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1. 发明授权

US4748140A In situ activation process for fluid bed oxidation catalysts 失效
标题翻译：流化床氧化催化剂的原位活化方法
公开(公告)号：US4748140A
公开(公告)日：1988-05-31
申请号：US685437
申请日：1984-12-24
申请人： Patricia R. Blum , Ernest C. Milberger , Mark L. Nicholas , Patricia A. Zock
发明人： Patricia R. Blum , Ernest C. Milberger , Mark L. Nicholas , Patricia A. Zock
IPC分类号： B01J27/198 , B01J37/16 , C07C51/215
CPC分类号： C07C51/215 , B01J23/002 , B01J27/198 , B01J37/16 , B01J2523/00
摘要： A process for activating fluid bed catalysts useful for producing maleic anhydride from 4 carbon atom hydrocarbons is provided including contacting the fluidized catalyst containing the mixed oxides of vanadium and phosphorus with oxygen and a reducing gas at least partially combustible with oxygen at elevated temperatures sufficient to cause such combustion, wherein the molar ratio of reducing gas to oxygen is greater than the stoichiometric ratio required for complete combustion of the reducing gas. Also provided are catalysts activated by the process of the invention, as well as a process for producing maleic anhydride utilizing the catalysts thus activated.
摘要翻译：提供一种活化用于从4个碳原子烃生产马来酸酐的流化床催化剂的方法，包括使含有钒和磷的混合氧化物的流化催化剂与氧气和至少部分可氧化的还原气体接触，所述还原气体在足以导致这种燃烧，其中还原气体与氧气的摩尔比大于完全燃烧还原气体所需的化学计量比。还提供了通过本发明的方法活化的催化剂，以及利用如此活化的催化剂生产马来酸酐的方法。

2. 发明授权

US4647673A Maleic anhydride process 失效
标题翻译：马来酸酐工艺
公开(公告)号：US4647673A
公开(公告)日：1987-03-03
申请号：US733441
申请日：1985-05-13
申请人： Noel J. Bremer , Dennis E. Dria , Ernest C. Milberger , Patricia R. Blum , Mark L. Nicholas
发明人： Noel J. Bremer , Dennis E. Dria , Ernest C. Milberger , Patricia R. Blum , Mark L. Nicholas
IPC分类号： B01J27/198 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： C07C51/215 , B01J23/002 , B01J27/198 , C07C51/25 , C07C51/252 , B01J2523/00
摘要： A process is provided for the preparation of attrition resistant, microspheroidal fluid bed catalysts comprising the mixed oxides of vanadium and phosphorus in which a vanadium phosphorus mixed oxided catalyst precursor is densified, comminuted, formed into fluidizable particles and calcined under fluidization-type conditions. The present invention further provides the attrition resistant fluidizable catalysts prepared by the inventive process, and further provides a process for utilizing such attrition resistant catalysts in the production of maleic anhydride in the vapor phase by the oxidation of 4 carbon atom hydrocarbons.
摘要翻译：提供了一种制备耐磨耗的微球形流化床催化剂的方法，其包含钒和磷的混合氧化物，其中钒磷混合氧化催化剂前体致密化，粉碎，形成可流化颗粒并在流化型条件下煅烧。本发明还提供了通过本发明方法制备的耐磨性可流化催化剂，并且还提供了通过氧化4个碳原子烃在气相中生产马来酸酐时利用这种耐磨催化剂的方法。

