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1. 发明授权

US08480764B1 Process for converting cellulose into a liquid biofuel using as an intermediate an acetal of hydroxymethyl furfural 有权
标题翻译：将纤维素转化为液体生物燃料的方法，使用羟甲基糠醛缩醛作为中间体
公开(公告)号：US08480764B1
公开(公告)日：2013-07-09
申请号：US13371410
申请日：2012-02-11
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C10L1/18 , C07D307/36
CPC分类号： C07D307/36 , C10L1/026 , Y02E50/13
摘要： Process for converting cellulose and hemicellulose into dimethyl furan, hydrolysing first cellulose in a mixture of N alkyl imidazolium chloride, hydrochloric acid 37% and an alcohol, to produce an acetal of glucose, making the dehydration to an acetal of hydroxymethyl furfural, extracting and making the hydrogenation of this acetal and distilling to produce dimethyl furan.
摘要翻译：将纤维素和半纤维素转化为二甲基呋喃的方法，将N烷基咪唑氯化物，37％的盐酸和醇的混合物中的第一纤维素水解，生成葡萄糖的缩醛，脱水为羟甲基糠醛的缩醛，提取和制备该缩醛的氢化并蒸馏生成二甲基呋喃。

2. 发明授权

US08987172B2 Herbicide containing glyphosate and a surfactant consisting essentially of a polyalkoxylated alkylamine wherein the alkyl group is branched 有权
标题翻译：含草甘膦的除草剂和基本上由聚烷氧基化烷基胺组成的表面活性剂，其中烷基是支链的
公开(公告)号：US08987172B2
公开(公告)日：2015-03-24
申请号：US13494493
申请日：2012-06-12
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： A01N25/00 , C07C213/00 , A01N57/20 , C07C215/00 , C07C217/00
CPC分类号： A01N57/20 , A01N25/30 , A01N2300/00
摘要： The present invention relates to glyphosate formulations (herbicides) containing glyphosate and a surfactant consisting essentially of a branched alkylamine where the nitrogen atom in the alkylamine is connected to a branched alkyl group and one, two or three chains of alkylene oxide units (e.g., ethylene oxide units and/or propylene oxide units, including copolymers of ethylene oxide and propylene oxide units).
摘要翻译：本发明涉及含有草甘膦和基本上由支链烷基胺组成的表面活性剂的草甘膦制剂（除草剂），其中烷基胺中的氮原子连接到支链烷基和一个，两个或三个环氧烷单元链（例如乙烯氧化物单元和/或环氧丙烷单元，包括环氧乙烷和环氧丙烷单元的共聚物）。

3. 发明申请

US20120058392A1 Rechargeable battery with aluminium anode, graphite cathode and an electrolyte containing aluminium vapour in plasma state 审中-公开
标题翻译：带铝阳极的可充电电池，石墨阴极和含有等离子体状态的铝蒸气的电解液
公开(公告)号：US20120058392A1
公开(公告)日：2012-03-08
申请号：US12876143
申请日：2010-09-05
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： H01M10/02
CPC分类号： H01M10/39 , H01M2/026 , H01M4/0459 , H01M4/0495 , H01M4/38 , H01M4/587 , H01M2300/002
摘要： We propose a rechargeable battery with aluminium anode. In order to avoid the high reactivity of aluminium ions with most liquid electrolytes, we present an electrolyte containing aluminium vapour in plasma state.The battery is contained in a quartz cylinder heated with microwaves to a sufficiently high temperature to ionise the aluminium ions in the vapour.The anode is graphite. By receiving electrons from the external circuit, carbon atoms in the graphite hexagonal structure receive 1 or 2 or 3 negative charges and combine with aluminium ions from the electrolyte. Four charges in the carbon atom corresponds to Al4C3, aluminium carbide, which can also be found. It has a melting point of 2100° C., it is a solid at the plasma temperature and sticks to the anode.
摘要翻译：我们提出一个带铝阳极的可充电电池。为了避免铝离子与大多数液体电解质的高反应性，我们提出了一种含有等离子体状态的铝蒸气的电解质。电池被包含在用微波加热到足够高的温度的石英圆筒中以离子化蒸汽中的铝离子。阳极是石墨。通过从外部电路接收电子，石墨六方结构中的碳原子接收1或2或3个负电荷并与来自电解质的铝离子结合。碳原子中的四个电荷对应于也可以发现的Al 4 C 3，碳化铝。它的熔点为2100°C，在等离子体温度下为固体，粘在阳极上。

