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1. 发明授权

US5578686A Phenolic allyl ethers 失效
标题翻译：酚醛烯丙基醚
公开(公告)号：US5578686A
公开(公告)日：1996-11-26
申请号：US505926
申请日：1995-07-24
申请人： Pen-Chung Wang , Donald R. Kelsey
发明人： Pen-Chung Wang , Donald R. Kelsey
IPC分类号： C08J3/24 , C07C41/16 , C07C43/20 , C07C43/215 , C08F290/00 , C08F299/00 , C08K5/13 , C08L79/08 , C08L65/00
CPC分类号： C07C43/215 , C08L79/085
摘要： A phenolic allyl ether is provided which can be prepared by reacting a polyphenol with an allyl halide, said polyphenol described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbomane linking moiety, L' is a divalent cycloaliphatic moiety, Allyl is a phenolic allyl ether group, and each of m and n is a number within the range of 0 to about 10. Such phenolic allyl ethers include the reaction product of allyl halide with the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyelohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting phenolic allyl ether resins are useful as processing agents for polymaleimides.
摘要翻译：提供了一种酚类烯丙基醚，其可以通过使多酚与烯丙基卤化物反应来制备，所述多酚通过其中Ar是芳族部分的式“IMAGE”描述，L是二价环己烷并联硼烷连接部分，L'是二价脂环族部分，烯丙基是酚烯丙基醚基团，m和n各自为0至约10的数。这种酚类烯丙基醚包括烯丙基卤与苯酚加成反应产物的反应产物环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯。所得酚醛烯丙基醚树脂可用作聚马来酰亚胺的加工剂。

2. 发明授权

US5284929A Epoxy resins with cyclohexenenorbornene moieties 失效
标题翻译：环氧树脂与环己烯降冰片烯部分
公开(公告)号：US5284929A
公开(公告)日：1994-02-08
申请号：US29192
申请日：1993-03-10
申请人： Pen-Chung Wang , Donald R. Kelsey
发明人： Pen-Chung Wang , Donald R. Kelsey
IPC分类号： C08G59/24 , C07C6/10 , C08G59/06 , C08G59/20 , C08G59/32 , C08G59/40 , C08G61/02 , C08L63/00 , H05K1/03 , C08G59/04
CPC分类号： C08G61/02 , C07C6/10 , C08G59/066 , C08G59/3218 , C08L63/00 , C07C2103/66 , H05K1/0326
摘要： An epoxy resin is provided which can be described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, Gly is a glycidyl ether group, and each of m and n is a number within the range of 0 to about 10. Such epoxy resins include the product of glycidation of the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting epoxy resins have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.
摘要翻译：提供一种环氧树脂，其可以通过其中Ar是芳族部分的式“IMAGE”来描述，L是二价环己烷基降冰片烷基连接部分，L'是二价脂环族部分，Gly是缩水甘油醚基团，m n为0〜10左右的数。这些环氧树脂包括苯酚加成反应产物与环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环的缩水甘油化产物 [2.2.1]庚-2-烯。所得环氧树脂在固化状态下具有低熔体粘度和低吸水率，并且可用作高性能电层压和封装配方的树脂组分。

3. 发明授权

US5495051A Phenolic allyl ethers 失效
标题翻译：酚醛烯丙基醚
公开(公告)号：US5495051A
公开(公告)日：1996-02-27
申请号：US294272
申请日：1994-08-22
申请人： Pen-Chung Wang , Donald R. Kelsey
发明人： Pen-Chung Wang , Donald R. Kelsey
IPC分类号： C08J3/24 , C07C41/16 , C07C43/20 , C07C43/215 , C08F290/00 , C08F299/00 , C08K5/13 , C08L79/08 , C07C43/162 , C07C41/01
CPC分类号： C07C43/215 , C08L79/085
摘要： A phenolic allyl ether is provided which can be prepared by reacting a polyphenol with an allyl halide, said polyphenol described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, Allyl is a phenolic allyl ether group, and each of m and n is a number within the range of 0 to about 10. Such phenolic allyl ethers include the reaction product of allyl halide with the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting phenolic allyl ether resins are useful as processing agents for polymaleimides.
摘要翻译：提供了一种酚类烯丙基醚，其可以通过使多酚与烯丙基卤化物反应来制备，所述多酚通过其中Ar是芳族部分的式“IMAGE”描述，L是二价环己烷基降冰片烷基连接部分，L'是二价环脂族部分，烯丙基是酚烯丙基醚基团，m和n各自为0至约10的数。这种酚类烯丙基醚包括烯丙基卤与苯酚加成反应产物的反应产物环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯。所得酚醛烯丙基醚树脂可用作聚马来酰亚胺的加工剂。

