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1. 发明授权

US07125933B2 Very low density polyethylene blends 有权
标题翻译：极低密度聚乙烯共混物
公开(公告)号：US07125933B2
公开(公告)日：2006-10-24
申请号：US10297777
申请日：2001-06-22
申请人： Paul Masten German , James McLeod Farley , Richard W. Halle , George Panagopoulos
发明人： Paul Masten German , James McLeod Farley , Richard W. Halle , George Panagopoulos
IPC分类号： C08L23/00 , C08L23/04
CPC分类号： C08L23/04 , B32B27/322 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2314/06 , Y10T428/31938 , C08L2666/06
摘要： Blends of very low density polyethylene produced using metallocene catalysts (mVLDPE) and linear low density polyethylene (LLDPE) are disclosed. The polymer blends include a metallocene-catalyzed VLDPE polymer having a density of less than 0.916 g/cm3, the VLDPE polymer preferably being linear and without long chain branching, and a LLDPE polymer having a density of from 0.916 to 0.940 g/cm3. The polymer blends are particularly suitable in blown and cast film applications.
摘要翻译：公开了使用金属茂催化剂（mVLDPE）和线性低密度聚乙烯（LLDPE）生产的非常低密度聚乙烯的共混物。聚合物共混物包括密度小于0.916g / cm 3的金属茂催化的VLDPE聚合物，VLDPE聚合物优选是直链的且不具有长链支化，密度为0.916-0.940g / cm3的LLDPE聚合物。聚合物共混物特别适用于吹塑和流延膜应用。

2. 发明授权

US06932592B2 Metallocene-produced very low density polyethylenes 有权
标题翻译：茂金属生产的非常低密度的聚乙烯
公开(公告)号：US06932592B2
公开(公告)日：2005-08-23
申请号：US10311114
申请日：2001-06-22
申请人： James M. Farley , Richard W. Halle , George Panagopoulos , Jerry M. Johnson , Douglas J. Laurent , Alan M. Malakoff
发明人： James M. Farley , Richard W. Halle , George Panagopoulos , Jerry M. Johnson , Douglas J. Laurent , Alan M. Malakoff
IPC分类号： C08L23/08 , H01B1/00 , B23B27/32
CPC分类号： C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/06 , Y10S526/943 , Y10T428/31692 , Y10T428/31899 , Y10T428/31909 , C08L2666/06
摘要： A very low density polyethylene having a density of 0.890 to 0.915 and a Dart Drop value of at least about 450 g/mil or above is disclosed. Gas phase polymerization methods are also disclosed for making very low density linear polyolefins utilizing a metallocene catalyst, and the resulting polyolefin products. In a specific embodiment, a gas phase polymerization process is disclosed relating to the formation of a linear polyethylene having a very low density, e.g., ranging from 0.890 to 0.915, but with improved toughness.
摘要翻译：公开了一种密度为0.890至0.915，Dart Drop值至少约450g / mil或更高的极低密度聚乙烯。还公开了气相聚合方法，用于制备使用茂金属催化剂的非常低密度的直链聚烯烃，以及得到的聚烯烃产物。在一个具体实施方案中，公开了一种气相聚合方法，其涉及形成具有非常低的密度，例如0.890至0.915，但具有改善的韧性的线性聚乙烯。

3. 发明授权

US07135526B2 Very low density polyethylene and high density polyethylene blends 有权
标题翻译：极低密度聚乙烯和高密度聚乙烯共混物
公开(公告)号：US07135526B2
公开(公告)日：2006-11-14
申请号：US10297900
申请日：2001-06-22
申请人： James M. Farley , Richard W. Halle , George Panagopoulos , Jerry M. Johnson
发明人： James M. Farley , Richard W. Halle , George Panagopoulos , Jerry M. Johnson
IPC分类号： C08L23/00 , C08L23/04
CPC分类号： C08L23/06 , C08L23/0815 , C08L2314/06 , C08L2666/06
摘要： Blends of very low density polyethylene produced using metallocene catalysts (mVLDPE) and high density polyethylene (HDPE) are disclosed. The polymer blends include a metallocene-catalyzed VLDPE polymer having a density of less than 0.916 g/cm3, the VLDPE polymer preferably being linear and without long chain branching, and a HDPE polymer having a density of greater than 0.940 g/cm3. The polymer blends are particularly suitable in blown and cast film applications.
摘要翻译：公开了使用金属茂催化剂（mVLDPE）和高密度聚乙烯（HDPE）制备的非常低密度聚乙烯的共混物。聚合物共混物包括密度小于0.916g / cm 3的金属茂催化的VLDPE聚合物，VLDPE聚合物优选是直链的且不具有长链支化，和密度为更大的HDPE聚合物大于0.940g / cm 3。聚合物共混物特别适用于吹塑和流延膜应用。