4. 发明授权

US09260674B2 Biofuel containing furanic compounds and alkoxy benzene compounds and the process for obtaining these compounds from sugar cane by hydrolysis of cellulose, sugars and lignin in ionic liquids 有权
标题翻译：含有呋喃化合物和烷氧基苯化合物的生物燃料以及通过在离子液体中水解纤维素，糖和木质素从甘蔗获得这些化合物的方法
公开(公告)号：US09260674B2
公开(公告)日：2016-02-16
申请号：US13616421
申请日：2012-09-14
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C10L1/14 , C10L1/16 , C10L1/02
CPC分类号： C10L1/023 , C10L1/026 , C10L2270/023 , C10L2270/026 , Y02E50/13
摘要： A biofuel consisting of a mixture of furanic compounds and polymethoxy benzene compounds which can be mixed with standard fuel consisting in hydrocarbons, and the process to obtain these compounds from sugar cane by converting cellulose, hemicellulose and sugars in furan derivatives and levullinic acid esthers and by converting lignin in alkoxy benzene compounds by hydrolyzing the cellulose and lignin of sugar cane first in a mixture of N alkyl imidazolium chloride, hydrochloric acid 37% and an alcohol, dehydrating pentoses and hexoses so obtained from cellulose, stabilizing the aldehyde groups as acetal and stabilizing the phenolic hydroxyls obtained from lignin as alkyl ethers.
摘要翻译：由呋喃化合物和多甲氧基苯化合物的混合物组成的生物燃料，其可以与由烃组成的标准燃料混合，以及通过在呋喃衍生物和levullinic acid esthers中将纤维素，半纤维素和糖转化成甘蔗来获得这些化合物的方法通过在N-烷基咪唑氯化物，37％的盐酸和醇的混合物中首先水解甘蔗的纤维素和木质素，将纤维素中的木质素转化成烷基苯化合物，将其从纤维素得到的脱水戊糖和己糖，使醛基稳定化为缩醛和稳定化由木质素作为烷基醚获得的酚羟基。

5. 发明授权

US08247581B2 Process for converting cellulose in a liquid biofuel using N-methyl imidazolium chloride 失效
标题翻译：使用N-甲基咪唑氯化物在液体生物燃料中转化纤维素的方法
公开(公告)号：US08247581B2
公开(公告)日：2012-08-21
申请号：US12476402
申请日：2009-06-02
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C07D315/00
CPC分类号： C07D309/04 , C07D309/32 , C10G2300/1014 , C10L1/02 , Y02P30/20
摘要： Process for converting cellulose and hemicellulose in hydroxymethylpyranone and isomers, using as a solvent and catalyst a mixture of N alkyl imidazolium chloride and hydrochloric acid 37%, where hydroxymethylpyranone is extracted with butanol and hydrogenated to methylpyran and isomers.
摘要翻译：将羟基甲基吡喃酮和异构体中的纤维素和半纤维素转化为异构体的方法，使用N，N-烷基咪唑氯化钾和37％盐酸的混合物，其中羟甲基吡喃酮用丁醇萃取并氢化成甲基吡喃和异构体。

