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1. 发明授权

US4107149A Poly(ethylene/alkylene) terephthalates which crystallize rapidly 失效
公开(公告)号：US4107149A
公开(公告)日：1978-08-15
申请号：US658817
申请日：1976-02-17
申请人： Peter Bier , Rudolph Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolph Binsack , Hugo Vernaleken
IPC分类号： C08L67/00 , C08G63/00 , C08G63/181 , C08G63/183 , C08G63/16
CPC分类号： C08G63/183
摘要： Terephthalic copolyesters, the diol component of which mainly consists of ethylene glycol units, crystallize more rapidly than pure polyethylene terephthalate and can be moulded in a way comparable to polybutylene terephthalate.

2. 发明授权

US3960815A Branched aromatic polyaryl-ether sulphones 失效
标题翻译：支链芳香聚醚醚砜
公开(公告)号：US3960815A
公开(公告)日：1976-06-01
申请号：US437643
申请日：1974-01-29
申请人： Gerhard Darsow , Paul Schiller , Eckart Reese , Ludwig Bottenbruch , Rudolph Binsack , Hugo Vernaleken , Joachim Wank
发明人： Gerhard Darsow , Paul Schiller , Eckart Reese , Ludwig Bottenbruch , Rudolph Binsack , Hugo Vernaleken , Joachim Wank
IPC分类号： C08G75/20 , C08G75/23
CPC分类号： C08G75/23 , C08G75/20
摘要： A branched, high molecular-weight polyaryl-ether sulphone which is the reaction product of approximately equimolar amounts of an aromatic dialkali metal bishydroxylate and a bis-(halogen-aryl) compound, whose aryl nuclei are linked by sulphonyl groups, and about 0.01 to about 2 mol %, based on the bishydroxylate or bis-(4-halogenaryl) compound, of an aromatic compound having at least three aromatically linked alkali metal hydroxylate substitutents and/or of a halogenaryl compound having at least three aryl-linked halogen substituents and which is capable of substitution under the reaction conditions of polyaryl-ether sulphone manufacture.
摘要翻译：作为大约等摩尔量的芳族二碱金属双羟基苯甲酸酯和双（卤素 - 芳基）化合物的反应产物的支链高分子量聚芳基醚砜，其芳基核子通过磺酰基连接，并且约0.01至基于二氯化物或双 - （4-卤代芳基）化合物的具有至少三个芳族化合物的碱金属羟基化物取代基的芳族化合物和/或具有至少三个芳基连接的卤素取代基的卤素芳基化合物的约2摩尔％其能够在聚芳基醚砜制造的反应条件下进行取代。

3. 发明授权

US4140730A Polycarbonate film 失效
标题翻译：聚碳酸酯膜
公开(公告)号：US4140730A
公开(公告)日：1979-02-20
申请号：US918996
申请日：1978-06-26
申请人： Rudolph Binsack , Manfred Grundmeier , Eckart Reese , Hugo Vernaleken
发明人： Rudolph Binsack , Manfred Grundmeier , Eckart Reese , Hugo Vernaleken
IPC分类号： C08L69/00 , C08L67/00
CPC分类号： C08L69/00
摘要： A polycarbonate film having improved flame resistance and good stress-corrosion-cracking resistance is prepared from a solution of a mixture of a low molecular weight polycarbonate containing at least about 5% by weight halogen and a higher molecular weight polycarbonate prepared from bisphenol containing at least 90 mol percent bisphenol A. The novel film can be used to advantage for self-supporting electrical insulating films.
摘要翻译：由具有至少约5重量％卤素的低分子量聚碳酸酯和由双酚至少包含的较高分子量聚碳酸酯的混合物的混合物的溶液制备具有改善的阻燃性和良好的耐应力腐蚀开裂性的聚碳酸酯薄膜双酚A为90摩尔％。新型薄膜可用于自支撑电绝缘薄膜。

4. 发明授权

US4136089A Molded articles of crystalline poly (ethylene/alkylene) terephthalates which crystallize rapidly 失效
标题翻译：晶体结晶（乙烯/亚苄基）三苯甲酸酯的成型物质快速结晶
公开(公告)号：US4136089A
公开(公告)日：1979-01-23
申请号：US825121
申请日：1977-08-16
申请人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08G63/183 , C08G63/78 , C08G63/18
CPC分类号： C08G63/183 , C08G63/78
摘要： Terephthalic copolyesters, the diol component of which consists of ethylene glycol and 2.2-diethyl propane-1.3-diol crystallize more rapidly than pure polyethylene terephthalate and can be molded in a way comparable to butylene terephthalate.

