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    • 9. 发明授权
    • Process for recovering terephthalic acid from waste polyethylene
terephthalate
    • 从废弃聚对苯二甲酸乙二醇酯中回收对苯二甲酸的方法
    • US4542239A
    • 1985-09-17
    • US501805
    • 1983-06-07
    • Richard A. LamparterBruce A. BarnaDavid R. Johnsrud
    • Richard A. LamparterBruce A. BarnaDavid R. Johnsrud
    • C07C27/02C07C51/09C07C51/487C07C29/88
    • C07C51/09
    • Terephthalic acid (TPA) is recovered from used polyethylene terephthalate beverage containers by reacting comminuted containers in a reaction zone with an aqueous medium containing ammonium hydroxide at elevated temperatures and pressures to form a water soluble diammonium salt of TPA, separating any undissolved solids from the reaction product, acidifying the remaining reaction product to liberate TPA, and separating the precipitated TPA. A portion of the liquid remaining after separation of TPA can be mixed with lime or slaked lime, the resulting mixture treated in an ammonia stripper to remove ammonia therefrom and the ammonia overheads from the stripper blended with another portion of the liquid remaining after separation of TPA to form a stream containing ammonium hydroxide which is recycled to the reaction zone. Ethylene glycol can be recovered from the bottoms from the ammonia stripper by distillation.
    • 通过使反应区中的粉碎容器与含有氢氧化铵的水性介质在升高的温度和压力下反应形成水溶性TPA的二铵盐,从反应中分离出任何未溶解的固体,从使用的聚对苯二甲酸乙二醇酯饮料容器中回收对苯二甲酸(TPA) 产物,酸化剩余的反应产物以释放TPA,并分离沉淀的TPA。 在分离TPA后残留的一部分液体可以与石灰或熟石灰混合,所得混合物在氨汽提器中处理以从其中除去氨,并且汽提塔中的氨塔顶馏出物与分离TPA后残留的另一部分液体混合 以形成含有氢氧化铵的物流,其被循环到反应区。 乙二醇可以通过蒸馏从氨汽提器的塔底回收。