3. 发明授权

US4518523A Method for adding make-up fluid bed oxidation catalysts for fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus 失效
标题翻译：添加含有钒和磷的混合氧化物的流化床氧化催化剂的补充流化床氧化催化剂的方法
公开(公告)号：US4518523A
公开(公告)日：1985-05-21
申请号：US472400
申请日：1983-03-04
申请人： Patricia R. Blum , Ernest C. Milberger , Mark L. Nicholas
发明人： Patricia R. Blum , Ernest C. Milberger , Mark L. Nicholas
IPC分类号： C07C51/215 , B01J27/14
CPC分类号： C07C51/215
摘要： A process is provided for activating fluidizable catalysts containing the mixed oxides of vanadium and phosphorus useful for the production of maleic anhydride from 4-carbon atom hydrocarbons and oxygen by subjecting the catalyst to fluidization conditions and contacting the fluidized catalyst with oxygen at a temperature at least 20.degree. C. greater than the temperature required to produce about 85 percent conversion of hydrocarbon. A process is also provided for adding make-up fluid bed catalyst to an equilibrated catalyst by introducing a calcined and unequilibrated make-up catalyst into the fluid bed vessel containing equilibrated catalyst, subjecting the mixture to fluidization conditions and contacting the fluidized catalyst mixture with oxygen at a temperature at least 20.degree. C. greater than the temperature required to produce about 85 percent conversion of the hydrocarbon. The catalysts so activated and a process for producing maleic anhydride from 4-carbon atom hydrocarbons is also provided.
摘要翻译：提供了一种用于激活含有钒和磷的混合氧化物的可流化催化剂的方法，其可用于从4-碳原子烃和氧生产马来酸酐，所述方法是使催化剂经过流化条件并使流化催化剂与氧在至少温度下接触大于产生约85％碳氢化合物转化所需的温度。还提供了一种方法，用于通过将煅烧和未平衡的补充催化剂引入含有平衡的催化剂的流化床容器中，将混合物进入流化条件并使流化催化剂混合物与氧接触而将补充流化床催化剂添加到平衡的催化剂中在比产生约85％烃转化所需的温度高至少20℃的温度下进行。还提供了如此活化的催化剂和由4-碳原子烃生产马来酸酐的方法。

4. 发明授权

US4525471A Attrition resistant microspheroidal fluid bed catalysts containing the mixed oxides of vanadium and phosphorus 失效
标题翻译：含有钒和磷的混合氧化物的耐磨微滴流化床催化剂
公开(公告)号：US4525471A
公开(公告)日：1985-06-25
申请号：US594959
申请日：1984-04-02
申请人： Noel J. Bremer , Dennis E. Dria , Ernest C. Milberger , Patricia R. Blum , Mark L. Nicholas
发明人： Noel J. Bremer , Dennis E. Dria , Ernest C. Milberger , Patricia R. Blum , Mark L. Nicholas
IPC分类号： C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , C07C51/215 , C07C51/25
摘要： A process is provided for the preparation of attrition resistant, microspheroidal fluid bed catalysts comprising the mixed oxides of vanadium and phosphorus in which a vanadium phosphorus mixed oxided catalyst precursor is densified, comminuted, formed into fluidizable particles and calcined under fluidization-type conditions. The present invention further provides the attrition resistant fluidizable catalysts prepared by the inventive process, and further provides a process for utilizing such attrition resistant catalysts in the production of maleic anhydride in the vapor phase by the oxidation of 4 carbon atom hydrocarbons.
摘要翻译：提供了一种制备耐磨耗的微球形流化床催化剂的方法，其包含钒和磷的混合氧化物，其中钒磷混合氧化催化剂前体致密化，粉碎，形成可流化的颗粒并在流化型条件下煅烧。本发明还提供了通过本发明方法制备的耐磨性可流化催化剂，并且还提供了通过氧化4个碳原子烃在气相中生产马来酸酐时利用这种耐磨催化剂的方法。

5. 发明授权

US4429137A Preparation of maleic anhydride 失效
标题翻译：马来酸酐的制备
公开(公告)号：US4429137A
公开(公告)日：1984-01-31
申请号：US388857
申请日：1982-06-16
申请人： Patricia R. Blum , Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
发明人： Patricia R. Blum , Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
IPC分类号： B01J23/22 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： C07C51/25 , B01J23/22 , C07C51/215 , C07C51/252
摘要： The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into a liquid medium, a mixed phosphorus component comprising orthophosphoric acid and pyrophosphoric acid is added to the liquid medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the mixed phosphorus component, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
摘要翻译：本发明提供了一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的，或气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。将钒化合物引入液体介质中，将包含正磷酸和焦磷酸的混合磷组分加入到液体介质中，将至少一部分钒还原至+4价态在或之前或之后进行回收混合磷成分的添加物和得到的钒 - 磷氧化物催化剂前体，干燥并煅烧。