4. 发明授权

US5500260A Dispersible film 失效
标题翻译：分散膜
公开(公告)号：US5500260A
公开(公告)日：1996-03-19
申请号：US261550
申请日：1994-06-17
申请人： Richard W. Halle , Dirk J. Michiels , Jeffrey A. Middlesworth
发明人： Richard W. Halle , Dirk J. Michiels , Jeffrey A. Middlesworth
IPC分类号： C08L23/08 , C08L23/22 , B32B27/32 , C08L23/16
CPC分类号： C08L23/0815 , C08L2205/02 , C08L23/0853 , Y10T428/1352 , Y10T428/31913
摘要： Bales of unvulcanized rubber, or compounding ingredients for unvulcanized rubber are packaged in film or bags made from an ethylene .alpha.-olefin copolymer having a Vicat softening point below 90.degree. C. and a melting point below 100.degree. C., and optionally a second ethylene copolymer is added to improve processability of the first ethylene copolymer. The second ethylene copolymer will contain more long-chain branches than the first ethylene copolymer. Such films may be included in a rubber compounding operation.
摘要翻译：未硫化橡胶的组合或未硫化橡胶的配混成分包装在由维卡软化点低于90℃和熔点低于100℃的乙烯α-烯烃共聚物制成的膜或袋中，以及任选的第二乙烯加入共聚物以改善第一乙烯共聚物的加工性能。第二乙烯共聚物将含有比第一乙烯共聚物更多的长链分支。这种膜可以包括在橡胶配混操作中。

5. 发明授权

US5376439A Soft films having enhanced physical properties 失效
标题翻译：软膜具有增强的物理性能
公开(公告)号：US5376439A
公开(公告)日：1994-12-27
申请号：US219754
申请日：1994-03-29
申请人： William J. Hodgson , Richard W. Halle , Charles L. Pierce
发明人： William J. Hodgson , Richard W. Halle , Charles L. Pierce
IPC分类号： B29C47/88 , B29K23/00 , B29L7/00 , B32B27/32 , C08J5/18 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/18
CPC分类号： C08J5/18 , B32B27/322 , C08L23/0815 , C08J2323/04 , C08L23/06 , Y10S526/943 , Y10T428/31913
摘要： The present invention provides for a polymer composition comprising a blend of from about 25 to about 90% by weight of a very low density ethylene polymer having a density on the range of from about 0.88 to 0.925 g/cm.sup.3, a melt index of from about 0.5 to about 7.5 dg/min, a molecular weight distribution not greater than about 3.5 and a compositional distribution breadth index greater than about 70%, and from about 10 to about 75% by weight of a low to medium density ethylene polymer having a density of from about 0.910 to about 0.935, a melt index of from about 0.5 to about 20, a molecular weight distribution greater than about 3.5 and a compositional breadth index less than about 70%.The invention also provides for films prepared from this blend having single layer construction or having laminar ABA construction wherein the A or skin layers comprise the blend of this invention and the B or core layer comprises a different olefin polymer such as high density polyethylene.Films of this invention exhibit excellent elongation, tensile and impact properties and also softness, feel and noise properties which render them eminently suitable for use as back sheet components in the fabrication of absorbent articles such as diapers, bed pads and like articles where such properties are desirable.
摘要翻译：本发明提供一种聚合物组合物，其包含约25至约90重量％的密度为约0.88至0.925g / cm 3的非常低密度乙烯聚合物的共混物，熔体指数为约 0.5至约7.5dg / min，分子量分布不大于约3.5，组成分布宽度指数大于约70％，约10至约75重量％的具有密度的低至中密度乙烯聚合物约0.910至约0.935，熔体指数为约0.5至约20，分子量分布大于约3.5，组分宽度指数小于约70％。本发明还提供由具有单层结构或具有层状ABA结构的该共混物制备的膜，其中A或表层包含本发明的共混物，B或芯层包含不同的烯烃聚合物，例如高密度聚乙烯。本发明的薄膜表现出优异的伸长率，拉伸和冲击性能以及柔软度，手感和噪音性能，使其非常适合用作制造吸收制品如尿布，床垫和类似物品的背板组件，合意。

