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    • 1. 发明授权
    • Adhesion promoters for thiolene adhesive formulations
    • 硫醇粘合剂配方的粘合促进剂
    • US5028661A
    • 1991-07-02
    • US443046
    • 1989-11-27
    • Paul J. ClarkAnthony F. JacobineDavid M. Glaser
    • Paul J. ClarkAnthony F. JacobineDavid M. Glaser
    • C08G75/04
    • C08G75/045
    • Compounds useful as adhesion promoters for thermally cured thiolene adhesives include a) acrylic or norbornene acid phosphate esters such as ##STR1## b) maleic, acrylic, methacrylic, norbornene dicarboxylic, and fumaric acids and half acid esters and peresters of maleic fumaric and norbornene dicarboxylic acids; and c) norbornene, acrylic or methacrylic silanes having two or three hydrolyzable groups bound to the silicon atom thereof, such as 5-(triacetoxysilyl) norbornene.The adhesion promoters may be employed as surface primers for conventional thiolene compositions. Alternatively the thiolene compositions themselves may be modified by addition of 0.1 to 10% by weight of the adhesion promoter. Preferred thiolene compositions employ norbornene functional ene ingredients.
    • 可用作热固化硫醇粘合剂的粘合促进剂的化合物包括:a)丙烯酸或降冰片烯酸性磷酸酯,例如马来酸,丙烯酸,甲基丙烯酸,降冰片烯二羧酸和富马酸,马来酸的半酸酯和过酸酯 富马酸和降冰片烯二羧酸; 和c)具有两个或三个与其硅原子结合的可水解基团的降冰片烯,丙烯酸或甲基丙烯酸硅烷如5-(三乙酰氧基甲硅烷基)降冰片烯。 粘合促进剂可用作常规硫羟组合物的表面引物。 或者,硫醇组合物本身可以通过加入0.1至10重量%的粘合促进剂来改性。 优选的硫醇组合物使用降冰片烯功能烯成分。
    • 3. 发明授权
    • Lock bracket
    • 锁定支架
    • US5544505A
    • 1996-08-13
    • US325389
    • 1994-11-28
    • John D. McIntoshPaul J. Clark
    • John D. McIntoshPaul J. Clark
    • E05B67/38E05B73/00
    • E05B67/383Y10T70/40Y10T70/409Y10T70/493
    • A lock bracket comprises two bracket members which cooperate to define an area between them to secure together two adjacent objects. The bracket members are movable relative to each other between an open orientation, in which the lock bracket can be placed around or removed from the two adjacent objects and a closed orientation in which the two adjacent objects can be held securely in the area defined between the two bracket members. Each of the two bracket members has a padlock receiving area and the two padlock receiving areas cooperate when the lock bracket is in its closed orientation.
    • PCT No.PCT / AU93 / 00179 Sec。 371日期:1994年11月28日 102(e)日期1994年11月28日PCT 1993年4月28日PCT公布。 公开号WO93 / 22534 日期1993年11月11日锁定支架包括两个支架构件,这两个支架构件协作以在它们之间限定一个区域以将两个相邻物体固定在一起。 托架构件可以在打开的取向之间相对于彼此移动,在该取向中,锁定支架可以放置在两个相邻物体周围或从两个相邻的物体上移除,并且闭合取向,其中两个相邻物体可以牢固地保持在 两个支架成员。 两个支架构件中的每一个具有挂锁接收区域,并且当锁定支架处于其闭合取向时,两个挂锁接收区域协作。
    • 5. 发明授权
    • Modular roof covering system
    • 模块化屋面覆盖系统
    • US06606823B1
    • 2003-08-19
    • US10101320
    • 2002-03-20
    • William McDonoughMichael BraungartPaul J. Clark
    • William McDonoughMichael BraungartPaul J. Clark
    • A01G902
    • E04D11/002A01G9/033H02S20/24H02S20/32Y02A30/254Y02B10/12Y02B80/32
    • The present invention is a modular roof covering made up of a plurality of interlocking modular trays having moisture or water absorbing component or medium in the tray to absorb moisture and allow it to evaporate or otherwise dissipate over time. The trays interlock with each other and are held down by weights or other ballast to secure the trays to the roof without having to create a physical connection between the trays and the roof structure. The modular roof covering can be made up of different types of tray assemblies, where some have vegetation growing in the tray, others have merely water absorption and dissipation capability, while others have photovoltaic cells for the collection and use of solar energy. The present invention provides a light weight, low cost roof covering system for extending the life of current roof structures, and to restore and protect the environment, moderate and aid in controlling building temperature, manage stormwater runoff and collect and utilize solar energy.
    • 本发明是一种由多个互锁模块化托盘组成的模块化屋顶覆盖物,其在托盘中具有水分或吸水组分或介质以吸收水分并使其随时间蒸发或以其它方式消散。 托盘彼此互锁,并通过重物或其他压载物固定,以将托盘固定到屋顶,而不必在托盘和屋顶结构之间形成物理连接。 模块化屋顶覆盖物可以由不同类型的托盘组件组成,其中一些具有植物生长在托盘中,其他只具有吸水和消散能力,而其它托盘组件具有用于收集和使用太阳能的光伏电池。 本发明提供了一种重量轻,价格低廉的屋顶覆盖系统,用于延长当前屋顶结构的使用寿命,并恢复和保护环境,缓和并有助于控制建筑温度,管理雨水径流和收集和利用太阳能。
    • 7. 发明授权
    • Adhesive compositions comprising maleic acid peroxy compounds as
adhesive promoters
    • 包含马来酸过氧化合物作为粘合促进剂的粘合剂组合物
    • US4916184A
    • 1990-04-10
    • US356167
    • 1989-05-24
    • Paul J. Clark
    • Paul J. Clark
    • C08F4/32C08G75/04
    • C08G75/045
    • An adhesive composition comprising a component which is polymerizable or cross-linkable with a peroxy initator, e.g., a (meth)acrylic ester monomer, thiolene resin, or tough acrylic copolymer, and an initiator of the formula: ##STR1## wherein: R.sub.1 is H or lower alkyl; and R.sub.2 is H or --OR.sub.3, where R.sub.3 is H or lower alkyl.An appertaining method of bonding substrates, and bonded articles formed thereby, are also disclosed. The adhesive composition of the invention is particularly advantageous in bonding of metal substrates, on which the maleic acid peroxy compounds of the invention produce surface bonding enhancement of the adhesive composition, relative to the use of conventional polymerization/crosslinking peroxy initiators such as t-butyl perbenzoate.
    • 一种粘合剂组合物,其包含可与过氧引发剂例如(甲基)丙烯酸酯单体,硫羟树脂或韧性丙烯酸共聚物可聚合或可交联的组分和下式的引发剂:其中:R1是 H或低级烷基; 并且R 2是H或-OR 3,其中R 3是H或低级烷基。 还公开了一种接合基板的方法和由此形成的接合制品。 本发明的粘合剂组合物相对于常规的聚合/交联过氧化引发剂如叔丁基酯的使用,特别有利于粘合本发明马来酸过氧化合物的粘合剂组合物的表面粘结增强的金属基材的粘合 过苯甲酸盐。