6. 发明授权

US4410752A Process for the oxydehydrogenation of ethane to ethylene 失效
标题翻译：将乙烷氧化脱氢成乙烯的方法
公开(公告)号：US4410752A
公开(公告)日：1983-10-18
申请号：US346029
申请日：1982-02-05
申请人： Patricia R. Blum , Ernest C. Milberger
发明人： Patricia R. Blum , Ernest C. Milberger
IPC分类号： B01J27/198 , C07C5/48 , C07C5/38
CPC分类号： B01J23/002 , B01J27/198 , C07C5/48 , B01J2523/00 , Y02P20/52
摘要： The invention herein is directed toward a process for the oxydehydrogenation of ethane in fixed-bed or fluid-bed reactors at temperatures of less than about 600.degree. C. The process includes the step of contacting ethane and an oxygen-containing gas with a catalyst composition having the formula V.sub.1.0 P.sub.a O.sub.x. The catalyst can be employed in supported or unsupported form. A promoter metal can optionally be present in the catalyst.
摘要翻译：本发明涉及一种在固定床或流化床反应器中在小于约600℃的温度下乙烷氧化脱氢的方法。该方法包括使乙烷和含氧气体与催化剂组合物接触的步骤具有公式V1.0PaOx。催化剂可以以负载或非负载形式使用。助催化剂金属可任选地存在于催化剂中。

7. 发明授权

US4361501A Preparation of vanadium phosphorus catalysts using a mixed phosphorus source 失效
标题翻译：使用混合磷源制备钒磷催化剂
公开(公告)号：US4361501A
公开(公告)日：1982-11-30
申请号：US220629
申请日：1980-12-29
申请人： Patricia R. Blum , Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
发明人： Patricia R. Blum , Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
IPC分类号： C07D307/60 , B01J23/22 , B01J27/18 , B01J27/198 , C01B25/37 , C01B25/45 , C07B61/00 , C07C51/215 , C07C51/25 , B01J27/14
CPC分类号： C07C51/252 , B01J23/002 , B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , B01J2523/00
摘要： The present invention provides a process for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. A vanadium compound is introduced into a liquid medium, a mixed phosphorus component comprising orthophosphoric acid and pyrophosphoric acid is added to the liquid medium, reduction of at least a portion of the vanadium to a +4 valence state is effected either prior to or subsequent to the addition of the mixed phosphorus component, and the resulting vanadium-phosphorus oxide catalyst precursor is recovered, dried and calcined.
摘要翻译：本发明提供了一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的，或气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。将钒化合物引入液体介质中，将包含正磷酸和焦磷酸的混合磷组分加入到液体介质中，将至少一部分钒还原至+4价态在或之前或之后进行回收混合磷成分的添加物和得到的钒 - 磷氧化物催化剂前体，干燥并煅烧。

8. 发明授权

US4350639A Preparation of maleic anhydride 失效
标题翻译：马来酸酐的制备
公开(公告)号：US4350639A
公开(公告)日：1982-09-21
申请号：US258712
申请日：1981-04-29
申请人： Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
发明人： Ernest C. Milberger , Noel J. Bremer , Dennis E. Dria
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07D307/60
CPC分类号： C07C51/215 , B01J23/002 , B01J23/22 , B01J27/198 , B01J2523/00
摘要： The present invention provides improved oxidation catalysts containing mixed oxides of vanadium and phosphorus and the method for the preparation thereof, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce excellent yields of maleic anhydride with very good selectivity. At least one vanadium compound, a substantial portion of which is in the pentavalent state, and at least one phosphorus-containing compound is added to an organic liquid medium capable of reducing at least a portion of the vanadium to a +4 valence state, to form a reaction mixture. Partial reduction of the vanadium is effected in the presence of the phosphorus-containing compound and a highly ordered and uniform mixed vanadium phosphorus oxide-containing catalyst precursor is formed.
摘要翻译：本发明提供了含有钒和磷的混合氧化物的改进的氧化催化剂及其制备方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子的混合物中的氧化中特别有效氧气或含氧气体，以非常好的选择性产生优异的马来酸酐产率。将至少一种钒化合物（其大部分为五价态）和至少一种含磷化合物加入到能够将至少一部分钒还原成+4价态的有机液体介质中，至形成反应混合物。在含磷化合物的存在下进行钒的部分还原，形成高度均匀的混合的含氧化钒的催化剂前体。

