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1. 发明授权

US06545093B1 High mixture-quality bi-modal polyethylene blends 失效
标题翻译：高混合质量的双模聚乙烯混合物
公开(公告)号：US06545093B1
公开(公告)日：2003-04-08
申请号：US09806584
申请日：2001-04-02
申请人： Paulus de Lange , Andreas Deckers , Thomas Kessler , Wolfgang Rohde , Thomas Blümel , Martin Lux
发明人： Paulus de Lange , Andreas Deckers , Thomas Kessler , Wolfgang Rohde , Thomas Blümel , Martin Lux
IPC分类号： C08L2304
CPC分类号： C08L23/0815 , C08L23/12 , C08L2205/02 , C08L2314/02 , C08L2666/04
摘要： Bimodal polyethylene blends are made from a high-molecular-weight ethylene copolymer and a low-molecular-weight ethylene homo- or copolymer and have a melt flow rate MFR 190/21.6 of from 6 to 14 g/10 min, a density of from 0.94 to 0.97 g/cm3, an environmental-stress-cracking resistance ESCR>150 h and a value of less than 3 when the quality of blending in the blend is measured to ISO 13949. A process prepares polyethylene blends of this type by melting and homogenization in a mixing apparatus and discharge via a gear pump. The blends are used to produce moldings, in particular hollow articles and pressure pipes.
摘要翻译：双峰聚乙烯共混物由高分子量乙烯共聚物和低分子量乙烯均聚物或共聚物制成，熔体流动速率MFR 190 / 21.6为6至14g / 10min，密度为 0.94〜0.97g / cm 3，环境耐应力开裂性ESCR> 150h，当共混物的共混质量测定为ISO 13949时，其值小于3。一种方法通过熔融和在混合装置中均匀化并通过齿轮泵排出。混合物用于生产模制品，特别是中空制品和压力管。

2. 发明授权

US06462135B1 Low-odor polyethylene blends 失效
标题翻译：低气味聚乙烯混合物
公开(公告)号：US06462135B1
公开(公告)日：2002-10-08
申请号：US09743923
申请日：2001-01-17
申请人： Wolfgang Rohde , Peter Bauer , Dieter Lilge , Martin Lux , Paulus de Lange , Guido Funk
发明人： Wolfgang Rohde , Peter Bauer , Dieter Lilge , Martin Lux , Paulus de Lange , Guido Funk
IPC分类号： C08L2300
CPC分类号： C08L23/06 , C08L23/0815 , C08L2314/04 , Y10T428/1352 , Y10T428/31855 , C08L2666/04
摘要： In a low-odor polyethylene blend made from a high-molecular-weight ethylene copolymer obtainable by polymerization in the presence of a Ziegler catalyst and from a low-molecular-weight ethylene homopolymer or ethylene copolymer obtainable by polymerization in the presence of a chromocene catalyst on an oxidic support, the Al content of the high-molecular-weight component is from 5 to 60 mg/kg, the Al content of the low-molecular-weight component is from 0 to 5 mg/kg and the Al content of the blend is from 1 to 55 mg/kg. Processes are described for preparing blends of this type. Their use is described for producing moldings, in particular hollow articles and pipes. Moldings, in particular hollow articles and pipes, are produced from low-odor polyethylene blends.
摘要翻译：在由可在齐格勒催化剂存在下聚合得到的高分子量乙烯共聚物和可通过在色烯催化剂存在下聚合得到的低分子量乙烯均聚物或乙烯共聚物制成的低气味聚乙烯共混物在氧化载体上，高分子量成分的Al含量为5〜60mg / kg，低分子量成分的Al含量为0〜5mg / kg，Al 共混物为1至55mg / kg。描述了制备这种类型的共混物的方法。它们的用途描述用于生产模制品，特别是中空制品和管道。木制品，特别是中空制品和管道，由低气味聚乙烯混合物制成。