4. 发明授权

US5359023A Cyclohexanenorbornane epoxy resin with curing agent 失效
标题翻译：具有固化剂的环己烷降冰片烷环氧树脂
公开(公告)号：US5359023A
公开(公告)日：1994-10-25
申请号：US184539
申请日：1994-01-21
申请人： Pen-Chung Wang , Donald R. Kelsey
发明人： Pen-Chung Wang , Donald R. Kelsey
IPC分类号： C08G59/24 , C07C6/10 , C08G59/06 , C08G59/20 , C08G59/32 , C08G59/40 , C08G61/02 , C08L63/00 , H05K1/03 , C08G59/04 , C08G59/50 , C08G59/62
CPC分类号： C08G61/02 , C07C6/10 , C08G59/066 , C08G59/3218 , C08L63/00 , C07C2103/66 , H05K1/0326
摘要： An epoxy resin is provided which can be described by the formula ##STR1## in which Ar is an aromatic moiety, L is a divalent cyclohexanen or bornane linking moiety, L' is a divalent cycloaliphatic moiety, Gly is a glycidyl ether group, and each of m and n is a number within the range of 0 to about 10. Such epoxy resins include the product of glycidation of the product of the addition reaction of a phenol and a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting epoxy resins have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.
摘要翻译：提供了一种环氧树脂，其可以通过其中Ar是芳族部分的式“IMAGE”来描述，L是二价环己烷或烷烃连接部分，L'是二价脂环族部分，Gly是缩水甘油醚基团，的m和n是0至约10的范围内的数字。这种环氧树脂包括苯酚和环己烯降冰片烯化合物的加成反应产物的缩水甘油化产物，例如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯。所得环氧树脂在固化状态下具有低熔体粘度和低吸水率，并且可用作高性能电层压和封装配方的树脂组分。

5. 发明授权

US5340912A Cyanate resins 失效
标题翻译：氰酸酯树脂
公开(公告)号：US5340912A
公开(公告)日：1994-08-23
申请号：US23428
申请日：1993-02-23
申请人： Pen-Chung Wang , Donald R. Kelsey
发明人： Pen-Chung Wang , Donald R. Kelsey
IPC分类号： C07C265/14 , C08G73/06 , C08G73/10 , C07C261/02 , C08G73/00
CPC分类号： C07C265/14 , C08G73/0655 , C07C2101/14 , C07C2103/66 , C07C2103/68
摘要： A cyanate-functional compound is provided which can be described by the formula ##STR1## in which Ar is a C.sub.6-20 aromatic moiety, L is a hexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, and each of m and n is a number within the range of 0 to about 10. Such cyanate esters include the product of cyanation of the addition reaction of a phenol with a cyclohexene norbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1]hept-2-ene. The resulting cyanate esters have low melt viscosity and low water absorbance in the cured state and are useful as the resinous component of high-performance electrical laminating and encapsulation formulations.
摘要翻译：提供了一种氰酸酯官能化合物，其可以通过其中Ar是C6-20芳族部分的式“IMAGE”来描述，L是六亚烷基降冰片烷基连接部分，L'是二价脂环族部分，m和n各自是这种氰酸酯包括苯酚与环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环[2.2.1]的加成反应的氰化反应产物，庚-2-烯。所得氰酸酯在固化状态下具有低熔体粘度和低吸水率，并且可用作高性能电层压和包封配方的树脂组分。