9. 发明授权

US4250054A Catalysts for producing unsaturated aliphatic acids 失效
标题翻译：用于生产不饱和脂肪酸的催化剂
公开(公告)号：US4250054A
公开(公告)日：1981-02-10
申请号：US691691
申请日：1976-06-01
申请人： Wilfrid G. Shaw , Ernest C. Milberger , Serge R. Dolhyj
发明人： Wilfrid G. Shaw , Ernest C. Milberger , Serge R. Dolhyj
IPC分类号： B01J23/28 , B01J23/30 , B01J23/32 , B01J23/34 , B01J23/36 , B01J23/68 , B01J23/88 , B01J23/887 , B01J23/888 , B01J23/89 , B01J27/199 , C07C51/25 , B01J23/10 , B01J23/22 , B01J27/18
CPC分类号： B01J23/8878 , B01J23/002 , B01J23/28 , B01J23/30 , B01J23/32 , B01J23/34 , B01J23/36 , B01J23/68 , B01J23/887 , B01J23/8885 , B01J23/8993 , B01J27/199 , C07C51/25 , C07C51/252 , B01J2523/00
摘要： The present invention relates to a process for the production of unsaturated aliphatic acids and the catalyst therefor, by the vapor phase oxidation of the corresponding unsaturated aliphatic aldehydes with molecular oxygen, optionally in the presence of steam, in the presence of an oxidation catalyst consisting of the oxides of the elements molybdenum, vanadium, tungsten and lanthanum, and optionally one or more of the oxides of the elements manganese, iron, copper, aluminum, cobalt, nickel, phosphorus, zinc, bismuth, silver, cadmium, niobium, arsenic, chromium, the alkali and the alkaline earth elements.
摘要翻译：本发明涉及一种制备不饱和脂族酸及其催化剂的方法，通过相应的不饱和脂族醛与分子氧的气相氧化，任选地在蒸汽存在下，在氧化催化剂的存在下，在由元素钼，钒，钨和镧的氧化物，以及锰，铁，铜，铝，钴，镍，磷，锌，铋，银，镉，铌，砷，铬，碱和碱土元素。

10. 发明授权

US4400522A Preparation of maleic anhydride 失效
标题翻译：马来酸酐的制备
公开(公告)号：US4400522A
公开(公告)日：1983-08-23
申请号：US374219
申请日：1982-05-03
申请人： Michael F. Lemanski , Gregory G. Spitnale , Ernest C. Milberger
发明人： Michael F. Lemanski , Gregory G. Spitnale , Ernest C. Milberger
IPC分类号： B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , C07D307/60
CPC分类号： B01J23/002 , B01J23/22 , B01J27/198 , C07C51/215 , C07C51/25 , C07C51/252 , B01J2523/00
摘要： The present invention provides a method for the preparation of oxidation catalysts containing mixed oxides of vanadium and phosphorus, which catalysts are particularly effective in the oxidation of n-butane, n-butenes, 1,3-butadiene or a mixture thereof with molecular oxygen or an oxygen-containing gas in the vapor phase to produce high yields of maleic anhydride with good selectivity. Vanadium phosphorus mixed oxide catalyst precursors prepared in solution in organic media are extracted from the organic media with water, with subsequent drying down to recover a precursor solid, or impregnation of a support with the aqueous solution.
摘要翻译：本发明提供一种制备含有钒和磷的混合氧化物的氧化催化剂的方法，该催化剂在正丁烷，正丁烯，1,3-丁二烯或其与分子氧或其混合物的氧化中是特别有效的气相中的含氧气体，以产生高产率的马来酸酐，具有良好的选择性。在有机介质溶液中制备的钒磷混合氧化物催化剂前体用水从有机介质中萃取，随后干燥以回收前体固体，或用水溶液浸渍载体。

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