6. 发明申请

US20130266786A1 Polymers, Polymer Blends, and Articles Made Therefrom 审中-公开
标题翻译：聚合物，聚合物共混物及其制品
公开(公告)号：US20130266786A1
公开(公告)日：2013-10-10
申请号：US13796491
申请日：2013-03-12
申请人： Alan M. Malakoff , Richard W. Halle , Adriana S. Silva , Steve A. Best
发明人： Alan M. Malakoff , Richard W. Halle , Adriana S. Silva , Steve A. Best
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2203/16 , C08L2314/06
摘要： Polymer compositions including an ethylene-based polymer having a melt index of from about 0.1 g/10 min to about 5.0 g/10 min; a melt index ratio of from about 15 to about 30; a weight average molecular weight (Mw) of from about 20,000 to about 200,000; a molecular weight distribution (Mw/Mn) of from about 2.0 to about 4.5; and a density of from 0.900 to 0.920 g/cm3. Films having a thickness of 1 mil show a difference between the maximum seal strength and the minimum seal strength over the ranges of temperatures between 95.0° C. and 140.0° C. of ≦1.00×102 grams/cm.
摘要翻译：包括熔体指数为约0.1g / 10min至约5.0g / 10min的基于乙烯的聚合物的聚合物组合物; 熔体指数比为约15至约30; 重均分子量（Mw）为约20,000至约200,000; 分子量分布（Mw / Mn）为约2.0至约4.5; 密度为0.900〜0.920g / cm3。厚度为1密耳的膜在@ 1.00×102克/厘米2的温度范围为95.0℃至140.0℃之间显示最大密封强度和最小密封强度之间的差异。

7. 发明授权

US5462807A Heat sealable films and articles 失效
标题翻译：热封膜和制品
公开(公告)号：US5462807A
公开(公告)日：1995-10-31
申请号：US110179
申请日：1993-08-20
申请人： Richard W. Halle , Donna S. Davis , Charles R. Harris, Jr.
发明人： Richard W. Halle , Donna S. Davis , Charles R. Harris, Jr.
IPC分类号： B32B27/32 , B32B27/08 , C08F4/642 , C08F4/6592 , C08F10/00 , C08L23/08 , C09J123/08 , B32B27/00
CPC分类号： B32B27/08 , C08L23/0815 , C08L23/0876 , Y10S428/913 , Y10T428/1352 , Y10T428/24843 , Y10T428/2826 , Y10T428/31504 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938
摘要： The invention concerns a certain class of polymers, their production into films and applications for their use. These polymers have unique properties which make them particularly well suited for use in polymeric films. These films are very useful in applications requiring heat sealability, particularly those applications containing an ionomer film.It has been discovered that polymers derived from metallocene catalyst systems surprisingly heat seal extremely well, as compared to polymer produced by conventional Ziegler-Natta catalysts, to a class of polymers known as ionomers.
摘要翻译：本发明涉及一类聚合物，它们的生产成膜和应用。这些聚合物具有独特的性质，使得它们特别适用于聚合物膜。这些膜在需要热封性的应用中是非常有用的，特别是那些包含离聚物膜的应用。已经发现，与由常规齐格勒 - 纳塔催化剂生产的聚合物相比，衍生自茂金属催化剂体系的聚合物与称为离聚物的一类聚合物相比，令人惊奇地热密封地热密封。

8. 发明授权

US5415905A Dispersible film 失效
标题翻译：分散膜
公开(公告)号：US5415905A
公开(公告)日：1995-05-16
申请号：US128927
申请日：1993-09-29
申请人： Jeffrey A. Middlesworth , Richard W. Halle , Dirk J. Michiels
发明人： Jeffrey A. Middlesworth , Richard W. Halle , Dirk J. Michiels
IPC分类号： C08L23/08 , C08L23/22 , B32B27/32 , C08L23/16
CPC分类号： C08L23/0815 , C08L2205/02 , C08L23/0853 , Y10T428/1352 , Y10T428/31913
摘要： Bales of unvulcanized rubber, or compounding ingredients for unvulcanized rubber are packaged in film or bags made from an ethylene .alpha.-olefin copolymer having a Vicat softening point below 90.degree. C. end a melting point below 100.degree. C., and optionally a second ethylene copolymer is added to improve processability of the first ethylene copolymer. The second ethylene copolymer will contain more long-chain branches than the first ethylene copolymer. Such films may be included in a rubber compounding operation.
摘要翻译：将未硫化橡胶的组合或未硫化橡胶的配混成分包装在由维卡软化点低于90℃的乙烯α-烯烃共聚物制成的膜或袋中，结束熔点低于100℃，并且任选地含有第二乙烯加入共聚物以改善第一乙烯共聚物的加工性能。第二乙烯共聚物将含有比第一乙烯共聚物更多的长链分支。这种膜可以包括在橡胶配混操作中。

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