G18/706 , C08G18/8058 , C08G18/8064 , C08G18/8083
摘要： The present invention is directed to a process for the preparation of an aqueous dispersion containing both a blocked polyisocyanate and a polyhydroxyl compound by reacting an aqueously dispersed polyisocyanate having an isocyanate content of at least 12% by weight, based on the weight of the polyisocyanate, with a monofunctional blocking agent which is more reactive with isocyanate groups than water at an equivalent ratio of monofunctional blocking groups to isocyanate groups of 0.5:1 to 2:1 in the presence of a polyhydroxyl compound which is either water soluble or water dispersible, wherein the polyhydroxyl compound is present in an amount which is sufficient to provide an equivalent ratio of hydroxyl groups to blocked isocyanate groups of 0.6:1 to 1.25:1.
摘要翻译：本发明涉及一种制备含有封端多异氰酸酯和多羟基化合物的水性分散体的方法，该方法是使异氰酸酯含量至少为12重量％，基于多异氰酸酯的重量计，与在水溶性或水分散性的多羟基化合物存在下，以0.5:1至2:1的单官能封端基团与异氰酸酯基团的当量比例比异氰酸酯基团更具反应性的单官能封端剂，其中多羟基化合物的存在量足以使羟基与封端异氰酸酯基的当量比为0.6:1-1.25:1。

7. 发明授权

US5157074A Aqueous compositions containing an at least partially blocked polyisocyanates and a trimerization catalyst and coatings and binders prepared therefrom 失效
标题翻译：含有至少部分封闭的多异氰酸酯和三聚催化剂的水性组合物和由其制备的涂料和粘合剂
公开(公告)号：US5157074A
公开(公告)日：1992-10-20
申请号：US734384
申请日：1991-07-23
申请人： Sidney H. Metzger , Robin E. Tirpak , James W. Rosthauser
发明人： Sidney H. Metzger , Robin E. Tirpak , James W. Rosthauser
IPC分类号： C03C25/26 , C03C25/32 , C08G18/08 , C08G18/09 , C08G18/28 , C08G18/30 , C08G18/70 , C08G18/80
CPC分类号： C08G18/703 , C03C25/26 , C03C25/326 , C08G18/0804 , C08G18/092 , C08G18/283 , C08G18/302 , C08G18/8077
摘要： The present invention relates to an aqueous composition containinga) an at least partially blocked, aqueously dispersed polyisocyanatei) having an isocyanate content prior to blocking of at least 12% by weight, based on the weight of the unblocked polyisocyanate andii) containing at least 2 equivalent percent, based on the total equivalents of isocyanate groups, of blocked isocyanate groups, andb) a trimerization catalyst.The present invention also relates to coatings or binders prepared by heating the aqueous compositions to evaporate water and initiate trimerization.
摘要翻译：本发明涉及一种水性组合物，其含有a）至少部分封闭的，高度分散的多异氰酸酯i），其在基于未封端的多异氰酸酯的重量之前具有至少12重量％的阻塞之前的异氰酸酯含量，和ii）含有至少2当量％，基于异氰酸酯基团的总当量的封端异氰酸酯基团，和b）三聚催化剂。本发明还涉及通过加热水性组合物以蒸发水并开始三聚而制备的涂料或粘合剂。

8. 发明授权

US6165550A Symmetrical Polyurea-urethane fertilizer encapsulation 失效
标题翻译：对称聚脲 - 氨酯肥料包封
公开(公告)号：US6165550A
公开(公告)日：2000-12-26
申请号：US121482
申请日：1998-07-23
申请人： Peter H. Markusch , James W. Rosthauser
发明人： Peter H. Markusch , James W. Rosthauser
IPC分类号： C05G3/00 , C08G18/32 , C08G18/76 , C08G18/80 , B05D7/00
CPC分类号： C05G3/0029 , C08G18/3275 , C08G18/7664 , C08G18/8019 , C08G2310/00
摘要： This invention relates to processes for the production of symmetrical polyurea-urethane coated granular fertilizer products, and to the symmetrical polyurea-urethane coated granular fertilizer products produced by these processes. These processes comprise coating fertilizer granules with compounds which react to form urethane coatings which contain terminal isocyanate groups, followed by polymerization of these urethanes to form symmetrical polyurea-urethanes. Suitable compounds comprise a) an organic polyisocyanate component, and b) an alkanolamine component containing at least one tertiary amine group and at least one hydroxyl group. These compounds are present in sufficient quantities that the molar ratio of isocyanate groups to isocyanate-reactive groups is from about 1.6:1.0 up to about 10.0:1.0 in each encapsulating layer. It is necessary that sufficient amounts of these compounds are applied to the fertilizer granules such that the symmetrical polyurea-urethane coated granular fertilizer particles contain from about 0.5 to about 15% by weight of polyurea-urethane, based on the total weight of the encapsulated fertilizer particles.
摘要翻译：本发明涉及用于生产对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品的方法以及由这些方法生产的对称聚脲 - 氨基甲酸酯涂覆的颗粒肥料产品。这些方法包括用化合物涂覆化合物颗粒，所述化合物反应形成含有末端异氰酸酯基团的氨基甲酸酯涂料，随后聚合这些聚氨酯以形成对称的聚脲 - 氨基甲酸酯。合适的化合物包括a）有机多异氰酸酯组分，和b）含有至少一个叔胺基团和至少一个羟基的链烷醇胺组分。这些化合物以足够的量存在，每个包封层中异氰酸酯基与异氰酸酯反应性基团的摩尔比为约1.6:1.0至约10.0:1.0。需要将足够量的这些化合物施加到肥料颗粒上，使得对称的聚脲 - 氨基甲酸酯涂覆的颗粒肥料颗粒含有约0.5至约15重量％的聚脲 - 氨基甲酸酯，基于包封的肥料的总重量粒子。