6. 发明申请

US20100316914A1 Rechargeable battery with aluminium anode containing a non aqueous electrolyte consisting of an ether as solvent and a lithium salt of an imide 审中-公开
标题翻译：含铝阳极的可充电电池包含由醚作为溶剂组成的非水电解质和酰亚胺的锂盐
公开(公告)号：US20100316914A1
公开(公告)日：2010-12-16
申请号：US12484214
申请日：2009-06-14
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： H01M6/22 , H01M6/04
CPC分类号： H01M4/38 , H01M4/587 , H01M10/052 , H01M10/0565 , H01M10/0568
摘要： A rechargeable battery with aluminium anode containing a non aqueous electrolyte consisting of an ether as solvent and a lithium salt of an imideIt is welt known that the ionisation energy of aluminium to Al3+ is about 12 times as big as the ionisation energy of lithium to Li1+. The redox potential however does not reflect this big difference because of the high enthalpy consumed in the formation of aluminium hydroxide when it goes from the anode to the aqueous electrolyte.Also the use of aqueous electrolyte do not allow the aluminium batteries to be rechargeable, because of the very strong bond between the aluminium and the oxygen atom in the electrolyte.We propose now a rechargeable battery where the aluminium ion is connected to the nitrogen atom of an imide which improves the redox potential by reducing the enthalpy of formation of the aluminium-nitrogen bond in the salt contained in the electrolyte.As there are no hydrogen ions in the electrolyte, we found that the addition of a lithium salt of an imide is necessary to improve the characteristics of the battery.Lithium does not participate in the redox process, it just transports the electric current. The cathode may be carbon or can be made of other metals.
摘要翻译：包含铝阳极的可充电电池，其包含由醚作为溶剂和亚胺的锂盐组成的非水电解质已经知道，铝与Al 3+的电离能大约是锂对Li1 +的电离能量的约12倍，。然而，氧化还原电位没有反映出这种大的差异，因为当从阳极流到水性电解质时，形成氢氧化铝时的高焓消耗。此外，由于铝和电解质中的氧原子之间的非常强的键，因此使用含水电解质不能使铝电池可再充电。我们现在提出一种可充电电池，其中铝离子连接到酰亚胺的氮原子上，通过降低电解质中所含的盐中的铝 - 氮键的形成焓来改善氧化还原电位。由于电解质中没有氢离子，我们发现添加酰亚胺的锂盐是改善电池特性所必需的。锂不参与氧化还原过程，它只是传输电流。阴极可以是碳或可以由其它金属制成。

7. 发明授权

US09028789B2 Process to produce lithium carbonate directly from the aluminosilicate mineral 有权
标题翻译：从铝硅酸盐矿石直接生产碳酸锂的工艺
公开(公告)号：US09028789B2
公开(公告)日：2015-05-12
申请号：US13470360
申请日：2012-05-14
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C01D15/08
CPC分类号： C01D15/08 , Y02P20/544
摘要： Process for obtaining lithium carbonate directly from the mineral containing silicium, aluminum, lithium and other metal oxides without the need to dissolve previously all oxides in sulphuric acid or alkaline hydroxides at high temperatures and pressures, by using carbon dioxide and water at supercritical or near supercritical conditions acting directly on the fine powder of the mineral.
摘要翻译：直接从含有硅，铝，锂和其他金属氧化物的矿物中获得碳酸锂的方法，而不需要在高温和高压下通过使用二氧化碳和水在超临界或接近超临界状态下先前溶解在硫酸或碱性氢氧化物中的所有氧化物条件直接作用于矿物的细粉末。