6. 发明授权

US5406003A Phenolic compounds 失效
标题翻译：酚类化合物
公开(公告)号：US5406003A
公开(公告)日：1995-04-11
申请号：US296285
申请日：1994-08-25
申请人： Pen C. Wang , Donald R. Kelsey
发明人： Pen C. Wang , Donald R. Kelsey
IPC分类号： C07B61/00 , C07C37/14 , C07C39/17 , C07D303/24 , C08G59/32 , C08G61/02 , C08L63/00
CPC分类号： C08G61/02 , C07C37/14 , C07C39/17 , C07D303/24 , C08G59/3218 , C08L63/00 , C07C2101/14 , C07C2102/42 , C07C2103/86 , C07C2103/90
摘要： A phenolic compound is provided which can be described by the formula ##STR1## in which Ar is a C.sub.6-20 aromatic moiety, L is a cyclohexanenorbornane linking moiety, L' is a divalent cycloaliphatic moiety, and each of m and n is a number within the range of 0 to about 10. Such phenols include the product of the addition reaction of phenol with a cyclohexenenorbornene compound such as 5-(3-cyclohexen-1-yl)bicyclo[2.2.1 ]hept-2-ene.
摘要翻译：提供了一种酚类化合物，其可以通过其中Ar是C6-20芳族部分的式“IMAGE”描述，L是环己烷基降冰片烷基连接部分，L'是二价脂环族部分，m和n各自是数在0至约10的范围内。这种酚包括苯酚与环己烯降冰片烯化合物如5-（3-环己烯-1-基）双环[2.2.1]庚-2-烯的加成反应的产物。

7. 发明授权

US5276119A Transition metal hydrides as co-catalysts for olefin polymerization 失效
标题翻译：过渡金属氢化物作为烯烃聚合的助催化剂
公开(公告)号：US5276119A
公开(公告)日：1994-01-04
申请号：US997802
申请日：1992-12-29
申请人： Donald R. Kelsey
发明人： Donald R. Kelsey
IPC分类号： C08F4/76 , C08G61/08
CPC分类号： C08G61/08 , Y10S526/943
摘要： An improved olefin metathesis catalyst system is disclosed. The catalyst system comprises a transition metal halide metathesis catalyst and an organo transition metal hydride co-catalyst of the formulaL.sub.x --M--Hwherein M is a group IVB transition metal including zirconium, titanium or hafnium; L is a ligand selected independently from the group of hydrogen, halide and organic ligands such as an optionally substituted C.sub.1-20 alkyl or alkenyl, an optionally substituted C.sub.3-20 cycloalkyl or cycloalkenyl having 3 to 6 carbon atoms in the ring, an optionally substituted C.sub.5-20 cycloakadienyl having 5 carbon atoms in the cycloalkadienyl ring, or an optionally substituted C.sub.6-20 aryl or fused aryl, where at least one L is a cycloalkadienyl; and x is one less than the valence of M. The optional substitutions on the organic ligands include halogens, preferably chloride or flouride; C.sub.1-6 alkyl; C.sub.1-6 alkoxy; and C.sub.1-6 haloalkyl. The preferred ligand is a C.sub.5-20 cycloalkadienyl having 5 carbon atoms in the cycloalkadienyl group, e.g. cyclopentadienyl. The co-catalysts of this invention are combined with molybdenum or tungsten metathesis catalysts to provide an active catalytic system for the polymerization of cycloolefins, such as dicyclopentadiene.
摘要翻译：公开了改进的烯烃复分解催化剂体系。催化剂体系包括过渡金属卤化物复分解催化剂和式Lx-M-H的有机过渡金属氢化物助催化剂，其中M是含有锆，钛或铪的IVB族过渡金属; L是独立地选自氢，卤化物和有机配体如任选取代的C 1-20烷基或烯基，任选取代的C 3-20环烷基或环中具有3至6个碳原子的环烯基的配体，任选取代的在环二烯基环中具有5个碳原子的C 5-20环烷二烯基，或任选取代的C 6-20芳基或稠合芳基，其中至少一个L是环二烯基; 且x小于M的化合价。有机配体上的任选取代包括卤素，优选氯化物或氟化物; C 1-6烷基; C 1-6烷氧基和C 1-6卤代烷基。优选的配体是在环烷二烯基中具有5个碳原子的C 5-20环烷二烯基，环戊二烯基。本发明的助催化剂与钼或钨复分解催化剂组合以提供用于环烯烃如二环戊二烯聚合的活性催化体系。