9. 发明授权

US6022444A Modified PMDI for faster press times or lower press temperatures and reduction of MDI from hot presses 失效
标题翻译：改进的PMDI可以更快的压制时间或降低印刷温度，并减少热压机的MDI
公开(公告)号：US6022444A
公开(公告)日：2000-02-08
申请号：US225036
申请日：1994-04-08
申请人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
发明人： Karl W. Haider , John W. Frink , Heber D. Layton , Peter H. Markusch , James W. Rosthauser , Bonnie L. Lawson , Michael A. Joseph
IPC分类号： C08G18/10 , C08G18/76 , C08G18/80 , C08L97/02 , C09J175/04 , C07C271/28 , C08G18/50 , C09J175/08
CPC分类号： C08G18/8019 , C08G18/10 , C08G18/7664 , C08L97/02 , Y10S528/905
摘要： Isocyanate prepolymers which are useful as binders are made from a polyisocyanate mixture and a hydroxyl compound having at least about 1 hydroxyl group. The polyisocyanate mixture is made up of from about 50 to about 60% by weight of polyphenyl polymethylene polyisocyanate and from about 40 to about 50% by weight of an isomeric mixture of diphenylmethane diisocyanate (MDI). The isomeric mixture of MDI is made up of from about 4 to about 30% by weight of the 2,4'-isomer and from about 70 to about 96% by weight of the 4,4'-isomer. The binders of the present invention are advantageous in that they may be used in high moisture, low temperature conditions without a catalyst. Reduced MDI emissions are also achieved when the binders of the present invention are used to make composite materials.
摘要翻译：可用作粘合剂的异氰酸酯预聚物由多异氰酸酯混合物和具有至少约1个羟基的羟基化合物制成。多异氰酸酯混合物由约50至约60重量％的聚苯基多亚甲基多异氰酸酯和约40至约50重量％的二苯基甲烷二异氰酸酯（MDI）的异构体混合物组成。 MDI的异构体混合物由约4至约30重量％的2,4'-异构体和约70至约96重量％的4,4'-异构体组成。本发明的粘合剂的优点在于它们可以在没有催化剂的情况下在高水分，低温条件下使用。当本发明的粘合剂用于制造复合材料时，也可实现减少的MDI排放。

10. 发明授权

US5154950A Rapid curing, light stable, two-component polyurethane coating compositions 失效
标题翻译：快速固化，光稳定，双组分聚氨酯涂料组合物
公开(公告)号：US5154950A
公开(公告)日：1992-10-13
申请号：US447331
申请日：1989-12-07
申请人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
发明人： James W. Rosthauser , Edward P. Squiller , Peter H. Markusch
IPC分类号： C08G18/08 , C08G18/18
CPC分类号： C08G18/089 , C08G18/1891 , C08G2150/50
摘要： The present invention is directed to a process for the preparation of a polyurethane coating by a) preparing a coating composition having an improved potlife fromi) a compound containing at least two hydroxyl groups,ii) a polyisocyanate containing aliphatically-, cycloaliphatically- or araliphatically-bound isocyanate groups,iii) about 0.005 to 2.0 to weight percent, based on the weight of components i) and ii), of a tine catalyst andiv) at least about 50 mole percent, based on the tin catalyst, of hydrogen chloride,b) applying the coating composition to a substrate andc) curing the coating composition, optionally in the presence of an amine vapor, to form the polyurethane coating.
摘要翻译：本发明涉及一种制备聚氨酯涂层的方法，该方法是：a）制备具有改善的适用期的涂料组合物，其含有i）含有至少两个羟基的化合物，ii）含有脂族，脂环或芳烃的多异氰酸酯异氰酸酯基团，iii）基于催化剂组分i）和ii）的重量，约0.005至2.0重量％，和iv）基于锡催化剂的至少约50摩尔％的氯化氢 b）将涂料组合物施用到基材上，以及c）任选地在胺蒸气的存在下固化涂料组合物以形成聚氨酯涂层。

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