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    • 5. 发明申请
    • Drying Process for Linear Alpha Olefins
    • 线性α-烯烃的干燥过程
    • US20100217058A1
    • 2010-08-26
    • US11990163
    • 2006-06-13
    • Peter FritzHeinz BöltFuad MosaTalal Ali
    • Peter FritzHeinz BöltFuad MosaTalal Ali
    • C07C2/08
    • C07C11/02C07C2/08C07C7/005
    • The present invention relates to a method for preparing linear alpha-olefins by oligomerisation of ethylene, comprising the steps of: (i) oligomerising ethylene in a reactor in the presence of a solvent and a catalyst; (ii) transferring a liquid organic outlet stream of the reactor, containing solvent, catalyst, dissolved ethylene and linear alpha-olefins, to a catalyst deactivation section; (iii) deactivating the catalyst by washing the outlet stream with an aqueous basic phase to obtain a deactivated catalyst containing aqueous phase and a water saturated organic phase; (iv) separating the aqueous phase and the organic phase from step (iii); (v) transferring the water saturated organic phase to a distillation column; (vi) distilling the water saturated organic phase; and (vii) separating the distilled organic and aqueous phases.
    • 本发明涉及通过乙烯低聚制备线性α-烯烃的方法,包括以下步骤:(i)在溶剂和催化剂存在下,在反应器中使乙烯低聚; (ii)将含有溶剂,催化剂,溶解的乙烯和线性α-烯烃的反应器的液体有机出口流转移到催化剂失活部分; (iii)通过用碱性水相洗涤出口流来使催化剂失活以获得含有水相和水饱和有机相的失活催化剂; (iv)从步骤(iii)中分离水相和有机相; (v)将水饱和有机相转移至蒸馏塔; (vi)蒸馏水饱和有机相; 和(vii)分离蒸馏的有机相和水相。