8. 发明授权

US5254629A Polymerization of cyclic olefins 失效
标题翻译：环烯烃的聚合
公开(公告)号：US5254629A
公开(公告)日：1993-10-19
申请号：US875852
申请日：1992-04-29
申请人： Donald R. Kelsey , Dale L. Handlin, Jr.
发明人： Donald R. Kelsey , Dale L. Handlin, Jr.
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J31/22 , C08F4/628 , C08G61/08 , C08F4/629 , C08F4/78
CPC分类号： C08G61/08 , B01J31/0214 , B01J31/12 , B01J31/2208 , B01J2531/30 , B01J2531/64 , B01J2531/66
摘要： A catalyst and process for the polymerization of cyclic olefins, such as dicyclopentadiene, in the presence of an elastomer polymer, are disclosed. The catalyst includes a transition metal compound, a co-catalyst and a boron halide promoter. Polymerization can be carried out at fast reaction times in a reaction injection molding process to prepare a thermoset molded article having high Tg and superior toughness.
摘要翻译：公开了一种用于在弹性体聚合物存在下环状烯烃如二环戊二烯聚合的催化剂和方法。催化剂包括过渡金属化合物，助催化剂和卤化硼助催化剂。聚合可以在反应注射成型工艺中的快速反应时间进行，以制备具有高Tg和优异韧性的热固性模制品。

9. 发明授权

US4777235A Production of polyarylene ether from activated dihalo benzenoid monomer, dihydroxy benzenoid monomer and Bis(hydroxyphenyl) monomer 失效
标题翻译：由活性二卤代苯乙烯单体，二羟基苯乙烯单体和双（羟基苯基）单体生产聚芳醚
公开(公告)号：US4777235A
公开(公告)日：1988-10-11
申请号：US68972
申请日：1987-07-01
申请人： Donald R. Kelsey , Robert A. Clendinning , George T. Kwiatkowski
发明人： Donald R. Kelsey , Robert A. Clendinning , George T. Kwiatkowski
IPC分类号： C08G65/40 , C08G75/23
CPC分类号： C08G75/23
摘要： The method of preparing a thermoplastic polyarylether polymer which comprises reacting a first monomer composition comprising an activated dihalobenzenoid compound and dihydroxybenzenoid composition comprising hydroquinone, adding to the product a second monomer composition comprising a dihydroxybenzenoid composition consisting essentially of Bis-(hydroxyphenyl) compounds in a concentration of at least 50 mole percent of the total Bis-(hydroxyphenyl) compounds added in the monomer compositions and polymerizing.

10. 发明授权

US5459213A Catalyst system for olefin polymerization 失效
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：US5459213A
公开(公告)日：1995-10-17
申请号：US213345
申请日：1994-03-15
申请人： Donald R. Kelsey
发明人： Donald R. Kelsey
IPC分类号： C08F4/69 , C08F10/00 , C08F10/14 , C08G61/08
CPC分类号： C08G61/08
摘要： A catalyst system and process for the polymerization of cyclic olefins, such as dicyclopentadiene, are disclosed. The catalyst system contains a transition metal hydrotrispyrazolylborate complex having the formula:Tp--M--L.sub.3wherein Tp is a hydrotrispyrazolylborate ligand, M is tungsten or molybdenum, and L is independently a ligand selected from the group consisting of oxo, phenoxy, alkoxy, and halides, provided that at least one L is a halide, and a co-catalyst.
摘要翻译：公开了用于环烯烃聚合的催化剂体系和方法，例如二环戊二烯。催化剂体系含有下式的过渡金属氢化四吡唑基硼酸盐络合物：Tp-M-L3其中Tp是氢化四吡唑基硼酸盐配体，M是钨或钼，L独立地是选自氧代，苯氧基，烷氧基和卤化物，条件是至少一个L是卤化物，和助催化剂。

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