5. 发明授权

US4176224A Poly (ethylene/alkylene) terephthalates which crystallize rapidly 失效
标题翻译：聚（乙烯/亚烷基）对苯二甲酸酯快速结晶
公开(公告)号：US4176224A
公开(公告)日：1979-11-27
申请号：US889584
申请日：1978-03-23
申请人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08G63/00 , C08G63/18 , C08G63/181
CPC分类号： C08G63/18
摘要： The present invention is concerned with thermoplastic terephthalic acid copolyesters which crystallize more rapidly than homopolyethylene terephthalate and are based on a diol component which is about 98 to 99.9 mol % of ethylene glycol and the balance 2-ethylhexane-1,3-diol. The acid component may be up to about 10.0 mol % of other than terephthalic acid or its dimethyl ester.This invention is also concerned with a process of synthesizing such copolyesters by esterifying or transesterifying the acid and diol components between about 150.degree. and 250.degree. C. in the presence of appropriate catalysts. The condensation product may be subject to polycondensation at about 200.degree. to 300.degree. C. under reduced pressure in the presence of esterification catalysts. In a preferred embodiment the 2-ethylhexane-1,3-diol is added after the initial reaction between the acid component and the ethylene glycol and preferably after the degree of polycondensation is greater than 4.
摘要翻译：本发明涉及热塑性对苯二甲酸共聚酯，其比对苯二甲酸聚对苯二甲酸丙二醇酯更快地结晶，并且基于约98-99.9摩尔％的乙二醇和余量的2-乙基己烷-1,3-二醇的二醇组分。除了对苯二甲酸或其二甲酯之外，酸组分可以高达约10.0mol％。本发明还涉及通过在合适的催化剂存在下在约150℃和250℃之间酯化酯化或酯交换合成这种共聚酯的方法。在酯化催化剂存在下，缩合产物可在减压下在约200℃至300℃下进行缩聚反应。在优选的实施方案中，在酸组分和乙二醇的最初反应之后，优选在缩聚度大于4之后加入2-乙基己烷-1,3-二醇。

6. 发明授权

US4086212A Poly(ethylene/alkylene) terephthalates which crystallize rapidly 失效
标题翻译：聚（乙烯/亚烷基）对苯二甲酸酯快速结晶
公开(公告)号：US4086212A
公开(公告)日：1978-04-25
申请号：US658816
申请日：1976-02-17
申请人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
发明人： Peter Bier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08L67/00 , C08G63/00 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/78 , C08K3/40 , C08L67/02 , C08G63/12
CPC分类号： C08G63/183 , C08G63/78
摘要： Terephthalic copolyesters, the diol component of which mainly consists of ethylene glycol units, crystallize more rapidly than pure polyethylene terephthalate and can be moulded in a way comparable to polybutylene terephthalate.
摘要翻译：对苯二甲酸共聚酯，其二醇组分主要由乙二醇单元组成，比纯聚对苯二甲酸乙二醇酯更快地结晶，并且可以以与聚对苯二甲酸丁二醇酯相当的方式成型。

7. 发明授权

US5858903A Catalyst, its production and its use for the gas-phase polymerization of conjugated dienes 失效
标题翻译：催化剂，其制备及其在共轭二烯气相聚合中的应用
公开(公告)号：US5858903A
公开(公告)日：1999-01-12
申请号：US933597
申请日：1997-09-18
申请人： Gerd Sylvester , Hugo Vernaleken
发明人： Gerd Sylvester , Hugo Vernaleken
IPC分类号： C08F2/34 , C08F4/52 , C08F4/54 , C08F4/60 , C08F36/04 , B01J31/00
CPC分类号： C08F36/04 , Y10S526/901 , Y10S526/904
摘要： Catalysts consisting ofA) an alcoholate of the rare earths, a carboxylate of the rare earths, a complex compound of the rare earths with diketones and/or an addition compound of the halides of the rare earths with an oxygen or nitrogen donor compound,B) an aluminium trialkyl, a dialkyl aluminium hydride and/or an alumoxane,C) another Lewis acid andD) an inert, particulate inorganic solid with a specific surface of greater than 10 m.sup.2 /g (BET) and a pore volume of 0.3 to 15 ml/gare eminently suitable for the polymerization of conjugated dienes, more particularly butadiene, in the gas phase.
摘要翻译：由以下组成的催化剂：A）稀土的醇化物，稀土的羧酸盐，稀土与二酮的络合物和/或稀土卤化物的加成化合物与氧或氮给体化合物B，）三烷基铝，二烷基氢化铝和/或铝氧烷，C）另一种路易斯酸和D）比表面积大于10m 2 / g（BET）的惰性颗粒状无机固体，孔体积为0.3〜 15ml / g非常适合在气相中共轭二烯，更特别是丁二烯的聚合。