3. 发明授权

US06608151B1 Method for producing supported chrome catalysts and the use thereof for the polymerization of olefins 有权
标题翻译：负载型铬催化剂的制备方法及其在烯烃聚合中的应用
公开(公告)号：US06608151B1
公开(公告)日：2003-08-19
申请号：US10070341
申请日：2002-02-28
申请人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
发明人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
IPC分类号： C08F424
CPC分类号： C08F10/02 , B01J23/26 , B01J37/0203 , C08F210/16 , C08F4/24 , C08F4/025 , C08F210/14 , C08F2500/12 , C08F2500/13
摘要： The invention relates to a method for producing supported chromium catalysts for the polymerisation of olefins by loading a xerogel support with chromium by adding to the xerogel support a volume of a 0.025 to 15% by weight solution of a chromium compound or a volume of a solution comprising from 0.025 to 7.8% by weight of Cr which is essentially converted into a chromium(VI) compound on heating in a water-free stream of gas under oxidizing conditions at temperatures in the range from 300 to 1100° C. for a period of from 10 to 1000 minutes in a solvent which comprises a maximum of 20% by weight of water, and subsequently evaporating the solvent, where the volume of the chromium salt solution employed is smaller than the pore volume of the xerogel support.
摘要翻译：本发明涉及通过向干凝胶载体中加入0.025至15重量％的铬化合物或一定体积的溶液的体积来生产用于使烯烃聚合的负载型铬催化剂的方法，包括0.025至7.8重量％的Cr，其在氧化条件下在300至1100℃的温度范围内在无水气体流中加热，基本上转化为铬（VI）化合物一段时间在包含最多20重量％的水的溶剂中10至1000分钟，然后蒸发溶剂，其中所用的铬盐溶液的体积小于干凝胶载体的孔体积。

4. 发明授权

US06699947B1 Method for producing Phillips catalysts for polymerizing olefins with better productivity rates in the particle-form process 失效
标题翻译：用于在颗粒形成方法中以更好的生产率生产用于聚合烯烃的菲利普斯催化剂的方法
公开(公告)号：US06699947B1
公开(公告)日：2004-03-02
申请号：US10070805
申请日：2002-03-11
申请人： Kaspar Evertz , Guido Funk , Paulus de Lange , Peter Kölle , Andreas Deckers
发明人： Kaspar Evertz , Guido Funk , Paulus de Lange , Peter Kölle , Andreas Deckers
IPC分类号： C08F424
CPC分类号： C08F10/02 , B01J23/26 , C08F110/02 , C08F4/24 , C08F2/14 , C08F4/025 , C08F2500/12 , C08F2500/18
摘要： In a process for producing Phillips catalysts in which an oxidic support material is treated in suspension with a chromium salt solution and subsequently, after removing the solvent, calcined in an oxygen-containing atmosphere at above 300° C., the oxidic support material and/or the catalyst after calcination are/is, according to the present invention, comminuted until a mean particle size of
摘要翻译：在制备菲利普斯催化剂的方法中，其中氧化载体材料用铬盐溶液悬浮处理，随后在除去溶剂之后，在含氧气氛中在300℃以上煅烧，氧化载体材料和/ 或根据本发明的煅烧后的催化剂粉碎直至达到<100μm的平均粒度，并且尺寸<50μm的颗粒的比例为至少30％，优选在该范围内从40％到80％。还提供了在通过本发明的方法生产的催化剂存在下，在30至150℃的压力范围内，在环管反应器中制备乙烯的均聚物或共聚物的方法。

5. 发明授权

US06645900B2 Optimized method for the production of catalyst supports based on silica gel and chromium catalysts supported on silica gel 有权
标题翻译：基于硅胶和载于硅胶上的铬催化剂生产催化剂载体的优化方法
公开(公告)号：US06645900B2
公开(公告)日：2003-11-11
申请号：US10087012
申请日：2002-02-28
申请人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
发明人： Paulus de Lange , Guido Funk , Andreas Deckers , Peter Kölle
IPC分类号： B01J29035
CPC分类号： C08F10/00 , B01J21/08 , B01J37/0072 , B01J37/036 , C08F4/02 , C08F4/24
摘要： The invention relates to a catalyst support and to a method for the production of the catalyst support comprising the following steps: a) production of a silicic acid hydrogel having a solids content of from 10 to 25% by weight (calculated as SiO2) whose particles are substantially spherical, b) extraction of the hydrogel particles with an alcohol until at least 60% of the water present in the hydrogel has been removed, c) drying of the resultant hydrogel until the residual alcohol content is less than 10% by weight (xerogel formation) at temperatures of ≧160° C. at atmospheric pressure using an inert entraining gas, d) setting of the desired particle size of the resultant xerogel, in which the hydrogel particles have a particle size of ≧8 mm before the extraction, and to a catalyst and to a method for the production of the catalyst by loading the catalyst support with a chromium compound. The invention also relates to a method for the production of polyolefins using the catalyst.
摘要翻译：本发明涉及一种催化剂载体和用于生产催化剂载体的方法，包括以下步骤：a）制备固体含量为10至25重量％（以SiO 2计）的硅酸水凝胶，其颗粒基本上是球形的，b）用醇萃取水凝胶颗粒，直到水凝胶中存在的至少60％的水已被除去，c）干燥所得的水凝胶，直到残余的醇含量低于10重量％干燥剂形成），在大气压下使用惰性夹带气体，在大气压力= 160℃的温度下，d）设定所得干燥剂的所需粒度，其中水凝胶颗粒的颗粒尺寸> 萃取和催化剂的制备方法，以及通过用铬化合物负载催化剂载体来生产催化剂的方法。本发明还涉及使用该催化剂生产聚烯烃的方法。

