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    • 3. 发明授权
    • Multilayer materials
    • 多层材料
    • US06923978B2
    • 2005-08-02
    • US10368693
    • 2003-02-19
    • Ronald Christopher ChatelierLiming DaiHans Jörg GriesserSheng LiPaul ZientekDieter LohmannPeter Chabrecek
    • Ronald Christopher ChatelierLiming DaiHans Jörg GriesserSheng LiPaul ZientekDieter LohmannPeter Chabrecek
    • A61L27/00A61L27/34C08L101/16G02B1/04G02C7/04A61F2/00C08F8/00
    • G02B1/043A61L27/34C08L5/00
    • The invention is directed to a composite material, especially a biomedical device, e.g. an ophthalmic device, preferably a contact lens, with one or more wettable surfaces capable of holding a continuous layer of aqueous fluid thereon which composite material comprises a bulk material and a hydrophilic coating characterized in that the hydrophilic coating consists of a carbohydrate attached covalently to reactive groups at the surface of the bulk material, either directly or via functional groups of an oligofunctional compound, said oligofunctional compound in turn having functional groups being capable of reacting with said reactive groups at the surface of the bulk material and with the carbohydrate, wherein said reactive groups are either inherently (a priori) present in the bulk material or wherein said reactive groups have been attached to the surface of the bulk material by a plasma surface preparation, as well as to a process of manufacture of such a composite material.
    • 本发明涉及复合材料,特别是生物医学装置,例如, 眼科装置,优选隐形眼镜,具有能够在其上容纳水性流体的连续层的一个或多个可润湿表面,所述复合材料包括本体材料和亲水涂层,其特征在于,所述亲水性涂层由共价连接到反应性的碳水化合物 在本体材料表面的基团,直接地或通过低官能化合物的官能团,所述低官能化合物又具有能够与本体材料的表面与碳水化合物的所述反应性基团反应的官能团,其中所述 反应性基团本质上(先验地)存在于本体材料中,或者其中所述反应性基团已经通过等离子体表面制备被附着到散装材料的表面,以及制造这种复合材料的方法。
    • 5. 发明授权
    • Coating process
    • 涂层工艺
    • US06582754B1
    • 2003-06-24
    • US09697861
    • 2000-10-27
    • Paul PasicHans Jörg GriesserPeter KambourisPeter Chabrecek
    • Paul PasicHans Jörg GriesserPeter KambourisPeter Chabrecek
    • B05D138
    • B82Y30/00A61L27/34B05D1/185B05D7/00B82Y40/00C08J7/16G02B1/043
    • The invention relates to a process for coating a material surface, comprising the steps of: (a) covalently binding a compound comprising an ethylenically unsaturated double bond to the material surface; (b) polymerizing a monomer comprising a reactive or crosslinkable group on the surface and thereby providing a primary polymer coating comprising reactive or crosslinkable groups, (c) in case of a monomer comprising a reactive group in step (b) reacting the reactive groups of the primary coating with a further compound comprising an ethylenically unsaturated double bond and graft-polymerizing a hydrophilic monomer and optionally a co-monomer having a crosslinkable group onto the primary coating obtained according to step (b) and (d) in case of crosslinkable groups being present in step (b) or (c) initiating crosslinking of said groups. The coated articles that are obtainable by the process of the invention have desirable characteristics regarding adherence to the substrate, durability, hydrophilicity, wettability, biocompatibility and permeability and are thus useful for the manufacture of biomedical articles such as ophthalmic devices.
    • 本发明涉及一种用于涂覆材料表面的方法,包括以下步骤:(a)将包含烯键式不饱和双键的化合物共价结合到所述材料表面;(b)在表面上聚合包含反应性或可交联基团的单体 从而提供包含反应性或可交联基团的初级聚合物涂层,(c)在步骤(b)中包含反应性基团的单体的情况下,使初级涂层的反应性基团与包含烯属不饱和双键的另外的化合物和接枝 在步骤(b)或(c)中存在可交联基团的情况下,将亲水性单体和任选的具有可交联基团的共聚单体聚合到根据步骤(b)和(d)获得的初级涂层上,引发所述 团体 通过本发明的方法可获得的涂覆制品具有关于对基材的粘附性,耐久性,亲水性,润湿性,生物相容性和渗透性的所需特性,因此可用于制造生物医学制品如眼科装置。