8. 发明授权

US5219976A Process for the preparation of phenol resins using by-products of the chlorination of butadiene as reactants 失效
标题翻译：使用二苯乙烯作为反应物的氯化物副产物制备酚醛树脂的方法
公开(公告)号：US5219976A
公开(公告)日：1993-06-15
申请号：US655769
申请日：1991-02-15
申请人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
发明人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
IPC分类号： C08G61/02 , C08L21/00
CPC分类号： C08G61/02 , C08L21/00
摘要： By-products from the chlorination of butadiene may be reacted with phenols in the presence of iron catalysts to form Novolak type phenol resins.
摘要翻译：在铁催化剂存在下，来自丁二烯氯化的副产物可以与酚反应形成酚醛清漆型酚醛树脂。

9. 发明授权

US5061756A Process for the preparation of polyurethane powders 失效
标题翻译：制备聚氨酯粉末的方法
公开(公告)号：US5061756A
公开(公告)日：1991-10-29
申请号：US566017
申请日：1990-08-10
申请人： Tillmann Hassel , Hanns P. Muller , Hugo Vernaleken , Helmut Kipphardt , Rolf Dhein
发明人： Tillmann Hassel , Hanns P. Muller , Hugo Vernaleken , Helmut Kipphardt , Rolf Dhein
IPC分类号： C08J3/12 , C08G18/00 , C08G18/08 , C08G18/10
CPC分类号： C08G18/10 , C08G18/0871
摘要： The present invention is directed to an improved process for the direct preparation of polyurethane powders in a finely divided form by the reaction of polyisocyanates and isocyanate reactive compounds in a carrier phase, using interface active compounds, the improvement wherein the interface active compound used consists of at least one polymer of a urethane of (i) a long chain alkyl isocyanate and (ii) a hydroxyalkyl-acrylic or -metacrylic acid ester.
摘要翻译：本发明涉及一种用于使用界面活性化合物通过多异氰酸酯和异氰酸酯反应性化合物在载体相中反应而以细碎形式直接制备聚氨酯粉末的改进方法，其中使用的界面活性化合物由（i）长链烷基异氰酸酯和（ii）羟烷基 - 丙烯酸或 - 甲基丙烯酸酯的氨基甲酸酯的至少一种聚合物。

10. 发明授权

US4267127A Process for the production of phosphoric acid triesters 失效
标题翻译：磷酸三酯生产工艺
公开(公告)号：US4267127A
公开(公告)日：1981-05-12
申请号：US60679
申请日：1979-07-25
申请人： Harald Selbeck , Claus Wulff , Uwe Hucks , Erhard Tresper , Hugo Vernaleken
发明人： Harald Selbeck , Claus Wulff , Uwe Hucks , Erhard Tresper , Hugo Vernaleken
IPC分类号： C07F9/12 , C07F9/09
CPC分类号： C07F9/12
摘要： Phosphoric acid triesters of the formula ##STR1## are produced in two or more stages by reacting phosphorus oxyhalides, phosphorus pentahalides, phosphoric acid monoester dihalides or phosphoric acid diester halides corresponding to the following general formula:ZO PO Hal.sub.2 (ZO).sub.2 PO Halwherein Z is defined as above and Hal represents Cl and/or Br with at least one hydroxyaryl compound of the formula ##STR2## in a two-phase mixture of an organic solvent an aqueous alkaline earth metal and/or alkali metal hydroxide solution.
摘要翻译：通过使对应于以下通式的ZO PO Hal 2（ZO）2 PO Hal的卤代卤磷，五卤化磷，五氟化五磷酸，磷酸二酯二卤化物或磷酸二酯卤化物反应制备式“IMAGE”的磷酸三酯，其中Z 定义如上，Hal表示Cl和/或Br与至少一种式“IMAGE”的羟基芳基化合物在有机溶剂碱土金属水溶液和/或碱金属氢氧化物溶液的两相混合物中。

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