6. 发明授权

US06838563B2 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten 有权
标题翻译：铬，钼或钨的单环戊二烯基络合物
公开(公告)号：US06838563B2
公开(公告)日：2005-01-04
申请号：US10166068
申请日：2002-06-11
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： C08J5/18 , B01J31/22 , C07F11/00 , C07F17/00 , C08F4/44 , C08F4/60 , C08F4/639 , C08F4/69 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , D01F6/02 , B01J31/00
CPC分类号： B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/60 , B01J2531/62 , C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63925 , C08F4/6392 , C08F2500/03 , C08F2500/04 , C08F2500/17 , C08F2500/10
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl and heterocyclopentadienyl complexes of chromium, molybdenum or tungsten in which at least one of the substituents on the cyclopentadienyl ring carries a donor function which is bonded rigidly, not exclusively via sp3-hybridized carbon or silicon atoms, and a process for the polymerization of olefins.
摘要翻译：铬，钼或钨的取代的单环戊二烯基，单茚基，单芴基和杂环戊二烯基络合物，其中至少一个环戊二烯基环上的取代基具有刚性键合的供体功能，不排他地通过sp 3杂化的碳或硅原子，和烯烃聚合方法。

7. 发明授权

US06787498B2 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten 有权
标题翻译：铬，钼或钨的单环戊二烯基络合物
公开(公告)号：US06787498B2
公开(公告)日：2004-09-07
申请号：US10166140
申请日：2002-06-11
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： B01J3100
CPC分类号： B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/60 , B01J2531/62 , C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63925 , C08F4/6392 , C08F2500/03 , C08F2500/04 , C08F2500/17 , C08F2500/10
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl and heterocyclopentadienyl complexes of chromium, molybdenum or tungsten in which at least one of the substituents on the cyclopentadienyl ring carries a donor function which is bonded rigidly, not exclusively via sp3-hybridized carbon or silicon atoms, and a process for the polymerization of olefins.
摘要翻译：铬，钼或钨的取代的单环戊二烯基，单茚基，单芴基和杂环戊二烯基络合物，其中至少一个环戊二烯基环上的取代基具有刚性键合的供体功能，不排他地通过sp 3杂化的碳或硅原子，和烯烃聚合方法。

8. 发明授权

US06699948B2 Monocyclopentadienyl complexes of chromium, molybdenum or tungsten 有权
公开(公告)号：US06699948B2
公开(公告)日：2004-03-02
申请号：US10166130
申请日：2002-06-11
申请人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
发明人： Shahram Mihan , Dieter Lilge , Paulus de Lange , Günther Schweier , Martin Schneider , Ursula Rief , Udo Handrich , Johannes Hack , Markus Enders , Gunter Ludwig , Ralph Rudolph
IPC分类号： C08F469
CPC分类号： B01J31/143 , B01J31/2295 , B01J2231/12 , B01J2531/60 , B01J2531/62 , C07F17/00 , C08F4/63908 , C08F4/63912 , C08F4/63916 , C08F10/00 , C08F10/02 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/03 , C08F2420/01 , Y10S526/943 , C08F4/63925 , C08F4/6392 , C08F2500/03 , C08F2500/04 , C08F2500/17 , C08F2500/10
摘要： Substituted monocyclopentadienyl, monoindenyl, monofluorenyl and heterocyclopentadienyl complexes of chromium, molybdenum or tungsten in which at least one of the substituents on the cyclopentadienyl ring carries a donor function which is bonded rigidly, not exclusively via sp3-hybridized carbon or silicon atoms, and a process for the polymerization of olefins.