8. 发明申请

US20140075830A1 Biofuel containing furanic compounds and alkoxy benzene compounds and the process for obtaining these compounds from sugar cane by hydrolysis of cellulose, sugars and lignin in ionic liquids 审中-公开
标题翻译：含有呋喃化合物和烷氧基苯化合物的生物燃料以及通过在离子液体中水解纤维素，糖和木质素从甘蔗获得这些化合物的方法
公开(公告)号：US20140075830A1
公开(公告)日：2014-03-20
申请号：US13616421
申请日：2012-09-14
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C10L1/19
CPC分类号： C10L1/023 , C10L1/026 , C10L2270/023 , C10L2270/026 , Y02E50/13
摘要： A biofuel consisting of a mixture of furanic compounds and polymethoxy benzene compounds which can be mixed with standard fuel consisting in hydrocarbons, and the process to obtain these compounds from sugar cane by converting cellulose, hemicellulose and sugars in furan derivatives and levullinic acid esthers and by converting lignin in alkoxy benzene compounds by hydrolysing the cellulose and lignin of sugar cane first in a mixture of N alkyl imidazolium chloride, hydrochloric acid 37% and an alcohol, dehydrating pentoses and hexoses so obtained from cellulose, stabilising the aldehyde groups as acetal and stabilising the phenolic hydroxyls obtained from lignin as alkyl ethers.
摘要翻译：由呋喃化合物和多甲氧基苯化合物的混合物组成的生物燃料，其可以与由烃组成的标准燃料混合，以及通过在呋喃衍生物和levullinic acid esthers中转化纤维素，半纤维素和糖并通过在烷基苯化合物中通过水解甘蔗的纤维素和木质素首先在N-烷基咪唑氯化物，37％的盐酸和醇的混合物中水解木素，由纤维素得到的脱水戊糖和己糖，将醛基稳定化为缩醛和稳定化由木质素作为烷基醚获得的酚羟基。

9. 发明申请

US20130302237A1 Process to produce lithium carbonate direcly from the alumino silicate mineral 审中-公开
标题翻译：从铝硅酸盐矿物中直接生产碳酸锂的工艺
公开(公告)号：US20130302237A1
公开(公告)日：2013-11-14
申请号：US13470360
申请日：2012-05-14
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： C01D15/08
CPC分类号： C01D15/08 , Y02P20/544
摘要： Process for obtaining lithium carbonate directly from the mineral containing silicium, aluminium, lithium and other metal oxides without the need to dissolve previously all oxides in sulphuric acid or alkaline hydroxides at high temperatures and pressures, by using carbon dioxide and water at supercritical or near supercritical conditions acting directly on the fine powder of the mineral.
摘要翻译：直接从含有硅，铝，锂和其他金属氧化物的矿物中获得碳酸锂的方法，而不需要在高温和高压下通过使用二氧化碳和水在超临界或接近超临界状态下先前溶解在硫酸或碱性氢氧化物中的所有氧化物条件直接作用于矿物的细粉末。

10. 发明申请

US20120252675A1 HERBICIDE CONTAINING GLYPHOSATE AND A SURFACTANT CONSISTING ESSENTIALLY OF A POLYALKOXYLATED ALKYLAMINE WHEREIN THE ALKYL GROUP IS BRANCHED 有权
标题翻译：含有谷氨酸的除草剂和一种含有碱金属胺基的烷氧基胺的表面活性剂，其分子式分布
公开(公告)号：US20120252675A1
公开(公告)日：2012-10-04
申请号：US13494493
申请日：2012-06-12
申请人： Pedro Manuel Brito da Silva Correia
发明人： Pedro Manuel Brito da Silva Correia
IPC分类号： A01N57/20 , A01P13/00
CPC分类号： A01N57/20 , A01N25/30 , A01N2300/00
摘要： The present invention relates to glyphosate formulations (herbicides) containing glyphosate, and a surfactant consisting essentially of a branched alkylamine where the nitrogen atom in the alkylamine is connected to a branched alkyl group and one, two or three chains of alkylene oxide units(e.g., ethylene oxide units and/or propylene oxide units, including copolymers of ethylene oxide and propylene oxide units).
摘要翻译：本发明涉及含有草甘膦的草甘膦制剂（除草剂）和基本上由支链烷基胺组成的表面活性剂，其中烷基胺中的氮原子连接到支链烷基和一个或两个或三个环氧烷单元链（例如，环氧乙烷单元和/或环氧丙烷单元，包括环氧乙烷和环氧丙烷单元的共聚物）。

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