9. 发明申请

US20070264171A1 Apparatus for the Gas-Phase Polymerization of Olefins,in Particular Ethylene 有权
标题翻译：用于烯烃气相聚合的装置，特别是乙烯
公开(公告)号：US20070264171A1
公开(公告)日：2007-11-15
申请号：US11667349
申请日：2005-11-09
申请人： Eberhard Herrmann , Axel Sperber , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
发明人： Eberhard Herrmann , Axel Sperber , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
IPC分类号： C08F2/34
CPC分类号： B01J8/1872 , B01J8/0055 , B01J8/24 , B01J2208/00256 , B01J2208/00274 , B04C5/081 , C08F6/02 , C08F10/00 , C08F10/02 , C08F110/02 , C08L23/04 , C08F2/34
摘要： An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tube (5) extending essentially axially symmetrically down into the upper section and, if appropriate, the middle section for discharging the recycle gas which has been freed of the particles. According to the invention the ratio Hi of the distance hi from the lower end of the tube (5) extending downward into the cyclone to the intersection (6) of an imaginary extension of the wall of the downward-extending tube (5) with the wall of the middle section (3b) to the diameter di of the downward-extending tube (5) is from 3 to 8, in particular from 4 to 7.
摘要翻译：用于烯烃聚合的装置，特别是乙烯，包括气相流化床反应器（1），连接到反应器的再循环气体管线（2），用于排出和再循环包含未聚合烯烃的循环气流和旋流器（3），其位于循环气体管线中，用于还原和沉淀夹带在来自反应器的再循环气体中的固体颗粒，旋风分离器包括具有基本上垂直的中心轴线的上部分（3a），其上壁延伸沿着旋转对称体并且设置有相对于中心轴线偏心布置的旋风入口（4），邻近上部（3a）并且其壁沿旋转对称体延伸的中间部分（3b）用于排出邻近中间部分（3b）并且其壁延伸的再循环气体沉淀的固体颗粒的下部分（3c）旋转对称体和基本上轴向对称地延伸到上部的管（5）以及适当的中间部分用于排出已经没有颗粒的循环气体。根据本发明，与从下游进入旋风分离器的管（5）的下端距离h i i的距离h i i的比例H i 向下延伸的管（5）的壁与中间部分（3b）的壁与向下延伸的管（5）的直径d iI i的假想延伸为3至 8，特别是4到7。

10. 发明申请

US20080014128A1 Apparatus and Process for the Gas-Phase Polymerization of Olefins 有权
标题翻译：用于烯烃气相聚合的装置和方法
公开(公告)号：US20080014128A1
公开(公告)日：2008-01-17
申请号：US11667417
申请日：2005-11-08
申请人： Eberhard Herrmann , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
发明人： Eberhard Herrmann , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
IPC分类号： C08F10/00 , B01J19/18
CPC分类号： B01J8/003 , B01J8/006 , B01J8/1872 , B01J2208/00256 , B01J2208/00274 , B01J2208/00761 , C08F10/00 , C08F110/02 , C08F2/34
摘要： Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8). The inlet chamber (4) has a dividing wall (10) which is arranged essentially parallel to the filter medium (9) and separates the inlet chamber (4) into an inflow region (4a), which is connected to the gas inlet (6), and a filter region (4b) in which the filter medium is located and has an upper opening and a lower opening which are dimensioned so that from 60 to 90% of the volume flow flows through the upper opening so that flow along the filter medium (9) from the top downward results.
摘要翻译：用于烯烃聚合的设备，特别是乙烯，包括气相流化床反应器（1），用于从反应器（1）连续或不连续地获取聚合物颗粒的出口管线（15），该管线（15））连接到用于分离聚合物颗粒和气体的减压容器（2），用于释放连接到减压容器（2）的夹带的细颗粒的气体的循环气体过滤器（3），压缩已经被释放细颗粒并将其再循环到反应器（1）中，循环气体过滤器（3）具有设置有气体入口（6）的入口室（4），设置有气体出口的出口室（5） 7），用于保持将入口室（4）与出口室（5）分离的细颗粒和颗粒出口（8）的基本垂直的片状过滤介质（9）。入口室（4）具有基本上与过滤介质（9）平行布置的分隔壁（10），并将入口室（4）分离成入口区域（4a），该入口区域连接到气体入口 6）和过滤器区域（4b），其中过滤介质位于并具有上开口和下开口，其尺寸使得体积流量的60％至90％流过上开口，使得沿着过滤介质（9）从顶部向下的结果。

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